DK3411332T3 - Fremgangsmåde til direkte syntese af jernholdig aei-zeolitkatalysator - Google Patents

Fremgangsmåde til direkte syntese af jernholdig aei-zeolitkatalysator Download PDF

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Publication number
DK3411332T3
DK3411332T3 DK17702840.4T DK17702840T DK3411332T3 DK 3411332 T3 DK3411332 T3 DK 3411332T3 DK 17702840 T DK17702840 T DK 17702840T DK 3411332 T3 DK3411332 T3 DK 3411332T3
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Denmark
Prior art keywords
procedure
zeolite catalyst
direct synthesis
iron aid
iron
Prior art date
Application number
DK17702840.4T
Other languages
English (en)
Inventor
García Nuria Martín
Canós Avelino Corma
Marín Manuel Moliner
Joakim Reimer Thøgersen
Peter Nicolai Ravnborg Vennestrøm
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Umicore Ag & Co Kg
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Publication of DK3411332T3 publication Critical patent/DK3411332T3/da

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0246Coatings comprising a zeolite
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026After-treatment
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/202Alkali metals
    • B01D2255/2027Sodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20738Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
    • B01J29/7615Zeolite Beta
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
    • B01J29/763CHA-type, e.g. Chabazite, LZ-218
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/60Compounds characterised by their crystallite size
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
DK17702840.4T 2016-02-01 2017-01-30 Fremgangsmåde til direkte syntese af jernholdig aei-zeolitkatalysator DK3411332T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA201670053 2016-02-01
PCT/EP2017/051912 WO2017134006A1 (en) 2016-02-01 2017-01-30 Method for the direct synthesis of iron-containing aei-zeolite catalyst

Publications (1)

Publication Number Publication Date
DK3411332T3 true DK3411332T3 (da) 2021-05-17

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
DK17702840.4T DK3411332T3 (da) 2016-02-01 2017-01-30 Fremgangsmåde til direkte syntese af jernholdig aei-zeolitkatalysator

Country Status (7)

Country Link
US (1) US20180346341A1 (da)
EP (1) EP3411332B1 (da)
JP (1) JP6951343B2 (da)
KR (1) KR102688876B1 (da)
CN (1) CN109071245B (da)
DK (1) DK3411332T3 (da)
WO (1) WO2017134006A1 (da)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6987766B2 (ja) * 2016-02-01 2022-01-05 ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフトUmicore AG & Co.KG アルカリ金属を本質的に含まないfe−aeiゼオライト材料を含むscr触媒の存在下での選択触媒還元による排気ガスからの窒素酸化物の除去方法
WO2018064276A1 (en) * 2016-09-30 2018-04-05 Johnson Matthey Public Limited Company Novel synthesis of metal promoted zeolite catalyst
US12239965B2 (en) 2018-11-16 2025-03-04 Basf Se Process for the production of a zeolitic material having an AEI-type framework structure via solvent-free interzeolitic conversion
WO2021064483A1 (en) * 2019-10-02 2021-04-08 Chevron U.S.A. Inc. Small crystal ssz-27, its synthesis and use
JP7404765B2 (ja) * 2019-10-21 2023-12-26 東ソー株式会社 ゼオライト製造用アルミノシリケート
KR20210087743A (ko) * 2020-01-03 2021-07-13 현대자동차주식회사 촉매 및 촉매의 제조 방법
CN113371726A (zh) * 2021-06-25 2021-09-10 复旦大学 一种功能沸石分子筛材料及其制备方法
DE102022130469A1 (de) 2022-11-17 2024-05-23 Umicore Ag & Co. Kg Verfahren und Vorrichtung zum Herstellen eines Substrats für eine Abgasnachbehandlungseinrichtung
CN115924967B (zh) * 2023-03-08 2023-05-16 国能龙源环保有限公司 利用钛渣制备钛白粉的方法及其钛白粉
CN116328827B (zh) * 2023-03-30 2024-07-26 黄冈师范学院 金属负载分子筛的制备及作为氧化亚氮分解催化剂的应用
DE102023117464A1 (de) 2023-07-03 2025-01-09 Umicore Ag & Co. Kg Verfahren und Vorrichtung zum Herstellen eines Substrats für eine Abgasnachbehandlungseinrichtung
DE102023132075A1 (de) 2023-11-17 2025-05-22 Umicore Ag & Co. Kg Katalytischer Partikelfilter
CN121247835B (zh) * 2025-12-04 2026-03-10 吉林大学 一种ssz-39分子筛及金属复合ssz-39催化剂的制备方法

Family Cites Families (12)

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EP1701915B1 (en) * 2003-12-23 2012-10-17 ExxonMobil Chemical Patents Inc. Aei-type zeolite and its use in the conversion of oxygenates to olefins
WO2006039213A1 (en) * 2004-09-30 2006-04-13 Chevron U.S.A. Inc. Molecular sieve ssz-65
JP5777339B2 (ja) * 2007-04-26 2015-09-09 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Publiclimited Company 遷移金属/ゼオライトscr触媒
JP6176891B2 (ja) * 2007-08-13 2017-08-09 ピーキュー コーポレイション 新規鉄含有アルミノケイ酸塩ゼオライト、ならびにその作製方法および使用方法
CN106276952A (zh) * 2009-11-24 2017-01-04 巴斯夫欧洲公司 制备具有cha结构的沸石的方法
WO2013082560A1 (en) * 2011-12-02 2013-06-06 Pq Corporation Stabilized microporous crystalline material, the method of making the same, and the use for selective catalytic reduction of nox
IN2015DN02842A (da) * 2012-12-12 2015-09-11 Haldor Topsoe As
WO2014141200A1 (en) * 2013-03-15 2014-09-18 Johnson Matthey Public Limited Company Catalyst for treating exhaust gas
RU2744763C2 (ru) * 2013-12-02 2021-03-15 Джонсон Мэтти Паблик Лимитед Компани Синтез цеолита aei
US10850265B2 (en) * 2014-06-18 2020-12-01 Basf Corporation Molecular sieve catalyst compositions, catalytic composites, systems, and methods
EP3222583A4 (en) * 2014-11-21 2018-04-11 Mitsubishi Chemical Corporation Aei type zeolite, method for prodcuing same, and uses thereof
ES2586770B1 (es) * 2015-04-16 2017-08-14 Consejo Superior De Investigaciones Científicas (Csic) Método de síntesis directa del material cu-silicoaluminato con la estructura zeolítica aei, y sus aplicaciones catalíticas

Also Published As

Publication number Publication date
KR102688876B1 (ko) 2024-07-29
JP6951343B2 (ja) 2021-10-20
JP2019503327A (ja) 2019-02-07
EP3411332B1 (en) 2021-03-10
WO2017134006A1 (en) 2017-08-10
US20180346341A1 (en) 2018-12-06
CN109071245A (zh) 2018-12-21
EP3411332A1 (en) 2018-12-12
KR20180111908A (ko) 2018-10-11
CN109071245B (zh) 2022-03-04

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