ECSP17035769A - Método para mejorar la proporción de formación del producto de reacción de un ácido carboxílico y una urea vía adición ácida - Google Patents
Método para mejorar la proporción de formación del producto de reacción de un ácido carboxílico y una urea vía adición ácidaInfo
- Publication number
- ECSP17035769A ECSP17035769A ECIEPI201735769A ECPI201735769A ECSP17035769A EC SP17035769 A ECSP17035769 A EC SP17035769A EC IEPI201735769 A ECIEPI201735769 A EC IEPI201735769A EC PI201735769 A ECPI201735769 A EC PI201735769A EC SP17035769 A ECSP17035769 A EC SP17035769A
- Authority
- EC
- Ecuador
- Prior art keywords
- reaction product
- urea
- improve
- formation ratio
- acid
- Prior art date
Links
- 239000007795 chemical reaction product Substances 0.000 title abstract 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title abstract 3
- 239000002253 acid Substances 0.000 title abstract 3
- 230000015572 biosynthetic process Effects 0.000 title abstract 3
- 239000004202 carbamide Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- -1 CARBOXYL Chemical class 0.000 title 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- UJQLDFMZDSDZEY-UHFFFAOYSA-N n-(acetylcarbamoyl)acetamide Chemical compound CC(=O)NC(=O)NC(C)=O UJQLDFMZDSDZEY-UHFFFAOYSA-N 0.000 abstract 1
- DWTMJZUGKDTNRU-UHFFFAOYSA-N n-(formylcarbamoyl)formamide Chemical compound O=CNC(=O)NC=O DWTMJZUGKDTNRU-UHFFFAOYSA-N 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000002689 soil Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
- C07C273/1854—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety
- C07C273/1863—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety from urea
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C275/46—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylureas
- C07C275/48—Y being a hydrogen or a carbon atom
- C07C275/50—Y being a hydrogen or an acyclic carbon atom
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente invención está dirigida a un método para mejorar la proporción de formación de los productos de reacción de un ácido carboxílico y una urea con la fórmula: donde R1, R2, R3 y R4 son iguales o diferentes y se seleccionan del grupo que consiste en hidrógeno, grupos alquilo, alilo, vinilo y alcoxilo sustituidos y no sustituidos que tienen de 1 a 6 átomos de carbono, grupos fenilo sustituidos y no sustituidos y los haluros. La proporción de formación se mejora al agregar ácido a una solución que incluye el ácido carboxílico y la urea. Preferentemente, el producto de reacción de la presente invención es N,N'diformilurea o N,N'-diacetilurea. Se descubrió que estos productos de reacción, p. ej., diformilurea, producen crecimientos significativamente mejores en una variedad de productos agrícolas cuando se aplican a la semilla, al suelo circundante o al follaje de la planta emergente.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462098180P | 2014-12-30 | 2014-12-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ECSP17035769A true ECSP17035769A (es) | 2017-06-30 |
Family
ID=56163422
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ECIEPI201735769A ECSP17035769A (es) | 2014-12-30 | 2017-06-08 | Método para mejorar la proporción de formación del producto de reacción de un ácido carboxílico y una urea vía adición ácida |
Country Status (24)
| Country | Link |
|---|---|
| US (1) | US9920001B2 (es) |
| EP (1) | EP3240774B1 (es) |
| KR (1) | KR102654043B1 (es) |
| CN (1) | CN107108484B (es) |
| AR (1) | AR103335A1 (es) |
| AU (1) | AU2015374094B2 (es) |
| CA (1) | CA2962148C (es) |
| CL (1) | CL2017000861A1 (es) |
| CO (1) | CO2017004933A2 (es) |
| CR (1) | CR20170295A (es) |
| EC (1) | ECSP17035769A (es) |
| ES (1) | ES2776426T3 (es) |
| HR (1) | HRP20200365T1 (es) |
| HU (1) | HUE047943T2 (es) |
| LT (1) | LT3240774T (es) |
| MX (1) | MX390854B (es) |
| NI (1) | NI201700084A (es) |
| PE (1) | PE20171065A1 (es) |
| PH (1) | PH12017501227A1 (es) |
| PL (1) | PL3240774T3 (es) |
| PT (1) | PT3240774T (es) |
| RS (1) | RS60620B1 (es) |
| WO (1) | WO2016109622A1 (es) |
| ZA (1) | ZA201704904B (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110372541A (zh) * | 2019-07-26 | 2019-10-25 | 南通市争妍新材料科技有限公司 | 一种羧酸和尿素高效固相合成酰胺衍生物的方法 |
| CN115024389A (zh) * | 2022-07-06 | 2022-09-09 | 青岛元农生物科技有限公司 | 一种缓释非蛋白氮添加剂及其制备和使用方法 |
| CN116751140A (zh) * | 2023-05-29 | 2023-09-15 | 山东聊城鲁西硝基复肥有限公司 | 一种n-甲酸基脲废液的资源化利用方法及系统 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD87780A (es) * | 1971-11-17 | 1972-11-12 | ||
| US773251A (en) * | 1903-03-09 | 1904-10-25 | Firm Of E Merck | Ureide of dialkyl-acetic and process of making same. |
| PT955797E (pt) * | 1996-04-10 | 2005-11-30 | Stoller Ets | Diformilureia e produtos da reaccao da ureia com acidos carboxilicos |
| US6040273A (en) | 1997-04-09 | 2000-03-21 | Stoller Enterprises, Inc. | Diformylurea and reaction products of urea and carboxylic acids |
| EP2185505A2 (en) * | 2007-06-25 | 2010-05-19 | Yissum Research Development Company of the Hebrew University of Jerusalem Ltd | Acyl-urea derivatives and uses thereof |
| WO2013067103A2 (en) * | 2011-11-03 | 2013-05-10 | Bayer Cropscience Lp | Compositions and methods for enhancing plant quality |
-
2015
- 2015-12-30 AR ARP150104353A patent/AR103335A1/es active IP Right Grant
- 2015-12-30 WO PCT/US2015/067992 patent/WO2016109622A1/en not_active Ceased
- 2015-12-30 RS RS20200158A patent/RS60620B1/sr unknown
- 2015-12-30 US US14/984,049 patent/US9920001B2/en active Active
- 2015-12-30 KR KR1020177021082A patent/KR102654043B1/ko active Active
- 2015-12-30 LT LTEP15876223.7T patent/LT3240774T/lt unknown
- 2015-12-30 PT PT158762237T patent/PT3240774T/pt unknown
- 2015-12-30 MX MX2017008810A patent/MX390854B/es unknown
- 2015-12-30 HR HRP20200365TT patent/HRP20200365T1/hr unknown
- 2015-12-30 ES ES15876223T patent/ES2776426T3/es active Active
- 2015-12-30 HU HUE15876223A patent/HUE047943T2/hu unknown
- 2015-12-30 CN CN201580071463.XA patent/CN107108484B/zh active Active
- 2015-12-30 PE PE2017000567A patent/PE20171065A1/es unknown
- 2015-12-30 CA CA2962148A patent/CA2962148C/en active Active
- 2015-12-30 PL PL15876223T patent/PL3240774T3/pl unknown
- 2015-12-30 EP EP15876223.7A patent/EP3240774B1/en active Active
- 2015-12-30 AU AU2015374094A patent/AU2015374094B2/en active Active
- 2015-12-30 CR CR20170295A patent/CR20170295A/es unknown
-
2017
- 2017-04-07 CL CL2017000861A patent/CL2017000861A1/es unknown
- 2017-05-17 CO CONC2017/0004933A patent/CO2017004933A2/es unknown
- 2017-06-08 EC ECIEPI201735769A patent/ECSP17035769A/es unknown
- 2017-06-26 NI NI201700084A patent/NI201700084A/es unknown
- 2017-06-30 PH PH12017501227A patent/PH12017501227A1/en unknown
- 2017-07-19 ZA ZA2017/04904A patent/ZA201704904B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| LT3240774T (lt) | 2020-03-25 |
| HUE047943T2 (hu) | 2020-05-28 |
| KR102654043B1 (ko) | 2024-04-02 |
| PH12017501227B1 (en) | 2018-01-15 |
| ES2776426T3 (es) | 2020-07-30 |
| EP3240774B1 (en) | 2019-12-11 |
| RS60620B1 (sr) | 2020-09-30 |
| US20160185715A1 (en) | 2016-06-30 |
| CA2962148C (en) | 2023-04-25 |
| CN107108484A (zh) | 2017-08-29 |
| CL2017000861A1 (es) | 2017-11-10 |
| CA2962148A1 (en) | 2016-07-07 |
| KR20170104143A (ko) | 2017-09-14 |
| CN107108484B (zh) | 2021-04-13 |
| US9920001B2 (en) | 2018-03-20 |
| WO2016109622A1 (en) | 2016-07-07 |
| CO2017004933A2 (es) | 2017-07-28 |
| MX390854B (es) | 2025-03-21 |
| EP3240774A4 (en) | 2018-08-15 |
| MX2017008810A (es) | 2017-10-19 |
| AU2015374094B2 (en) | 2020-07-16 |
| AR103335A1 (es) | 2017-05-03 |
| PL3240774T3 (pl) | 2020-06-29 |
| AU2015374094A1 (en) | 2017-04-27 |
| PH12017501227A1 (en) | 2018-01-15 |
| NI201700084A (es) | 2017-07-18 |
| CR20170295A (es) | 2017-11-24 |
| EP3240774A1 (en) | 2017-11-08 |
| PE20171065A1 (es) | 2017-07-21 |
| ZA201704904B (en) | 2018-12-19 |
| HRP20200365T1 (hr) | 2020-08-21 |
| PT3240774T (pt) | 2020-03-10 |
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