EA201401232A1 - Смесь однокомпонентных изоцианатных преполимеров для приготовления полиуретанового продукта за одноступенчатый процесс и способ приготовления однокомпонентной полиуретановой пены - Google Patents
Смесь однокомпонентных изоцианатных преполимеров для приготовления полиуретанового продукта за одноступенчатый процесс и способ приготовления однокомпонентной полиуретановой пеныInfo
- Publication number
- EA201401232A1 EA201401232A1 EA201401232A EA201401232A EA201401232A1 EA 201401232 A1 EA201401232 A1 EA 201401232A1 EA 201401232 A EA201401232 A EA 201401232A EA 201401232 A EA201401232 A EA 201401232A EA 201401232 A1 EA201401232 A1 EA 201401232A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- component
- mixture
- isocyanate
- container
- preparing
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 8
- 238000000034 method Methods 0.000 title abstract 6
- 229920005830 Polyurethane Foam Polymers 0.000 title abstract 5
- 239000011496 polyurethane foam Substances 0.000 title abstract 5
- 229920002635 polyurethane Polymers 0.000 title abstract 2
- 239000004814 polyurethane Substances 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 abstract 3
- 239000012948 isocyanate Substances 0.000 abstract 3
- 150000002513 isocyanates Chemical class 0.000 abstract 3
- 239000003380 propellant Substances 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- -1 ethylene glycol ethers Chemical class 0.000 abstract 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 2
- JIABEENURMZTTI-UHFFFAOYSA-N 1-isocyanato-2-[(2-isocyanatophenyl)methyl]benzene Chemical compound O=C=NC1=CC=CC=C1CC1=CC=CC=C1N=C=O JIABEENURMZTTI-UHFFFAOYSA-N 0.000 abstract 1
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000005442 diisocyanate group Chemical group 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
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- C—CHEMISTRY; METALLURGY
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- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
- C08G18/2835—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds having less than 5 ether groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4812—Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
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- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
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- C08J9/141—Hydrocarbons
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- C08J9/142—Compounds containing oxygen but no halogen atom
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
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- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
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- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
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- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
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- C08J2207/00—Foams characterised by their intended use
- C08J2207/04—Aerosol, e.g. polyurethane foam spray
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- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Группа изобретений относится в области химии высокомолекулярных соединений, преимущественно к технологии получения пенополиуретанов, а конкретнее к составу однокомпонентной пены с низким содержанием мономерного диизоцианата (2,2'-метилендифенилизоцианата, 2,4'-метилендифенилизоцианата и 4,4'-метилендифенилизоцианата), и способу приготовления однокомпонентной полиуретановой пены с использованием указанного состава. Первым объектом группы изобретений является смесь однокомпонентных изоцианатных преполимеров для приготовления полиуретанового продукта за одноступенчатый процесс, где содержимое мономерного метилендифенилдиизоцианата (МДИ) в названной смеси не превышает 3%, в предпочтительном случае составляет менее 2%, а в оптимальном случае менее 1% от общей массы, содержащая монофункциональный спирт, изоцианатный компонент или смесь изоцианатных компонентов, пропеллент, катализатор, стабилизатор, один или несколько полиолов. Монофункциональный спирт представляет собой эфиры этиленгликоля или эфиры пропиленгликоля, а также способ приготовления однокомпонентной полиуретановой пены на основе названной смеси. Вторым объектом группы изобретений является способ приготовления однокомпонентной полиуретановой пены, характеризующейся тем, что он содержит следующие этапы: подготавливается дозирующий контейнер, в контейнер транспортируется смесь, определенная в одном из пп.1-7 формулы, предпочтительно таким образом, чтобы пропеллент оставался за пределами контейнера, дозирующий контейнер закрывают, в предпочтительном случае пропеллент подают в контейнер.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL406843A PL235304B1 (pl) | 2014-01-14 | 2014-01-14 | Jednoskładnikowa mieszanina prepolimeru izocyjanianu oraz sposób wytwarzania pianki poliuretanowej w pojemniku dozującym w jednoetapowym procesie |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201401232A1 true EA201401232A1 (ru) | 2015-07-30 |
| EA033967B1 EA033967B1 (ru) | 2019-12-13 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201401232A EA033967B1 (ru) | 2014-01-14 | 2014-12-08 | Однокомпонентная смесь изоцианатных преполимеров для приготовления полиуретанового вспененного продукта одноступенчатым способом и способ приготовления однокомпонентной полиуретановой пены |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9738747B2 (ru) |
| EP (1) | EP2894181A1 (ru) |
| KR (1) | KR101663875B1 (ru) |
| CN (1) | CN104387556A (ru) |
| BR (1) | BR102014029745A2 (ru) |
| EA (1) | EA033967B1 (ru) |
| PL (1) | PL235304B1 (ru) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017058559A1 (en) * | 2015-09-30 | 2017-04-06 | Dow Global Technologies Llc | One-component fenestration foam formulation demonstrating low initial shrinkage |
| ES2852199T3 (es) | 2016-03-23 | 2021-09-13 | Fuller H B Co | Composición adhesiva termofusible reactiva |
| JP6924409B2 (ja) * | 2017-07-26 | 2021-08-25 | 日油株式会社 | ウレタン塗料組成物、硬化塗膜、および樹脂部材 |
| PL3990510T3 (pl) | 2019-06-25 | 2025-02-10 | H.B. Fuller Company | Utwardzalna wilgocią kompozycja poliuretanowego kleju topliwego o niskim poziomie monomeru diizocyjanianu |
| CN111303376B (zh) * | 2020-02-17 | 2022-02-18 | 成都高端聚合物科技有限公司 | 压力罐装可表面喷涂单组分聚氨酯泡沫及制备方法、应用 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3401129A1 (de) | 1984-01-14 | 1985-07-18 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur herstellung gemischter polyurethan-prepolymerer |
| WO1991015530A1 (en) | 1990-03-30 | 1991-10-17 | H.B. Fuller Licensing & Financing Inc. | Hot melt moisture-cure polyurethane adhesive |
| CA2184107A1 (en) * | 1994-02-24 | 1995-08-31 | Hermann Kluth | Foam plastic from disposable pressurized containers |
| DE4409043A1 (de) | 1994-03-17 | 1995-09-21 | Bayer Ag | Verfahren zur Herstellung von gegebenenfalls zellförmigen Polyurethanen |
| DE19700014A1 (de) | 1997-01-02 | 1998-07-09 | Henkel Kgaa | Monomerenarmes PU-Prepolymer |
| PL213302B1 (pl) | 2000-08-08 | 2013-02-28 | Dow Global Technologies Inc | Jednoskladnikowa kompozycja do wytwarzania pianki poliuretanowej, zastosowanie tej kompozycji piankotwórczej i sposób wytwarzania pianki poliuretanowej |
| GB0106988D0 (en) * | 2001-03-20 | 2001-05-09 | Baxenden Chem | Flexible one component foam |
| DE10225982B4 (de) * | 2002-06-11 | 2012-04-19 | Jowat Ag | Polyurethan-Zusammensetzungen mit geringem Anteil von Diisocyanatmonomeren |
| US7053142B2 (en) * | 2003-12-19 | 2006-05-30 | Acushnet Company | Plasticized polyurethanes for use in golf balls |
| PL361365A1 (en) * | 2003-07-21 | 2004-01-12 | ORION Sp.z o.o. | Prepolymer compound for producing polyurethane foam in earosol container, featuring low content of isocyanate monomer |
| DE102004057292A1 (de) * | 2004-11-26 | 2006-06-01 | Klebchemie, M.G. Becker Gmbh & Co Kg | Verfahren zur Herstellung von reaktiven Polyurethanzusammensetzungen |
| EP1894954A1 (de) * | 2006-09-01 | 2008-03-05 | Basf Se | Isocyanatkomponente daraus hergestellte Prepolymere sowie Polyurethan Ein- und Zweikomponentenschäume daraus |
| JP2010510339A (ja) * | 2006-11-17 | 2010-04-02 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリフェニレンポリメチレンポリイソシアネート及びポリウレタンフォームを製造するための、その使用方法 |
| RU2010127150A (ru) * | 2007-12-03 | 2012-01-10 | Басф Се (De) | Однокомпонентный полиуретановый клей |
| US8455679B2 (en) * | 2008-12-12 | 2013-06-04 | Basf Se | Prepolymer systems having reduced monomeric isocyanate contents |
| EP2272883A1 (de) * | 2009-07-08 | 2011-01-12 | Basf Se | Monomerarmes Polyisocyanatprepolymer und monomerarmer Dosenschaum |
| DE102009045027A1 (de) * | 2009-09-25 | 2011-03-31 | Henkel Ag & Co. Kgaa | Monomerarme Polyurethanschäume |
| EP2360197A1 (de) * | 2010-02-17 | 2011-08-24 | Basf Se | Lagerstabile Polyisocyanatprepolymere enthaltend Flammschutzmittel |
| EP2481764A1 (en) | 2011-01-27 | 2012-08-01 | de Schrijver, Aster | Composition for one-component polyurethane foams having low free monomeric MDI content |
| WO2014123434A1 (en) | 2013-02-06 | 2014-08-14 | "Selena Labs" Społka Z Ograniczona Odpowiedzialnoscia | One component isocyanate prepolymer mixture for production in one step process of the polyurethane product |
-
2014
- 2014-01-14 PL PL406843A patent/PL235304B1/pl unknown
- 2014-10-09 EP EP14188232.4A patent/EP2894181A1/en not_active Withdrawn
- 2014-10-22 US US14/520,865 patent/US9738747B2/en not_active Expired - Fee Related
- 2014-11-04 KR KR1020140152225A patent/KR101663875B1/ko not_active Expired - Fee Related
- 2014-11-17 CN CN201410653300.XA patent/CN104387556A/zh active Pending
- 2014-11-27 BR BR102014029745A patent/BR102014029745A2/pt not_active Application Discontinuation
- 2014-12-08 EA EA201401232A patent/EA033967B1/ru not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| PL406843A1 (pl) | 2015-07-20 |
| CN104387556A (zh) | 2015-03-04 |
| BR102014029745A2 (pt) | 2015-09-15 |
| US9738747B2 (en) | 2017-08-22 |
| EA033967B1 (ru) | 2019-12-13 |
| US20150197596A1 (en) | 2015-07-16 |
| KR101663875B1 (ko) | 2016-10-07 |
| PL235304B1 (pl) | 2020-06-29 |
| EP2894181A1 (en) | 2015-07-15 |
| KR20150084642A (ko) | 2015-07-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KZ KG TJ TM RU |