EA201190238A1 - Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и с получением электрического тока и водорода - Google Patents

Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и с получением электрического тока и водорода

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EA201190238A1
EA201190238A1 EA201190238A EA201190238A EA201190238A1 EA 201190238 A1 EA201190238 A1 EA 201190238A1 EA 201190238 A EA201190238 A EA 201190238A EA 201190238 A EA201190238 A EA 201190238A EA 201190238 A1 EA201190238 A1 EA 201190238A1
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hydrogen
membrane
aromatic hydrocarbons
catalyst
electric current
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EA201190238A
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EA020383B1 (ru
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Жоана Кельхо Тсоу
Александр Панченко
Аннебарт Энгберт Вентинк
Зебастиан Аренс
Томас Хайдеманн
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Басф Се
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Abstract

Данное изобретение относится к способу превращения алифатических углеводородов, содержащих 1-4 С-атома, в ароматические углеводороды, включающему следующие стадии: a) превращение исходного потока Е, содержащего как минимум один алифатический углеводород с 1-4 С-атомами, в присутствии катализатора при неокислительных условиях в продуктный поток Р, содержащий ароматические углеводороды и водород, и b) электрохимическое отделение как минимум части водорода, образовавшегося при превращении, из продуктного потока Р с помощью не пропускающего газ ансамбля мембрана-электрод, который включает как минимум одну селективную мембрану, проводящую (пропускающую) протон, и на каждой стороне мембраны как минимум один электродный катализатор, причем на удерживающей стороне мембраны как минимум часть водорода на анодном катализаторе окисляется в протоны, и протоны после пересечения мембраны на пропускающей стороне на катоде катализатора в соответствии с b1) в результате приложения напряжения частично восстанавливаются в водород и частично в соответствии с b2) подвергают взаимодействию с кислородом с образованием воды и созданием электрического тока, причем источником кислорода служит содержащий кислород поток О, который приводится в контакт с пропускающей стороной мембраны.
EA201190238A 2009-04-06 2010-03-30 Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и с получением электрического тока и водорода EA020383B1 (ru)

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EP09157397 2009-04-06
PCT/EP2010/054155 WO2010115768A1 (de) 2009-04-06 2010-03-30 Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff unter erzeugung von elektrischem strom und wasserstoff

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EA201190238A1 true EA201190238A1 (ru) 2012-04-30
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EA (1) EA020383B1 (ru)
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JP5393872B2 (ja) * 2009-04-06 2014-01-22 ビーエーエスエフ ソシエタス・ヨーロピア 反応混合物から水素を電気化学的に分離する方法
CN102365252B (zh) * 2009-04-06 2014-07-16 巴斯夫欧洲公司 使天然气反应成芳族化合物同时电化学除去氢气并使氢气电化学反应成水的方法
PL2417059T3 (pl) * 2009-04-06 2015-05-29 Basf Se Sposób przeprowadzania gazu ziemnego w węglowodory aromatyczne z elektrochemicznym wydzielaniem wodoru

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US8487152B2 (en) 2013-07-16
JP2012522821A (ja) 2012-09-27
EP2417084B1 (de) 2014-11-26
CN102365251B (zh) 2014-01-22
KR20120027136A (ko) 2012-03-21
ES2529554T3 (es) 2015-02-23
CN102365251A (zh) 2012-02-29
EP2417084A1 (de) 2012-02-15
JP5415610B2 (ja) 2014-02-12
WO2010115768A1 (de) 2010-10-14
PL2417084T3 (pl) 2015-04-30
EA020383B1 (ru) 2014-10-30

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