DK2814082T3 - Elektrokemiske celler med glasholdige separatorer - Google Patents
Elektrokemiske celler med glasholdige separatorer Download PDFInfo
- Publication number
- DK2814082T3 DK2814082T3 DK14163569.8T DK14163569T DK2814082T3 DK 2814082 T3 DK2814082 T3 DK 2814082T3 DK 14163569 T DK14163569 T DK 14163569T DK 2814082 T3 DK2814082 T3 DK 2814082T3
- Authority
- DK
- Denmark
- Prior art keywords
- electrochemical cell
- separator
- ceramic particles
- particles
- glass
- Prior art date
Links
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/446—Composite material consisting of a mixture of organic and inorganic materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/387—Tin or alloys based on tin
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/403—Manufacturing processes of separators, membranes or diaphragms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/431—Inorganic material
- H01M50/434—Ceramics
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/443—Particulate material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
- H01M50/451—Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
- H01M50/457—Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/10—Batteries in stationary systems, e.g. emergency power source in plant
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Cell Separators (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Claims (9)
1. Coatingfremgangsmåde til fremstilling af en porøs separator, der omfatter flere lag, hvor hvert lag omfatter både glaspartikler og keramiske partikler, hvor fremgangsmåden omfatter følgende trin - tilvejebringelse af en blanding af et organisk polymermateriale af både glaspartikler og keramiske partikler og mindst to opløsningsmidler, hvor glaspartiklerne og de keramiske partikler omfatter 5-95% af blandingen, hvor det organiske polymermateriale omfatter 5-95% af blandingen og er valgt fra gruppen omfattende poly(vinylidenfluorid)-hexafluorpropen (PVDF-HFP), polyvinylidenfluo-rid (PVDF), PTFE, polymethylmethacrylat (PMMA), polypropylen (PP), poly-acrylsyre (PAA), polyvinylpyrrolidon (PVP), vandbaseret PVDF, acrylat, poly-acrylat, styrenbutadiengummi (SBR), naturlige og syntetiske gummier, latex, OPPANOL®, polyethylen (PE), ethylen-vinylacetat-copolymer (EVA), polyvinyl-alkohol (PVA) og blandinger deraf, hvor de keramiske partikler er fremstillet af et materiale valgt fra gruppen omfattende lithiumaluminiumtitanphosphat LixAly. Tiz(P04)3, hvor 1 < x < 2, 0 < y < 1, og 1 < z < 2, aluminiumoxid (AI2O3)af nano-størrelse, Zr02, SiC, UAIO2, Sn02 eller BaTi03, hvor opløsningsmidlet er valgt fra gruppen omfattende tetrahydrofuran (THF), acetone, ethanol, eddikesyre, dimethylacetamid (DMAC), dimethylsulfoxid (DMSO), hexamethylphosphoramid (HMPA), N-methylpyrrolidon (NMP), triethylphosphat (TEP), trimethylphosphat (TMP), tetramethylurinstof (TMU), butanon, propylencarbonat (PC), butanol-vand, silanol, silandiol, ethylenglycolmonohexylether, N,N-dimethylethanolamin, isopropylalkohol, toluen, normal butylalkohol, maleinsyreanhydrid, xylen og blandinger deraf og - fremstilling af et multilag ved faseinversion.
2. Fremgangsmåde ifølge krav 1, hvor den separator, der omfatter flere lag af både glaspartikler og keramiske partikler, deponeres i et enkelt trin.
3. Fremgangsmåde ifølge krav 1 eller 2, hvor glaspartiklerne og/eller de keramiske partikler er ionledende og/eller ikke-ionledende partikler.
4. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 3, hvor et adhæsionsadditiv tilsættes til blandingen.
5. Fremgangsmåde ifølge krav 4, hvor adhæsionsadditivet er valgt fra gruppen omfattende urethan og resiner.
6. Elektrokemisk celle, der omfatter en elektrokemisk celleelektrolyt, en anode, en katode og en separator, hvor separatoren fremstilles ved fremgangsmåden ifølge et hvilket som helst af kravene 1 til 5.
7. Elektrokemisk celle ifølge krav 6, hvor den elektrokemiske celle er en elektrokemisk celle i storskala.
8. Elektrokemisk celle ifølge krav 6, hvor anodematerialet er valgt fra gruppen omfattende grafit eller andre carbonbaserede materialer, Si eller kompositter omfattende Si, Li4Ti50i2, Li2Ti307, LixTi02 (hvor 0 S x < 1), Ti02, Ti02(0H)x (hvor x > 1) og blandinger deraf.
9. Anvendelse af en elektrokemisk celle ifølge krav 6 i forbrugerelektronik, stationære anvendelser som lagring af vedvarende energi, netnivellering, solenergi, store hybriddieselmotorer, militær, hybride elektriske køretøjer (HEV'er) og rumfartsanvendelser.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1310059.9A GB2514821A (en) | 2013-06-06 | 2013-06-06 | Electrochemical cells with glass containing separators |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2814082T3 true DK2814082T3 (da) | 2018-06-25 |
Family
ID=48805815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK14163569.8T DK2814082T3 (da) | 2013-06-06 | 2014-04-04 | Elektrokemiske celler med glasholdige separatorer |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US9806313B2 (da) |
| EP (1) | EP2814082B1 (da) |
| JP (2) | JP2015008124A (da) |
| KR (1) | KR20140143318A (da) |
| CY (1) | CY1120500T1 (da) |
| DK (1) | DK2814082T3 (da) |
| ES (1) | ES2668146T3 (da) |
| GB (1) | GB2514821A (da) |
| HR (1) | HRP20180711T1 (da) |
| HU (1) | HUE037119T2 (da) |
| LT (1) | LT2814082T (da) |
| NO (1) | NO2814082T3 (da) |
| PL (1) | PL2814082T3 (da) |
| PT (1) | PT2814082T (da) |
| SI (1) | SI2814082T1 (da) |
| TR (1) | TR201806316T4 (da) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10347934B2 (en) | 2014-09-26 | 2019-07-09 | Ut-Battelle, Llc | Shear activated impact resistant electrolyte |
| KR102546315B1 (ko) * | 2015-09-25 | 2023-06-21 | 삼성전자주식회사 | 리튬전지용 전극 복합분리막 어셈블리 및 이를 포함한 리튬전지 |
| CN109314203B (zh) * | 2016-06-08 | 2021-11-30 | 远景Aesc 日本有限公司 | 非水电解质二次电池 |
| CN109314216B (zh) | 2016-06-08 | 2021-08-17 | 远景Aesc 日本有限公司 | 非水电解质二次电池 |
| CN105977476B (zh) * | 2016-07-28 | 2018-11-20 | 深圳市贝特瑞纳米科技有限公司 | 一种多元正极材料的表面包覆方法及其用途 |
| CN106784552B (zh) * | 2016-12-27 | 2021-09-21 | 深圳市星源材质科技股份有限公司 | 一种锂离子电池涂覆隔膜及其制备方法 |
| US10347945B2 (en) | 2017-12-08 | 2019-07-09 | Ut-Battelle, Llc | Stabilized shear thickening electrolyte |
| US10637100B2 (en) | 2018-04-20 | 2020-04-28 | Ut-Battelle, Llc | Fabrication of films and coatings used to activate shear thickening, impact resistant electrolytes |
| CN108976938B (zh) * | 2018-07-10 | 2020-11-17 | 福建师范大学 | 含有一价离子磷酸盐涂覆层的涂覆膜制备方法 |
| DE102018217756A1 (de) | 2018-10-17 | 2020-04-23 | Robert Bosch Gmbh | Verfahren zur Herstellung einer Elektrodeneinheit für eine Batteriezelle und Batteriezelle |
| CN109216548A (zh) * | 2018-10-22 | 2019-01-15 | 东莞理工学院 | 一种钙钛矿太阳能电池的刮涂制备方法 |
| CN113224466B (zh) * | 2020-01-19 | 2023-06-16 | 厦门大学 | 一种压敏高分子改性隔膜及其制备方法和应用 |
| EP4060780B1 (en) * | 2021-03-15 | 2023-07-26 | Evonik Operations GmbH | Dispersion and coating composition containing lithium metal phosphate |
| US12567600B2 (en) | 2023-12-14 | 2026-03-03 | Safire Technology Group, Inc. | Systems and methods for enhancing safety of electrochemical cells via electrolyte thickening |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110165471A9 (en) * | 1999-11-23 | 2011-07-07 | Sion Power Corporation | Protection of anodes for electrochemical cells |
| US7282295B2 (en) * | 2004-02-06 | 2007-10-16 | Polyplus Battery Company | Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture |
| KR100666821B1 (ko) | 2004-02-07 | 2007-01-09 | 주식회사 엘지화학 | 유/무기 복합 다공성 코팅층이 형성된 전극 및 이를포함하는 전기 화학 소자 |
| KR100628305B1 (ko) * | 2004-09-10 | 2006-09-27 | 한국전자통신연구원 | 나노입자가 충진된 상반전 고분자 전해질 제조 방법 |
| KR100659820B1 (ko) * | 2004-11-17 | 2006-12-19 | 삼성에스디아이 주식회사 | 리튬 이온 이차 전지 |
| BRPI0620590B1 (pt) * | 2005-12-06 | 2019-07-09 | Lg Chem, Ltd. | Separador compósito orgânico/inorgânico, método para fabricar um separador compósito orgânico/inorgânico e dispositivo eletroquímico |
| WO2007075867A2 (en) * | 2005-12-19 | 2007-07-05 | Polyplus Battery Company | Composite solid electrolyte for protection of active metal anodes |
| WO2009070600A2 (en) * | 2007-11-27 | 2009-06-04 | Ceramatec, Inc. | Substantially solid, flexible electrolyte for alkili-metal-ion batteries |
| US10320033B2 (en) * | 2008-01-30 | 2019-06-11 | Enlighten Innovations Inc. | Alkali metal ion battery using alkali metal conductive ceramic separator |
| EP2260523B1 (en) * | 2008-04-08 | 2014-02-26 | SK Innovation Co. Ltd. | Method of manufacturing the microporous polyolefin composite film with a thermally stable layer at high temperature |
| KR20130067139A (ko) * | 2011-12-13 | 2013-06-21 | 삼성전자주식회사 | 보호음극, 이를 포함하는 리튬공기전지 및 이를 포함하는 전고체 전지 |
| KR101363113B1 (ko) | 2012-02-24 | 2014-02-14 | 성균관대학교산학협력단 | 내열성이 향상된 세퍼레이터 및 이를 구비한 전기화학소자 |
| GB2510413A (en) | 2013-02-04 | 2014-08-06 | Leclanch Sa | Electrolyte composition for electrochemical cells |
-
2013
- 2013-06-06 GB GB1310059.9A patent/GB2514821A/en not_active Withdrawn
-
2014
- 2014-04-04 DK DK14163569.8T patent/DK2814082T3/da active
- 2014-04-04 ES ES14163569.8T patent/ES2668146T3/es active Active
- 2014-04-04 PT PT141635698T patent/PT2814082T/pt unknown
- 2014-04-04 PL PL14163569T patent/PL2814082T3/pl unknown
- 2014-04-04 EP EP14163569.8A patent/EP2814082B1/en not_active Revoked
- 2014-04-04 HU HUE14163569A patent/HUE037119T2/hu unknown
- 2014-04-04 LT LTEP14163569.8T patent/LT2814082T/lt unknown
- 2014-04-04 NO NO14163569A patent/NO2814082T3/no unknown
- 2014-04-04 SI SI201430723T patent/SI2814082T1/en unknown
- 2014-04-04 TR TR2018/06316T patent/TR201806316T4/tr unknown
- 2014-04-18 KR KR20140046435A patent/KR20140143318A/ko not_active Ceased
- 2014-04-18 JP JP2014086328A patent/JP2015008124A/ja active Pending
- 2014-06-06 US US14/297,648 patent/US9806313B2/en active Active
-
2018
- 2018-05-07 HR HRP20180711TT patent/HRP20180711T1/hr unknown
- 2018-05-30 CY CY20181100580T patent/CY1120500T1/el unknown
-
2019
- 2019-05-14 JP JP2019091105A patent/JP7075374B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| PT2814082T (pt) | 2018-05-09 |
| KR20140143318A (ko) | 2014-12-16 |
| ES2668146T3 (es) | 2018-05-17 |
| PL2814082T3 (pl) | 2018-08-31 |
| HUE037119T2 (hu) | 2018-08-28 |
| GB201310059D0 (en) | 2013-07-17 |
| US20140363738A1 (en) | 2014-12-11 |
| HRP20180711T1 (hr) | 2018-06-15 |
| NO2814082T3 (da) | 2018-08-18 |
| JP2015008124A (ja) | 2015-01-15 |
| GB2514821A (en) | 2014-12-10 |
| EP2814082B1 (en) | 2018-03-21 |
| JP2019149383A (ja) | 2019-09-05 |
| TR201806316T4 (tr) | 2018-06-21 |
| CY1120500T1 (el) | 2019-07-10 |
| SI2814082T1 (en) | 2018-07-31 |
| LT2814082T (lt) | 2018-05-10 |
| JP7075374B2 (ja) | 2022-05-25 |
| EP2814082A1 (en) | 2014-12-17 |
| US9806313B2 (en) | 2017-10-31 |
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