EP0067076A1 - Verfahren zur kontinuierlichen Herstellung in wässriger Umgebung von Latex oder analoge Zusammensetzungen und/oder Phenoplaste oder Aminoplaste enthaltenden Faserbahnen, die so hergestellten Bahnen und ihre mögliche Wiederverwendung - Google Patents

Verfahren zur kontinuierlichen Herstellung in wässriger Umgebung von Latex oder analoge Zusammensetzungen und/oder Phenoplaste oder Aminoplaste enthaltenden Faserbahnen, die so hergestellten Bahnen und ihre mögliche Wiederverwendung Download PDF

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Publication number
EP0067076A1
EP0067076A1 EP82400654A EP82400654A EP0067076A1 EP 0067076 A1 EP0067076 A1 EP 0067076A1 EP 82400654 A EP82400654 A EP 82400654A EP 82400654 A EP82400654 A EP 82400654A EP 0067076 A1 EP0067076 A1 EP 0067076A1
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EP
European Patent Office
Prior art keywords
latex
fibrous materials
addition
fibrous
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP82400654A
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English (en)
French (fr)
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EP0067076B1 (de
Inventor
René Bartelloni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Papeteries de Jean dHeurs SA
Original Assignee
Papeteries de Jean dHeurs SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority claimed from FR8109400A external-priority patent/FR2505896A1/fr
Application filed by Papeteries de Jean dHeurs SA filed Critical Papeteries de Jean dHeurs SA
Priority to AT82400654T priority Critical patent/ATE18685T1/de
Publication of EP0067076A1 publication Critical patent/EP0067076A1/de
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/47—Condensation polymers of aldehydes or ketones
    • D21H17/48—Condensation polymers of aldehydes or ketones with phenols
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/35—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/47—Condensation polymers of aldehydes or ketones
    • D21H17/49—Condensation polymers of aldehydes or ketones with compounds containing hydrogen bound to nitrogen
    • D21H17/50—Acyclic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/47—Condensation polymers of aldehydes or ketones
    • D21H17/49—Condensation polymers of aldehydes or ketones with compounds containing hydrogen bound to nitrogen
    • D21H17/51—Triazines, e.g. melamine
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/04—Addition to the pulp; After-treatment of added substances in the pulp
    • D21H23/06—Controlling the addition
    • D21H23/08—Controlling the addition by measuring pulp properties, e.g. zeta potential, pH
    • D21H23/10—Controlling the addition by measuring pulp properties, e.g. zeta potential, pH at least two kinds of compounds being added

Definitions

  • the present invention relates to a new process for the continuous production in aqueous medium of sheets of fibrous materials - and especially paper - containing latex or the like and / or phenoplasts or aminoplasts, to sheets obtained by means of this process. as well as their possible reuse.
  • the fibrous material may consist of pulp and / or glass fibers and / or synthetic fibers and / or textile fibers.
  • the process described in the present invention is more particularly suitable for the manufacture of paper irrespective of the starting pulp: mechanical pulp, semi-chemical pulp, chemical pulp, unbleached chemical pulp, bleached chemical pulp, soda paste, sulphate pulp, kraft pulp, sulphite pulp, rag dough, macerated straw paste, leached straw paste, etc.
  • the polyelectrolyte used is a high molecular weight polyelectrolyte of greater than 15,000, with a high positive potential, and the latex used is in the form of a finely suspended suspension. divided and stabilized at an acid pH of between 4 and 5 and preferably between 4.2 and 4.5.
  • the latex used is the natural latex.
  • the latex used is an artificial latex (chlorobutadiene polymer or acrylic latex in particular).
  • the latex solution used has a solids content of between 5 and 50%, and preferably between 7 and 15%, its viscosity (Brookfield) is between 30 and 650 centipoise at 25 °, and the amount of latex is between 3 and 75% (as dry product) based on the total dry weight of fibrous materials).
  • the diameter of the divided latex particles is between 0.01 and 0.5 g and preferably between 0.1 and 0.2 g.
  • the polyelectrolyte solution used has a solids content of between 0.2 and 10%, and the amount introduced into the suspension of fibrous materials is between 0.1 and 3.5% of the dry product relative to the total dry weight of the latex for the first addition and between 0.1 and 2% of the dry product relative to the dry weight total of fibrous materials, for the second addition.
  • the antifoam solution has a solids content of between 2 and 20%, and the amount added to the total mixture is between 0.05% and 0.25% of the total dry weight of fibrous materials.
  • the pH is adjusted using hydrochloric acid and / or sulfuric acid and / or alumina sulphate.
  • the phenolic resin (or aminoplast) solution has a content of about 50 to 85% solids, a viscosity (Brookfield) of between 5,500 and 7,000 centipoise, and the amount added to mixture (dry product) is between 0.01 and 50% based on the total dry weight of the fibrous materials.
  • the fibrous material also contains, in its mass, dyes and pigments and / or fungicides and / or insecticides and / or flame retardants and / or bonding agents and / or an inert mineral filler.
  • different products from the group comprising: starches, carboxymethylcelluloses, suspensions can be applied.
  • the fibrous material used is a fibrous material based on pulp recycled from waste paper
  • the added latex consists of a mixture of copolymers of ethylacrylate and acrylonitrile and its proportion relative to the dry weight of the materials. fibrous is between 40 and 55%.
  • the release material layer is formed by an aqueous suspension of carboxymethylcellulose of a content of between 0.01 and 10% and carried for 5 to 25 minutes at 90-95 ° C.
  • the suspension of carboxymethylcellulose additionally contains from 0.01% to 85% of polyester and / or from 0.01% to 75% of a silicone emulsion. of anionic or nonionic potential stabilized in an aqueous medium at a pH of between 5 and 6.
  • the present invention also relates to sheets of fibrous materials obtained according to the process according to the invention.
  • the paper thus obtained and which can be used for many industrial purposes (abrasive paper, adhesive paper, tearproof papers for bags, posters, etc ..., papers for the preparation of artificial leather, paper for book covers, envelopes papers waterproof, papers for the manufacture of bags for vacuum cleaners, etc )., has excellent mechanical characteristics which rank it among the best, and this thanks, in particular to its breaking length, its resistance to burst, its tensile strength, at its aptitude for thermoforming, its high resistance to use in an aqueous medium, its resistance to repeated bending, etc.
  • Another extremely important characteristic of the paper according to the invention is its homogeneity demonstrated by the electron microscope and which clearly differentiates it from all the other papers currently on the market.
  • the present invention relates to the reuse and recovery of fibrous materials obtained according to the method described.
  • One of the advantages and not least of the process according to the present invention resides in the possibility of relatively easily recycling any fibrous material obtained according to the present invention, and this in contrast to all the papers containing latex and prepared according to the methods of the prior art.
  • This repulpability and recycling operation is characterized in that it is carried out in an aqueous medium, cold, in the presence of a wetting agent and in the presence of a small amount (0.01 to 0.15% relative to volume of water and 0.2 to 1.5% based on the weight of dry fibrous materials) chloride ions and / or sulfate ions and / or sulphamate ions. It is of course the extremely fine crosslinking of the latex molecules on the fibrous material which explains the easy repulbability of the papers prepared in accordance with the present invention.
  • the present invention is particularly directed to the process and the installations for producing sheets of fibrous materials (and in particular paper) containing, in their bulk, latex or the like and / or phenoplasts or aminoplasts and sheets of fibrous materials as well as obtained, as well as the means specific to the implementation of these methods, as well as the overall processes and the production lines in which are included the methods and facilities according to the present invention.
  • the fibrous material from a pulp mill is introduced into the tank 1 in the presence of water and coloring matter if necessary, and undergoes appropriate agitation therein to suspend the fibrous particles.
  • the solids content of the mixture is adjusted to about 2.5%.
  • the prepared fibrous suspension is conveyed into the storage tank 2, then into the so-called section 3 of refining and hydration of the fiber, so that the fibrous material undergoes the structural modifications necessary for subsequent sheet setting.
  • the structural modification must give the mixture a freeness value according to the SCHOPPER-RIEGLER method, between 10 and 50 ° SR.
  • the fibrous material thus prepared is then introduced into the mixing tank 8.
  • the treatments in sections 23 and / or 24 are optional, but these additional operations may provide properties for particular uses. If sections 23 and / or 24 are not used, the sheet is fed directly into section 25 where it is wound into a reel.
  • This sheet of paper is prepared in a con tinue, as described in Example 1, however without passing through section 16, but with the passage in section 23 for calibration, then directly to section 25.
  • This paper is prepared with passage in sections 16 -> 22 -> 23 -> 25.
  • This paper is prepared according to the method described in Example 1, with a direct passage from section 15 to section 25.
  • This paper is prepared according to the method described in Example 1, with the passage in sections 16 -> 22 -> 25.
  • This paper is prepared as described in Example 6.
  • Example 8 Preparation of a paper with a release layer
  • an aqueous solution is prepared containing about 20% (expressed as dry matter) of previously stabilized polyester emulsion at pH 5.4, an emulsion whose Brookfield viscosity (at 25 ° C.) is between 200 and 1. 000 centipoises.
  • the dry extract of the solution contained in the tank is between 2 and 8%.
  • the agitator 102 is turned on and stirred until about 80% of the paper is disintegrated. This disintegration is verified by the control methods usual in stationery. At this stage, there are still some very fine agglomerates called in paper jargon "buttons" or "pellets". the mixture thus obtained is then passed into a disintegration apparatus 105, called “de-tater” (for example, "Hydraflaker” brand de-spatter produced by BLACK CLAWSON), by recycling the juice via the pipework 105 to the tank 101 .
  • de-tater for example, "Hydraflaker” brand de-spatter produced by BLACK CLAWSON
  • the repulpability time in the tank 101 was 25 minutes, the break-up time 15 minutes, for a total of 40 minutes to make reusable the 500 kg of the fibrous material, directed to reuse by the pipe 104.
  • Example 10 Recovery of used paper with a very high latex content
  • composition of the starting paper is Composition of the starting paper:
  • the procedure is as described in Example 2, but 0.15% bleach p / volume is introduced.
  • the disintegration time was 40 minutes and the peeling time 15 minutes, ie 55 minutes for the 500 kg of material used.
  • the raw material thus recovered is reused in a conventional printing-writing medium production at a rate of 10% of dry product relative to the total dry weight of the support manufactured.
  • Table 1 summarizes the mechanical characteristics and Table II shows the characteristics of a paper in which a recycled pulp fiber material was used:
  • the papers obtained according to the method according to the present invention not only have excellent physical strength, but their ability to print coated sheets is quite good, both in exposure and in ink, clarity and rendering. colors.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)
EP82400654A 1981-05-12 1982-04-09 Verfahren zur kontinuierlichen Herstellung in wässriger Umgebung von Latex oder analoge Zusammensetzungen und/oder Phenoplaste oder Aminoplaste enthaltenden Faserbahnen, die so hergestellten Bahnen und ihre mögliche Wiederverwendung Expired EP0067076B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT82400654T ATE18685T1 (de) 1981-05-12 1982-04-09 Verfahren zur kontinuierlichen herstellung in waessriger umgebung von latex oder analoge zusammensetzungen und/oder phenoplaste oder aminoplaste enthaltenden faserbahnen, die so hergestellten bahnen und ihre moegliche wiederverwendung.

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR8109400 1981-05-12
FR8109400A FR2505896A1 (fr) 1981-05-12 1981-05-12 Nouveau procede de fabrication continue en milieu aqueux de feuilles de matieres fibreuses contenant du latex ou analogues et/ou des phenoplastes ou aminoplastes, et feuilles ainsi obtenues
FR8200224 1982-01-08
FR8200224A FR2519663B2 (fr) 1981-05-12 1982-01-08 Perfectionnements apportes au procede de fabrication en milieu aqueux de feuilles en matieres fibreuses contenant du latex ou analogue et/ou des phenoplastes ou aminoplastes, nouvelles feuilles ainsi obtenues et leur eventuelle reutilisation

Publications (2)

Publication Number Publication Date
EP0067076A1 true EP0067076A1 (de) 1982-12-15
EP0067076B1 EP0067076B1 (de) 1986-03-19

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP82400654A Expired EP0067076B1 (de) 1981-05-12 1982-04-09 Verfahren zur kontinuierlichen Herstellung in wässriger Umgebung von Latex oder analoge Zusammensetzungen und/oder Phenoplaste oder Aminoplaste enthaltenden Faserbahnen, die so hergestellten Bahnen und ihre mögliche Wiederverwendung

Country Status (9)

Country Link
US (1) US4445972A (de)
EP (1) EP0067076B1 (de)
JP (1) JPS57199896A (de)
BR (1) BR8202072A (de)
CA (1) CA1183660A (de)
DE (2) DE3269930D1 (de)
ES (1) ES8307955A1 (de)
FR (1) FR2519663B2 (de)
MX (1) MX160400A (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0109900A1 (de) * 1982-11-17 1984-05-30 Papeteries De Jeand'heurs Verfahren zur Herstellung von Latexhaltenden Papieren und so erhaltene Papierbahnen
FR2647819A1 (fr) * 1989-05-31 1990-12-07 Dalle & Lecomte Papeteries Procede de preparation de produits fibreux en forme de feuilles et a base de cellulose par voie papetiere et enrichis de resines elastomeres

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0643680B2 (ja) * 1984-07-12 1994-06-08 敏 木村 単層繊維板の製造方法
US4550131A (en) * 1984-10-30 1985-10-29 The Dow Chemical Company Aqueous slurry process for preparing reinforced polymeric composites
JPH0429700U (de) * 1990-07-02 1992-03-10
US5895557A (en) * 1996-10-03 1999-04-20 Kimberly-Clark Worldwide, Inc. Latex-saturated paper
EP0991816B1 (de) * 1997-06-12 2002-02-13 WKP Württembergische Kunststoffplatten-Werke GmbH & Co. KG Verfahren zum herstellen von papier
US6572736B2 (en) 2000-10-10 2003-06-03 Atlas Roofing Corporation Non-woven web made with untreated clarifier sludge
US20030121627A1 (en) * 2001-12-03 2003-07-03 Sheng-Hsin Hu Tissue products having reduced lint and slough
US6752905B2 (en) * 2002-10-08 2004-06-22 Kimberly-Clark Worldwide, Inc. Tissue products having reduced slough
CA2652063C (en) * 2009-01-30 2016-03-08 3M Innovative Properties Company Tape comprising recycled paper
EP2386614A1 (de) * 2010-04-21 2011-11-16 Neenah Gessner GmbH Umweltfreundliches Klebebandpapier und daraus hergestelltes Klebeband

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2563897A (en) * 1945-07-13 1951-08-14 American Cyanamid Co Sizing cellulosic fibers with cationic melamine resin and hydrophobic material
US2601597A (en) * 1946-09-06 1952-06-24 American Cyanamid Co Application of dispersed coating materials to cellulosic fibers
US3502497A (en) * 1964-08-26 1970-03-24 Johnson & Johnson Pressure-sensitive adhesive product
DE2013077A1 (en) * 1970-03-19 1971-10-07 Creped release paper
US3619347A (en) * 1969-03-13 1971-11-09 Salvox Mfg Co Recovery of wastepaper treated with urea or the like resins to impart wet strength
US3873411A (en) * 1973-06-29 1975-03-25 Johnson & Johnson Methods of recovering reusable fibers
EP0006390A1 (de) * 1978-06-20 1980-01-09 Arjomari-Prioux S.A. Verfahren zur Herstellung einer Faserbahn nach einer Papierherstellungsmethode im Hinblick auf eine Verbesserung der Bindung und der Retention, eine nach diesem Verfahren hergestellte Bahn und ihre Verwendung als Ersatzmaterial für Asbestprodukte und als Druck- oder Schreibunterlage

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5236138B2 (de) * 1972-06-26 1977-09-13
NL7707451A (nl) * 1976-07-06 1978-01-10 Rochette Cenpa Gevormd vezelachtig materiaal in de vorm van een vel en de bereiding ervan.
FR2429293A1 (fr) * 1978-06-20 1980-01-18 Arjomari Prioux Feuille minerale, son procede de preparation et son utilisation notamment dans le domaine des revetements et des supports d'impression-ecriture
FR2435554A1 (fr) * 1978-09-08 1980-04-04 Dalle & Lecomte Papeteries Produit papetier a forte teneur en charge
US4274916A (en) * 1979-10-01 1981-06-23 Congoleum Corporation Dimensionally stable backing materials for surface coverings and methods of making the same

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2563897A (en) * 1945-07-13 1951-08-14 American Cyanamid Co Sizing cellulosic fibers with cationic melamine resin and hydrophobic material
US2601597A (en) * 1946-09-06 1952-06-24 American Cyanamid Co Application of dispersed coating materials to cellulosic fibers
US3502497A (en) * 1964-08-26 1970-03-24 Johnson & Johnson Pressure-sensitive adhesive product
US3619347A (en) * 1969-03-13 1971-11-09 Salvox Mfg Co Recovery of wastepaper treated with urea or the like resins to impart wet strength
DE2013077A1 (en) * 1970-03-19 1971-10-07 Creped release paper
US3873411A (en) * 1973-06-29 1975-03-25 Johnson & Johnson Methods of recovering reusable fibers
EP0006390A1 (de) * 1978-06-20 1980-01-09 Arjomari-Prioux S.A. Verfahren zur Herstellung einer Faserbahn nach einer Papierherstellungsmethode im Hinblick auf eine Verbesserung der Bindung und der Retention, eine nach diesem Verfahren hergestellte Bahn und ihre Verwendung als Ersatzmaterial für Asbestprodukte und als Druck- oder Schreibunterlage

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
ABSTRACT BULLETIN OF THE INSTITUTE OF PAPER CHEMISTRY, vol.51, no.3, septembre 1980, Appleton, Wisc. (US) *
TAPPI, vol.60, no.7, juillet 1977 *
TAPPI, vol.61, no.11, novembre 1978, Atlanta G.A., (US) *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0109900A1 (de) * 1982-11-17 1984-05-30 Papeteries De Jeand'heurs Verfahren zur Herstellung von Latexhaltenden Papieren und so erhaltene Papierbahnen
FR2647819A1 (fr) * 1989-05-31 1990-12-07 Dalle & Lecomte Papeteries Procede de preparation de produits fibreux en forme de feuilles et a base de cellulose par voie papetiere et enrichis de resines elastomeres
EP0406039A1 (de) * 1989-05-31 1991-01-02 Papeteries Dalle Et Lecomte S.A. Verfahren zur Herstellung von mit elastomerischen Harzen angereicherten Faserbahnen aus Zellstoff nach Papiermacherart

Also Published As

Publication number Publication date
DE3269930D1 (en) 1986-04-24
CA1183660A (en) 1985-03-12
ES510869A0 (es) 1983-07-01
BR8202072A (pt) 1983-03-22
US4445972A (en) 1984-05-01
JPS57199896A (en) 1982-12-07
FR2519663B2 (fr) 1985-08-16
FR2519663A2 (fr) 1983-07-18
MX160400A (es) 1990-02-16
ES8307955A1 (es) 1983-07-01
EP0067076B1 (de) 1986-03-19
DE67076T1 (de) 1983-05-11

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