EP0163356A2 - Verfahren zur Aufbereitung von stabilen Gemischen von Kohle und Öl - Google Patents

Verfahren zur Aufbereitung von stabilen Gemischen von Kohle und Öl Download PDF

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Publication number
EP0163356A2
EP0163356A2 EP85200842A EP85200842A EP0163356A2 EP 0163356 A2 EP0163356 A2 EP 0163356A2 EP 85200842 A EP85200842 A EP 85200842A EP 85200842 A EP85200842 A EP 85200842A EP 0163356 A2 EP0163356 A2 EP 0163356A2
Authority
EP
European Patent Office
Prior art keywords
coal
mixture
oil
water
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP85200842A
Other languages
English (en)
French (fr)
Other versions
EP0163356A3 (de
Inventor
Mariano Carello
Fabio Romanini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agip Petroli SpA
Original Assignee
Agip Petroli SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agip Petroli SpA filed Critical Agip Petroli SpA
Publication of EP0163356A2 publication Critical patent/EP0163356A2/de
Publication of EP0163356A3 publication Critical patent/EP0163356A3/de
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/32Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • C10L1/324Dispersions containing coal, oil and water

Definitions

  • the present invention relates to a process for the preparation of stable mixtures of coal and oil, using water as the stabilizer additive.
  • coal is presently hindered to a determining_extent by the need of substantial investments having to be done to the purpose of modify the fuel combustion, storage and handling systems.
  • One of such technologies is that of producing mixtures of coal and fuel oil.
  • the first type consits in accomplishing a ultra-fine grinding of the coal, so as to produce a colloidal suspen sion.
  • Such a type of process requires high investment and operating costs for the ultra-grinding, and requires as well the use of equipment which is not yet completely reliable from the constructive viewpoint.
  • a known process using water as the stabilizer additive consists in grinding coal down-to particle size comprised within the range of from 3 to 6 mm, mixing it with water, mixing the water-coal mixture with oil and finally grinding the mixture formed down to 0.5 mm.
  • the process which is the object of the present invention comprises the following steps:
  • the homogenizing can be obtained by means of the impact of the mixture containing water, coal and oil against a surface preferably perpendicular to the flow direction of the mixture itself.
  • the water content in the mixture as under point (c) is preferably comprised within the range of from 8 to 12% by weight relatively to the mixture itself.
  • the usable oil can be fuel oil.
  • the coal ground has been mixed first with water in an amount of about 22.2% by weight relatively to the coal and then with heavy fuel oil; the mixture formed has been homogenized by means of the emulsifier equipment schematically shown in herewith enclosed figura, a brief explanation of which is now given.
  • the mixture of coal, oil and water (1) enters, delivered under pressure, the equipment, runs through the feed ing duct (2), then through the convergent cone-frustum shaped duct (3), subsequently at high speed through the duct of constant section (4), and penetrates then into a chamber (5), called plenum chamber, of cylindrical shape with movable adjustable bottom (6), going to collide with the same bottom of said chamber.
  • the mixture passes from the ple num chamber through a plurality of holes (7) uniformly dis tributed in the lateral wall (8) of said chamber into a discharge chamber (9) annular and coaxial to the said plenum chamber and leaves (10) the device.
  • the discharge chamber is bounded by the outer wall of the plenum chamber and by a cylindrical manifold (11).
  • the feeding duct, the cone-frustum shaped duct and the duct of constant section are made in two blocks (12) and (13).
  • the movable adjustable bottom allows the length and obviously the volume of the plenum chamber to be varied above all on the basis of the flow rate and of the composition of the mixture.
  • the dimensions of the emulsifier used are the following: angle between the major base and the lateral wall of the cone-frustum shaped duct 60°
  • the diameter of the plenum chamber and the diameter - of the constant-section duct have been so selected, as to obtain a 5 bar drop in mixture pressure between the inlet of the constant-section duct and the plenum chamber.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
EP85200842A 1984-05-29 1985-05-23 Verfahren zur Aufbereitung von stabilen Gemischen von Kohle und Öl Ceased EP0163356A3 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT2113884 1984-05-29
IT21138/84A IT1183057B (it) 1984-05-29 1984-05-29 Procedimento per la preparazione di miscele stabili di carbone e olio

Publications (2)

Publication Number Publication Date
EP0163356A2 true EP0163356A2 (de) 1985-12-04
EP0163356A3 EP0163356A3 (de) 1988-01-27

Family

ID=11177306

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85200842A Ceased EP0163356A3 (de) 1984-05-29 1985-05-23 Verfahren zur Aufbereitung von stabilen Gemischen von Kohle und Öl

Country Status (4)

Country Link
EP (1) EP0163356A3 (de)
DK (1) DK236985A (de)
GR (2) GR851288B (de)
IT (1) IT1183057B (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992003521A1 (en) * 1990-08-22 1992-03-05 Union Oil Company Of California Separable coal-oil slurries having controlled sedimentation properties suitable for transport by pipeline

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2162200A (en) * 1935-05-24 1939-06-13 Ig Farbenindustrie Ag Process of preparing dispersions of coal and oil
US4394132A (en) * 1980-05-19 1983-07-19 Ergon, Inc Particulate coal-in-liquid mixture and process for the production thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5096461A (en) * 1989-03-31 1992-03-17 Union Oil Company Of California Separable coal-oil slurries having controlled sedimentation properties suitable for transport by pipeline
WO1992003521A1 (en) * 1990-08-22 1992-03-05 Union Oil Company Of California Separable coal-oil slurries having controlled sedimentation properties suitable for transport by pipeline

Also Published As

Publication number Publication date
IT1183057B (it) 1987-10-05
IT8421138A0 (it) 1984-05-29
GR851288B (de) 1985-11-25
DK236985A (da) 1985-11-30
EP0163356A3 (de) 1988-01-27
DK236985D0 (da) 1985-05-28
GR851287B (de) 1985-11-25

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Inventor name: ROMANINI, FABIO

Inventor name: CARELLO, MARIANO