EP0130659A1 - Verfahren zur Erlangung einer metallisierten Oberfläche durch Härtung mittels Elektronenstrahlen - Google Patents
Verfahren zur Erlangung einer metallisierten Oberfläche durch Härtung mittels Elektronenstrahlen Download PDFInfo
- Publication number
- EP0130659A1 EP0130659A1 EP84300108A EP84300108A EP0130659A1 EP 0130659 A1 EP0130659 A1 EP 0130659A1 EP 84300108 A EP84300108 A EP 84300108A EP 84300108 A EP84300108 A EP 84300108A EP 0130659 A1 EP0130659 A1 EP 0130659A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- substrate
- transfer agent
- varnish
- electron beam
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 63
- 230000008569 process Effects 0.000 title claims abstract description 50
- 238000001227 electron beam curing Methods 0.000 title claims abstract description 19
- 239000000758 substrate Substances 0.000 claims abstract description 69
- 238000012546 transfer Methods 0.000 claims abstract description 66
- 239000002966 varnish Substances 0.000 claims abstract description 62
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 59
- 238000000576 coating method Methods 0.000 claims abstract description 32
- 239000011248 coating agent Substances 0.000 claims abstract description 28
- 238000001723 curing Methods 0.000 claims abstract description 17
- 238000010030 laminating Methods 0.000 claims abstract description 12
- 238000000151 deposition Methods 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 16
- 238000001465 metallisation Methods 0.000 claims description 14
- -1 polypropylene Polymers 0.000 claims description 14
- 238000007639 printing Methods 0.000 claims description 14
- 238000010894 electron beam technology Methods 0.000 claims description 10
- 239000000123 paper Substances 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- 238000013461 design Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 230000005855 radiation Effects 0.000 claims description 6
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 5
- 239000004800 polyvinyl chloride Substances 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 239000010931 gold Substances 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- 239000004627 regenerated cellulose Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 3
- 239000011111 cardboard Substances 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- 239000010985 leather Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 239000002023 wood Substances 0.000 claims description 2
- 239000002923 metal particle Substances 0.000 claims 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- 239000011347 resin Substances 0.000 claims 2
- 229920005989 resin Polymers 0.000 claims 2
- 239000010409 thin film Substances 0.000 claims 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- 238000007865 diluting Methods 0.000 claims 1
- 239000010408 film Substances 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 229920003023 plastic Polymers 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 239000011135 tin Substances 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 4
- 238000003475 lamination Methods 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 9
- 239000012467 final product Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000011888 foil Substances 0.000 description 6
- 238000000926 separation method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 230000032798 delamination Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000007647 flexography Methods 0.000 description 3
- 238000001459 lithography Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000581017 Oliva Species 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 206010073306 Exposure to radiation Diseases 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 238000005234 chemical deposition Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 230000005672 electromagnetic field Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000005026 oriented polypropylene Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/10—Applying flat materials, e.g. leaflets, pieces of fabrics
- B44C1/14—Metallic leaves or foils, e.g. gold leaf
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
- B05D1/286—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers using a temporary backing to which the coating has been applied
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/068—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using ionising radiations (gamma, X, electrons)
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/02—Metal coatings
- D21H19/04—Metal coatings applied as foil
Definitions
- the substrate which is to be coated with the metallic film may be in a web or sheet form and have a rough or smooth surface.
- Suitable substrates include any sheet material such as paper, cardboard, wood, leather and other fabrics.
- the optimum amount of varnish that may be applied is readily determined by those skilled in this art. This amount varies depending upon the viscosity of the varnish, the degree to which the varnish is reduced with solvents, the pressure used during the lamination step, the hardness of the pressure rolls, and the porosity and surface irregularities of the substrate.
- the transfer agent undergoes the step of metallic deposition at step 22 in accordance with the method of metallization described in detail in U.S. Patent No. 4,215,170.
- transfer agent 20 is fed into a conventional vacuum chamber where a metal such as aluminum is deposited upon the transfer agent. While thicker metallic coatings may be desirable for some applications, the resultant metallic film on the transfer agent preferably has a thickness of approximately 100 ⁇ to 500i (0.01 to 0.05pm) and this extremely small thickness permits minimal use of metallic materials yet upon conclusion of the process gives the appearance of a completely metallized and continuous metal surface.
- a varnish designated KC80-384 (Sun, GPI) is printed by lithography on a coated board.
- the printed substrate is immediately laminated with a vacuum metallized, biaxially oriented, untreated polypropylene film and passed through the electron beam curing unit where it is cured with a dose of 3 Mrad electron beam radiation.
- the polypropylene film is immediately delaminated from the coated board.
Landscapes
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemically Coating (AREA)
- Decoration By Transfer Pictures (AREA)
- Physical Vapour Deposition (AREA)
- Printing Methods (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US50909583A | 1983-06-28 | 1983-06-28 | |
| US509095 | 1983-06-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0130659A1 true EP0130659A1 (de) | 1985-01-09 |
Family
ID=24025244
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP84300108A Withdrawn EP0130659A1 (de) | 1983-06-28 | 1984-01-09 | Verfahren zur Erlangung einer metallisierten Oberfläche durch Härtung mittels Elektronenstrahlen |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0130659A1 (de) |
| JP (1) | JPS609796A (de) |
| KR (1) | KR910007132B1 (de) |
| AU (1) | AU2317484A (de) |
| BR (1) | BR8401388A (de) |
| ES (1) | ES532886A0 (de) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU580725B2 (en) * | 1986-10-15 | 1989-01-27 | National Starch & Chemical Corporation | Method of manufacture of highly reflective metallized paper |
| NL1000614C2 (nl) * | 1995-06-20 | 1996-12-23 | Leer Koninklijke Emballage | Werkwijze voor het vervaardigen van een gelamineerd produkt. |
| FR2736649A1 (fr) * | 1995-07-10 | 1997-01-17 | Bordage Michel | Procede et dispositif pour fixer au moins une matiere sur une base, notamment souple, telle que tissu ou cuir, et objet ainsi obtenu |
| EP0858912A3 (de) * | 1997-02-12 | 1999-02-10 | TRW Inc. | Folientransfermetallisierungsverfahren |
| WO2004035856A1 (en) * | 2002-10-19 | 2004-04-29 | Stephen Anthony Noble | Process for metal-coating wood |
| US6858253B2 (en) | 2001-05-31 | 2005-02-22 | 3M Innovative Properties Company | Method of making dimensionally stable composite article |
| CN115516167A (zh) * | 2020-05-07 | 2022-12-23 | 斯道拉恩索公司 | 生产纳米涂覆的基材的工艺 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2311337B1 (es) * | 2006-02-21 | 2009-10-26 | Jose Antonio Menendez Hevia | "procedimiento de pintura". |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4215170A (en) * | 1978-02-28 | 1980-07-29 | Eurographics Holding, N. V. | Metallization process |
| EP0050398A2 (de) * | 1980-10-02 | 1982-04-28 | Scott Paper Company | Trennfolie sowie Verfahren und Vorrichtung zum Erhalten eines Oberflächenabzugs in einem klebstoffabweisenden Überzug |
-
1984
- 1984-01-09 EP EP84300108A patent/EP0130659A1/de not_active Withdrawn
- 1984-01-10 AU AU23174/84A patent/AU2317484A/en not_active Abandoned
- 1984-01-14 JP JP59005504A patent/JPS609796A/ja active Pending
- 1984-03-26 BR BR8401388A patent/BR8401388A/pt unknown
- 1984-05-03 KR KR1019840002405A patent/KR910007132B1/ko not_active Expired
- 1984-05-28 ES ES532886A patent/ES532886A0/es active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4215170A (en) * | 1978-02-28 | 1980-07-29 | Eurographics Holding, N. V. | Metallization process |
| EP0050398A2 (de) * | 1980-10-02 | 1982-04-28 | Scott Paper Company | Trennfolie sowie Verfahren und Vorrichtung zum Erhalten eines Oberflächenabzugs in einem klebstoffabweisenden Überzug |
Non-Patent Citations (1)
| Title |
|---|
| ABSTRACT BULLETIN OF THE INSTITUTE OF PAPER CHEMISTRY, vol. 52, no. 1, July 1981, page 124, no. 1032, Appleton, Wisc., US & JP - A - 55 163 294 (T. TAKAHASHI et al.) 19-12-1980 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU580725B2 (en) * | 1986-10-15 | 1989-01-27 | National Starch & Chemical Corporation | Method of manufacture of highly reflective metallized paper |
| NL1000614C2 (nl) * | 1995-06-20 | 1996-12-23 | Leer Koninklijke Emballage | Werkwijze voor het vervaardigen van een gelamineerd produkt. |
| WO1997000782A1 (en) * | 1995-06-20 | 1997-01-09 | Koninklijke Emballage Industrie Van Leer B.V. | Process of manufacturing a laminated product |
| FR2736649A1 (fr) * | 1995-07-10 | 1997-01-17 | Bordage Michel | Procede et dispositif pour fixer au moins une matiere sur une base, notamment souple, telle que tissu ou cuir, et objet ainsi obtenu |
| WO1997002957A1 (fr) * | 1995-07-10 | 1997-01-30 | Ted Lapidus | Procede et dispositif pour fixer des materiaux sur une base, et objet obtenu |
| EP0858912A3 (de) * | 1997-02-12 | 1999-02-10 | TRW Inc. | Folientransfermetallisierungsverfahren |
| US6858253B2 (en) | 2001-05-31 | 2005-02-22 | 3M Innovative Properties Company | Method of making dimensionally stable composite article |
| WO2004035856A1 (en) * | 2002-10-19 | 2004-04-29 | Stephen Anthony Noble | Process for metal-coating wood |
| CN115516167A (zh) * | 2020-05-07 | 2022-12-23 | 斯道拉恩索公司 | 生产纳米涂覆的基材的工艺 |
| US12286756B2 (en) | 2020-05-07 | 2025-04-29 | Stora Enso Oyj | Process for production of nano-coated substrate |
Also Published As
| Publication number | Publication date |
|---|---|
| ES8600423A1 (es) | 1985-10-01 |
| JPS609796A (ja) | 1985-01-18 |
| BR8401388A (pt) | 1985-04-30 |
| KR910007132B1 (ko) | 1991-09-18 |
| KR850000309A (ko) | 1985-02-26 |
| AU2317484A (en) | 1985-01-03 |
| ES532886A0 (es) | 1985-10-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Designated state(s): AT BE CH DE FR GB IT LI LU NL SE |
|
| 17P | Request for examination filed |
Effective date: 19850409 |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: PFAHL, KURT ALBERT Inventor name: GLASSCOCK, STEPHEN Inventor name: HEINZER, PAUL A. Inventor name: BROWN, WILLIAMEDWARD |
|
| 17Q | First examination report despatched |
Effective date: 19860423 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19870806 |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: PFAHL, KURT ALBERT Inventor name: GLASSCOCK, STEPHEN Inventor name: BROWN, WILLIAMEDWARD Inventor name: HEINZER, PAUL A. |