EA201400499A1 - Способ переработки отходящего газа синтеза фишера-тропша - Google Patents

Способ переработки отходящего газа синтеза фишера-тропша

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Publication number
EA201400499A1
EA201400499A1 EA201400499A EA201400499A EA201400499A1 EA 201400499 A1 EA201400499 A1 EA 201400499A1 EA 201400499 A EA201400499 A EA 201400499A EA 201400499 A EA201400499 A EA 201400499A EA 201400499 A1 EA201400499 A1 EA 201400499A1
Authority
EA
Eurasian Patent Office
Prior art keywords
column
adsorbent
fischer
hydrogen
mixture
Prior art date
Application number
EA201400499A
Other languages
English (en)
Other versions
EA025157B1 (ru
Inventor
Мартен Брахт
Десмонд Эндрю Бюнгкю
Юстус Теодорус Герардус Те Браке
Ваутер Давид Ван Де Граф
Ксандер Линдерс
Виджаякумари Сивакумар Садасиван
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Publication of EA201400499A1 publication Critical patent/EA201400499A1/ru
Publication of EA025157B1 publication Critical patent/EA025157B1/ru

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/32—Purifying combustible gases containing carbon monoxide with selectively adsorptive solids, e.g. active carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/116—Molecular sieves other than zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/10—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/502—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40001—Methods relating to additional, e.g. intermediate, treatment of process gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40007—Controlling pressure or temperature swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/406—Further details for adsorption processes and devices using more than four beds
    • B01D2259/4062—Further details for adsorption processes and devices using more than four beds using six beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/414—Further details for adsorption processes and devices using different types of adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Изобретение относится к способу получения газа, содержащего по меньшей мере 80 об.% монооксида углерода, из отходящего газа синтеза Фишера-Тропша. Способ включает в себя следующие стадии: (1) подача отходящего газа синтеза Фишера-Тропша через колонку, которая содержит слой адсорбента, при высоком давлении и выпускание отходящего потока; (2) незначительное снижение давления в колонке и слое; (3) продувка колонки и слоя адсорбента метаном или смесью метана и диоксида углерода; (4) снижение давления в колонке и слое адсорбента до низкого давления; (5) продувка колонки и слоя адсорбента смесью водорода и азота; (6) создание в колонке и слое адсорбента высокого давления снова с использованием смеси водорода и азота. Полученный на стадии (3) поток продукта, который содержит по меньшей мере 80 об.% монооксида углерода, может подаваться в качестве сырья синтеза Фишера-Тропша. В предпочтительно варианте осуществления также получается газ, содержащий по меньшей мере 80 об.% водорода.
EA201400499A 2011-10-25 2012-10-25 Способ переработки отходящего газа синтеза фишера-тропша EA025157B1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11186514 2011-10-25
EP11186511 2011-10-25
PCT/EP2012/071182 WO2013060795A1 (en) 2011-10-25 2012-10-25 Method for processing fischer-tropsch off-gas

Publications (2)

Publication Number Publication Date
EA201400499A1 true EA201400499A1 (ru) 2014-10-30
EA025157B1 EA025157B1 (ru) 2016-11-30

Family

ID=47076243

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201400499A EA025157B1 (ru) 2011-10-25 2012-10-25 Способ переработки отходящего газа синтеза фишера-тропша

Country Status (7)

Country Link
US (1) US8956441B2 (ru)
EP (1) EP2771093B1 (ru)
AU (1) AU2012330384B2 (ru)
EA (1) EA025157B1 (ru)
MY (1) MY167568A (ru)
WO (1) WO2013060795A1 (ru)
ZA (1) ZA201402881B (ru)

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AU2013369184B2 (en) * 2012-12-31 2016-06-23 Shell Internationale Research Maatschappij B.V. Method for processing Fischer-Tropsch off-gas
AU2013369186B2 (en) * 2012-12-31 2016-06-23 Shell Internationale Research Maatschappij B.V. Method for processing Fischer-Tropsch off-gas
EA036089B1 (ru) * 2014-06-30 2020-09-25 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ переработки газообразной смеси
PE20171677A1 (es) * 2015-02-10 2017-11-22 Shell Int Research Metodo y sistema para obtener un gas rico en hidrogeno
MY188965A (en) * 2015-03-03 2022-01-14 Shell Int Research Method for treating off gas and producing hydrogen
JP6697014B2 (ja) * 2018-02-09 2020-05-20 Ｊｘｔｇエネルギー株式会社 圧力スイング吸着（ｐｓａ）装置及び圧力スイング吸着方法
US11879099B1 (en) 2022-08-04 2024-01-23 Uop Llc Method for making liquid hydrocarbons

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Also Published As

Publication number Publication date
MY167568A (en) 2018-09-20
US20130276630A1 (en) 2013-10-24
AU2012330384A1 (en) 2014-05-22
EA025157B1 (ru) 2016-11-30
AU2012330384B2 (en) 2016-04-14
EP2771093B1 (en) 2015-12-09
US8956441B2 (en) 2015-02-17
WO2013060795A1 (en) 2013-05-02
EP2771093A1 (en) 2014-09-03
ZA201402881B (en) 2015-12-23

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