EP0063925A1 - Procédé d'électro-déposition et produits ainsi obtenus - Google Patents
Procédé d'électro-déposition et produits ainsi obtenus Download PDFInfo
- Publication number
- EP0063925A1 EP0063925A1 EP82302060A EP82302060A EP0063925A1 EP 0063925 A1 EP0063925 A1 EP 0063925A1 EP 82302060 A EP82302060 A EP 82302060A EP 82302060 A EP82302060 A EP 82302060A EP 0063925 A1 EP0063925 A1 EP 0063925A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- connector
- plating
- process according
- connector element
- masking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title claims abstract description 32
- 238000009713 electroplating Methods 0.000 title claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 28
- 238000007747 plating Methods 0.000 claims abstract description 27
- 230000000873 masking effect Effects 0.000 claims abstract description 21
- 230000000717 retained effect Effects 0.000 claims abstract description 4
- 229910000881 Cu alloy Inorganic materials 0.000 claims abstract description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 11
- 229910052737 gold Inorganic materials 0.000 claims description 11
- 239000010931 gold Substances 0.000 claims description 11
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 239000010935 stainless steel Substances 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 239000010948 rhodium Substances 0.000 claims description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910000906 Bronze Inorganic materials 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000792 Monel Inorganic materials 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- LMBWSYZSUOEYSN-UHFFFAOYSA-N diethyldithiocarbamic acid Chemical compound CCN(CC)C(S)=S LMBWSYZSUOEYSN-UHFFFAOYSA-N 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- -1 for example Polymers 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/02—Electroplating of selected surface areas
Definitions
- the present invention relates to a process for electro-plating and in particular to a process for electro-plating selected surface areas of electrical connector contacts, asmay be used in the assembly of computers and other electrical and electronic systems, and to the products of that process.
- the contacts which are usually of copper alloy (e.g. brass, bronze or monel) with a thin layer of, for example, gold, silver, palladium or rhodium, or possibly some other precious metal.
- copper alloy e.g. brass, bronze or monel
- the electrical contact area of male/ female connector contacts may require a layer of plated material of from 1.25 to 5 microns thick, depending upon the end use of the connector. In practice such thicknesses have generally been found to give satsifactory electrical contact while at the same time providing sufficient plating material to meet the normal wear and tear to which the contact is subjected.
- plating material arsising from (1) the presence of plating on non-contact external parts of a connector, and (2) the presence of excess plating on non-contact external parts of a connector where the contact area is internal.
- a selected surface area electro-plating process is provided, which significantly reduces the use of unnecessary plating material.
- the present invention provides a process for electro-plating a selected surface area of an electrical connector contact element comprising electro-plating the connector element in the absence of a masking element to give the required thickness of plating material in the selected area, applying a masking element to the selected area of the connector element where the plating material is to be retained, and removing the plating material from the unmasked parts of the connector element, so that the connector element remains plated in the selected area only.
- the present invention also provides an electrical connector contact element which has been selectively electro-plated according to the above process.
- connector contacts may also be produced by e.g. rotary table transfer machining, cold heading techniques or high speed stamping machines.
- the masking element which is usually in the form of an elongate pin (female connector) or tubular sheath (male connector) must clearly make a good fit with the connector contact to mimimize the risk of loss of plating material from the contact area, and such a fit may, if necessary, be improved by the presence of an inert sealing substance, such as a silicone grease.
- the masking element is preferably of inert material as regards the process of the invention and in practice, materials such as stainless steel or plastics, for example, silicone rubbers, may be employed. Alternatively, a masking ink or wax may also be used, if appropriate.
- the accompanying figure illustrates diagrammatically the positioning of a cylindrical masking element 1 in relation to a female connector contact 2 in which the cylindrical internal electrical contact surface area 3 of the female connector is to be masked. Reference to the figure is also made in the following example of a process embodying the present invention, where appropriate.
- the connector contact 2 is optionally electro-plated with copper (employing, for example, copper gleam PC or cupral B solution) * to give a 1 micron thick layer in the contact area 3, and/or nickel (employing, for example, LCT semi-bright nickel solution) * to give a 2 to 4 micron layer in the same area.
- copper employing, for example, copper gleam PC or cupral B solution
- nickel employing, for example, LCT semi-bright nickel solution
- the connector is then conventionally electro-plated with gold (employing, for example, as appropriate Aurospeed E, Auronal MRC, Auronal MRN, Auro Vel HV, Auronal 44, Auro Glo PN, or Auro Glo PC solutions) * to give the required thickness in the contact area 3.
- the thickness of plated material in the contact area may vary from 0.5 to 5 microns subject to end use.
- the connector After washing with de-ionized water (drag-out), the connector is cleaned in the usual manner and dried.
- a masking pin 1 for example, in stainless steel, is now carefully inserted into the female connector 2 to cover all of the electrical contact area 3 of the cylindrical internal surface of the connector where the gold plate is to be retained. It is important to ensure that the masking pin fits accurately and tightly over the whole of the selected contact area in order to minimize loss of gold plate therefrom in the next stage of the process, when the connector is placed in a gold stripping solution (for example, Super Strip 101 solution) * until all unmasked areas of the connector have been stripped of gold-plated material. After stripping, the connector is washed and dried as before and the masking pin removed.
- a gold stripping solution for example, Super Strip 101 solution
- the connector contact may finally be flash-plated with, for example, a layer of 0.15 microns of gold (as measured on the external surface), for cosmetic purposes.
- the application of the present invention to a male connector contact is identical to that outlined above in respect of female contacts, except that the masking device is placed on to the contact instead of inserted into the contact.
- the parts may be split or tapered or otherwise modified.
- the present invention enables the use of plating material to be limited to the requisite thickness in the electrical contact area only of the connector contact, thereby resulting in a substantial saving of the plating material concerned.
- the masking elements may be loaded, either into or on to the connector contacts, as the case may be, by an automatic assembly machine. Subsequently, the contacts may be stripped, cleaned, dried and unloaded where the process is fully automatic.
- the masking elements can, of course, be fitted manually when the number of connector contacts involved is small.
- the recovery of gold from the saturated stripping solution is carried out by the usual well established techniques, when the recovery of gold can be as high as 99%.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Manufacturing Of Electrical Connectors (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8112666 | 1981-04-24 | ||
| GB8112666A GB2097426B (en) | 1981-04-24 | 1981-04-24 | Electro-plating process and products therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0063925A1 true EP0063925A1 (fr) | 1982-11-03 |
Family
ID=10521334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP82302060A Ceased EP0063925A1 (fr) | 1981-04-24 | 1982-04-22 | Procédé d'électro-déposition et produits ainsi obtenus |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0063925A1 (fr) |
| GB (1) | GB2097426B (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3447032C1 (de) * | 1984-12-22 | 1985-09-26 | Minnesota Mining And Manufacturing Co., Saint Paul, Minn. | Verfahren zum galvanischen Herstellen einer örtlich begrenzten Edelmetall-Auflage |
| WO1986007205A1 (fr) * | 1985-05-20 | 1986-12-04 | American Telephone & Telegraph Company | Dispositif de contact electrique a base de nickel |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5397598A (en) * | 1993-11-12 | 1995-03-14 | International Business Machines Corporation | Method for selectively coating a member having a shank by masking a portion of the shank with a washer |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1287563A (fr) * | 1961-02-03 | 1962-03-16 | Procédé de chromage alvéolaire | |
| GB1485083A (en) * | 1976-02-03 | 1977-09-08 | Standard Telephones Cables Ltd | Selective electro-plating |
-
1981
- 1981-04-24 GB GB8112666A patent/GB2097426B/en not_active Expired
-
1982
- 1982-04-22 EP EP82302060A patent/EP0063925A1/fr not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1287563A (fr) * | 1961-02-03 | 1962-03-16 | Procédé de chromage alvéolaire | |
| GB1485083A (en) * | 1976-02-03 | 1977-09-08 | Standard Telephones Cables Ltd | Selective electro-plating |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3447032C1 (de) * | 1984-12-22 | 1985-09-26 | Minnesota Mining And Manufacturing Co., Saint Paul, Minn. | Verfahren zum galvanischen Herstellen einer örtlich begrenzten Edelmetall-Auflage |
| WO1986007205A1 (fr) * | 1985-05-20 | 1986-12-04 | American Telephone & Telegraph Company | Dispositif de contact electrique a base de nickel |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2097426B (en) | 1984-01-18 |
| GB2097426A (en) | 1982-11-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2069363A1 (fr) | Recuit thermique d'alliages de palladium | |
| US2417967A (en) | Contact element | |
| TWI225322B (en) | Terminal having ruthenium layer and a connector with the terminal | |
| WO2002049077A2 (fr) | Couche d'arret pour connexions electriques et methodes d'application de la couche | |
| US5190486A (en) | Selectively plating electrically conductive pin | |
| US3219557A (en) | Method of producing a rotary coupling | |
| CA1062650A (fr) | Methode et composition pour l'electro-deposition du palladium | |
| CA1331325C (fr) | Connecteurs | |
| EP0063925A1 (fr) | Procédé d'électro-déposition et produits ainsi obtenus | |
| US3948736A (en) | Method of selective electroplating and products produced thereby | |
| US4895771A (en) | Electrical contact surface coating | |
| GB2186597A (en) | Electrical contact surface coating | |
| US4360411A (en) | Aluminum electrical contacts and method of making same | |
| KR830002066A (ko) | 구리이온이 함유되어 있는 욕(浴)에서 구리이온을 제거하는 방법 | |
| US3175181A (en) | Electrical connector | |
| US6572420B2 (en) | Electrical contacts with specialized surface treatments | |
| CN114843811A (zh) | 一种电连接器用探针的电镀工艺 | |
| Antler et al. | Sliding wear of inlay clad metals and electrodeposited cobalt-gold | |
| JPH11238413A (ja) | 導電性の金属帯板および金属帯板から作製されたコネクタ | |
| CA2305371A1 (fr) | Douille de connecteur electroconductrice et resistant a la corrosion | |
| James | Electroplating Process and Products Therefrom | |
| JPS5475585A (en) | Aluminium terminal | |
| JPS6448331A (en) | Terminal member | |
| GB1461474A (en) | Electrical connectors and a method of preparing stable electro platings | |
| US5116458A (en) | Electrical edge contact member and a method of manufacturing same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Designated state(s): BE CH DE FR IT NL SE |
|
| 17P | Request for examination filed |
Effective date: 19830427 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN REFUSED |
|
| 18R | Application refused |
Effective date: 19860228 |