DK2809745T3 - Samtidig fremstilling af basisolie- og brændstofbestanddele ud fra vedvarende råmateriale - Google Patents

Samtidig fremstilling af basisolie- og brændstofbestanddele ud fra vedvarende råmateriale Download PDF

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DK2809745T3
DK2809745T3 DK12795014.5T DK12795014T DK2809745T3 DK 2809745 T3 DK2809745 T3 DK 2809745T3 DK 12795014 T DK12795014 T DK 12795014T DK 2809745 T3 DK2809745 T3 DK 2809745T3
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reaction
catalyst
base oil
ketonisation
components
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DK12795014.5T
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Mika Kettunen
Jukka Myllyoja
Rami Piilola
Göran Sandström
Pekka Aalto
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Neste Oyj
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/12—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation
    • C11C3/123—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation using catalysts based principally on nickel or derivates
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    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
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Claims (16)

1. Fremgangsmåde til samtidig fremstilling af bestanddele, der er egnede til fremstilling af basisolie- og brændstofbestanddele, omfattende trinnene: a) at indføre med en gennemstrømningshastighed på 0,1 til 10 h'1 et råmateriale omfattende fedtsyrer og/eller fedtsyreestere i en reaktionszone med et temperaturområde fra 200 til 450 °C og b) at udsætte råmaterialet for en ketoniseringsreaktion i reaktionszonen under hydrogentryk på mindre end 10 MPa, i nærvær af et dobbeltkatalysator-system, der er udformet til at udføre en ketoniseringsreaktion og en hydrobe-handlingsreaktion, hvilket katalysatorsystem omfatter en metaloxidketoniseringskatalysator, i hvilken metallet er udvalgt fra gruppen bestående af Na, Mg, K, Ca, Sc, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sr, Ti, Y, Zr, Mo, Rh, Cd, Sn, La, Pb, Bi, Ti, V og andre sjældne jordartsmetaller og en hvilken som helst kombination deraf; og en metalhydrobehandlingskatalysator, hvor metallet er udvalgt fra gruppen bestående af Fe, Pd, Pt, Ni, Mo, Co, Ru, Rh, W og en hvilken som helst kombination deraf, og c) fra ketoniseringsreaktionen at opnå ketoner ud over lineære carbonhydri-der ud fra fedtsyrerne og/eller fedtsyreesterne.
2. Fremgangsmåde ifølge krav 1, hvor de opnåede ketoner yderligere hydro-deoxygeneres til dannelse af lineære carbonhydrider.
3. Fremgangsmåde ifølge krav 1 eller 2, hvor fedtsyreesterne er triglycerider.
4. Fremgangsmåde ifølge et hvilket som helst af kravene 1-3, hvor råmaterialet er mindst delvist, fortrinsvis fuldstændingt, i flydende form, når det kommer ind i reaktionszonen.
5. Fremgangsmåde ifølge et hvilket som helst af kravene 1-4, hvor trykket i reaktionszonen er fra 0,1 til 5 MPa.
6. Fremgangsmåde ifølge et hvilket som helst af kravene 1-5, hvor temperaturen i reaktionszonen er fra 280 til 400 °C.
7. Fremgangsmåde ifølge et hvilket som helst af kravene 1-6, hvor forholdet mellem hydrogen og råmateriale er fra 100 til 600 Nl/I, fortrinsvis fra 100 til 500 Nl/I.
8. Fremgangsmåde ifølge krav 1, hvor dobbeltkatalysatorsystemet omfatter en blanding eller kombination af en ketoniseringskatalysator og en hydrobe-handlingskatalysator.
9. Fremgangsmåde ifølge krav 8, hvor dobbeltkatalysatorsystemet indeholder 40 - 90 vægt-% af keton iseringskatalysatoren, fortrinsvis 70 - 90 vægt-% af ketoniseringskatalysatoren.
10. Fremgangsmåde ifølge et hvilket som helst af kravene 8-9, hvor ketoniseringskatalysatoren er en metaloxid katalysator, i hvilken metallet er udvalgt fra gruppen bestående af K, Ti og en kombination deraf.
11. Fremgangsmåde ifølge et hvilket som helst af kravene 8-10, hvor dobbeltkatalysatorsystemet er understøttet, fortrinsvis på en bærer af alumina, silica eller aktivt kul.
12. Fremgangsmåde ifølge et hvilket som helst af kravene 8-11, hvor dobbeltkatalysatorsystemet omfatter NiMo og K2O/T1O2 på en bærer.
13. Fremgangsmåde ifølge et hvilket som helst af kravene 8-12, hvor dobbeltkatalysatorsystemet omfatter en sulfideret hydrobehandlings- og/eller ketoniseringskatalysator.
14. Fremgangsmåde ifølge krav 2, hvilken fremgangsmåde yderligere omfatter trinnene (d) at indføre de fremkomne lineære carbonhydrider i en isomeriseringsen-hed under isomeriseringsbetingelser, hvor der dannes en blanding af forgrenede carbonhydrider, og (e) at fraseparere fra blandingen af forgrenede carbonhydrider bestanddele, der er egnede til anvendelse som basisolie, med et carbonnummerinterval fra C24-C43, og carbonhydrider, der er egnede til anvendelse som brændstof-bestanddele, med et carbonnummerinterval fra C5 til C23.
15. Dobbeltkatalysatorsystem, der er udformet til at udføre en keton iserings-reaktion og en hydrobehandlingsreaktion, hvor dobbeltsystemet omfatter NiMo og K2O/T1O2 på en bærer.
16. Fremstillingssystem til samtidig fremstilling af basisoliebestanddele og brændstofbestanddele, omfattende: (a) mindst en reaktionsenhed omfattende mindst en reaktionszone indbefattende et dobbeltkatalysatorsystem, der er udformet til at udføre en ketonise-ringsreaktion og en hydrobehandlingsreaktion under hydrogentryk til fremstilling af ketoner og lineære carbonhydrider, hvilket katalysatorsystem omfatter en metaloxidketoniseringskatalysator, hvori metallet er udvalgt fra gruppen bestående af Na, Mg, K, Ca, Sc, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sr, Ti, Y, Zr, Mo, Rh, Cd, Sn, La, Pb, Bi, Ti, V og andre sjældne jordartsmetaller og en hvilken som helst kombination deraf; og en metalhydrobehandlingskatalysator, hvor metallet er udvalgt fra gruppen bestående af Fe, Pd, Pt, Ni, Mo, Co, Ru, Rh, W og en hvilken som helst kombination deraf; og (b) mindst en reaktionsenhed omfattende mindst en reaktionszone, der er udformet til at udføre hydrodeoxygenering af ketonerne til lineære carbonhydrider; og (c) mindst en reaktionsenhed omfattende mindst en reaktionszone, der er udformet til at isomerisere de lineære carbonhydrider; og (d) mindst en destillationsindretning, der er udformet til at separate basisoliebestanddele fra brændstofbestanddele; hvor mindst en reaktionsenhed (a) er forbundet med mindst en reaktionsenhed (b), og hvor mindst en reaktionsenhed (b) er forbundet med mindst en destillationsindretning (c), og hvor mindst en reaktionsenhed (c) er forbundet med mindst en destillationsindretning (d), hvor systemet yderligere omfatter en strømningsvej til recirkulering af carbonhydrider fra enhed (b), (c) eller (d) tilbage til enhed (a).
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