EP0111074A2 - Concentré d'adoucisseur du linge - Google Patents

Concentré d'adoucisseur du linge Download PDF

Info

Publication number: EP0111074A2
Authority: EP; European Patent Office
Prior art keywords: laundry; carbon atoms; concentrate; chloride; laundry softening
Prior art date: 1982-11-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP83109466A

Other languages

German (de)

English (en)

Other versions

EP0111074B2 (fr

EP0111074B1 (fr

EP0111074A3 (en

Inventor

Karl-Hans Dr. Müller

Manfred Dr. Diehl

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Evonik Operations GmbH

Original Assignee

Degussa GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-11-27

Filing date

1983-09-23

Publication date

1984-06-20

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6179241&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0111074(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1983-09-23 Application filed by Degussa GmbH filed Critical Degussa GmbH

1983-09-23 Priority to AT83109466T priority Critical patent/ATE25402T1/de

1984-06-20 Publication of EP0111074A2 publication Critical patent/EP0111074A2/fr

1985-08-14 Publication of EP0111074A3 publication Critical patent/EP0111074A3/de

1987-02-04 Application granted granted Critical

1987-02-04 Publication of EP0111074B1 publication Critical patent/EP0111074B1/fr

1990-04-18 Publication of EP0111074B2 publication Critical patent/EP0111074B2/fr

2003-09-23 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000012141 concentrate Substances 0.000 title claims abstract description 18
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 26
239000000377 silicon dioxide Substances 0.000 claims abstract description 11
239000002904 solvent Substances 0.000 claims abstract description 5
239000004902 Softening Agent Substances 0.000 claims description 14
239000000203 mixture Substances 0.000 claims description 2
239000000843 powder Substances 0.000 abstract description 5
230000009969 flowable effect Effects 0.000 abstract 1
235000012239 silicon dioxide Nutrition 0.000 abstract 1
125000004432 carbon atom Chemical group C* 0.000 description 15
239000006185 dispersion Substances 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
150000001412 amines Chemical class 0.000 description 4
239000000126 substance Substances 0.000 description 4
239000003784 tall oil Substances 0.000 description 4
XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 4
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 3
239000004744 fabric Substances 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
150000003856 quaternary ammonium compounds Chemical class 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
239000002253 acid Substances 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000003599 detergent Substances 0.000 description 2
IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 2
REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical class [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
CJSBVQVTGSIUAN-UHFFFAOYSA-M (2,6-dimethyl-4-phenylheptan-4-yl)-dimethyl-(2-phenoxyethyl)azanium;chloride Chemical compound [Cl-].C=1C=CC=CC=1OCC[N+](C)(C)C(CC(C)C)(CC(C)C)C1=CC=CC=C1 CJSBVQVTGSIUAN-UHFFFAOYSA-M 0.000 description 1
HPCNCHRYSMQHBL-UHFFFAOYSA-N 1-(4,5-dihydro-1H-imidazol-1-ium-1-yl)nonadecan-1-ol chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCC(O)[NH+]1CCN=C1 HPCNCHRYSMQHBL-UHFFFAOYSA-N 0.000 description 1
MSJLMQTXVKCUCD-UHFFFAOYSA-M 2-dodecylisoquinolin-2-ium;bromide Chemical compound [Br-].C1=CC=CC2=C[N+](CCCCCCCCCCCC)=CC=C21 MSJLMQTXVKCUCD-UHFFFAOYSA-M 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
239000013543 active substance Substances 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
-1 amine salts Chemical class 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
150000001450 anions Chemical group 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
125000004104 aryloxy group Chemical group 0.000 description 1
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
229960001927 cetylpyridinium chloride Drugs 0.000 description 1
YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000003240 coconut oil Substances 0.000 description 1
235000019864 coconut oil Nutrition 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 1
PSLWZOIUBRXAQW-UHFFFAOYSA-M dimethyl(dioctadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC PSLWZOIUBRXAQW-UHFFFAOYSA-M 0.000 description 1
125000005313 fatty acid group Chemical group 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
150000002462 imidazolines Chemical class 0.000 description 1
JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
229920000847 nonoxynol Polymers 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
229940083254 peripheral vasodilators imidazoline derivative Drugs 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
230000001698 pyrogenic effect Effects 0.000 description 1
230000003381 solubilizing effect Effects 0.000 description 1
SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
239000004753 textile Substances 0.000 description 1
LBLYYCQCTBFVLH-UHFFFAOYSA-M toluenesulfonate group Chemical group C=1(C(=CC=CC1)S(=O)(=O)[O-])C LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 1
SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1
GDJZZWYLFXAGFH-UHFFFAOYSA-M xylenesulfonate group Chemical group C1(C(C=CC=C1)C)(C)S(=O)(=O)[O-] GDJZZWYLFXAGFH-UHFFFAOYSA-M 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads

Definitions

the invention relates to a laundry softener concentrate.
Laundry softening agents are added to the wash liquor to improve the feel and to increase the softness of textile fabrics.
Such laundry softeners can be especially cationic tetraalkylammonium compounds and imidazoline derivatives, the effectiveness of which depends on the chemical nature of the alkyl groups.
laundry softening agents are not water-soluble because of these long alkyl residues, they come on the market in the form of a 5-8% aqueous dispersion.
the large dilution has significant economic disadvantages. Large, bulky and expensive containers are required and, above all, a lot of water is transported. Furthermore, a conceivable automatic dosing in a household washing machine would be made difficult by the large volume of the tanks required.
laundry softener concentrates which are also dispersions and have a laundry softener content of 15 to 30%.
the invention relates to a laundry softening agent concentrate which consists of a mixture of one or more laundry softening agents, synthetic silica and optionally one or more solubilizers.
the laundry softener concentrate can consist solely of the laundry softener and up to 50% by weight of synthetic silica.
the laundry softener concentrate can contain 30 to 35% by weight of synthetic silica.
the active substance content is then up to 70%.
spray-dried precipitated silicas which are both ground and not ground can be used as synthetic silicas.
High-temperature hydrolysis (pyrogenic) silicas can also be used.
the cationic laundry softening agents present in the laundry softening agent concentrate according to the invention are commercially known products. They are preferably cationic nitrogen-containing compounds, such as quaternary ammonium compounds and amine salts, which have one or two straight-chain organic radicals having at least 8 carbon atoms, of which at least one radical is advantageous Contains 12 to 22 carbon atoms.
Quaternary ammonium compounds of the following formula are preferably present as laundry softeners in the agent according to the invention: wherein R 1 for a long-chain aliphatic radical with 8 to 22 carbon atoms or a fatty acid ester group, R 2 for a long-chain aliphatic radical with 8 to 22 carbon atoms or an alkyl radical with 1 to 6 carbon atoms or an aryl, aryloxy, alkoxy or aralkyl radical 6 to 28 carbon atoms or a fatty acid ester group, R 3 and R 4 represent alkyl or hydroxyalkyl radicals having 1 to 6 carbon atoms or hydroxypolyalkoxyalkyl radicals having 4 to 20 carbon atoms and X is an anion which forms a water-soluble salt, such as a halide (chloride, bromide, iodide) ), Sulfate, methosulfate, acetate, hydroxide anion or a similar inorganic solubilizing mono
the nitrogen can be a ring nitrogen and the radicals R and R 3 can be replaced by a ring formed from 4 to 5 carbon atoms. Particularly good results are obtained with those compounds of the formula given in which the radicals R 1 , R 2 , R 3 and R 4 are each straight-chain aliphatic radicals, such as, for example, alkyl radicals.
quaternary ammonium compounds which can be used as laundry softening agents in the laundry softening agent according to the invention are: hydrogenated di-tall oil dimethyl ammonium chloride; ethoxylated distearyl dimethyl ammonium chloride; Dimethyl distearylammonium chloride; Trimethylstearyl ammonium bromide; Cetyltrimethyl ammonium chloride; Di-cocodimethyl ammonium chloride; Cetylpyridinium chloride; Alkyldimethylbenzylammonium chloride with higher alkyl group; Diisobutylphenoxyethyldimethylbenzylammonium chloride; Laurylisoquinolinium bromide; Distearyldimethylammonium bromide; Distearyldimethylammonium methosulfate; Dimethyl-diacachidyl-behenyl-ammonium chloride; Di (soy) dimethyl ammonium chloride; Stearyldimethylbenz
R 5 is a long-chain aliphatic radical having 8 to 22 carbon atoms
R 6 is an alkyl radical having 1 to 6 carbon atoms
R 7 is an alkylamidoalkyl radical having 8 to 22 carbon atoms or a hydroxyalkyl radical having 2 to 6 carbon atoms.
Examples of these are 2-heptadecyl-1-methyl-1- [(2-stearyl-amido) -ethyl] -imidazoline methyl sulfate and 2-heptadecyl-1-hydroxyethyl-imidazoline chloride,
Examples of amines which can be used in the form of their water-soluble salts in the laundry softening agent according to the invention are primary tall oil amine, primary cocoamine, primary hydrogenated tall oil amine, tall oil 1,3-propylene diamine, and oil 1,3- propylene diamine and coco-1,3-propylene diamine.
the particularly useful water-soluble salts of the amines listed above are, for example, the sulfate, the hydrogen sulfate and the chloride.
the term "Coco" stands for fatty acid groups that are present in the fatty acids of coconut oil. Such acids contain 8 to 18 carbon atoms per molecule; the acids with 12 to 14 carbon atoms predominate.
the laundry softener concentrates according to the invention can contain up to a total of 35% by weight of a solubilizer and water, based on the amount of laundry softener.
solubilizers can be used as solubilizers: isopropanol, ethanol, glycol, benzenesulfonates, toluenesulfonates, xylenesulfonates or wetting agents, e.g. nonionic surfactants such as nonylphenol ethoxylates, fatty alcohol ethoxylates and others
the laundry softener concentrate according to the invention is a free-flowing powder. It can be stored and, due to its powdery nature, requires only a small packaging space. It is easy to dose and can be combined with detergent if necessary.
the Sipernat 22 silica used is a precipitated and spray-dried silica. It has the following physico-chemical characteristics:
the Sipernat 22 S silica used is a spray-dried and ground precipitated silica with the following physico-chemical characteristics:
the Sipernat 50 and 50 S silicas used are spray-dried precipitated silica with the following physico-chemical data:

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Detergent Compositions (AREA)
Woven Fabrics (AREA)
Chemical Or Physical Treatment Of Fibers (AREA)

EP83109466A 1982-11-27 1983-09-23 Concentré d'adoucisseur du linge Expired - Lifetime EP0111074B2 (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
AT83109466T ATE25402T1 (de)	1982-11-27	1983-09-23	Waescheweichmachmittelkonzentrat.

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE3243983		1982-11-27
DE3243983A DE3243983C2 (de)	1982-11-27	1982-11-27	Wäscheweichmachmittelkonzentrat

Publications (4)

Publication Number	Publication Date
EP0111074A2 true EP0111074A2 (fr)	1984-06-20
EP0111074A3 EP0111074A3 (en)	1985-08-14
EP0111074B1 EP0111074B1 (fr)	1987-02-04
EP0111074B2 EP0111074B2 (fr)	1990-04-18

Family

ID=6179241

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP83109466A Expired - Lifetime EP0111074B2 (fr)	1982-11-27	1983-09-23	Concentré d'adoucisseur du linge

Country Status (7)

Country	Link
US (1)	US4589989A (fr)
EP (1)	EP0111074B2 (fr)
JP (1)	JPS59106575A (fr)
AT (1)	ATE25402T1 (fr)
CA (1)	CA1226704A (fr)
DE (2)	DE3243983C2 (fr)
IL (1)	IL70057A (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0163910A1 (fr) *	1984-05-04	1985-12-11	Hoechst Aktiengesellschaft	Produits de lavage contenant un agent adoucissant
EP0151936A3 (en) *	1984-01-25	1986-11-20	Rewo Chemische Werke Gmbh	Powdery laundry softening agent, process for its production and washing agent containing the same
EP0175287A3 (en) *	1984-09-21	1987-01-07	Hoechst Aktiengesellschaft	Organophilic modified layered-silicic acid adsorbents
US5700387A (en) *	1994-04-07	1997-12-23	Lever Brothers Company, Division Of Conopco, Inc.	Fabric softening composition
US5773409A (en) *	1994-04-07	1998-06-30	Lever Brothers Company, Division Of Conopco, Inc.	Fabric softening composition
EP0881279A3 (fr) *	1997-05-26	1999-06-16	Henkel Kommanditgesellschaft auf Aktien	Procédé de préparation de granules contenant un tensioactif cationique
US6914042B2 (en)	2002-03-28	2005-07-05	Unilever Home & Personal Care Usa, A Division Of Conopco, Inc.	Solid fabric conditioning compositions
US6916779B2 (en)	2002-03-28	2005-07-12	Unilever Home & Personal Care Usa Division Of Conopco, Inc.	Fabric conditioning compositions
US6989361B2 (en)	2002-03-28	2006-01-24	Unilever Home & Personal Care Usa Division Of Conopco, Inc.	Solid fabric conditioning compositions
US7704940B2 (en)	2004-04-09	2010-04-27	The Sun Products Corporation	Granulate for use in a cleaning product and process for its manufacture

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DE3243983C2 (de) *	1982-11-27	1984-11-22	Degussa Ag, 6000 Frankfurt	Wäscheweichmachmittelkonzentrat
JPH0742649B2 (ja) *	1987-05-26	1995-05-10	花王株式会社	柔軟仕上剤
ZA907746B (en) *	1989-10-16	1992-05-27	Colgate Palmolive Co	New softening compositions and methods for making and using same
US5185088A (en) *	1991-04-22	1993-02-09	The Procter & Gamble Company	Granular fabric softener compositions which form aqueous emulsion concentrates
GB9209170D0 (en) *	1992-04-28	1992-06-10	Unilever Plc	Rinse conditioner
WO1994007979A1 (fr) *	1992-09-28	1994-04-14	The Procter & Gamble Company	Procede d'utilisation d'un adoucissant de tissu en particules solides dans un distributeur de dosage automatique
US5458799A (en) *	1993-08-03	1995-10-17	Amway Corporation	Mix process for formulating detergents
US5714451A (en) *	1996-03-15	1998-02-03	Amway Corporation	Powder detergent composition and method of making
WO1997033958A1 (fr) *	1996-03-15	1997-09-18	Amway Corporation	Particules d'azurant disjointes, leur procede de fabrication et detergent en poudre les contenant
WO1997033957A1 (fr) *	1996-03-15	1997-09-18	Amway Corporation	Composition detergente en poudre presentant une solubilite amelioree
US5714450A (en) *	1996-03-15	1998-02-03	Amway Corporation	Detergent composition containing discrete whitening agent particles
US6177397B1 (en)	1997-03-10	2001-01-23	Amway Corporation	Free-flowing agglomerated nonionic surfactant detergent composition and process for making same
US6130193A (en) *	1998-02-06	2000-10-10	Precision Fabrics Group, Inc.	Laundry detergent compositions containing silica for laundry detergent sheets
US5990423A (en) *	1998-05-28	1999-11-23	Eze Weigh, Llc	Mobile hospital bed scale
US7232962B2 (en) *	1998-05-28	2007-06-19	Richard Rynd	Mobile hospital bed scale
EP1502942A1 (fr) *	2003-07-29	2005-02-02	Clariant International Ltd.	Composition adoucissante solide
US20070130694A1 (en) *	2005-12-12	2007-06-14	Michaels Emily W	Textile surface modification composition
US7655609B2 (en)	2005-12-12	2010-02-02	Milliken & Company	Soil release agent
EP3954743A1 (fr)	2020-08-12	2022-02-16	Evonik Operations GmbH	Utilisation de dioxyde de silicium pour améliorer la conductivité des revêtements

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US3095373A (en) *	1959-01-30	1963-06-25	Wyandotte Chemicals Corp	Fabric softeners
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US3533942A (en) *	1968-04-29	1970-10-13	American Potash & Chem Corp	Process for loading expanded water-solution hydrate salt particles
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US4001123A (en) *	1972-09-11	1977-01-04	Colgate-Palmolive Company	Fabric softener compositions containing N-alkyl-1,3-propylene diamine treated with maleic anhydride
US3977980A (en) *	1974-01-04	1976-08-31	American Can Company	Solid fabric conditioner composition
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US4255294A (en) *	1975-04-01	1981-03-10	Lever Brothers	Fabric softening composition
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US4025444A (en) *	1975-08-18	1977-05-24	The Procter & Gamble Company	Fabric softening agents
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1982
- 1982-11-27 DE DE3243983A patent/DE3243983C2/de not_active Expired
1983
- 1983-09-23 DE DE8383109466T patent/DE3369699D1/de not_active Expired
- 1983-09-23 AT AT83109466T patent/ATE25402T1/de not_active IP Right Cessation
- 1983-09-23 EP EP83109466A patent/EP0111074B2/fr not_active Expired - Lifetime
- 1983-10-26 IL IL70057A patent/IL70057A/xx unknown
- 1983-11-25 JP JP58220823A patent/JPS59106575A/ja active Granted
- 1983-11-25 CA CA000441938A patent/CA1226704A/fr not_active Expired
1984
- 1984-11-16 US US06/672,164 patent/US4589989A/en not_active Expired - Fee Related

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0151936A3 (en) *	1984-01-25	1986-11-20	Rewo Chemische Werke Gmbh	Powdery laundry softening agent, process for its production and washing agent containing the same
EP0163910A1 (fr) *	1984-05-04	1985-12-11	Hoechst Aktiengesellschaft	Produits de lavage contenant un agent adoucissant
AU574460B2 (en) *	1984-05-04	1988-07-07	Clariant Gmbh	Softener-containing washing composition which optionally contains quaternary ammonium compounds
EP0175287A3 (en) *	1984-09-21	1987-01-07	Hoechst Aktiengesellschaft	Organophilic modified layered-silicic acid adsorbents
US5700387A (en) *	1994-04-07	1997-12-23	Lever Brothers Company, Division Of Conopco, Inc.	Fabric softening composition
US5773409A (en) *	1994-04-07	1998-06-30	Lever Brothers Company, Division Of Conopco, Inc.	Fabric softening composition
EP0881279A3 (fr) *	1997-05-26	1999-06-16	Henkel Kommanditgesellschaft auf Aktien	Procédé de préparation de granules contenant un tensioactif cationique
US6914042B2 (en)	2002-03-28	2005-07-05	Unilever Home & Personal Care Usa, A Division Of Conopco, Inc.	Solid fabric conditioning compositions
US6916779B2 (en)	2002-03-28	2005-07-12	Unilever Home & Personal Care Usa Division Of Conopco, Inc.	Fabric conditioning compositions
US6989361B2 (en)	2002-03-28	2006-01-24	Unilever Home & Personal Care Usa Division Of Conopco, Inc.	Solid fabric conditioning compositions
US7704940B2 (en)	2004-04-09	2010-04-27	The Sun Products Corporation	Granulate for use in a cleaning product and process for its manufacture

Also Published As

Publication number	Publication date
JPH0152506B2 (fr)	1989-11-09
IL70057A (en)	1987-10-30
EP0111074B2 (fr)	1990-04-18
DE3243983A1 (de)	1984-05-30
DE3243983C2 (de)	1984-11-22
EP0111074B1 (fr)	1987-02-04
JPS59106575A (ja)	1984-06-20
CA1226704A (fr)	1987-09-15
IL70057A0 (en)	1984-01-31
EP0111074A3 (en)	1985-08-14
US4589989A (en)	1986-05-20
DE3369699D1 (en)	1987-03-12
ATE25402T1 (de)	1987-02-15

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Publication	Publication Date	Title
EP0111074B1 (fr)	1987-02-04	Concentré d'adoucisseur du linge
DE69032769T2 (de)	1999-07-22	Weichspülerzusammensetzungen und Verfahren zu deren Herstellung und Verwendung
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EP0783560B1 (fr)	2002-04-10	Detergents desinfectants pour surfaces dures
DE2318324C3 (de)	1981-11-26	Weichspülmittelmischungen für Textilien
AT395614B (de)	1993-02-25	Bestaendige, waessrige, giessbare und wasserdispergierbare textilweichmachungszusammensetzung
EP0240727A2 (fr)	1987-10-14	Concentré pour adoucir les matières textiles
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EP1018541A1 (fr)	2000-07-12	Compositions adoucissantes et transparentes
DE2304204A1 (de)	1973-08-02	Herbicide zusammensetzung
DE1130956B (de)	1962-06-07	Amphotere oberflaechenaktive Mittel und quaternaere Verbindungen enthaltende Reinigungsmittel
DE69109579T2 (de)	1995-12-21	Textilweichmacherzusammensetzung.
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DE4437032A1 (de)	1996-04-18	Textile Weichmacher-Konzentrate
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DE2906490C2 (fr)	1990-07-26
DE69407297T2 (de)	1998-07-09	Wäscheweichmachenzusammensetzungen
DE2060849A1 (de)	1971-06-24	Waschmittel zum gleichzeitigen Reinigen und Weichmachen
CH638829A5 (de)	1983-10-14	Konzentrierte waescheweichspuelzusammensetzung, verfahren zu deren herstellung und deren verwendung.
CH627214A5 (fr)	1981-12-31
DE69327969T2 (de)	2000-10-26	Waescheweichmacherzusammensetzung fuer gewebe
EP0074078A2 (fr)	1983-03-16	Produit de rinçage adoucissant pour le linge
DE3816328A1 (de)	1989-11-23	Verfahren zur herstellung von quaternaeren ammoniumsalzen langkettiger aliphatischer carbonsaeuren und verwendung dieser ammoniumsalze
DE69117995T2 (de)	1996-09-05	Verfahren zur Herstellung und Zusammensetzung von mehrkomponentigen hundertprozent festen Wäscheweichmachmitteln