DK3094708T3 - Flydende biobrændstoffer - Google Patents

Flydende biobrændstoffer Download PDF

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Publication number
DK3094708T3
DK3094708T3 DK15735308.7T DK15735308T DK3094708T3 DK 3094708 T3 DK3094708 T3 DK 3094708T3 DK 15735308 T DK15735308 T DK 15735308T DK 3094708 T3 DK3094708 T3 DK 3094708T3
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DK
Denmark
Prior art keywords
bio
oil
fuel
biomass
pyrolysis
Prior art date
Application number
DK15735308.7T
Other languages
English (en)
Inventor
Corredores Maria Magdalena Ramirez
Vicente Sanchez
Lorenz J Bauer
Original Assignee
Inaeris Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US14/153,830 external-priority patent/US9617489B2/en
Application filed by Inaeris Tech Llc filed Critical Inaeris Tech Llc
Application granted granted Critical
Publication of DK3094708T3 publication Critical patent/DK3094708T3/da

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/008—Incineration of waste; Incinerator constructions; Details, accessories or control therefor adapted for burning two or more kinds, e.g. liquid and solid, of waste being fed through separate inlets
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/10—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of field or garden waste or biomasses
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
    • C10B49/22—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/14—Function and purpose of a components of a fuel or the composition as a whole for improving storage or transport of the fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/02—Combustion or pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/12—Regeneration of a solvent, catalyst, adsorbent or any other component used to treat or prepare a fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00—Special features of, or arrangements for incinerators
    • F23G2900/50205—Waste pre-treatment by pyrolysis, gasification or cracking followed by condensation of gas into combustible oil or fat
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/12—Heat utilisation in combustion or incineration of waste
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Sustainable Energy (AREA)
  • Wood Science & Technology (AREA)
  • Sustainable Development (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Claims (11)

1. Flydende biobrændstof, omfattende: 50 til 95 vægtprocent oxygenerede car-bonhydrider; 5 til 50 vægtprocent ikke-oxygenerede carbonhydrider; ikke mere end 15 vægtprocent vand; og ikke mere end 2.500 ppmw faststoffer, hvor det flydende biobrændstof har en tændingstemperatur i området 175 til 300 °C og en højere varmeværdi på mindst 20.934 kJ/kg (9,000 btu/lb).
2. Flydende biobrændstof ifølge krav 1 med en stabilitetsparameter på ikke mere end 0,02 Pa-s/h (20 cp/h), et oxygenindhold på ikke mere end 20 vægtprocent, et totalt syretal på ikke mere end 90 mg KOH/g, et indhold af hårde faststoffer på ikke mere end 1.000 ppmw og en viskositet ved 40 °C på ikke mere end 0,125 Pa-s (125 cps).
3. Flydende biobrændstof ifølge et hvilket som helst af kravene 1 - 2 med et indhold af aromatiske forbindelser på mindst 40 vægtprocent baseret på den samlede vægt af de ikke-oxygenerede carbonhydrider og et phenolindhold på ikke mere end 80 vægtprocent baseret på den samlede vægt af de oxygenerede carbonhydrider.
4. Flydende biobrændstof ifølge et hvilket som helst af kravene 1 - 3 med et 10 %-kogepunkt i området 160 til 420 °C, et 50 %-kogepunkt i området 340 til 520 °C, og et 90 %-kogepunkt i området 620 til 940 °C.
5. Flydende biobrændstof ifølge et hvilket som helst af kravene 1 - 4 med en vægtfylde i området 0,75 til 1,1, et flammepunkt i området 40 til 120 °C, et calciumindhold på ikke mere end 5.000 ppmw, et kaliumindhold på ikke mere end 5.000 ppmw og et natriumindhold på ikke mere end 1.000 ppmw.
6. Flydende biobrændstof ifølge et hvilket som helst af kravene 1 - 5, omfattende 75 til 90 vægtprocent af de oxygenerede carbonhydrider; 10 til 25 vægtprocent af de ikke-oxygenerede carbonhydrider; i området 2 til 10 vægtprocent vand; og ikke mere end 500 ppmw af faststofferne, hvor tændingstemperaturen er i området 210 til 265 °C, og den højere varmeværdi er i området 24.423 til 31.401 kJ/kg (10.500 til 13.500 btu/lb).
7. Flydende biobrændstof ifølge et hvilket som helst af kravene 1 - 6, hvor det flydende biobrændstof er fremstillet via pyrolyse af biomasse.
8. Flydende biobrændstof ifølge krav 7, hvor pyrolysen er flashpyrolyse, og biomassen omfatter lignocellulosisk biomasse.
9. Fremgangsmåde til betjening af en brændstofdrevet indretning, hvilken fremgangsmåde omfatter: (a) forbrænding af petroleumafledt brændstof i en brændstofdrevet indretning, således at der derved frembringes termisk og/eller mekanisk energi; og (b) forbrænding af det flydende biobrændstof ifølge et hvilket som helst af kravene 1 -8 i den brændstofdrevne indretning, således at der derved frembringes termisk og/eller mekanisk energi, hvor den brændstofdrevne indretning ikke er mekanisk modificeret til at tage højde for brændstofændringen mellem trin (a) og (b), hvor det flydende biobrændstof fremstilles via pyrolyse af biomasse.
10. Fremgangsmåde ifølge krav 9, hvor den brændstofdrevne indretning er en kedel, en turbine, en forbrændingsmotor eller et termisk oxideringsmiddel, hvor det petroleumafledte brændstof er fyringsolie.
11. Fremgangsmåde ifølge et hvilket som helst af kravene 9-10, hvor varme-værdierne, vægtfylderne, tændingstemperaturerne og flammepunkterne af det flydende biobrændstof og det petroleumafledte brændstof er inden for 10 % i forhold til hinanden.
DK15735308.7T 2014-01-13 2015-01-02 Flydende biobrændstoffer DK3094708T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/153,830 US9617489B2 (en) 2011-02-11 2014-01-13 Liquid bio-fuels
PCT/US2015/010056 WO2015105732A1 (en) 2014-01-13 2015-01-02 Liquid bio-fuels

Publications (1)

Publication Number Publication Date
DK3094708T3 true DK3094708T3 (da) 2018-12-03

Family

ID=53524266

Family Applications (1)

Application Number Title Priority Date Filing Date
DK15735308.7T DK3094708T3 (da) 2014-01-13 2015-01-02 Flydende biobrændstoffer

Country Status (4)

Country Link
EP (1) EP3094708B1 (da)
CA (1) CA2936390A1 (da)
DK (1) DK3094708T3 (da)
WO (1) WO2015105732A1 (da)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT201600111822A1 (it) * 2016-11-07 2018-05-07 Reset S R L Impianto di cogenerazione a biomassa legnosa per la produzione in continuo di calore ed elettricità.
SE546793C2 (en) * 2022-12-19 2025-02-18 Votion Biorefineries Ab A method for the production of bio-oil
SE546792C2 (en) * 2022-12-19 2025-02-18 Votion Biorefineries Ab Method for base-catalyzed liquefaction of biomass with subsequent removal of salts and metals
SE548066C2 (en) * 2022-12-19 2026-02-17 Votion Biorefineries Ab A method for the production of lignin oil
SE546791C2 (en) * 2022-12-19 2025-02-18 Votion Biorefineries Ab A method for preparation of bark oil with subsequent removal of salts and inorganic compounds
WO2024217699A1 (en) * 2023-04-21 2024-10-24 Btg Bioliquids B.V. Pyrolysis oil with reduced total acid number (value)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE45413E1 (en) * 2005-11-26 2015-03-17 Exen Holdings, Llc Multi fuel co-injection system for internal combustion and turbine engines
US8545581B2 (en) * 2007-08-01 2013-10-01 Virginia Tech Intellectual Properties, Inc. Production of stable biomass pyrolysis oils using fractional catalytic pyrolysis
US8628589B2 (en) * 2011-02-11 2014-01-14 Kior, Inc. Renewable heating oil
US8669405B2 (en) * 2011-02-11 2014-03-11 Kior, Inc. Stable bio-oil
US8822745B2 (en) * 2011-12-06 2014-09-02 Phillips 66 Company Pyrolysis oil upgrading to gasoline range liquids

Also Published As

Publication number Publication date
EP3094708B1 (en) 2018-10-17
CA2936390A1 (en) 2015-07-16
EP3094708A1 (en) 2016-11-23
WO2015105732A1 (en) 2015-07-16
EP3094708A4 (en) 2017-09-27

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