EA201190238A1 - Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и с получением электрического тока и водорода - Google Patents

Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и с получением электрического тока и водорода

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EA201190238A1
EA201190238A1 EA201190238A EA201190238A EA201190238A1 EA 201190238 A1 EA201190238 A1 EA 201190238A1 EA 201190238 A EA201190238 A EA 201190238A EA 201190238 A EA201190238 A EA 201190238A EA 201190238 A1 EA201190238 A1 EA 201190238A1
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hydrogen
membrane
aromatic hydrocarbons
catalyst
electric current
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Жоана Кельхо Тсоу
Александр Панченко
Аннебарт Энгберт Вентинк
Зебастиан Аренс
Томас Хайдеманн
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Басф Се
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Abstract

Данное изобретение относится к способу превращения алифатических углеводородов, содержащих 1-4 С-атома, в ароматические углеводороды, включающему следующие стадии: a) превращение исходного потока Е, содержащего как минимум один алифатический углеводород с 1-4 С-атомами, в присутствии катализатора при неокислительных условиях в продуктный поток Р, содержащий ароматические углеводороды и водород, и b) электрохимическое отделение как минимум части водорода, образовавшегося при превращении, из продуктного потока Р с помощью не пропускающего газ ансамбля мембрана-электрод, который включает как минимум одну селективную мембрану, проводящую (пропускающую) протон, и на каждой стороне мембраны как минимум один электродный катализатор, причем на удерживающей стороне мембраны как минимум часть водорода на анодном катализаторе окисляется в протоны, и протоны после пересечения мембраны на пропускающей стороне на катоде катализатора в соответствии с b1) в результате приложения напряжения частично восстанавливаются в водород и частично в соответствии с b2) подвергают взаимодействию с кислородом с образованием воды и созданием электрического тока, причем источником кислорода служит содержащий кислород поток О, который приводится в контакт с пропускающей стороной мембраны.
EA201190238A 2009-04-06 2010-03-30 Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и с получением электрического тока и водорода EA020383B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09157397 2009-04-06
PCT/EP2010/054155 WO2010115768A1 (de) 2009-04-06 2010-03-30 Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff unter erzeugung von elektrischem strom und wasserstoff

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EA201190238A1 true EA201190238A1 (ru) 2012-04-30
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US (1) US8487152B2 (ru)
EP (1) EP2417084B1 (ru)
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CN (1) CN102365251B (ru)
EA (1) EA020383B1 (ru)
ES (1) ES2529554T3 (ru)
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JP2011526328A (ja) 2008-06-30 2011-10-06 ビーエーエスエフ ソシエタス・ヨーロピア 炭化水素の電気化学的直接アミノ化法
PL2417058T5 (pl) * 2009-04-06 2021-12-13 Basf Se Sposób elektrochemicznego oddzielania wodoru z mieszaniny reakcyjnej
KR20120022756A (ko) * 2009-04-06 2012-03-12 바스프 에스이 수소를 전기화학적으로 제거하고 그 수소를 전기화학적으로 물로 전환시키면서 천연 가스를 방향족화합물로 전환시키는 방법
EP2417059B1 (de) * 2009-04-06 2014-12-10 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff

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JP2012522821A (ja) 2012-09-27
CN102365251A (zh) 2012-02-29
US8487152B2 (en) 2013-07-16
JP5415610B2 (ja) 2014-02-12
KR20120027136A (ko) 2012-03-21
WO2010115768A1 (de) 2010-10-14
PL2417084T3 (pl) 2015-04-30
EP2417084A1 (de) 2012-02-15
US20110303550A1 (en) 2011-12-15
EA020383B1 (ru) 2014-10-30
EP2417084B1 (de) 2014-11-26
CN102365251B (zh) 2014-01-22

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