EP0002397A1 - Feuerverzögerndes elektrisches Kabel und Verfahren zu dessen Herstellung - Google Patents
Feuerverzögerndes elektrisches Kabel und Verfahren zu dessen Herstellung Download PDFInfo
- Publication number
- EP0002397A1 EP0002397A1 EP78400154A EP78400154A EP0002397A1 EP 0002397 A1 EP0002397 A1 EP 0002397A1 EP 78400154 A EP78400154 A EP 78400154A EP 78400154 A EP78400154 A EP 78400154A EP 0002397 A1 EP0002397 A1 EP 0002397A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cable
- layer
- powder
- ignition
- ignition product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 4
- 239000003063 flame retardant Substances 0.000 title 1
- 239000004020 conductor Substances 0.000 claims abstract description 19
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 10
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 10
- 230000001681 protective effect Effects 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims description 26
- 239000000839 emulsion Substances 0.000 claims description 9
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- NDRKXFLZSRHAJE-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4-tribromophenyl)benzene Chemical group BrC1=C(Br)C(Br)=CC=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br NDRKXFLZSRHAJE-UHFFFAOYSA-N 0.000 claims description 2
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 2
- 238000004804 winding Methods 0.000 claims description 2
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 229920002994 synthetic fiber Polymers 0.000 claims 1
- 239000003340 retarding agent Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 8
- 239000000654 additive Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229920003020 cross-linked polyethylene Polymers 0.000 description 4
- 239000004703 cross-linked polyethylene Substances 0.000 description 4
- 206010061218 Inflammation Diseases 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- 239000006223 plastic coating Substances 0.000 description 2
- -1 polyvinyl chloride Chemical class 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- AQPHBYQUCKHJLT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4,5,6-pentabromophenyl)benzene Chemical group BrC1=C(Br)C(Br)=C(Br)C(Br)=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br AQPHBYQUCKHJLT-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
Definitions
- the present invention relates to an electric cable resistant to the propagation of fire, and to a method of manufacturing such a cable.
- Known electrical cables generally consist of an assembly formed of insulated and assembled conductors, and of an outer sheath of plasticized polyvinyl chloride. These cables are usually flammable and contribute to a fire, the extension of it.
- the chlorine level of the mixture can also be increased by adding chlorinated compounds such as chlorinated paraffins.
- a cable comprises a certain number of insulated conductors whose insulation material is flammable, such as crosslinked polyethylene for example, assembled in a bundle and covered with a sheath of polyvinyl chloride or elastomer, it can happen that the protection provided by this sheath is not sufficient in the event of a fire and the cable is completely destroyed.
- insulation material such as crosslinked polyethylene for example
- the present invention aims to avoid these drawbacks, enables a p erfec- tioned electric cable having excellent fire resistance and the spread thereof, and relates to a manufacturing method of such a cable .
- An electric cable resistant to the spread of fire provided with a set of electrically insulated conductors and assembled, and an outer sheath of protection in plasticized polyvinyl chloride, is characterized in that it comprises, between this set of insulated conductors and the outer protective sheath, at least one layer of anti-ignition product in powder form.
- a known electrical cable comprises a set of 19 conductors of 1.5 mm 2 insulated by chemically crosslinked polyethylene and assembled. Over this set, we extruded a polyvinyl chloride sheath, the composition of which comprises antimony oxide and chlorinated paraffins. In a test, in accordance with the operating mode (2-2) of French Standard NF C 32070 of May 1971 and additive n ° 1, carried out in an electric oven described in this standard, the cable known above is completely destroyed .
- a cable 1 produced in accordance with the invention illustrated schematically in the drawing comprises, like. known cables, a set of one or more conductors 2 insulated by a coating of crosslinked polyethylene, or a material based on ethylene propylene, natural or synthetic rubber or polyvinyl chloride and an outer sheath 3 in material such as polychloride vinyl, polychloroprene, chlorinated polyethylene or a material usually used in the production of this sheath.
- the electric cable 1 comprises, between its set of insulated conductors 2 and its outer sheath 3, at least one layer of pulverulent anti-ignition product 4, that is to say a product in the form a powder which in its decomposition under the action of heat, releases active compounds or elements which do not maintain the flame and prevent its propagation.
- This pulverulent anti-ignition product is constituted for example by a powder of halogenated product or compound, such as polyvinyl chloride, chlorinated polyethylenes, or by that of a brominated compound such as decabromodiphenyl) ether, octabromodiphenyl. .
- a method for manufacturing an electric cable 1 resistant to the propagation of the above flame comprises at least one covering of a set of insulated conductors 2 with a layer of silicone emulsion 5, a formation a layer of powder of anti-ignition product 4 on this layer of silicone emulsion 5 and of a winding of a layer of plastic tape 6 on this layer of anti-ignition product powder 4, before carrying out an extrusion of a outer protective sheath 3 of the cable.
- the formation of the silicone emulsion layer 5 on the set of conductors 2 can be carried out by spraying this emulsion by means of a gun, not shown.
- the establishment of the anti-ignition powder layer 4 is preferably carried out by electrostatic means. For this purpose, a voltage of a hundred kilovolts is applied between the set of insulated conductors 2 coated with a layer of silicone emulsion, and a gun, not shown, for spraying the anti-ignition powder.
- the pulverulent form of the layer of anti-ignition product ensures the cable of the invention by its faster decomposition in the presence of heat, better resistance to the propagation of the flame while contributing to give by its divided form, to this cable, a great mechanical flexibility.
- the silicone emulsion layer makes it possible to maintain a homogeneous layer of anti-ignition powder in place: for the entire length of the cable.
- the layer of tape outside the powder layer of anti-ignition product, contributes to strengthening the retention in place of this powder layer and protects it during the extrusion of the outer sheath of the cable.
- the electric cable comprises a set of isolated conductors which are individually coated with a layer of powder of anti-ignition product and between this set and the outer sheath of the cable another layer of anti-inflammation product.
- an electrical cable comprises a set of 19 conductors of ..5 mm 2 insulated by chemically crosslinked polyethylene, covered, from the inside to the outside, by an emulsion layer.
- silicone a layer of polyvinyl chloride powder, a layer of polyester tape, an outer protective sheath of polyvinyl chloride.
Landscapes
- Insulated Conductors (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7736704A FR2411475A1 (fr) | 1977-12-06 | 1977-12-06 | Cable electrique resistant a la propagation de l'incendie, et procede de fabrication d'un tel cable |
| FR7736704 | 1977-12-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0002397A1 true EP0002397A1 (de) | 1979-06-13 |
| EP0002397B1 EP0002397B1 (de) | 1980-08-06 |
Family
ID=9198504
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP78400154A Expired EP0002397B1 (de) | 1977-12-06 | 1978-10-27 | Feuerverzögerndes elektrisches Kabel und Verfahren zu dessen Herstellung |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0002397B1 (de) |
| DE (1) | DE2860122D1 (de) |
| FR (1) | FR2411475A1 (de) |
| IT (1) | IT1202803B (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0809261A3 (de) * | 1996-05-24 | 1998-06-03 | Alcatel | Brandsicheres elektrisches Kabel oder brandsichere elektrische Leitung und Verfahren zur Herstellung |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2966496D1 (en) * | 1978-11-07 | 1984-01-26 | Cables De Lyon Geoffroy Delore | Flame retardant insulating material for an electrical cable and electrical cable made with such a material |
| EP0076560B1 (de) * | 1981-09-30 | 1986-10-08 | Northern Telecom Limited | Nachrichtenkabel für Innenverlegung |
| US4562302A (en) * | 1981-10-05 | 1985-12-31 | Northern Telecom Limited | Inside telecommunication cable |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2008293A1 (de) * | 1968-05-11 | 1970-01-16 | Kabel Metallwerke Ghh | |
| FR2310619A1 (fr) * | 1975-05-05 | 1976-12-03 | Northern Telecom Ltd | Procede de fabrication d'un conducteur electrique isole thermiquement et revetu de polymere et conducteur ainsi obtenu |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA459789A (en) * | 1949-09-20 | W. Duggan Fred | Flameproof elastomer and electrical insulation thereof | |
| US3005038A (en) * | 1958-12-31 | 1961-10-17 | Mc Graw Edison Co | High temperature radio frequency cable and method of making the same |
| DE2025351C3 (de) * | 1970-05-23 | 1974-08-15 | Kabel- Und Metallwerke Gutehoffnungshuette Ag, 3000 Hannover | Schutzhülle gegen Hitze- und Feuereinwirkung von außen für Rohrbündelkabel |
| CA974682A (en) * | 1970-07-08 | 1975-09-16 | Charles F. Raley (Jr.) | Flame retardant olefin polymer composition |
| BE787171A (fr) * | 1971-08-13 | 1973-02-05 | Cables De Lyon Geoffroy Delore | Procede de fabrication d'une barriere d'etancheite pour cable electrique |
| GB1427729A (en) * | 1972-09-04 | 1976-03-10 | Pyrotenax Ltd | Method of manufacturing a mineral insulated electric cable |
| CA1011020A (en) * | 1973-02-08 | 1977-05-24 | Bruno L. Gaeckel | Flame resistant polyethylene composition |
-
1977
- 1977-12-06 FR FR7736704A patent/FR2411475A1/fr active Granted
-
1978
- 1978-10-27 DE DE7878400154T patent/DE2860122D1/de not_active Expired
- 1978-10-27 EP EP78400154A patent/EP0002397B1/de not_active Expired
- 1978-12-05 IT IT30536/78A patent/IT1202803B/it active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2008293A1 (de) * | 1968-05-11 | 1970-01-16 | Kabel Metallwerke Ghh | |
| FR2310619A1 (fr) * | 1975-05-05 | 1976-12-03 | Northern Telecom Ltd | Procede de fabrication d'un conducteur electrique isole thermiquement et revetu de polymere et conducteur ainsi obtenu |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0809261A3 (de) * | 1996-05-24 | 1998-06-03 | Alcatel | Brandsicheres elektrisches Kabel oder brandsichere elektrische Leitung und Verfahren zur Herstellung |
Also Published As
| Publication number | Publication date |
|---|---|
| IT1202803B (it) | 1989-02-09 |
| EP0002397B1 (de) | 1980-08-06 |
| DE2860122D1 (en) | 1980-11-27 |
| IT7830536A0 (it) | 1978-12-05 |
| FR2411475B1 (de) | 1980-08-22 |
| FR2411475A1 (fr) | 1979-07-06 |
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