DK2866581T3 - Termisk inhiberet stivelse og stivelsesholdige mel - Google Patents
Termisk inhiberet stivelse og stivelsesholdige mel Download PDFInfo
- Publication number
- DK2866581T3 DK2866581T3 DK12733067.8T DK12733067T DK2866581T3 DK 2866581 T3 DK2866581 T3 DK 2866581T3 DK 12733067 T DK12733067 T DK 12733067T DK 2866581 T3 DK2866581 T3 DK 2866581T3
- Authority
- DK
- Denmark
- Prior art keywords
- starch
- starches
- process according
- thermal treatment
- temperature
- Prior art date
Links
- 229920002472 Starch Polymers 0.000 claims description 117
- 235000019698 starch Nutrition 0.000 claims description 116
- 239000008107 starch Substances 0.000 claims description 81
- 238000000034 method Methods 0.000 claims description 23
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 15
- 239000001301 oxygen Substances 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- 235000013312 flour Nutrition 0.000 claims description 13
- 229920002261 Corn starch Polymers 0.000 claims description 9
- 239000008120 corn starch Substances 0.000 claims description 9
- 238000007669 thermal treatment Methods 0.000 claims description 9
- 229920000856 Amylose Polymers 0.000 claims description 6
- 229920000945 Amylopectin Polymers 0.000 claims description 5
- 239000000047 product Substances 0.000 description 21
- 238000010438 heat treatment Methods 0.000 description 18
- 230000015556 catabolic process Effects 0.000 description 16
- 229920000881 Modified starch Polymers 0.000 description 15
- 235000019426 modified starch Nutrition 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 235000013339 cereals Nutrition 0.000 description 11
- 239000004368 Modified starch Substances 0.000 description 10
- 230000005764 inhibitory process Effects 0.000 description 9
- 239000000523 sample Substances 0.000 description 8
- 238000006731 degradation reaction Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000005022 packaging material Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 241000167854 Bourreria succulenta Species 0.000 description 4
- 235000019693 cherries Nutrition 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 4
- 238000006297 dehydration reaction Methods 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 235000018102 proteins Nutrition 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 240000006394 Sorghum bicolor Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000013467 fragmentation Methods 0.000 description 2
- 238000006062 fragmentation reaction Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 240000001592 Amaranthus caudatus Species 0.000 description 1
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 240000005561 Musa balbisiana Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 229920002494 Zein Polymers 0.000 description 1
- 108010055615 Zein Proteins 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 235000012735 amaranth Nutrition 0.000 description 1
- 239000004178 amaranth Substances 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- 235000021015 bananas Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 230000026731 phosphorylation Effects 0.000 description 1
- 238000006366 phosphorylation reaction Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000019710 soybean protein Nutrition 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- -1 that is Polymers 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000005019 zein Substances 0.000 description 1
- 229940093612 zein Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/212—Starch; Modified starch; Starch derivatives, e.g. esters or ethers
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/06—Drying; Forming
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
- C08B30/14—Cold water dispersible or pregelatinised starch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
- C08B30/16—Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/20—Amylose or amylopectin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/18—Oxidised starch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H99/00—Subject matter not provided for in other groups of this subclass, e.g. flours, kernels
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Nutrition Science (AREA)
- Food Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Grain Derivatives (AREA)
Claims (9)
1. Fremgangsmåde til fremstilling af termisk inhiberet stivelse og stivelsesholdige mel ved termisk behandling af naturlig stivelse, som er blevet for-tørret til et tørstofindhold på mere end eller lig med 98 masse-%, især fortrinsvis 99 masse-%, og har en pH på mindst 7, kendetegnet ved, at den termiske behandling sker i nærvær af mindst 0,1 vol.-% oxygen til atmosfærisk oxygen ved en produkttemperatur på mellem 150 og 200 °C i en vibrerende spiraltransportør.
2. Fremgangsmåden ifølge krav 1, kendetegnet ved, at den termiske behandling sker i nærvær af mindst 0,5 vol.-% oxygen.
3. Fremgangsmåde ifølge krav 1 eller krav 2, kendetegnet ved, at den termiske behandling sker i nærvær af mindst 5 vol.-% oxygen.
4. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 3, kendetegnet ved, at den termiske behandling sker i nærvær af mindst 10 vol.-% oxygen.
5. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 4, kendetegnet ved, at den termiske behandling sker i nærvær af atmosfærisk oxygen.
6. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 5, kendetegnet ved, at den termiske behandling sker ved en produkttemperatur på mellem 155 og 175 °C.
7. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 6, kendetegnet ved, at stivelsen er til stede i granulær form.
8. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 7, kendetegnet ved, at stivelsen har et amyloseindhold på mindre end 5 masse-%, fortrinsvis mindre end 2 masse-%.
9. Fremgangsmåde ifølge krav 8, kendetegnet ved, at stivelsen er en amylopek-tin-rig majsstivelse.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2012/062715 WO2014000813A1 (de) | 2012-06-29 | 2012-06-29 | Thermisch inhibierte stärke und stärkehaltige mehle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2866581T3 true DK2866581T3 (da) | 2018-11-05 |
Family
ID=46466492
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK12733067.8T DK2866581T3 (da) | 2012-06-29 | 2012-06-29 | Termisk inhiberet stivelse og stivelsesholdige mel |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US20150368370A1 (da) |
| EP (1) | EP2866581B1 (da) |
| JP (1) | JP6122108B2 (da) |
| KR (1) | KR102075364B1 (da) |
| CN (1) | CN104427885A (da) |
| BR (1) | BR112014032619B1 (da) |
| DK (1) | DK2866581T3 (da) |
| ES (1) | ES2691701T3 (da) |
| PL (1) | PL2866581T3 (da) |
| PT (1) | PT2866581T (da) |
| RU (1) | RU2602282C2 (da) |
| UA (1) | UA113655C2 (da) |
| WO (1) | WO2014000813A1 (da) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210106034A1 (en) | 2017-03-22 | 2021-04-15 | Beneo Remy | Remoistening of thermally inhibited starch and/or flour |
| US11180575B2 (en) | 2018-12-28 | 2021-11-23 | Corn Products Development, Inc. | Thermally inhibited starch and process for making |
| EP4059965A1 (de) | 2021-03-17 | 2022-09-21 | Südzucker AG | Verwendung von wachsweizenstärke als viskositätsverbesserer |
| KR102478528B1 (ko) * | 2021-05-25 | 2022-12-19 | 김두곤 | 전분계 중합체를 이용한 친환경 탄성 하이드로젤, 그 제조 방법 및 바이오엘라스토머의 착색 방법 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2818357A (en) * | 1952-07-12 | 1957-12-31 | Henkel & Compagnie G M B H | Method of producing transformation products of high molecular carbohydrates |
| US3067067A (en) * | 1960-01-13 | 1962-12-04 | Staley Mfg Co A E | Starch fractionation |
| US3977897A (en) | 1975-09-08 | 1976-08-31 | National Starch And Chemical Corporation | Process for preparing a non-chemically inhibited starch |
| US4303452A (en) | 1979-04-16 | 1981-12-01 | Ajinomoto Company Incorporated | Method of producing improved starch by smoking |
| US4303451A (en) | 1980-03-31 | 1981-12-01 | General Foods Corporation | Method for modifying texture and flavor of waxy maize starch |
| JPH072763B2 (ja) | 1985-05-08 | 1995-01-18 | 日澱化學株式会社 | 変性澱粉の製造方法 |
| US5720822A (en) * | 1995-06-07 | 1998-02-24 | National Starch And Chemical Investment Holding Corporation | Thermally-inhibited pregelatinized non-granular starches and flours and process for their production |
| US5932017A (en) * | 1993-07-30 | 1999-08-03 | National Starch And Chemical Investment Holding Corporation | Thermally-inhibited non-pregelatinized granular starches and flours and process for their preparation |
| ES2211393T5 (es) | 1994-07-29 | 2009-04-16 | National Starch And Chemical Investment Holding Corporation | Almidones y harinas termicamente inhibidos, y procedimiento para su fabricacion. |
| WO1996023104A1 (en) * | 1995-01-24 | 1996-08-01 | National Starch And Chemical Investment Holding Corporation | Paper containing thermally-inhibited starches |
| CA2210455A1 (en) * | 1995-01-24 | 1996-08-01 | National Starch And Chemical Investment Holding Corporation | Water-based adhesives containing thermally-inhibited starches |
| US5846786A (en) * | 1997-08-21 | 1998-12-08 | National Starch And Chemical Investment Holding Corporation | Thermally-inhibited, subsequently enzymatically-treated starches |
| US6277186B1 (en) * | 1999-06-01 | 2001-08-21 | National Starch And Chemical Investment Holding Corporation | Thermally-inhibited starch prepared with oligosaccharides |
| US8268989B2 (en) | 2008-05-07 | 2012-09-18 | Corn Products Development Inc. | Thermally inhibited polysaccharides and process of preparing |
| ZA200902999B (en) * | 2008-05-07 | 2010-03-31 | Brunob Ii Bv | Thermally inhibited polysaccharides and process of preparing |
| US8471003B2 (en) * | 2009-04-14 | 2013-06-25 | Corn Products Development Inc. | Thermally inhibited polysaccharides and process of preparing |
-
2012
- 2012-06-29 PL PL12733067T patent/PL2866581T3/pl unknown
- 2012-06-29 RU RU2015102793/13A patent/RU2602282C2/ru active
- 2012-06-29 EP EP12733067.8A patent/EP2866581B1/de active Active
- 2012-06-29 JP JP2015518861A patent/JP6122108B2/ja active Active
- 2012-06-29 KR KR1020157002587A patent/KR102075364B1/ko active Active
- 2012-06-29 PT PT12733067T patent/PT2866581T/pt unknown
- 2012-06-29 DK DK12733067.8T patent/DK2866581T3/da active
- 2012-06-29 ES ES12733067.8T patent/ES2691701T3/es active Active
- 2012-06-29 WO PCT/EP2012/062715 patent/WO2014000813A1/de not_active Ceased
- 2012-06-29 BR BR112014032619-3A patent/BR112014032619B1/pt active IP Right Grant
- 2012-06-29 CN CN201280074285.2A patent/CN104427885A/zh active Pending
- 2012-06-29 UA UAA201500653A patent/UA113655C2/uk unknown
- 2012-06-29 US US14/410,507 patent/US20150368370A1/en not_active Abandoned
-
2019
- 2019-04-01 US US16/371,322 patent/US11155644B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2866581A1 (de) | 2015-05-06 |
| RU2602282C2 (ru) | 2016-11-20 |
| US20150368370A1 (en) | 2015-12-24 |
| CN104427885A (zh) | 2015-03-18 |
| US11155644B2 (en) | 2021-10-26 |
| WO2014000813A1 (de) | 2014-01-03 |
| UA113655C2 (xx) | 2017-02-27 |
| PL2866581T3 (pl) | 2019-01-31 |
| JP2015521671A (ja) | 2015-07-30 |
| BR112014032619A2 (pt) | 2017-06-27 |
| RU2015102793A (ru) | 2016-08-20 |
| EP2866581B1 (de) | 2018-07-18 |
| ES2691701T3 (es) | 2018-11-28 |
| KR102075364B1 (ko) | 2020-02-10 |
| KR20150036291A (ko) | 2015-04-07 |
| JP6122108B2 (ja) | 2017-04-26 |
| PT2866581T (pt) | 2018-11-09 |
| US20200062864A1 (en) | 2020-02-27 |
| BR112014032619B1 (pt) | 2020-03-10 |
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