DK2809744T3 - Fremgangsmåde til fremstilling af carbonhydrider ved øgning af kædelængden af carbonhydrider - Google Patents

Fremgangsmåde til fremstilling af carbonhydrider ved øgning af kædelængden af carbonhydrider Download PDF

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DK2809744T3
DK2809744T3 DK12790931.5T DK12790931T DK2809744T3 DK 2809744 T3 DK2809744 T3 DK 2809744T3 DK 12790931 T DK12790931 T DK 12790931T DK 2809744 T3 DK2809744 T3 DK 2809744T3
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fatty acids
reaction zone
process according
hydrocarbons
feedstock
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DK12790931.5T
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Jukka Myllyoja
Pekka Aalto
Rami Piilola
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Neste Oyj
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Claims (11)

1. Fremgangsmåde til øgning af carbonhydrid-kædelængde, omfattende trinnene: (i) at tilvejebringe et råmateriale omfattende fedtsyrer og/eller fedtsyreestere med carbonhydrid-kædelængde under C23, og (ii) at indføre råmaterialet med en strømningshastighed fra 0,1 til 10 h'1 i en reaktionszone med en temperatur på 200 til 450 °C, hvori ketonisering af fedtsyrerne og/eller fedtsyreesterne udføres i nærvær af en hydrobehand-lingskatalysator, der er udvalgt som en metal katalysator, hvor metallet er udvalgt fra gruppen bestående af Fe, Pd, Pt, Ni, Mo, Co, Ru, Rh, W og en hvilken som helst kombination deraf under hydrogentryk på mindre end 2,0 MPa, og hvor forholdet mellem hydrogen og råmateriale er fra 100 til 600 Nl/I i ke-toniseringsreaktionszonen, og (iii) at opnå fra reaktionszonen ketoner med carbonhydrid-kædelængde på fra C24 til C43.
2. Fremgangsmåde ifølge krav 1, hvor de opnåede ketoner yderligere hydro-deoxygeneres i et sidste hydrodeoxygeneringstrin til dannelse af lineære carbonhydrider.
3. Fremgangsmåde ifølge et hvilket som helst af kravene 1-2, hvor ketoniser-ingen og det sidste hydrodeoxygeneringstrin udføres i den samme reaktionszone.
4. Fremgangsmåde ifølge et hvilket som helst af kravene 2-3, hvor det sidste hydrodeoxygeneringstrin udføres i en separat reaktionszone efter ketonise-ringsreaktionen.
5. Fremgangsmåde ifølge et hvilket som helst af kravene 1-4, hvor trykket i ketoniseringsreaktionszonen er mindre end 1 MPa.
6. Fremgangsmåde ifølge et hvilket som helst af kravene 1-5, hvor temperaturen i ketoniseringsreaktionszonen er fra 350 til 450 °C.
7. Fremgangsmåde ifølge et hvilket som helst af kravene 1-6, hvor forholdet mellem hydrogen og råmateriale er fra 130 til 300 Nl/I i ketoniseringsreakti-onszonen.
8. Fremgangsmåde ifølge krav 1, hvor hydrobehandlingskatalysatoren er NiMo eller CoMo.
9. Fremgangsmåde ifølge et hvilket som helst af kravene 1-8, hvor hydrobehandlingskatalysatoren er en sulfideret hydrobehandlingskatalysator.
10. Fremgangsmåde ifølge et hvilket som helst af kravene 1-9, hvor hydrobehandlingskatalysatoren er på en bærer, fortrinsvis på en bærer af aktiveret carbon, alumina og/eller silica.
11. Fremgangsmåde ifølge et hvilket som helst af kravene 2-3, hvilken fremgangsmåde yderligere omfatter: (iv) at indføre det fremkomne materiale i en isomeriseringsenhed, hvor der dannes en blanding af forgrenede carbonhydrider, og (v) at fraseparere fra blandingen carbonhydrider, der er egnede til anvendelse som basisoliebestanddele med et carbonnummerinterval fra C24-C43, og carbonhydrider, der er egnede til anvendelse som brændstofbestanddele med et carbonnummerinterval fra C5 til C20.
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Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9221725B2 (en) 2012-07-18 2015-12-29 Exxonmobil Research And Engineering Company Production of lubricant base oils from biomass
WO2014099371A2 (en) * 2012-12-18 2014-06-26 Exxonmobil Research And Engineering Company Process for making saturated hydrocarbons from renewable feeds
SG11201502700YA (en) 2012-12-18 2015-05-28 Exxonmobil Res & Eng Co Process for making lube base stocks from renewable feeds
EP3115439B1 (en) * 2014-03-03 2019-02-06 National Institute of Advanced Industrial Science and Technology Biodiesel fuel hydrogenation method
ES2762517T3 (es) * 2014-03-26 2020-05-25 Neste Oyj Método para la conversión catalítica de cetoácidos e hidrotratamiento en hidrocarburos
PL3132005T3 (pl) 2014-03-26 2022-03-28 Neste Oyj Sposób konwersji termicznej ketokwasów i hydrorafinacji do węglowodorów
ES2697648T3 (es) 2014-10-24 2019-01-25 Neste Oyj Método para la cetonización de material biológico
FI128441B (en) * 2015-02-09 2020-05-15 Neste Oil Oyj Fatty acid composition
JP6420221B2 (ja) * 2015-09-29 2018-11-07 富士フイルム株式会社 生体センサ制御装置とその作動方法および作動プログラム、並びに生体センサシステム
PL3187569T3 (pl) * 2015-12-29 2019-11-29 Neste Oyj Kompozycja odnawialnego paliwa dieslowego
KR102549463B1 (ko) * 2016-08-30 2023-06-30 삼성전자주식회사 이미지 처리 방법 및 이를 지원하는 전자 장치
EP3301144B1 (en) * 2016-09-29 2021-03-17 Neste Oyj Diesel fuel comprising 5-nonanone
US10240099B2 (en) 2016-10-27 2019-03-26 Uop Llc Processes for producing a fuel from a renewable feedstock
CA3064957C (en) * 2017-06-19 2024-02-13 Neste Oyj Renewable base oil in lubricant formulations
US10450256B2 (en) * 2017-10-06 2019-10-22 Exxonmobil Research And Engineering Company Renewable ketone waxes with unique carbon chain lengths and polarities
FI128062B (en) * 2017-12-19 2019-08-30 Neste Oyj A process for the preparation of ketones for fuel and oil applications
KR102047029B1 (ko) 2018-02-13 2019-12-02 부경대학교 산학협력단 동식물유로부터 바이오중유를 제조하기 위한 전이금속 탄화물 촉매를 이용한 동식물유의 산가 및 요오드가 저감 방법
WO2019229035A1 (en) * 2018-05-30 2019-12-05 Total Research & Technology Feluy Hydrodynamic cavitation process to protect catalytic processes used to deoxygenate complex mixtures of natural occurring fats & oils into oxygen-free hydrocarbons
FI128115B2 (en) 2018-07-20 2024-08-20 Neste Oyj Purification of recycled and renewable organic material
FI128911B2 (en) * 2018-07-20 2025-05-27 Neste Oyj Cleaning of recycled and renewable organic material
FI128121B (en) 2018-07-20 2019-10-15 Neste Oyj Production of hydrocarbons from recycled or renewable organic material
FI128069B2 (en) 2018-07-20 2024-04-24 Neste Oyj Purification of recycled and renewable organic material
FI128174B (en) 2018-07-20 2019-11-29 Neste Oyj Purification of recycled and renewable organic material
WO2020141255A1 (en) * 2018-12-31 2020-07-09 Neste Oyj Process for integrated production of renewable fuels and chemicals
FI128570B (en) * 2018-12-31 2020-08-14 Neste Oyj Process for making renewable products
US11643606B2 (en) 2018-12-31 2023-05-09 Neste Oyj Method for producing renewable base oil and renewable fuel components
FI129457B (en) * 2018-12-31 2022-02-28 Neste Oyj Process for the catalytic production of propanol
FI128952B (en) 2019-09-26 2021-03-31 Neste Oyj Preparation of renewable alkenes including metathesis
WO2021094645A1 (en) * 2019-11-15 2021-05-20 Neste Oyj Production of paraffinic products
US12454497B2 (en) * 2020-06-02 2025-10-28 Alliance For Sustainable Energy, Llc Fuels and methods of making the same
EP4244309A4 (en) * 2020-11-11 2024-07-24 Neste Oyj ELECTROTECHNICAL FLUID AND METHOD FOR ITS PRODUCTION
US12448580B2 (en) 2021-09-08 2025-10-21 Auburn University Bio-lubricant compositions and methods thereof
CA3256602A1 (en) * 2022-06-30 2024-01-04 Neste Oyj HYDROCARBON COMPONENT
US11993752B1 (en) 2022-12-21 2024-05-28 Neste Oyj Process for manufacturing of renewable hydrocarbons from renewable feedstock comprising phosphorus as an impurity

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2661907B1 (fr) 1990-05-14 1994-04-15 Centre Coop Internale Recherc Ag Procede de condensation catalytique d'acides organiques et/ou de leurs derives et son application a la preparation de cetones, alcools, amines et amides.
DE4121117A1 (de) 1991-06-26 1993-01-07 Henkel Kgaa Verfahren zur herstellung von fettketonen
EP2993218A1 (en) 2005-07-04 2016-03-09 Neste Oil Oyj Process for the manufacture of diesel range hydrocarbons
US7998339B2 (en) * 2005-12-12 2011-08-16 Neste Oil Oyj Process for producing a hydrocarbon component
PL1963461T3 (pl) 2005-12-12 2018-10-31 Neste Oyj Sposób wytwarzania składnika węglowodorowego
EP1966357B1 (en) 2005-12-12 2019-04-24 Neste Oyj Base oil
US8048290B2 (en) * 2007-06-11 2011-11-01 Neste Oil Oyj Process for producing branched hydrocarbons
US8772555B2 (en) 2008-07-24 2014-07-08 Chevron U.S.A. Inc. Conversion of vegetable oils to base oils and transportation fuels

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