ECSP10010435A - Proceso para la acetilación de madera y producto del mismo - Google Patents
Proceso para la acetilación de madera y producto del mismoInfo
- Publication number
- ECSP10010435A ECSP10010435A EC2010010435A ECSP10010435A ECSP10010435A EC SP10010435 A ECSP10010435 A EC SP10010435A EC 2010010435 A EC2010010435 A EC 2010010435A EC SP10010435 A ECSP10010435 A EC SP10010435A EC SP10010435 A ECSP10010435 A EC SP10010435A
- Authority
- EC
- Ecuador
- Prior art keywords
- wood
- product
- class
- acetylation
- durability
- Prior art date
Links
- 239000002023 wood Substances 0.000 title abstract 5
- 230000021736 acetylation Effects 0.000 title abstract 3
- 238000006640 acetylation reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/36—Aliphatic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/14—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood board or veneer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0254—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/04—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
- B05D3/0466—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases the gas being a non-reacting gas
- B05D3/0473—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases the gas being a non-reacting gas for heating, e.g. vapour heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/0278—Processes; Apparatus involving an additional treatment during or after impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/346—Grafting onto wood fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/001—Heating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B3/00—Preparation of cellulose esters of organic acids
- C08B3/06—Cellulose acetate, e.g. mono-acetate, di-acetate or tri-acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H8/00—Macromolecular compounds derived from lignocellulosic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/0207—Pretreatment of wood before impregnation
- B27K3/0214—Drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/08—Impregnating by pressure, e.g. vacuum impregnation
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Materials Engineering (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
Un proceso para la acetilación de la madera que comprende sumergir la madera en un fluido de acetilación bajo presión, y calentar posteriormente la madera bajo condiciones controladas para iniciar dos reacciones exotérmicas distintas. El proceso permite el aprovechamiento simultáneo de grandes cantidades de tamaños comerciales de madera que tienen una durabilidad clase 4 o clase 5 con un único producto durabilidad clase 1 o clase 2.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0801880A GB0801880D0 (en) | 2008-02-01 | 2008-02-01 | Process and product thereof |
| GB0814785A GB0814785D0 (en) | 2008-08-13 | 2008-08-13 | Process and product thereof II |
| GB0823012A GB0823012D0 (en) | 2008-02-01 | 2008-12-18 | Process and product thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ECSP10010435A true ECSP10010435A (es) | 2010-09-30 |
Family
ID=40469343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EC2010010435A ECSP10010435A (es) | 2008-02-01 | 2010-08-31 | Proceso para la acetilación de madera y producto del mismo |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US8512815B2 (es) |
| EP (2) | EP2818287A1 (es) |
| JP (2) | JP5749019B2 (es) |
| KR (1) | KR101591030B1 (es) |
| CN (1) | CN103481342B (es) |
| AU (1) | AU2009208791B2 (es) |
| BR (1) | BRPI0906605A2 (es) |
| CA (2) | CA2713402C (es) |
| DK (1) | DK2242624T3 (es) |
| EC (1) | ECSP10010435A (es) |
| ES (1) | ES2611460T3 (es) |
| GB (2) | GB2456915B (es) |
| IL (1) | IL207186A0 (es) |
| MA (1) | MA32127B1 (es) |
| MY (2) | MY155134A (es) |
| NZ (1) | NZ586948A (es) |
| TW (2) | TWI480145B (es) |
| WO (1) | WO2009095687A1 (es) |
| ZA (1) | ZA201005240B (es) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101583837B (zh) | 2005-09-22 | 2012-02-15 | 伊斯曼化学公司 | 具有开缝阵列波导的微波反应器 |
| WO2007038196A2 (en) | 2005-09-22 | 2007-04-05 | Eastman Chemical Company | Microwave reactor having a slotted array waveguide coupled to a waveguide bend |
| CN103481342B (zh) | 2008-02-01 | 2018-09-07 | 泰坦木业有限公司 | 乙酰化的木材 |
| US20100331531A1 (en) * | 2009-06-25 | 2010-12-30 | Eastman Chemical Company | Methods for esterifying lignocellulosic material |
| US8906466B2 (en) * | 2009-06-25 | 2014-12-09 | Eastman Chemical Company | Esterified lignocellulosic materials and methods for making them |
| JP2013518743A (ja) * | 2010-02-04 | 2013-05-23 | チタン ウッド リミテッド | 木材成分のアセチル化方法 |
| DE102010031892B4 (de) | 2010-07-21 | 2019-01-03 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Faserverstärkte Verbundstoffe, Verfahren zu deren Herstellung sowie deren Verwendung |
| US9151000B2 (en) | 2010-09-17 | 2015-10-06 | Titan Wood Limited | Treatment of wood pieces |
| US20120160839A1 (en) | 2010-12-23 | 2012-06-28 | Eastman Chemical Company | Microwave wood heater with enhanced spatial usage efficiency and uniformity of heat distribution |
| MX353017B (es) | 2011-09-28 | 2017-12-18 | Titan Wood Ltd | Paneles de fibras de densidad media. |
| EP2623281A1 (en) * | 2012-01-31 | 2013-08-07 | Titan Wood Limited | Acetylated wood |
| CN104284905B (zh) * | 2012-02-07 | 2017-06-09 | 泰坦木业有限公司 | 木材乙酰化的方法和乙酰化木材 |
| US20130202789A1 (en) * | 2012-02-08 | 2013-08-08 | Eastman Chemical Company | Methods of acetylation of wood involving multiple acetylation cycles |
| BR112014029241B1 (pt) | 2012-05-22 | 2021-01-05 | Titan Wood Limited | sistema de reator e processo para a acetilação de materiais lignocelulósicos e uso de um sistema de reator para conduzir um processo para a acetilação de materiais lignocelulósicos |
| US20140065340A1 (en) * | 2012-08-29 | 2014-03-06 | Eastman Chemical Company | Moisturized acetylated wood and methods for making the same |
| CN103659967B (zh) * | 2012-09-05 | 2016-03-09 | 中国林业科学研究院木材工业研究所 | 一种乙酰化纤维材料的处理方法和由该方法得到的材料 |
| GB2511120B (en) * | 2013-02-26 | 2017-06-21 | Medite Europe Ltd | Acetylated wood fibre |
| GB2511121B (en) * | 2013-02-26 | 2017-10-04 | Medite Europe Ltd | Process for manufacturing products from acetylated wood fibre |
| NL2013034C2 (nl) | 2013-06-20 | 2015-01-27 | Volkerrail Nederland B V | Geluidscherm langs een openbare weg of spoorweg. |
| CN103522377B (zh) * | 2013-09-27 | 2015-09-23 | 上海华谊能源化工有限公司 | 一种用于木材乙酰化生产的装置系统及工艺 |
| WO2015173226A1 (en) * | 2014-05-13 | 2015-11-19 | Tricoya Technologies Ltd | Method for the modification of wood |
| WO2016008995A2 (en) | 2014-07-16 | 2016-01-21 | Tricoya Technologies Ltd | Process for the acetylation of wood |
| GB201412839D0 (en) * | 2014-07-18 | 2014-09-03 | Tricoya Technologies Ltd | Wood acetylation process |
| NZ729089A (en) * | 2014-08-19 | 2019-09-27 | Solvay Acetow Gmbh | Process for the recovery of carboxylic acid and wood treatment process |
| UY36621A (es) * | 2015-04-13 | 2016-11-30 | Tricoya Technologies Ltd | Método para la acetilación continua de elementos de madera |
| BR112017022023B1 (pt) * | 2015-04-13 | 2022-07-05 | Tricoya Technologies Ltd | Método para a acetilação de madeira |
| US11338468B2 (en) | 2015-04-13 | 2022-05-24 | Tricoya Technologies Ltd. | Method for continuous acetylation of wood elements |
| CN105128107A (zh) * | 2015-06-24 | 2015-12-09 | 南通亚振东方家具有限公司 | 一种乙酰化木材的处理方法 |
| CN106217547B (zh) * | 2016-08-15 | 2017-11-03 | 东阳市荣轩工艺品有限公司 | 一种提升红木尺寸稳定性的处理方法 |
| EP3774241B1 (en) | 2018-04-13 | 2023-05-31 | Tricoya Technologies Ltd | Acetylated wood and method of making same |
| US12377574B2 (en) | 2019-02-01 | 2025-08-05 | Tricoya Technologies Ltd | Boards from acetylated rubberwood |
| ES3040747T3 (en) | 2019-05-22 | 2025-11-04 | Basf Se | Fibre mouldings |
| US20230271912A1 (en) | 2020-07-28 | 2023-08-31 | Titan Wood Limited | Purification of wood acetylation fluid |
| EP4313527A1 (en) | 2021-03-25 | 2024-02-07 | Peter Klaas | A combined process of hydrolysis and esterification of wood |
| WO2024002448A1 (en) | 2022-06-29 | 2024-01-04 | Alpha Holding Brande Aps | Elevated pressure hybrid wood modification |
| WO2024058246A1 (ja) | 2022-09-16 | 2024-03-21 | 国立大学法人京都大学 | 組成物 |
| WO2024100210A1 (en) | 2022-11-09 | 2024-05-16 | Tricoya Technologies Ltd | Purification of acetic acid by heteroazeotropic distillation with water |
| WO2024200869A1 (en) | 2023-03-31 | 2024-10-03 | Titan Wood Limited | Production of acetic acid anhydride |
| WO2026012605A1 (en) | 2023-07-14 | 2026-01-15 | Titan Wood Limited | Process for the acetylation of wood |
| WO2025026976A1 (en) | 2023-07-28 | 2025-02-06 | Titan Wood Limited | Acetic acid corrosivity reduction |
| AU2024317084A1 (en) | 2023-07-28 | 2026-02-19 | Titan Wood Limited | Acetylated wood colouring process |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3094431A (en) * | 1961-03-22 | 1963-06-18 | Koppers Co Inc | Process of acetylating wood |
| US3183114A (en) * | 1961-04-24 | 1965-05-11 | American Mach & Foundry | Treatment of wood with ethylene oxide gas or propylene oxide gas |
| NL299220A (es) * | 1962-10-15 | 1900-01-01 | ||
| US3720661A (en) * | 1971-01-05 | 1973-03-13 | Rhodiaceta | Process for producing acetylated regenerated cellulose articles |
| JPS587310A (ja) * | 1982-05-24 | 1983-01-17 | 大建工業株式会社 | 木質材 |
| DE3581737D1 (de) * | 1985-08-28 | 1991-03-14 | A Cell Acetyl Cellulosics | Verfahren zur verbesserung von dimensionsbestaendigkeit und vom biologischen widerstand von lignocellulosestoff. |
| JPS63147602A (ja) * | 1986-12-11 | 1988-06-20 | 大倉工業株式会社 | 改質木材の製法 |
| JPH0720605B2 (ja) * | 1987-02-13 | 1995-03-08 | 大建工業株式会社 | 木質材の改質方法 |
| JPH02155604A (ja) * | 1988-12-07 | 1990-06-14 | Sanyo Kokusaku Pulp Co Ltd | 改質木材の製造方法 |
| JPH0681685B2 (ja) * | 1989-03-10 | 1994-10-19 | 永大産業株式会社 | アセチル化木材の製造方法 |
| JPH079411A (ja) * | 1993-06-25 | 1995-01-13 | Sumitomo Chem Eng Kk | セルロース含有材のアセチル化法および改質木材の製造方法 |
| GB9403509D0 (en) * | 1994-02-24 | 1994-04-13 | Bp Chem Int Ltd | Acetylation of lignocellulosic materials |
| DK0680810T3 (da) * | 1994-05-04 | 1999-04-26 | Stichting Hout Research Shr | Fremgangsmåde til acetylering af massivt træ |
| WO2002006046A1 (en) * | 2000-07-14 | 2002-01-24 | Board Of Control Of Michigan Technological University | Wood-based composite board and method of manufacture |
| AT500342B1 (de) * | 2002-11-28 | 2006-08-15 | Ami Agrolinz Melamine Int Gmbh | Verfahren zur herstellung von acetyliertem holz |
| JP2004262152A (ja) * | 2003-03-03 | 2004-09-24 | Hokusan Kk | 年輪突板/透明板積層体の製造方法 |
| US7300705B2 (en) * | 2003-06-23 | 2007-11-27 | Weyerhaeuser Company | Methods for esterifying hydroxyl groups in wood |
| KR100543652B1 (ko) | 2003-10-16 | 2006-01-20 | 주식회사 엘지화학 | 목질가공품의 치수안정화 및 가공방법 |
| NZ531217A (en) | 2004-02-18 | 2005-12-23 | Nz Forest Research Inst Ltd | Impregnation process |
| JP4686775B2 (ja) * | 2006-02-15 | 2011-05-25 | 独立行政法人森林総合研究所 | 木材の改質方法 |
| CN103481342B (zh) | 2008-02-01 | 2018-09-07 | 泰坦木业有限公司 | 乙酰化的木材 |
-
2008
- 2008-12-19 CN CN201310224817.2A patent/CN103481342B/zh active Active
-
2009
- 2009-01-30 GB GB0901554A patent/GB2456915B/en active Active
- 2009-01-30 WO PCT/GB2009/000268 patent/WO2009095687A1/en not_active Ceased
- 2009-01-30 GB GB1204313.9A patent/GB2485945B/en active Active
- 2009-01-30 KR KR1020107018353A patent/KR101591030B1/ko not_active Expired - Fee Related
- 2009-01-30 CA CA2713402A patent/CA2713402C/en active Active
- 2009-01-30 EP EP14175220.4A patent/EP2818287A1/en not_active Ceased
- 2009-01-30 MY MYPI2010003503A patent/MY155134A/en unknown
- 2009-01-30 BR BRPI0906605-5A patent/BRPI0906605A2/pt not_active IP Right Cessation
- 2009-01-30 ES ES09706379.6T patent/ES2611460T3/es active Active
- 2009-01-30 EP EP09706379.6A patent/EP2242624B1/en active Active
- 2009-01-30 DK DK09706379.6T patent/DK2242624T3/en active
- 2009-01-30 US US12/865,571 patent/US8512815B2/en active Active
- 2009-01-30 AU AU2009208791A patent/AU2009208791B2/en not_active Ceased
- 2009-01-30 NZ NZ586948A patent/NZ586948A/xx not_active IP Right Cessation
- 2009-01-30 MY MYPI2014003003A patent/MY180246A/en unknown
- 2009-01-30 JP JP2010544779A patent/JP5749019B2/ja active Active
- 2009-01-30 CA CA2921442A patent/CA2921442C/en active Active
- 2009-02-02 TW TW098103207A patent/TWI480145B/zh not_active IP Right Cessation
- 2009-02-02 TW TW103139185A patent/TWI577520B/zh not_active IP Right Cessation
-
2010
- 2010-07-22 ZA ZA2010/05240A patent/ZA201005240B/en unknown
- 2010-07-25 IL IL207186A patent/IL207186A0/en unknown
- 2010-08-31 EC EC2010010435A patent/ECSP10010435A/es unknown
- 2010-09-01 MA MA33131A patent/MA32127B1/fr unknown
-
2013
- 2013-07-12 US US13/941,233 patent/US9393762B2/en active Active
-
2014
- 2014-06-03 JP JP2014114466A patent/JP5977286B2/ja active Active
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