EA201400204A1 - Полимерные диспергаторы с улучшенной температурной стабильностью - Google Patents
Полимерные диспергаторы с улучшенной температурной стабильностьюInfo
- Publication number
- EA201400204A1 EA201400204A1 EA201400204A EA201400204A EA201400204A1 EA 201400204 A1 EA201400204 A1 EA 201400204A1 EA 201400204 A EA201400204 A EA 201400204A EA 201400204 A EA201400204 A EA 201400204A EA 201400204 A1 EA201400204 A1 EA 201400204A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- polymer
- relates
- temperature stability
- improved temperature
- polymer dispersants
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title abstract 6
- 239000002270 dispersing agent Substances 0.000 title abstract 2
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 2
- 239000011707 mineral Substances 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 239000000725 suspension Substances 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 239000012634 fragment Substances 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2641—Polyacrylates; Polymethacrylates
- C04B24/2647—Polyacrylates; Polymethacrylates containing polyether side chains
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2652—Nitrogen containing polymers, e.g. polyacrylamides, polyacrylonitriles
- C04B24/2658—Nitrogen containing polymers, e.g. polyacrylamides, polyacrylonitriles containing polyether side chains
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/04—Acids; Metal salts or ammonium salts thereof
- C08F120/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
- C08G81/025—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/205—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
- C08J3/21—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0045—Polymers chosen for their physico-chemical characteristics
- C04B2103/0059—Graft (co-)polymers
- C04B2103/006—Comb polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/40—Surface-active agents, dispersants
- C04B2103/408—Dispersants
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/52—Grinding aids; Additives added during grinding
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Изобретение в целом относится к полимеру, содержащему основную углеводородную цепь, несущую карбоксильные группы и полиалкоксилированные цепи, и от 0,01 до 4 мас.% антиоксидантных фрагментов, привитых на основную цепь, относительно веса конечного полимера. Оно также относится к способу получения такого полимера, а также к добавке, используемой в качестве диспергатора суспензий минеральных частиц, содержащей такой полимер. Наконец оно относится к применению такого полимера для разжижения суспензий минеральных частиц и уменьшения водопотребности гидравлических композиций.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1157306A FR2978965B1 (fr) | 2011-08-11 | 2011-08-11 | Polymeres dispersants a stabilite thermique amelioree |
| PCT/EP2012/065581 WO2013021029A1 (fr) | 2011-08-11 | 2012-08-09 | Polymeres dispersants à stabilité thermique améliorée |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201400204A1 true EA201400204A1 (ru) | 2016-01-29 |
| EA025980B1 EA025980B1 (ru) | 2017-02-28 |
Family
ID=46642539
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201400204A EA025980B1 (ru) | 2011-08-11 | 2012-08-09 | Полимерные диспергаторы с улучшенной температурной стабильностью |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US9546111B2 (ru) |
| EP (1) | EP2742089B1 (ru) |
| JP (1) | JP6085300B2 (ru) |
| KR (1) | KR101819274B1 (ru) |
| CN (1) | CN103987760B (ru) |
| AU (1) | AU2012293597B2 (ru) |
| BR (1) | BR112014003114B1 (ru) |
| CA (1) | CA2844537C (ru) |
| CL (1) | CL2014000348A1 (ru) |
| DK (1) | DK2742089T3 (ru) |
| EA (1) | EA025980B1 (ru) |
| ES (1) | ES2554248T3 (ru) |
| FR (1) | FR2978965B1 (ru) |
| MX (1) | MX349266B (ru) |
| MY (1) | MY163322A (ru) |
| PL (1) | PL2742089T3 (ru) |
| PT (1) | PT2742089E (ru) |
| UA (1) | UA112318C2 (ru) |
| WO (1) | WO2013021029A1 (ru) |
| ZA (1) | ZA201401025B (ru) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3029524B1 (fr) | 2014-12-08 | 2018-03-02 | Coatex | Procede continu d'esterification et ou d'amidification, sans solvant organique, d'un homopolymere ou copolymere acide |
| WO2024137840A1 (en) | 2022-12-20 | 2024-06-27 | Gcp Applied Technologies Inc. | Polyacrylic acid grinding aid for enhanced cement powder flowability |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2509654C2 (de) * | 1974-03-06 | 1985-08-29 | Gerald Birmingham Scott | Verfahren zur Herstellung gegen Oxidation stabiler Polymere |
| GB2202226A (en) * | 1987-03-19 | 1988-09-21 | Gerald Scott | Bound antioxidant masterbatches |
| FR2776285B1 (fr) | 1998-03-19 | 2000-06-09 | Chryso | Dispersant hydrosoluble ou hydrodispersable pour compositions de ciment et suspensions aqueuses de particules minerales, et adjuvants contenant un tel dispersant |
| DE19843730A1 (de) * | 1998-09-24 | 2000-03-30 | Sueddeutsche Kalkstickstoff | Stabilisierte, wasserlösliche Polymerpulver auf Basis von Polyoxyalkylenglykol-Carboxylaten und Verfahren zu deren Herstellung |
| CA2575952A1 (en) * | 2004-01-21 | 2005-08-04 | University Of Massachusetts Lowell | Post-coupling synthetic approach for polymeric antioxidants |
| JP2006265478A (ja) | 2005-03-25 | 2006-10-05 | Aisin Seiki Co Ltd | 電解質材料及びその製造方法 |
| FR2900930B1 (fr) | 2006-05-12 | 2008-08-08 | Coatex Sas | Procede de fabrication de polymeres peigne par sechage puis fonctionnalisation de la chaine principale (meth)acrylique, polymeres obtenus et leurs utilisations |
| FR2926558B1 (fr) | 2008-01-17 | 2010-03-05 | Coatex Sas | Amelioration d'un procede de fabrication de polymeres peignes par ajout d'un antioxydant, polymeres obtenus et leurs applications |
| CA2770090C (fr) * | 2009-08-05 | 2017-07-25 | Lafarge | Protection d'un dispersant pendant un broyage |
-
2011
- 2011-08-11 FR FR1157306A patent/FR2978965B1/fr not_active Expired - Fee Related
-
2012
- 2012-08-09 WO PCT/EP2012/065581 patent/WO2013021029A1/fr not_active Ceased
- 2012-08-09 MX MX2014001656A patent/MX349266B/es active IP Right Grant
- 2012-08-09 EP EP12745856.0A patent/EP2742089B1/fr active Active
- 2012-08-09 JP JP2014525404A patent/JP6085300B2/ja active Active
- 2012-08-09 PT PT127458560T patent/PT2742089E/pt unknown
- 2012-08-09 PL PL12745856T patent/PL2742089T3/pl unknown
- 2012-08-09 DK DK12745856.0T patent/DK2742089T3/en active
- 2012-08-09 KR KR1020147006440A patent/KR101819274B1/ko active Active
- 2012-08-09 CN CN201280049779.5A patent/CN103987760B/zh active Active
- 2012-08-09 ES ES12745856.0T patent/ES2554248T3/es active Active
- 2012-08-09 EA EA201400204A patent/EA025980B1/ru not_active IP Right Cessation
- 2012-08-09 BR BR112014003114-2A patent/BR112014003114B1/pt not_active IP Right Cessation
- 2012-08-09 AU AU2012293597A patent/AU2012293597B2/en active Active
- 2012-08-09 MY MYPI2014000350A patent/MY163322A/en unknown
- 2012-08-09 CA CA2844537A patent/CA2844537C/fr active Active
- 2012-08-09 US US14/238,190 patent/US9546111B2/en active Active
- 2012-09-08 UA UAA201402450A patent/UA112318C2/uk unknown
-
2014
- 2014-02-10 ZA ZA2014/01025A patent/ZA201401025B/en unknown
- 2014-02-11 CL CL2014000348A patent/CL2014000348A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2978965A1 (fr) | 2013-02-15 |
| US9546111B2 (en) | 2017-01-17 |
| KR101819274B1 (ko) | 2018-01-16 |
| EP2742089A1 (fr) | 2014-06-18 |
| JP6085300B2 (ja) | 2017-02-22 |
| AU2012293597A1 (en) | 2014-03-27 |
| KR20140050721A (ko) | 2014-04-29 |
| FR2978965B1 (fr) | 2015-02-13 |
| CN103987760A (zh) | 2014-08-13 |
| BR112014003114A2 (pt) | 2017-03-14 |
| CA2844537A1 (fr) | 2013-02-14 |
| CL2014000348A1 (es) | 2014-11-03 |
| JP2014524491A (ja) | 2014-09-22 |
| ES2554248T3 (es) | 2015-12-17 |
| DK2742089T3 (en) | 2015-12-07 |
| PT2742089E (pt) | 2016-01-25 |
| UA112318C2 (uk) | 2016-08-25 |
| WO2013021029A1 (fr) | 2013-02-14 |
| EA025980B1 (ru) | 2017-02-28 |
| MY163322A (en) | 2017-09-15 |
| MX349266B (es) | 2017-07-20 |
| MX2014001656A (es) | 2014-07-30 |
| CA2844537C (fr) | 2019-04-09 |
| US20150148455A1 (en) | 2015-05-28 |
| PL2742089T3 (pl) | 2016-03-31 |
| BR112014003114B1 (pt) | 2020-10-06 |
| EP2742089B1 (fr) | 2015-10-07 |
| AU2012293597B2 (en) | 2015-12-03 |
| ZA201401025B (en) | 2021-05-26 |
| CN103987760B (zh) | 2015-08-12 |
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