DK2870107T3 - Fremgangsmåde til reduktion af seksvalent chrom i oxidiske faste stoffer - Google Patents
Fremgangsmåde til reduktion af seksvalent chrom i oxidiske faste stoffer Download PDFInfo
- Publication number
- DK2870107T3 DK2870107T3 DK13734753.0T DK13734753T DK2870107T3 DK 2870107 T3 DK2870107 T3 DK 2870107T3 DK 13734753 T DK13734753 T DK 13734753T DK 2870107 T3 DK2870107 T3 DK 2870107T3
- Authority
- DK
- Denmark
- Prior art keywords
- process according
- weight
- oxidic
- solid
- oxidic solid
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 107
- 239000007787 solid Substances 0.000 title claims description 68
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 claims description 130
- 150000001875 compounds Chemical class 0.000 claims description 43
- 239000000203 mixture Substances 0.000 claims description 36
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 33
- 239000007788 liquid Substances 0.000 claims description 32
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 30
- 229910052799 carbon Inorganic materials 0.000 claims description 29
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 28
- 229910001868 water Inorganic materials 0.000 claims description 26
- 239000000292 calcium oxide Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000011651 chromium Substances 0.000 claims description 21
- 239000007795 chemical reaction product Substances 0.000 claims description 20
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 16
- 239000004568 cement Substances 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 229920001223 polyethylene glycol Polymers 0.000 claims description 12
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 11
- 239000002202 Polyethylene glycol Substances 0.000 claims description 11
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 11
- 239000004571 lime Substances 0.000 claims description 11
- 230000001681 protective effect Effects 0.000 claims description 10
- 239000004566 building material Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 6
- 239000010426 asphalt Substances 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 3
- 239000000047 product Substances 0.000 claims description 3
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical group [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims 3
- 235000011187 glycerol Nutrition 0.000 claims 3
- 238000001704 evaporation Methods 0.000 claims 1
- 230000001698 pyrogenic effect Effects 0.000 claims 1
- 238000005057 refrigeration Methods 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 41
- 230000029087 digestion Effects 0.000 description 32
- 238000006722 reduction reaction Methods 0.000 description 32
- 238000006243 chemical reaction Methods 0.000 description 18
- 239000003638 chemical reducing agent Substances 0.000 description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
- 239000002245 particle Substances 0.000 description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- PXLIDIMHPNPGMH-UHFFFAOYSA-N sodium chromate Chemical compound [Na+].[Na+].[O-][Cr]([O-])(=O)=O PXLIDIMHPNPGMH-UHFFFAOYSA-N 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 11
- 229910052804 chromium Inorganic materials 0.000 description 11
- 239000004575 stone Substances 0.000 description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 238000000926 separation method Methods 0.000 description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 description 8
- BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 description 8
- QDOXWKRWXJOMAK-UHFFFAOYSA-N chromium(III) oxide Inorganic materials O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 7
- 229930006000 Sucrose Natural products 0.000 description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 6
- 238000005299 abrasion Methods 0.000 description 6
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- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 239000012065 filter cake Substances 0.000 description 5
- -1 hydrogen sulphite ions Chemical class 0.000 description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 229910052720 vanadium Inorganic materials 0.000 description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
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- 239000002244 precipitate Substances 0.000 description 4
- 238000011946 reduction process Methods 0.000 description 4
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- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- DNWNZRZGKVWORZ-UHFFFAOYSA-N calcium oxido(dioxo)vanadium Chemical compound [Ca+2].[O-][V](=O)=O.[O-][V](=O)=O DNWNZRZGKVWORZ-UHFFFAOYSA-N 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
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- 238000010405 reoxidation reaction Methods 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- KSPIHGBHKVISFI-UHFFFAOYSA-N Diphenylcarbazide Chemical compound C=1C=CC=CC=1NNC(=O)NNC1=CC=CC=C1 KSPIHGBHKVISFI-UHFFFAOYSA-N 0.000 description 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
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- 238000009835 boiling Methods 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Inorganic materials [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 description 2
- 150000004692 metal hydroxides Chemical class 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
- 229910052756 noble gas Inorganic materials 0.000 description 2
- 150000002835 noble gases Chemical class 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000012048 reactive intermediate Substances 0.000 description 2
- 238000012958 reprocessing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
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- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910001948 sodium oxide Inorganic materials 0.000 description 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
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- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical class [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 241000906149 Leucobacter sp. Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
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- 235000011132 calcium sulphate Nutrition 0.000 description 1
- BCFSVSISUGYRMF-UHFFFAOYSA-N calcium;dioxido(dioxo)chromium;dihydrate Chemical compound O.O.[Ca+2].[O-][Cr]([O-])(=O)=O BCFSVSISUGYRMF-UHFFFAOYSA-N 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
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- 239000010459 dolomite Substances 0.000 description 1
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- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 239000013056 hazardous product Substances 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- FLTRNWIFKITPIO-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe] FLTRNWIFKITPIO-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000006213 oxygenation reaction Methods 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
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- 238000010992 reflux Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- UNHKSXOTUHOTAB-UHFFFAOYSA-N sodium;sulfane Chemical compound [Na].S UNHKSXOTUHOTAB-UHFFFAOYSA-N 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 229910052566 spinel group Inorganic materials 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000004291 sulphur dioxide Substances 0.000 description 1
- 235000010269 sulphur dioxide Nutrition 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/30—Oxides other than silica
- C04B14/308—Iron oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/30—Oxides other than silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G37/00—Compounds of chromium
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/34—Hydraulic lime cements; Roman cements ; natural cements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/44—Carbon
- C09C1/48—Carbon black
- C09C1/56—Treatment of carbon black ; Purification
- C09C1/58—Agglomerating, pelleting, or the like by wet methods
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/02—Roasting processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
- C22B7/002—Dry processes by treating with halogens, sulfur or compounds thereof; by carburising, by treating with hydrogen (hydriding)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
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Claims (19)
1. Fremgangsmåde til reduktion af seksvalent chrom i oxidiske faste stoffer indeholdende trinnene: a) sammenblanding af det oxidiske faste stof indeholdende Cr(VI) med en carbonholdig, flydende forbindelse i området fra 20 til 100 °C, b) behandling af den ifølge a) opnåede blanding under beskyttelsesatmosfære i en indirekte opvarmet reaktor ved en temperatur på 700 °C til 1.100 °C, særligt foretrukket ved en temperatur på 800 °C til 1.000 °C, c) afkøling af det ifølge b) opnåede reaktionsprodukt under beskyttelsesatmosfære til i det mindste 300 °C, fortrinsvis til i det mindste 150°C, idet der som carbonholdig forbindelse anvendes en polyhydroxyforbindelse, fortrinsvis glycerin eller en flydende polyethylenglykol, særligt foretrukket polyethylenglykol med en molarmasse på op til 600, og den carbonholdige forbindelse nedbrydes i stedet for at fordampe fortrinsvis ved temperaturer > 150 °C.
2. Fremgangsmåde ifølge krav 1, kendetegnet ved, at det anvendte oxidiske faste stof indeholder calciumoxid i en andel på mindre end 15 vægt-%, særligt foretrukket mindre end 10 vægt-% calciumoxid, ganske særligt foretrukket mindre end 5 vægt-% calciumoxid.
3. Fremgangsmåde ifølge krav 1, kendetegnet ved, at det anvendte oxidiske faste stof er en chromertsremanens.
4. Fremgangsmåde ifølge krav 1, kendetegnet ved, at der som den i trin a) nævnte carbonholdige forbindelse anvendes glycerin, polyethylenglykol med en molarmasse på 380 til 420 eller en blanding af begge i et masseforhold på 4:1 til 15:1, baseret på massen af Cr(VI).
5. Fremgangsmåde ifølge krav 1, kendetegnet ved, at carbonen i den i trin a) nævnte carbonholdige forbindelse anvendes i et molært forhold til Cr(VI) på 5 : 1 til 35 : 1.
6. Fremgangsmåde ifølge krav 1, kendetegnet ved, at der som den i trin a) nævnte carbonholdige forbindelse anvendes glycerin, polyethylenglykol med en molarmasse fra 380 til 420 eller en blanding af begge, og at carbonen i den i trin a) nævnte carbonholdige forbindelse anvendes i et molært forhold til Cr(VI) på 9 : 1 til 23 : 1.
7. Fremgangsmåde ifølge krav 1, kendetegnet ved, at trin a) foregår i et kontinuerligt arbejdende blandingsaggregat.
8. Fremgangsmåde ifølge krav 1, kendetegnet ved, at trin b) foregår i en kontinuerligt arbejdende indirekte opvarmet reaktor.
9. Fremgangsmåde ifølge krav 1, kendetegnet ved, at trin c) foregår i et kontinuerligt arbejdende køleaggregat.
10. Fremgangsmåde ifølge krav 1, kendetegnet ved, at det oxidiske faste stof anvendes i en form indeholdende vand i trin a) , fortrinsvis med et vandindhold på op til 2.0 vægt-% vand, særligt foretrukket på mindre end 1.0 vægt-% vand.
11. Fremgangsmåde ifølge krav 1, kendetegnet ved, at der til det oxidiske faste stof i trin a) ud over den carbonholdige forbindelse tilsættes andre hjælpemidler til forarbejdeligheden af den fremstillede blanding, fortrinsvis pyrogen kiselsyre, silikater, aluminater og alumosilikater.
12. Fremgangsmåde ifølge krav 1, kendetegnet ved, at det oxidiske faste stof indeholder op til 80.000 ppm, særligt foretrukket op til 50.000 ppm, Cr(VI).
13. Fremgangsmåde ifølge krav 3, kendetegnet ved, at chromertsremanensen indeholder op til 10.000 ppm Cr(VI).
14. Fremgangsmåde ifølge krav 3, kendetegnet ved, at der anvendes en blanding af chromertsremanens og øvrig remanens, fortrinsvis vanadat-holdig, idet blandingen indeholder op til 20.000 ppm Cr(VI).
15. Fremgangsmåde ifølge krav 1, kendetegnet ved, at fremgangsmådeproduktet har et Cr(VI)-indhold < 640 ppb, fortrinsvis på < 107 ppb.
16. Reduceret oxidisk fast stof fremstillet ifølge et af kravene 1 til 15.
17. Reduceret, oxidisk fast stof ifølge krav 16, kendetegnet ved, at det oxidiske fast stof indeholder calciumoxid i en andel på mindre end 15 vægt-%, fortrinsvis mindre end 10 vægt-% calciumoxid, særligt foretrukket mindre end 5 vægt-% calciumoxid.
18. Anvendelse af det reducerede oxidiske faste stof ifølge et af kravene 16 eller 17 som fyldstof ved fremstillingen af kalk- og/eller cementbundne byggematerialer og/eller af asfalt.
19. Kalk- eller cementbundne byggematerialer eller asfalt indeholdende det reducerede oxidiske faste stof ifølge krav 16 eller 17.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12175378.4A EP2682370A1 (de) | 2012-07-06 | 2012-07-06 | Verfahren zur Reduktion von sechswertigem Chrom in oxidischen Feststoffen |
| EP13155203 | 2013-02-14 | ||
| PCT/EP2013/064292 WO2014006196A1 (de) | 2012-07-06 | 2013-07-05 | Verfahren zur reduktion von sechswertigem chrom in oxidischen feststoffen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2870107T3 true DK2870107T3 (da) | 2018-04-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK13734753.0T DK2870107T3 (da) | 2012-07-06 | 2013-07-05 | Fremgangsmåde til reduktion af seksvalent chrom i oxidiske faste stoffer |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US9725364B2 (da) |
| EP (1) | EP2870107B1 (da) |
| CN (1) | CN104487388B (da) |
| AR (1) | AR091681A1 (da) |
| DK (1) | DK2870107T3 (da) |
| ES (1) | ES2663683T3 (da) |
| HR (1) | HRP20180577T1 (da) |
| HU (1) | HUE036505T2 (da) |
| IN (1) | IN2014DN10774A (da) |
| LT (1) | LT2870107T (da) |
| NO (1) | NO2870107T3 (da) |
| PL (1) | PL2870107T3 (da) |
| PT (1) | PT2870107T (da) |
| RU (1) | RU2646085C2 (da) |
| SI (1) | SI2870107T1 (da) |
| WO (1) | WO2014006196A1 (da) |
| ZA (1) | ZA201500849B (da) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2918564A1 (de) | 2014-03-13 | 2015-09-16 | LANXESS Deutschland GmbH | Feuerfeste Materialien enthaltend einen Mischkristall mit Spinell-Struktur |
| EP3020690A1 (de) * | 2014-11-13 | 2016-05-18 | LANXESS Deutschland GmbH | Verfahren zur Reduktion von sechswertigem Chrom in oxidischen Feststoffen |
| EP3601625B1 (en) | 2017-03-21 | 2021-05-19 | Brother Group (Hong Kong) Limited | Process for preparing iron- and chrome-containing particles |
| EP3628753B1 (en) | 2018-09-26 | 2022-05-04 | Brother Group (Hong Kong) Limited | Process for preparing iron- and chrome-containing pellets |
| EP3760748B1 (en) | 2019-07-02 | 2023-09-20 | Brother Group (Hong Kong) Limited | Process for preparing optimized calcined, iron- and chrome-containing pellets |
| EP3763837A1 (de) | 2019-07-09 | 2021-01-13 | Brother Group (Hong Kong) Limited | Formgebung von chromerzprozess-rückständen |
| EP4025724A1 (fr) * | 2019-09-06 | 2022-07-13 | Aperam | Procédé de récupération du chrome contenu dans un bain de décapage de matériaux métalliques et installation pour sa mise en oeuvre |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5025915B1 (da) * | 1971-02-16 | 1975-08-27 | ||
| JPS6038341B2 (ja) * | 1981-02-13 | 1985-08-31 | 工業技術院長 | 六価クロムの還元方法 |
| DE3518555C1 (de) | 1985-05-23 | 1986-01-09 | Fried. Krupp Gmbh, 4300 Essen | Verfahren zur Reduktion von eisenhaltigen Chromerzen |
| IT1262918B (it) * | 1992-01-21 | 1996-07-22 | Procedimento ed impianto per la riduzione del cromo esavalente contenuto nei residui della lavorazione dei minerali di cromo | |
| RU2083497C1 (ru) * | 1995-01-17 | 1997-07-10 | Акционерное общество открытого типа "Хромпик" | Способ переработки шлама хроматного производства |
| DE19502814A1 (de) * | 1995-01-30 | 1996-08-01 | Starck H C Gmbh Co Kg | Verfahren zur Sanierung von Böden und Altlasten |
| TW477818B (en) * | 1997-03-27 | 2002-03-01 | Kawasaki Steel Co | Method for processing chromium oxide-containing substances in large quantities, method for utilizing the processed substances, and products comprising the processed substances |
| JP4307849B2 (ja) | 2003-01-07 | 2009-08-05 | 株式会社神戸製鋼所 | クロム含有原料の還元方法 |
| US6872247B1 (en) * | 2003-10-07 | 2005-03-29 | W. R. Grace & Co.-Conn. | Amine-based, hexavalent chromium reducing agents for cement |
| RU2368680C2 (ru) | 2003-10-31 | 2009-09-27 | ЭНСТИТЮ НАСЬОНАЛЬ ЭНТЕРЮНИВЕРСИТЭР ДЕ СИЛИКАТ, СОЛЬ Э МАТЕРЬЕ (И.Н.И.С.Ма)а.с.б.л. | Способ обезвреживания материала, содержащего шестивалентный хром |
| AU2004297504B9 (en) * | 2003-11-21 | 2010-06-03 | W.R. Grace & Co.-Conn. | Sulfate dispersion chromate reducer |
| US7232483B2 (en) * | 2005-02-01 | 2007-06-19 | W. R. Grace & Co.-Conn. | Cement composition having chromium reducer |
| FR2884509B1 (fr) * | 2005-04-18 | 2007-07-06 | Chryso Soc Par Actions Simplif | Adjuvant pour reduire les ions chrome (vi) en chrome (iii) |
| CN100999335A (zh) | 2006-01-09 | 2007-07-18 | 中国科学院过程工程研究所 | 一种采用水热还原铬酸盐制备氧化铬粉体的方法 |
| EP1992595A1 (en) * | 2007-05-10 | 2008-11-19 | Lafarge | Process to reduce the amount of Cr (VI) in a cement-containing composition and a composition comprising cement and coated metallic sulphate particles |
| CN102107205A (zh) * | 2009-12-23 | 2011-06-29 | 湖南布鲁斯凯环保科技发展有限公司 | 一种铬渣无害化处理方法 |
| CN102502916B (zh) * | 2011-10-28 | 2014-02-26 | 中国科学院过程工程研究所 | 一种光还原六价铬的方法 |
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- 2013-07-05 RU RU2015103809A patent/RU2646085C2/ru active
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- 2013-07-05 WO PCT/EP2013/064292 patent/WO2014006196A1/de not_active Ceased
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Also Published As
| Publication number | Publication date |
|---|---|
| PL2870107T3 (pl) | 2018-06-29 |
| SI2870107T1 (en) | 2018-05-31 |
| CN104487388B (zh) | 2017-04-12 |
| RU2646085C2 (ru) | 2018-03-01 |
| EP2870107A1 (de) | 2015-05-13 |
| IN2014DN10774A (da) | 2015-09-04 |
| US20150166411A1 (en) | 2015-06-18 |
| CN104487388A (zh) | 2015-04-01 |
| LT2870107T (lt) | 2018-05-10 |
| HRP20180577T1 (hr) | 2018-05-18 |
| WO2014006196A1 (de) | 2014-01-09 |
| ES2663683T3 (es) | 2018-04-16 |
| US9725364B2 (en) | 2017-08-08 |
| PT2870107T (pt) | 2018-03-28 |
| NO2870107T3 (da) | 2018-06-16 |
| ZA201500849B (en) | 2017-03-29 |
| AR091681A1 (es) | 2015-02-18 |
| RU2015103809A (ru) | 2016-08-27 |
| HUE036505T2 (hu) | 2018-07-30 |
| EP2870107B1 (de) | 2018-01-17 |
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