DK2337452T3 - Kombinationer af derivatiserede saccharidsurfaktanter og etheraminoxidsurfaktanter som herbicidadjuvanter - Google Patents
Kombinationer af derivatiserede saccharidsurfaktanter og etheraminoxidsurfaktanter som herbicidadjuvanter Download PDFInfo
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- DK2337452T3 DK2337452T3 DK09774287.8T DK09774287T DK2337452T3 DK 2337452 T3 DK2337452 T3 DK 2337452T3 DK 09774287 T DK09774287 T DK 09774287T DK 2337452 T3 DK2337452 T3 DK 2337452T3
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- surfactant
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- glyphosate
- linear
- independently
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- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 229940046947 oleth-10 phosphate Drugs 0.000 description 1
- 229940095127 oleth-20 Drugs 0.000 description 1
- 231100000418 oral toxicity Toxicity 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 230000000885 phytotoxic effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- FVEFRICMTUKAML-UHFFFAOYSA-M sodium tetradecyl sulfate Chemical class [Na+].CCCCC(CC)CCC(CC(C)C)OS([O-])(=O)=O FVEFRICMTUKAML-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 229940086735 succinate Drugs 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- 150000003866 tertiary ammonium salts Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Claims (19)
1. Sammensætning omfattende glyphosat eller et salt eller ester deraf, en derivatiseret saccharidsurfaktant og en aminoxidsurfaktant med en gruppe svarende til formlen R1-(XR2)m.(OR3)n-Z- forbundet med aminoxidgruppen via en carbon-nitrogen-binding, hvor R1 er en hydrocarbylgruppe omfattende fra 6 til 22 carbonatomer, R2 og R3 uafhængigt er udvalgt fra alkylengrupper omfattende fra 2 til 4 carbonatomer, Z er en carbon-nitrogen-binding eller en oxyhydrocarbylengruppe omfattende fra 2 til 6 carbonatomer, hvert X uafhængigt er en ether-, thioether-, sulfoxid-, ester-, thioester- eller amidforbindelse, m er et gennemsnitstal fra 0 til 9, n er et gennemsnitstal fra 0 til 5, og m+n > 1, hvor vægtforholdet mellem den derivatiserede saccharidsurfaktant og aminoxidsurfaktanten er større end 1:1.
2. Sammensætning ifølge krav 2 omfattende en aminoxidsurfaktant med en oxyalkylen- eller polyoxyalkylengruppe bundet til aminoxidgruppen via en nitrogen-carbon-binding, hvor oxyalkylen- eller polyoxyalkylengruppen ved en terminus væk fra nitrogen-carbon-bindingen er capped med en hydrocarbylgruppe via en etherforbindelse.
3. Sammensætning ifølge krav 1 eller 2, hvor aminoxidet omfatter en surfak-tant med formlen:
hvor R1 er C1-22 hydrocarbyl med lineær eller forgrenet kæde, hvert X uafhængigt er en ether-, thioether-, sulfoxid-, ester-, thioester- eller amidforbindelse, hvert R2 uafhængigt er C2-6 alkylen, hvert R3 uafhængigt er C2-4 alky-len, hvert R4 uafhængigt er C2-4 alkylen, og R5 samt R6 uafhængigt er hydrogen, C1-4 alkyl eller C2-4 acyl; x og y er gennemsnitstal, således at summen af x og y er fra 2 til 60, m er fra 0 til 9, og n er fra 0 til 5.
4. Sammensætning ifølge krav 3, hvor R1 er Cs-is alkyl med lineær eller forgrenet kæde, aryl eller alkaryl, og m er 0.
5. Sammensætning ifølge krav 4, hvor R1 er Ce-ie alkyl med lineær eller forgrenet kæde, R3 er ethyl, n-propyl eller i-propyl, n er fra 1 til 3, R4 er ethylen, summen af x og y er fra 2 til 20, og R5 samt R6 er hydrogen.
6. Sammensætning ifølge et af kravene 1 til 5, hvor det derivatiserede sac-charid omfatter en surfaktant med formlen:
hvor: R11 er C4-22 hydrocarbyl med lineær eller forgrenet kæde; sug er en åben eller cyklisk saccharidrest udvalgt fra gruppen bestående af ribose, xylose, arabinose, glucose, galactose, mannose, telose, gulose, allo- se, altrose, idose, lyxose, ribulose, sorbose (sorbitan) og fructose, sug er et disaccharid udvalgt fra maltose, lactose og sakkarose, eller sug er et disaccharid, oligosaccharid eller polysaccharid udvalgt fra to eller flere identiske saccharider eller to eller flere forskellige saccharider udvalgt fra gruppen bestående af ribose, xylose, arabinose, glucose, galactose, mannose, telose, gulose, allose, altrose, idose, lyxose, ribulose, sorbose (sorbitan) og fructose; og u er et gennemsnitstal fra 1 til 10.
7. Sammensætning ifølge krav 6, hvor R11 er Ce-ie alkyl med lineær eller forgrenet kæde, sug er et glucosid, og u er et gennemsnitstal fra 1 til 5.
8. Sammensætning ifølge et af kravene 1 til 7, hvor vægtforholdet mellem den derivatiserede saccharidsurfaktant og aminoxidsurfaktanten er fra 2:1 til 10:1.
9. Sammensætning ifølge et af kravene 1 til 8, hvor herbicidet omfatter et salt af glyphosat udvalgt fra mono(isopropylamin)-, trimethylsulfonium-, mono-ethanolammonium-, monoammonium-, diammonium-, natrium- og kaliumsalt.
10. Sammensætning ifølge krav 9, hvor saltet er kaliumsaltet.
11. Sammensætning ifølge krav 9 eller krav 10, hvor sammensætningen er et vandigt koncentrat, hvor glyphosatkoncentrationen er fra 300 til 600 gram syreækvivalent per liter.
12. Sammensætning ifølge krav 9 eller krav 10, hvor sammensætningen er en vandig påført blanding, hvor glyphosatkoncentrationen er fra 1 til 20 gram syreækvivalent per liter.
13. Sammensætning ifølge krav 9, hvor glyphosatet er i form af ammonium-, diammonium- eller natriumsalt deraf, og sammensætningen er et fast koncentrat, hvor glyphosatkoncentrationen er fra 20 til 90 vægtprocent syreækvivalent.
14. Sammensætning ifølge et af kravene 9 til 13, hvor vægtforholdet mellem glyphosatsyreækvivalenten og den samlede surfaktant er fra 2:1 til 10:1.
15. Sammensætning ifølge krav 8, hvor vægtforholdet mellem glyphosatsyreækvivalenten og den samlede surfaktant er fra 2:1 til 5:1.
16. Sammensætning ifølge et af kravene 9 til 15, hvor vægtforholdet mellem den derivatiserede saccharidsurfaktant og aminoxidsurfaktanten er fra 2:1 til 8:1.
17. Sammensætning ifølge krav 16, hvor vægtforholdet mellem den derivatiserede saccharidsurfaktant og aminoxidsurfaktanten er fra 2:1 til 6:1.
18. Sammensætning ifølge krav 17, hvor vægtforholdet mellem glyphosatsyreækvivalenten og den samlede surfaktant er fra 2:1 til 5:1.
19. Fremgangsmåde til kontrahering af plantevæksten, hvilken fremgangsmåde omfatter påføringen af sammensætningen ifølge et af kravene 1 til 18 på planten.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7811308P | 2008-07-03 | 2008-07-03 | |
| PCT/US2009/049170 WO2010002836A2 (en) | 2008-07-03 | 2009-06-30 | Combinations of derivatized saccharide surfactants and etheramine oxide surfactants as herbicide adjuvants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2337452T3 true DK2337452T3 (da) | 2014-12-15 |
Family
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| DK09774287.8T DK2337452T3 (da) | 2008-07-03 | 2009-06-30 | Kombinationer af derivatiserede saccharidsurfaktanter og etheraminoxidsurfaktanter som herbicidadjuvanter |
Country Status (13)
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| US (2) | US8536095B2 (da) |
| EP (2) | EP2337452B1 (da) |
| CN (2) | CN104872125B (da) |
| AR (2) | AR072434A1 (da) |
| AU (1) | AU2009267127B2 (da) |
| BR (1) | BRPI0915368B1 (da) |
| CA (1) | CA2729738C (da) |
| DK (1) | DK2337452T3 (da) |
| ES (2) | ES2526651T3 (da) |
| LT (1) | LT2939538T (da) |
| MX (2) | MX356148B (da) |
| PL (2) | PL2939538T3 (da) |
| WO (1) | WO2010002836A2 (da) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
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| PL1722634T3 (pl) | 2004-03-10 | 2011-12-30 | Monsanto Technology Llc | Kompozycje herbicydowe zawierające N-fosfonometyloglicynę i herbicyd auksynowy |
| US8410022B2 (en) | 2004-08-19 | 2013-04-02 | Monsanto Technology Llc | Glyphosate salt herbicidal composition |
| CA2608206C (en) | 2005-05-24 | 2015-11-24 | Monsanto Technology Llc | Herbicide compatibility improvement |
| DK2337452T3 (da) * | 2008-07-03 | 2014-12-15 | Monsanto Technology Llc | Kombinationer af derivatiserede saccharidsurfaktanter og etheraminoxidsurfaktanter som herbicidadjuvanter |
| US20120142532A1 (en) | 2009-08-10 | 2012-06-07 | Monsanto Technology Llc | Low volatility auxin herbicide formulations |
| AU2012328638B2 (en) | 2011-10-26 | 2016-11-17 | Monsanto Technology Llc | Salts of carboxylic acid herbicides |
| EP2809232B1 (en) * | 2012-01-30 | 2016-10-12 | Sensoria Inc. | Sensors, interfaces and sensor systems for data collection and integrated remote monitoring of conditions at or near body surfaces |
| UY34845A (es) * | 2012-06-04 | 2014-01-31 | Monsanto Technology Llc | ?composiciones herbicidas concentradas acuosas que contienen sales de glifosato y sales de dicamba |
| CA3123572A1 (en) | 2013-02-27 | 2014-09-04 | Monsanto Technology Llc | Glyphosate composition for dicamba tank mixtures with improved volatility |
| BR112015022797A2 (pt) * | 2013-03-13 | 2017-11-07 | Monsanto Technology Llc | método para controle de ervas daninhas, composição herbicida, cassete de expressão microbiano e método de produção de polinucleotídeo |
| EP3454658B1 (en) | 2016-05-11 | 2024-11-27 | Monsanto Technology LLC | Glyphosate formulations containing amidoalkylamine surfactants |
| US10433544B2 (en) * | 2017-03-29 | 2019-10-08 | University Of Kentucky Research Foundation | Herbicide |
| CN110123839B (zh) * | 2018-02-02 | 2021-02-19 | 上海睿泰生物科技股份有限公司 | 负载光敏药物的人多能干细胞外泌体及制备与用途 |
| US20220304300A1 (en) * | 2018-12-21 | 2022-09-29 | Battelle Uk Limited | Agrochemical composition |
| CN112471170B (zh) * | 2020-11-27 | 2021-09-07 | 湖北泰盛化工有限公司 | 一种草甘膦异丙胺盐水剂助剂 |
Family Cites Families (175)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3505377A (en) | 1966-08-12 | 1970-04-07 | Union Carbide Corp | Siloxane-oxyalkylene copolymer foam stabilizers |
| US3799758A (en) | 1971-08-09 | 1974-03-26 | Monsanto Co | N-phosphonomethyl-glycine phytotoxicant compositions |
| US3853530A (en) | 1971-03-10 | 1974-12-10 | Monsanto Co | Regulating plants with n-phosphonomethylglycine and derivatives thereof |
| US3977860A (en) | 1971-08-09 | 1976-08-31 | Monsanto Company | Herbicidal compositions and methods employing esters of N-phosphonomethylglycine |
| US4405531A (en) | 1975-11-10 | 1983-09-20 | Monsanto Company | Salts of N-phosphonomethylglycine |
| US4140513A (en) | 1978-01-03 | 1979-02-20 | Monsanto Company | Sodium sesquiglyphosate |
| DE2946520A1 (de) | 1979-11-17 | 1981-06-11 | Bedmor Beteiligungs- und Verwaltungsgesellschaft mbH, 2980 Norden | Integrierte flotations-filtrations-anlage |
| US4315765A (en) | 1980-12-04 | 1982-02-16 | Stauffer Chemical Company | Trialkylsulfonium salts of n-phosphonomethylglycine and their use as plant growth regulators and herbicides |
| US4481026A (en) | 1982-11-16 | 1984-11-06 | Stauffer Chemical Company | Aluminum N-phosphonomethylglycine and its use as a herbicide |
| IL68716A (en) | 1983-05-17 | 1987-03-31 | Geshuri Lab Ltd | Process for producing n-phosphonomethylglycine |
| US4931080A (en) | 1985-05-29 | 1990-06-05 | Chan Jimmy H | Solid, phytoactive compositions, methods of use and methods of preparation |
| US5580841A (en) | 1985-05-29 | 1996-12-03 | Zeneca Limited | Solid, phytoactive compositions and method for their preparation |
| BR8605102A (pt) | 1985-10-21 | 1987-07-21 | Stauffer Chemical Co | Composicao fitoativa liquida e composicao herbicida liquida |
| US5468718A (en) | 1985-10-21 | 1995-11-21 | Ici Americas Inc. | Liquid, phytoactive compositions and method for their preparation |
| DE3545908A1 (de) | 1985-12-23 | 1987-06-25 | Henkel Kgaa | Verwendung von langkettigen ethern in pflanzenschutzmitteln |
| KR900701793A (ko) | 1988-05-23 | 1990-12-04 | 제임스 제이. 플린 | 제초제 옥사비사이클로알칸 에테르 |
| AU3756889A (en) | 1988-06-01 | 1990-01-05 | The Texas A & M University System | Method for transforming plants via the shoot apex |
| NZ230875A (en) | 1988-10-13 | 1991-02-26 | Ici Australia Operations | Herbicidal composition comprising n-phosphonomethylglycine and an alkyl glucoside |
| EP0473890A1 (en) | 1990-08-28 | 1992-03-11 | American Cyanamid Company | Aqueous herbicidal compositions of 2-(2-imidazolin-2-yl)-pyridines and quinolines |
| DE4029304A1 (de) | 1990-09-15 | 1992-03-19 | Hoechst Ag | Synergistische herbizide mittel |
| US5308827A (en) | 1990-11-28 | 1994-05-03 | Fumakilla Limited | Herbicidal foam composition |
| ES2033569B1 (es) | 1990-12-31 | 1993-12-16 | En E Ind Aragonesas | Composiciones concentradas herbicidas, procedimiento para su obtencion y su empleo. |
| AU650091B2 (en) | 1991-02-08 | 1994-06-09 | Monsanto Europe S.A. | Glyphosate compositions and their use |
| EP0498145B1 (en) | 1991-02-08 | 1995-11-15 | Monsanto Europe S.A./N.V. | Solid glyphosate compositions and their use |
| US5258359A (en) | 1991-08-02 | 1993-11-02 | Monsanto Company | Glyphosant-containing herbicidal compositions comprising acetylenic diol rainfastness enhancing agents |
| JPH05201815A (ja) | 1991-08-02 | 1993-08-10 | Monsanto Co | 除草剤組成物、その製造方法およびその使用方法 |
| US5266553A (en) | 1991-10-21 | 1993-11-30 | Riverdale Chemical Company | Method of manufacturing a dry water-soluble herbicidal salt composition |
| GB9125115D0 (en) | 1991-11-23 | 1992-01-22 | Ciba Geigy Ag | Corrosion and/or scale inhibition |
| EP0577914A1 (en) | 1992-07-08 | 1994-01-12 | Monsanto Europe S.A./N.V. | Improved glyphosate compositions and their use |
| MY111437A (en) | 1992-07-31 | 2000-05-31 | Monsanto Co | Improved glyphosate herbicide formulation. |
| GB9225075D0 (en) | 1992-12-01 | 1993-01-20 | Ici Plc | Low foam polyglycoside formulations |
| DK169734B1 (da) | 1993-03-09 | 1995-01-30 | Kvk Agro As | Herbicidpræparat, fremgangsmåde til fremstilling heraf samt aktiverende additiv til opblanding med herbicidpræparater |
| US5504054A (en) | 1993-03-30 | 1996-04-02 | Osi Specialties, Inc. | Super-spreading, low-foam surfactant for agricultural spray mixtures |
| AU7043794A (en) | 1993-05-28 | 1994-12-20 | Crop Genetics International Corporation | A new bacterial toxin for use as a plant growth regulator and herbicide |
| US5356861A (en) | 1993-11-19 | 1994-10-18 | Cenex/Land O'lakes Agronomy Company | Homogenous herbicidal adjuvant blend comprising glyphosate, ammonium sulfate, and alkyl polysaccharide |
| ES2161747T3 (es) | 1993-11-24 | 2001-12-16 | Rhodia Chimie Sa | Procedimiento de preparacion de poliimidas o de sus hidrolizados polipeptidicos biodegradables. |
| AU2380595A (en) | 1994-04-15 | 1995-11-10 | Henkel Corporation | Biologically active composition |
| GB9412722D0 (en) | 1994-06-24 | 1994-08-17 | Zeneca Ltd | Herbicidal composition |
| WO1996008150A1 (en) | 1994-09-15 | 1996-03-21 | Akzo Nobel N.V. | Aqueous pesticidal microemulsion compositions |
| US5514641A (en) | 1994-11-04 | 1996-05-07 | Zeneca Limited | Solid herbicidal compositions containing N-phosphonomethylglycine |
| AUPN029994A0 (en) | 1994-12-23 | 1995-01-27 | Ici Australia Operations Proprietary Limited | Alkypolysaccharide derivatives & compositions |
| US5543383A (en) | 1994-12-30 | 1996-08-06 | Hampshire Chemical Corp. | Herbicidal compositions comprising solutions of glyphosate and polyurea and/or polyurethane |
| US5843866A (en) | 1994-12-30 | 1998-12-01 | Hampshire Chemical Corp. | Pesticidal compositions comprising solutions of polyurea and/or polyurethane |
| US5698210A (en) | 1995-03-17 | 1997-12-16 | Lee County Mosquito Control District | Controlled delivery compositions and processes for treating organisms in a column of water or on land |
| NZ305278A (en) | 1995-04-10 | 1999-02-25 | Monsanto Co | Herbicidal compositions comprising glyphosate and an etheramine surfactant |
| US5750468A (en) | 1995-04-10 | 1998-05-12 | Monsanto Company | Glyphosate formulations containing etheramine surfactants |
| SE506265C2 (sv) | 1995-04-28 | 1997-11-24 | Akzo Nobel Nv | Vattenhaltig komposition innehållande en alkylglykosid och användning därav som vätmedel |
| MY114016A (en) | 1995-06-27 | 2002-07-31 | Kao Corp | Liquid enhancer composition for amino acid series herbicides |
| CN1915016B (zh) | 1995-11-08 | 2010-12-22 | 默沙东公司 | 农药制剂 |
| GB9526441D0 (en) | 1995-12-22 | 1996-02-21 | Zeneca Ltd | Herbicidal composition |
| US5917117A (en) | 1996-03-21 | 1999-06-29 | Phytotech, Inc. | Inducing hyperaccumulation of metals in plant shoots |
| US20020165115A1 (en) | 1996-04-16 | 2002-11-07 | Judith Daniels | Non-ionic surfactant compositions |
| PY970104A (es) | 1996-08-30 | 2001-12-03 | Monsanto Co | Nuevos fluidos solubles en agua para trabajar metales |
| BR9713191A (pt) | 1996-09-03 | 1999-11-03 | Novartis Ag | Composições agroquìmicas |
| US5770543A (en) | 1996-09-06 | 1998-06-23 | Henkel Corporation | Agricultural compositions comprising alkyl polyglycosides and fatty acids |
| EP0929222B1 (en) | 1996-10-07 | 2002-05-15 | Syngenta Limited | Glyphosate formulations |
| AUPO405696A0 (en) | 1996-12-06 | 1997-01-09 | Ici Australia Operations Proprietary Limited | Herbicidal compositions |
| US5906961A (en) | 1997-05-29 | 1999-05-25 | Helena Chemical Company | Alkanolamide spreader-sticker surfactant combination |
| US5928563A (en) | 1997-06-20 | 1999-07-27 | Henkel Corporation | Agricultural adjuvant |
| US6068849A (en) | 1997-07-14 | 2000-05-30 | Henkel Corporation | Surfactants for use in agricultural formulations |
| DE19735790A1 (de) | 1997-08-18 | 1999-02-25 | Henkel Kgaa | Mikroemulsionen |
| GB9718139D0 (en) | 1997-08-27 | 1997-10-29 | Zeneca Ltd | Agrochemical Formulation |
| JP4669608B2 (ja) | 1998-02-13 | 2011-04-13 | モンサント テクノロジー エルエルシー | 外因性化学物質およびシロキサン界面活性剤を含有する貯蔵安定性組成物 |
| BR9908696B1 (pt) | 1998-03-09 | 2011-05-31 | composição herbicida e método de controle de ervas daninhas em um campo. | |
| ATE226012T1 (de) | 1998-03-20 | 2002-11-15 | Dow Agrosciences Llc | Pestizide hilfsmittel |
| GB9808304D0 (en) | 1998-04-20 | 1998-06-17 | Zeneca Ltd | Improvements in or relating to organic compounds |
| US20010019996A1 (en) | 1998-04-24 | 2001-09-06 | Gerard G. Soula | Process and compositions promoting biological effectiveness of exogenous chemical substances in plants |
| US5985648A (en) | 1998-05-29 | 1999-11-16 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Natural Resources | Fusarium avenaceum and its use as biological control agent for rubus species |
| US6855327B1 (en) | 1998-07-02 | 2005-02-15 | Cognis Corporation | Pesticide dispersant |
| EP1112347A4 (en) | 1998-09-09 | 2004-09-29 | Northwest Plant Breeding Co | METHOD FOR THE PRODUCTION OF DOUBLE HAPLOID PLANTS |
| GB9819693D0 (en) | 1998-09-10 | 1998-11-04 | Zeneca Ltd | Glyphosate formulation |
| EP1002535A1 (en) | 1998-10-28 | 2000-05-24 | Hrissanthi Ikonomidou | New use of glutamate antagonists for the treatment of cancer |
| CA2349333A1 (en) | 1998-12-18 | 2000-06-22 | Du Pont Pharmaceuticals Company | Vitronectin receptor antagonist pharmaceuticals |
| US6569402B1 (en) | 1998-12-18 | 2003-05-27 | Bristol-Myers Squibb Pharma Company | Vitronectin receptor antagonist pharmaceuticals |
| US6432878B1 (en) | 1999-01-15 | 2002-08-13 | Cognis Corporation | Adjuvant composition |
| US6383984B1 (en) | 1999-01-29 | 2002-05-07 | Basf Aktiengesellschaft | Aqueous suspension concentrate |
| GB9904012D0 (en) | 1999-02-22 | 1999-04-14 | Zeneca Ltd | Agrochemical formulation |
| EP1179982B1 (en) | 1999-03-11 | 2003-10-01 | Ecoval Corporation | Herbicidal composition |
| GB9907669D0 (en) | 1999-04-01 | 1999-05-26 | Zeneca Ltd | Agrochemical composition |
| US6593299B1 (en) | 1999-04-21 | 2003-07-15 | University Of Florida Research Foundation, Inc. | Compositions and methods for controlling pests |
| IT1312111B1 (it) | 1999-05-18 | 2002-04-04 | Lamberti Spa | Miscele tensioattive atte all'uso come bagnanti ed emulsionati incomposizioni agrochimiche |
| US6774087B1 (en) | 1999-06-22 | 2004-08-10 | Fmc Corporation | Liquid herbicide composition |
| FR2795726A1 (fr) | 1999-06-30 | 2001-01-05 | Aventis Cropscience Sa | Nouveaux pyrazoles fongicides |
| EP1064844A1 (en) | 1999-06-30 | 2001-01-03 | Dow Corning Corporation | Surfactant blends containing organosilicone surfactants and diphenyl oxide sulfonate surfactants useful as agricultural adjuvants |
| US6395693B1 (en) | 1999-09-27 | 2002-05-28 | Cabot Microelectronics Corporation | Cleaning solution for semiconductor surfaces following chemical-mechanical polishing |
| FR2800092A1 (fr) | 1999-10-21 | 2001-04-27 | Centre Nat Rech Scient | Gene chimere codant pour un facteur de transcription myb30 et expression dans les plantes |
| WO2001035740A2 (de) | 1999-11-17 | 2001-05-25 | Bayer Aktiengesellschaft | Selektive herbizide auf basis von 2,6-disubstituierten pyridin-derivaten |
| DE19958381A1 (de) | 1999-12-03 | 2001-06-07 | Bayer Ag | Herbizide auf Basis von N-Aryl-uracilen |
| CN100425701C (zh) | 1999-12-16 | 2008-10-15 | 孟山都技术有限公司 | 新型植物表达构建物 |
| US20010034304A1 (en) | 2000-01-21 | 2001-10-25 | Greg Volgas | Manufacture and use of an deposition aid |
| US20020053097A1 (en) | 2000-03-20 | 2002-05-02 | Susan Lindquist | Transgenic plants containing heat shock protein |
| NZ509436A (en) | 2000-03-24 | 2002-05-31 | Goldschmidt Ag Th | Siloxane-containing oil compositions with good spreading properties |
| FR2807756A1 (fr) | 2000-04-13 | 2001-10-19 | Rhobio | Polypeptides pla2 de plantes impliques dans la reaction de defense des plantes, polynucleotides codant ces polypeptides et plantes transformees les contenant |
| US20010051591A1 (en) | 2000-04-13 | 2001-12-13 | Ferrett Richard E. | Safening crops from the phytotoxic effects of herbicidally active N-phosphonomethyl-glycines |
| DE10022990A1 (de) | 2000-05-11 | 2001-11-22 | Aventis Cropscience Gmbh | Kombination von Pflanzenschutzmitteln mit Wasserstoffbrücken bildenden Polymeren |
| US20050054532A1 (en) | 2000-05-11 | 2005-03-10 | Jean Kocur | Combination of crop protection agents with hydrogen bond-forming polymers |
| US6992045B2 (en) * | 2000-05-19 | 2006-01-31 | Monsanto Technology Llc | Pesticide compositions containing oxalic acid |
| US7135437B2 (en) * | 2000-05-19 | 2006-11-14 | Monsanto Technology Llc | Stable liquid pesticide compositions |
| JP2004503513A (ja) | 2000-06-12 | 2004-02-05 | 呉羽化学工業株式会社 | マイクロカプセル懸濁液およびその方法 |
| SE522195C2 (sv) | 2000-06-15 | 2004-01-20 | Akzo Nobel Nv | Användning av aminföreningar med förbättrad bionedbrytbarhet som effektförhöjande hjälpkemikalier för pesticider och gödningsmedel |
| FR2811514B1 (fr) | 2000-07-11 | 2003-01-24 | Seppic Sa | Composition herbicide comprenant du glyphosate et au moins un alkyl polyxyloside |
| US6541424B2 (en) | 2000-08-07 | 2003-04-01 | Helena Chemical Company | Manufacture and use of a herbicide formulation |
| DE10041393A1 (de) | 2000-08-23 | 2002-03-07 | Stockhausen Chem Fab Gmbh | Wasser-in-Öl-Polymerdispersionen mit verbesserter Umweltverträglichkeit |
| GB0023912D0 (en) | 2000-09-29 | 2000-11-15 | Zeneca Ltd | Agrochemical Composition |
| EP1333721B1 (en) | 2000-10-17 | 2006-04-26 | Victorian Chemical International Pty. Ltd. | Herbicide composition |
| DE10052489A1 (de) | 2000-10-23 | 2002-05-02 | Hermania Dr Schirm Gmbh | Feste Glyphosat-Formulierung und Verfahren zur Herstellung |
| DE10052588A1 (de) | 2000-10-24 | 2002-05-02 | Cognis Deutschland Gmbh | Pestizidhaltige wäßrige Mittel |
| AUPR183200A0 (en) | 2000-12-01 | 2001-01-04 | Huntsman Corporation Australia Pty Ltd | Herbicidal compositions |
| US6831038B2 (en) | 2001-02-20 | 2004-12-14 | Helena Holding Company | Agricultural formulation |
| DE10112104A1 (de) | 2001-03-14 | 2002-09-26 | Bayer Ag | Herbizide auf Basis von substituierten Arylketonen |
| CN1288974C (zh) * | 2001-05-21 | 2006-12-13 | 孟山都技术公司 | 含有醚胺表面活性剂的农药浓缩物 |
| FR2826593B1 (fr) | 2001-06-27 | 2004-04-16 | Rhodia Chimie Sa | Dispersion comprenant une emulsion dont la phase aqueuse est de force ionique elevee, preparation et utilisation |
| DE10142334A1 (de) | 2001-08-30 | 2003-03-20 | Bayer Cropscience Ag | Herbizide auf Basis von substituierten Arylketonen |
| DE10142333A1 (de) | 2001-08-30 | 2003-03-20 | Bayer Cropscience Ag | Herbizide Mischungen auf Basis von substituierten Arylketonen |
| IL145236A0 (en) | 2001-09-03 | 2002-06-30 | Agro Vant Ltd | Multi-layer adjuvants for controlled delivery of agro-materials into plant tissue |
| US6746988B2 (en) | 2001-09-07 | 2004-06-08 | Syngenta Crop Protection, Inc. | Surfactant systems for agriculturally active compounds |
| DE10146591A1 (de) | 2001-09-21 | 2003-04-10 | Bayer Cropscience Ag | Herbizide auf Basis von substituierten Thien-3-yl-sulfonylamino(thio)carbonyl-triazolin(thi)onen |
| AU2002364783A1 (en) | 2001-11-21 | 2003-06-10 | Affinium Pharmaceuticals, Inc. | Purified polypeptides involved in general metabolism |
| US6734141B2 (en) | 2001-11-21 | 2004-05-11 | Goldschmidt Ag | Use of non-spreading silicone surfactants in agrochemical compositions |
| DE10159659A1 (de) | 2001-12-05 | 2003-06-26 | Bayer Cropscience Ag | Herbizide auf Basis von substituierten Carbonsäureaniliden |
| US20030158042A1 (en) | 2002-01-29 | 2003-08-21 | Valerio Bramati | Concentrated aqueous phytopathological formulation comprising a herbicide and a betaine type surfactant |
| EP1471984A2 (fr) | 2002-02-06 | 2004-11-03 | Rhodia Chimie | Utilisation d un melange solvant / substance antimousse dans des formulations aqueuses et formulations |
| GB0204482D0 (en) | 2002-02-26 | 2002-04-10 | Syngenta Ltd | Glyphosate formulation |
| US6797673B1 (en) | 2002-05-01 | 2004-09-28 | Platte Chemical Company | Lecithin-containing drift reduction composition for use in spraying agricultural acreage |
| AU2003229178A1 (en) | 2002-05-13 | 2003-11-11 | Ceres Environmental Solution Industry Incorporated | Urea based natural herbicide compositions |
| WO2003094616A1 (en) | 2002-05-13 | 2003-11-20 | Nicca Chemical Co., Ltd. | Antibacterial |
| EP1366662B1 (en) | 2002-05-31 | 2006-07-12 | Kao Corporation | Enhancer for agricultural chemicals |
| US20040077498A1 (en) | 2002-07-01 | 2004-04-22 | Lynch John F. | Agricultural seed having protective coatings |
| AU2003281148A1 (en) | 2002-07-12 | 2004-02-02 | Bayer Cropscience Ag | Liquid adjuvants |
| US20040058821A1 (en) | 2002-07-16 | 2004-03-25 | Mickey Brigance | Ionically balanced polyacrylamide composition |
| DE10232780A1 (de) | 2002-07-18 | 2004-02-12 | Basf Ag | Co-Tenside auf Basis von Aldehyden |
| EP2292095A2 (en) * | 2002-08-31 | 2011-03-09 | Monsanto Technology LLC | Pesticide compositions containing a dicarboxylic acid or derivative thereof |
| WO2004019684A2 (en) * | 2002-08-31 | 2004-03-11 | Monsanto Technology Llc | Process for the preparation of a dry pesticidal composition containing a dicarbodylate component |
| US20060194699A1 (en) | 2003-01-10 | 2006-08-31 | Moucharafieh Nadim C | Sprayable non-aqueous, oil-continuous microemulsions and methods of making same |
| US8138120B2 (en) | 2003-03-11 | 2012-03-20 | Cognis Ip Management Gmbh | Microemulsions as adjuvants for agricultural chemicals |
| US8470741B2 (en) | 2003-05-07 | 2013-06-25 | Croda Americas Llc | Homogeneous liquid saccharide and oil systems |
| US9668471B2 (en) | 2003-05-28 | 2017-06-06 | AgQuam LLC | Manufacture and use of agricultural spray adjuvants for hard water conditions |
| EP1636333A4 (en) | 2003-06-19 | 2007-10-24 | Evogene Ltd | NUCLEOTIDE SEQUENCES FOR REGULATING GENE EXPRESSION IN VEGETABLE TRICHROMES, AND HYBRID GENES AND METHODS IN WHICH THEY INTERVENE |
| KR101011789B1 (ko) | 2003-07-01 | 2011-02-07 | 고유 아그리 가부시키가이샤 | 환경 보전형 유해생물 방제제 |
| BRPI0413266B8 (pt) | 2003-08-04 | 2022-06-28 | Dow Agrosciences Llc | Composição de concentrado herbicida de alta potência, e método para controle de vegetação indesejável |
| US6762289B1 (en) | 2003-08-18 | 2004-07-13 | S. Ltech Llc | Silicone functionalized alkyl polyglucoside surfactants |
| DE10351647A1 (de) | 2003-11-05 | 2005-06-09 | Bayer Cropscience Ag | 2-Halogen-6-alkyl-phenyl substituierte Tetramsäure-Derivate |
| EP1689227B1 (en) | 2003-12-04 | 2014-01-15 | Syngenta Participations AG | Herbicidal composition |
| GB0328528D0 (en) | 2003-12-09 | 2004-01-14 | Syngenta Ltd | Agrochemical composition |
| US20070082819A1 (en) | 2003-12-09 | 2007-04-12 | Perry Richard B | Agrochemical compositions |
| US20050289670A1 (en) | 2004-05-20 | 2005-12-29 | Pioneer Hi-Bred International, Inc. | Plant myo-inositol kinase polynucleotides and methods of use |
| US20080039322A1 (en) | 2004-05-24 | 2008-02-14 | Yueh Wang | Stable and Water-Soluble Plant Growth Regulator Liquid Compositions and Methods for Use of Same |
| DE102004026937A1 (de) | 2004-06-01 | 2005-12-22 | Bayer Cropscience Gmbh | Konzentrierte wäßrige Formulierungen für den Pflanzenschutz |
| US20060009360A1 (en) | 2004-06-25 | 2006-01-12 | Robert Pifer | New adjuvant composition |
| AU2005270091B2 (en) | 2004-07-02 | 2012-04-12 | Specialty Operations France | Spray composition having a deposition control agent |
| US7691908B2 (en) | 2004-08-04 | 2010-04-06 | University Of Utah Research Foundation | Emulsion based oil simulant and associated methods |
| MX2007008012A (es) | 2004-12-30 | 2007-08-23 | Rhone Poulenc Chimie | Composicion herbicida que comprende una sal de aminofosfato o de aminofosfonato y una betaina. |
| US9919979B2 (en) | 2005-01-21 | 2018-03-20 | Bayer Cropscience Lp | Fertilizer-compatible composition |
| US20060205600A1 (en) | 2005-03-14 | 2006-09-14 | Sumitomo Chemical Company, Limited | Herbicidal composition |
| ITMI20051138A1 (it) | 2005-06-17 | 2006-12-18 | Sipcam Spa | Processo per preparare granuli di glifosate ammonico |
| EP1947946A2 (de) | 2005-09-08 | 2008-07-30 | Bayer Cropscience Ag | Neue sulfonamid-haltige feste formulierungen |
| AU2006302237C1 (en) | 2005-10-07 | 2012-11-08 | The University Of Alabama | Multi-functional ionic liquid compositions |
| US8008231B2 (en) | 2005-10-13 | 2011-08-30 | Momentive Performance Materials Inc. | Extreme environment surfactant compositions comprising hydrolysis resistant organomodified disiloxane surfactants |
| US7265055B2 (en) | 2005-10-26 | 2007-09-04 | Cabot Microelectronics Corporation | CMP of copper/ruthenium substrates |
| JP5083501B2 (ja) | 2006-03-01 | 2012-11-28 | 日産化学工業株式会社 | 効果に優れる農薬組成物 |
| AU2007260586B2 (en) | 2006-06-14 | 2012-08-02 | Elders Toll Formulation Pty Ltd | Herbicidal composition and method for removing unwanted foliage |
| ITVA20070047A1 (it) | 2007-05-24 | 2008-11-25 | Lamberti Spa | Microemulsioni e loro uso per migliorare l'efficacia biologica dei pesticidi |
| JP5360364B2 (ja) | 2007-08-02 | 2013-12-04 | 日産化学工業株式会社 | 効果に優れる農薬組成物 |
| JP2009114075A (ja) | 2007-11-01 | 2009-05-28 | Nissan Chem Ind Ltd | 低粘度農薬組成物 |
| US20100331185A1 (en) | 2007-11-30 | 2010-12-30 | Cognis Ip Management Gmbh | Herbicidal Compositions of Lithium Glyphosate and Adjuvants |
| WO2009075591A1 (en) | 2007-12-13 | 2009-06-18 | Donaghys Industries Limited | Herbicidal formulations for combinations of dimethylamine and potassium salts of glyphosate |
| EP2262363B1 (en) | 2008-02-06 | 2017-09-20 | Excel Crop Care Limited | Improved herbicidal formulation |
| ES2326018B1 (es) | 2008-03-26 | 2010-07-05 | Consejo Superior De Investigaciones Cientificas (Csic) | Material ceramico denso y homogeneo de nanotubos de carbono/nitruro de silicio, procedimiento de elaboracion y sus aplicaciones. |
| DK2337452T3 (da) | 2008-07-03 | 2014-12-15 | Monsanto Technology Llc | Kombinationer af derivatiserede saccharidsurfaktanter og etheraminoxidsurfaktanter som herbicidadjuvanter |
| ES2673320T3 (es) | 2008-07-08 | 2018-06-21 | Akzo Nobel Chemicals International B.V. | Mezcla de tensioactivos útil en agricultura |
| EP2181594A1 (en) | 2008-10-28 | 2010-05-05 | Cognis IP Management GmbH | Agricultural compositions |
| PL2341778T3 (pl) | 2008-11-06 | 2014-06-30 | Sn Biotech Tech Sp Z O O Sp K | Ciekła, homogeniczna kompozycja herbicydowa, sposób zwalczania chwastów, sposób wytwarzania ciekłej, homogenicznej kompozycji herbicydu i zastosowanie ciekłej, homogenicznej kompozycji herbicydowej do zwalczania chwastów |
| CN101406179A (zh) | 2008-11-18 | 2009-04-15 | 深圳大学 | 一种用于除草剂的助剂组合物及除草剂组合物 |
| IT1393222B1 (it) | 2009-03-03 | 2012-04-11 | Lamberti Spa | Composizioni acquose adiuvanti per erbicidi |
| BRPI1016228B1 (pt) | 2009-03-06 | 2021-02-09 | Syngenta Participations Ag | formulação pesticida aquosa compatibilizada, método de inibir pelo menos uma peste em uma área de colheita e método de formar a referida formulação aquosa |
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| Publication number | Publication date |
|---|---|
| MX2011000098A (es) | 2011-02-25 |
| US9351486B2 (en) | 2016-05-31 |
| CN102143685B (zh) | 2015-05-27 |
| BRPI0915368A2 (pt) | 2018-05-22 |
| AU2009267127A1 (en) | 2010-01-07 |
| EP2337452A2 (en) | 2011-06-29 |
| US20110263430A1 (en) | 2011-10-27 |
| CN102143685A (zh) | 2011-08-03 |
| WO2010002836A2 (en) | 2010-01-07 |
| CA2729738C (en) | 2018-01-09 |
| EP2939538A1 (en) | 2015-11-04 |
| AR103551A2 (es) | 2017-05-17 |
| CA2729738A1 (en) | 2010-01-07 |
| ES2526651T3 (es) | 2015-01-14 |
| BRPI0915368B1 (pt) | 2019-01-15 |
| ES2711207T3 (es) | 2019-04-30 |
| CN104872125A (zh) | 2015-09-02 |
| US20140113822A1 (en) | 2014-04-24 |
| EP2337452B1 (en) | 2014-11-05 |
| MX356148B (es) | 2018-05-15 |
| US8536095B2 (en) | 2013-09-17 |
| AU2009267127B2 (en) | 2015-02-19 |
| LT2939538T (lt) | 2019-03-12 |
| AR072434A1 (es) | 2010-08-25 |
| WO2010002836A3 (en) | 2011-01-06 |
| CN104872125B (zh) | 2018-02-02 |
| PL2939538T3 (pl) | 2019-05-31 |
| EP2939538B1 (en) | 2018-11-14 |
| PL2337452T3 (pl) | 2015-05-29 |
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