DK3509745T3 - Katalysatorsammensætning omfattende modificeret krystallinsk aluminosilikat til dehydrering af alkoholer - Google Patents

Katalysatorsammensætning omfattende modificeret krystallinsk aluminosilikat til dehydrering af alkoholer Download PDF

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Publication number
DK3509745T3
DK3509745T3 DK17761276.9T DK17761276T DK3509745T3 DK 3509745 T3 DK3509745 T3 DK 3509745T3 DK 17761276 T DK17761276 T DK 17761276T DK 3509745 T3 DK3509745 T3 DK 3509745T3
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Prior art keywords
crystallinic
aluminosilicate
dehydration
alcohols
catalyst composition
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DK17761276.9T
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English (en)
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Nikolai Nesterenko
Colin Dupont
Thibault Heinz
Sylvie Maury
Vincent Coupard
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Total Res & Technology Feluy
Ifp Energies Now
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7023—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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    • B01J29/7026—MFS-type, e.g. ZSM-57
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J29/703—MRE-type, e.g. ZSM-48
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/7042—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7046—MTT-type, e.g. ZSM-23, KZ-1, ISI-4 or EU-13
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/19—Catalysts containing parts with different compositions
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    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
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    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
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    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/12—Oxidising
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    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
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    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
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    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
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    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
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    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J2029/081—Increasing the silica/alumina ratio; Desalumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2235/05—Nuclear magnetic resonance [NMR]
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    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
DK17761276.9T 2016-09-09 2017-09-06 Katalysatorsammensætning omfattende modificeret krystallinsk aluminosilikat til dehydrering af alkoholer DK3509745T3 (da)

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EP16290172 2016-09-09
PCT/EP2017/072297 WO2018046516A1 (en) 2016-09-09 2017-09-06 Catalyst composition comprising modified crystalline aluminosilicate for dehydration of alcohols

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US (3) US10899682B2 (da)
EP (2) EP3509746B1 (da)
CN (1) CN109890503B (da)
BR (1) BR112019004601B1 (da)
DK (1) DK3509745T3 (da)
ES (2) ES2819698T3 (da)
UA (1) UA123237C2 (da)
WO (2) WO2018046516A1 (da)

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WO2018046516A1 (en) * 2016-09-09 2018-03-15 Total Research & Technology Feluy Catalyst composition comprising modified crystalline aluminosilicate for dehydration of alcohols
CN111253199B (zh) * 2018-11-30 2021-11-02 中国科学院大连化学物理研究所 一种乙醇脱水制乙烯的方法
FR3089973B1 (fr) 2018-12-14 2020-12-25 Ifp Energies Now Procédé de déshydratation de l'éthanol en éthylène à basse consommation énergétique
FR3114590B1 (fr) 2020-09-25 2022-09-09 Ifp Energies Now Procédé de deshydrogenation de l’éthanol en reacteur multitubulaire
CN112357933A (zh) * 2020-11-12 2021-02-12 重庆大学 一种利用钢铁渣矿化co2联产can型沸石的方法
FR3131306A1 (fr) 2021-12-23 2023-06-30 IFP Energies Nouvelles Procédé de deshydrogenation de l’éthanol avec élimination de l’hydrogene et intégration thermique
US20250059448A1 (en) * 2023-08-17 2025-02-20 ExxonMobil Technology and Engineering Company Intensified reactor and process heat integration for conversion of alcohol to fuels

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WO2018046516A1 (en) * 2016-09-09 2018-03-15 Total Research & Technology Feluy Catalyst composition comprising modified crystalline aluminosilicate for dehydration of alcohols

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CN109890503B (zh) 2022-03-29
EP3509746A1 (en) 2019-07-17
ES2819698T3 (es) 2021-04-19
US20210101850A1 (en) 2021-04-08
US20190233348A1 (en) 2019-08-01
WO2018046515A1 (en) 2018-03-15
EP3509745B1 (en) 2020-05-13
US20190194090A1 (en) 2019-06-27
BR112019004601A2 (pt) 2019-06-11
UA123237C2 (uk) 2021-03-03
ES2805084T3 (es) 2021-02-10
EP3509746B1 (en) 2020-07-29
US10899682B2 (en) 2021-01-26
US10851028B2 (en) 2020-12-01
EP3509745A1 (en) 2019-07-17
US11584698B2 (en) 2023-02-21
BR112019004601B1 (pt) 2022-08-02
WO2018046516A1 (en) 2018-03-15

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