EP0222696A1 - Procédé de post-traitement de matière cellulosique teinte avec des colorants contenant des groupes sulfoniques - Google Patents

Procédé de post-traitement de matière cellulosique teinte avec des colorants contenant des groupes sulfoniques Download PDF

Info

Publication number: EP0222696A1
Authority: EP; European Patent Office
Prior art keywords: cellulose material; aftertreatment; dyed; acid; sodium
Prior art date: 1985-10-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP86810445A

Other languages

German (de)

English (en)

Other versions

EP0222696B1 (fr

Inventor

Jean-François Dr. Landré

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Novartis AG

Original Assignee

Ciba Geigy AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-10-14

Filing date

1986-10-08

Publication date

1987-05-20

1986-10-08 Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG

1987-05-20 Publication of EP0222696A1 publication Critical patent/EP0222696A1/fr

1990-05-23 Application granted granted Critical

1990-05-23 Publication of EP0222696B1 publication Critical patent/EP0222696B1/fr

2006-10-08 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000463 material Substances 0.000 title claims abstract description 29
238000000034 method Methods 0.000 title claims abstract description 19
229920002678 cellulose Polymers 0.000 claims abstract description 22
239000001913 cellulose Substances 0.000 claims abstract description 22
-1 alkaline earth metal salt Chemical class 0.000 claims abstract description 16
229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 10
239000000985 reactive dye Substances 0.000 claims abstract description 8
239000003513 alkali Substances 0.000 claims abstract description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 21
238000004043 dyeing Methods 0.000 claims description 21
FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Inorganic materials [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 18
239000000975 dye Substances 0.000 claims description 16
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
239000011780 sodium chloride Substances 0.000 claims description 10
239000000243 solution Substances 0.000 claims description 10
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 8
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
230000002378 acidificating effect Effects 0.000 claims description 6
238000001035 drying Methods 0.000 claims description 6
239000011734 sodium Substances 0.000 claims description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
229910052783 alkali metal Inorganic materials 0.000 claims description 4
150000001340 alkali metals Chemical class 0.000 claims description 4
239000011591 potassium Substances 0.000 claims description 4
229910052708 sodium Inorganic materials 0.000 claims description 4
239000007864 aqueous solution Substances 0.000 claims description 3
150000007522 mineralic acids Chemical class 0.000 claims description 3
230000007935 neutral effect Effects 0.000 claims description 3
150000007524 organic acids Chemical class 0.000 claims description 3
229910052700 potassium Inorganic materials 0.000 claims description 3
239000001103 potassium chloride Substances 0.000 claims description 3
235000011164 potassium chloride Nutrition 0.000 claims description 3
235000011151 potassium sulphates Nutrition 0.000 claims description 3
235000015424 sodium Nutrition 0.000 claims description 3
229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
235000011152 sodium sulphate Nutrition 0.000 claims description 3
JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 2
159000000007 calcium salts Chemical class 0.000 claims description 2
239000008367 deionised water Substances 0.000 claims description 2
229910021641 deionized water Inorganic materials 0.000 claims description 2
AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 claims description 2
229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
150000003230 pyrimidines Chemical class 0.000 claims description 2
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims 1
239000012266 salt solution Substances 0.000 claims 1
239000002253 acid Substances 0.000 abstract description 4
239000000982 direct dye Substances 0.000 abstract description 2
235000002639 sodium chloride Nutrition 0.000 description 17
239000004744 fabric Substances 0.000 description 15
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
229920000742 Cotton Polymers 0.000 description 8
150000003839 salts Chemical group 0.000 description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
239000004952 Polyamide Substances 0.000 description 5
229920002647 polyamide Polymers 0.000 description 5
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 4
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
150000003254 radicals Chemical class 0.000 description 3
UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 3
229920002994 synthetic fiber Polymers 0.000 description 3
239000012209 synthetic fiber Substances 0.000 description 3
239000004753 textile Substances 0.000 description 3
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
229920003043 Cellulose fiber Polymers 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
229920000297 Rayon Polymers 0.000 description 2
239000001361 adipic acid Substances 0.000 description 2
235000011037 adipic acid Nutrition 0.000 description 2
239000000987 azo dye Substances 0.000 description 2
239000001110 calcium chloride Substances 0.000 description 2
229910001628 calcium chloride Inorganic materials 0.000 description 2
235000011148 calcium chloride Nutrition 0.000 description 2
ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
239000007859 condensation product Substances 0.000 description 2
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
239000000203 mixture Substances 0.000 description 2
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
235000019353 potassium silicate Nutrition 0.000 description 2
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
235000017557 sodium bicarbonate Nutrition 0.000 description 2
229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
235000017550 sodium carbonate Nutrition 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
235000021286 stilbenes Nutrition 0.000 description 2
MRERMGPPCLQIPD-NBVRZTHBSA-N (3beta,5alpha,9alpha,22E,24R)-3,5,9-Trihydroxy-23-methylergosta-7,22-dien-6-one Chemical compound C1C(O)CCC2(C)C(CCC3(C(C(C)/C=C(\C)C(C)C(C)C)CCC33)C)(O)C3=CC(=O)C21O MRERMGPPCLQIPD-NBVRZTHBSA-N 0.000 description 1
VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 description 1
BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
244000025254 Cannabis sativa Species 0.000 description 1
235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
229920002284 Cellulose triacetate Polymers 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
240000000491 Corchorus aestuans Species 0.000 description 1
235000011777 Corchorus aestuans Nutrition 0.000 description 1
235000010862 Corchorus capsularis Nutrition 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
239000007832 Na2SO4 Substances 0.000 description 1
229930192627 Naphthoquinone Natural products 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
239000001000 anthraquinone dye Substances 0.000 description 1
150000004056 anthraquinones Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
159000000009 barium salts Chemical class 0.000 description 1
ZYGHJZDHTFUPRJ-UHFFFAOYSA-N benzo-alpha-pyrone Natural products C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
239000001639 calcium acetate Substances 0.000 description 1
235000011092 calcium acetate Nutrition 0.000 description 1
229960005147 calcium acetate Drugs 0.000 description 1
235000009120 camo Nutrition 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
235000005607 chanvre indien Nutrition 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
235000001671 coumarin Nutrition 0.000 description 1
125000000332 coumarinyl group Chemical class O1C(=O)C(=CC2=CC=CC=C12)* 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
230000000694 effects Effects 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000002657 fibrous material Substances 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000011487 hemp Substances 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
125000002883 imidazolyl group Chemical group 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
235000011147 magnesium chloride Nutrition 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002791 naphthoquinones Chemical class 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
125000004999 nitroaryl group Chemical group 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
150000004893 oxazines Chemical class 0.000 description 1
IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
235000015497 potassium bicarbonate Nutrition 0.000 description 1
239000011736 potassium bicarbonate Substances 0.000 description 1
229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
239000004323 potassium nitrate Substances 0.000 description 1
235000010333 potassium nitrate Nutrition 0.000 description 1
239000000047 product Substances 0.000 description 1
150000003216 pyrazines Chemical class 0.000 description 1
150000003219 pyrazolines Chemical class 0.000 description 1
CJABVFCUCRAVOK-UHFFFAOYSA-N pyrene-1,2-dione Chemical class C1=C2C(=O)C(=O)C=C(C=C3)C2=C2C3=CC=CC2=C1 CJABVFCUCRAVOK-UHFFFAOYSA-N 0.000 description 1
150000003220 pyrenes Chemical class 0.000 description 1
239000002964 rayon Substances 0.000 description 1
239000004627 regenerated cellulose Substances 0.000 description 1
229940001593 sodium carbonate Drugs 0.000 description 1
239000004317 sodium nitrate Substances 0.000 description 1
235000010344 sodium nitrate Nutrition 0.000 description 1
PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
150000001629 stilbenes Chemical class 0.000 description 1
229940042055 systemic antimycotics triazole derivative Drugs 0.000 description 1
YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/62—Natural or regenerated cellulose using direct dyes
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile

Definitions

a sodium, potassium or calcium salt of hydrochloric acid, sulfuric acid or acetic acid is preferably used, and sodium or potassium chloride or sulfate are particularly preferred.
salts are preferably used as aqueous solutions containing 0.1 to 10% by weight, in particular 0.5 to 5% by weight, of salt.
Suitable cellulose material for the process is textile material made of cellulose fibers or mixtures thereof with synthetic fibers, the cellulose fibers being those made from natural and regenerated cellulose, such as e.g. Hemp, linen, jute, viscose silk, rayon or especially cotton.
the dyeings with reactive dyes are usually carried out in an alkaline medium, but this is often followed by a further treatment which requires an acidic pH value, so that this
the method according to the invention often also has advantages when dyeing with such dyes.
the cellulose material is optionally rinsed with water and then dried in the customary manner.
a cotton fabric is padded with the liquor obtained, so that it increases by 70% of its weight, and then docked at the same edge.
the cotton fabric is stored for 6 hours at room temperature.
the scarlet color obtained has very good wet fastness properties.

Landscapes

Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Coloring (AREA)

EP86810445A 1985-10-14 1986-10-08 Procédé de post-traitement de matière cellulosique teinte avec des colorants contenant des groupes sulfoniques Expired - Lifetime EP0222696B1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CH441985		1985-10-14
CH4419/85		1985-10-14

Publications (2)

Publication Number	Publication Date
EP0222696A1 true EP0222696A1 (fr)	1987-05-20
EP0222696B1 EP0222696B1 (fr)	1990-05-23

Family

ID=4275785

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP86810445A Expired - Lifetime EP0222696B1 (fr)	1985-10-14	1986-10-08	Procédé de post-traitement de matière cellulosique teinte avec des colorants contenant des groupes sulfoniques

Country Status (4)

Country	Link
US (1)	US4826503A (fr)
EP (1)	EP0222696B1 (fr)
JP (1)	JPS6290384A (fr)
DE (1)	DE3671487D1 (fr)

Cited By (1)

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WO2005045125A1 (fr) *	2003-11-11	2005-05-19	Ciba Specialty Chemicals Holding Inc.	Procede de teinture ou d'impression de materiaux a base de fibres textiles mettant en oeuvre des colorants reactifs

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Publication number	Priority date	Publication date	Assignee	Title
JPS6414380A (en) *	1987-06-30	1989-01-18	Norinsuisansho Sanshi Shikenjo	Dyeing of fiber
US5207800A (en) *	1991-10-07	1993-05-04	Burlington Chemical Co., Inc.	Low toxicity, biodegradable salt substitute for dyeing textiles: magnesium acetate in direct or reactive dyeing of cotton
US5330539A (en) *	1991-12-18	1994-07-19	Hoechst Celanese Corporation	Fiber reactive dyes - applications with low salt
EP0610156B1 (fr) *	1993-02-05	1997-05-28	Ciba SC Holding AG	Procédé de teinture ou d'impression de matériaux textiles cellulosiques
WO2002066730A1 (fr) *	2001-02-22	2002-08-29	Toa Kasei Co., Ltd.	Procede de coloration de materiau contenant des fibres de cellulose et article contenant ces fibres de cellulose colore par ce procede

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1986
- 1986-10-08 DE DE8686810445T patent/DE3671487D1/de not_active Expired - Lifetime
- 1986-10-08 EP EP86810445A patent/EP0222696B1/fr not_active Expired - Lifetime
- 1986-10-09 US US06/917,348 patent/US4826503A/en not_active Expired - Fee Related
- 1986-10-14 JP JP61242193A patent/JPS6290384A/ja active Pending

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WO2005045125A1 (fr) *	2003-11-11	2005-05-19	Ciba Specialty Chemicals Holding Inc.	Procede de teinture ou d'impression de materiaux a base de fibres textiles mettant en oeuvre des colorants reactifs
CN100429347C (zh) *	2003-11-11	2008-10-29	西巴特殊化学品控股有限公司	使用活性染料染色或印刷纺织纤维材料的方法
US7553339B2 (en)	2003-11-11	2009-06-30	Huntsman International Llc	Method of dyeing or printing textile fibre materials using reactive dyes

Also Published As

Publication number	Publication date
DE3671487D1 (de)	1990-06-28
JPS6290384A (ja)	1987-04-24
US4826503A (en)	1989-05-02
EP0222696B1 (fr)	1990-05-23

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Publication	Publication Date	Title
EP0222696B1 (fr)	1990-05-23	Procédé de post-traitement de matière cellulosique teinte avec des colorants contenant des groupes sulfoniques
EP0546372A1 (fr)	1993-06-16	Mélanges de colorants réactifs
DE3337799A1 (de)	1984-04-26	Disazoverbindungen, verfahren zu ihrer herstellung und verwendung derselben in einem faerbeverfahren
EP0250365A1 (fr)	1987-12-23	Procédé de post-traitement d'une matière fibreuse cellulosique teinte
DE4305453A1 (de)	1994-08-25	Reaktivfarbstoffblaumischungen mit verbesserter Metamerie
EP0597330A1 (fr)	1994-05-18	Composition de colorants réactifs pour mélanges de fibres polyester/cellulose
DE3141082A1 (de)	1983-04-28	Verfahren zum kontinuierlichen faerben von fasergut von aus organischen loesemitteln versponnenen acrylnitril-polymerisaten im gelzustand
DE2146761C3 (de)	1975-10-02	Verfahren zur Herstellung ichtechter Färbungen auf synthetischen Fasern
EP0273300A2 (fr)	1988-07-06	Procédé de teinture en un seul bain et une seule étape de mélanges de fibres en polyester pouvant être teintes sans véhiculeur et de fibres cellulosiques
DE2815511A1 (de)	1979-10-18	Verfahren zum faerben und bedrucken von textilmaterialien aus zellulose/polyesterfaser-mischungen
EP0044026A1 (fr)	1982-01-20	Procédé pour la teinture de matières fibreuses synthétiques
DE742078C (de)	1943-12-10	Verfahren zur Verbesserung der Reibechtheit von Faerbungen mit direkt ziehenden Farbstoffen auf Mischgeweben aus Wolle und Cellulosefasern
DE2023179C (de)	1972-12-21	Verfahren zum Farben und Bedrucken von Textilfasern
DE2023179A1 (de)	1970-11-19	Verfahren zum Faerben und Bedrucken von Textilfasern
EP0109030B1 (fr)	1986-09-10	Procédé de teinture de produits textiles contenant des fibres de polyester linéaire ignifugées
DE2402599A1 (de)	1974-08-01	Verfahren zum faerben von synthetischen hydrophoben fasern
DE1619513C (de)	1972-04-27	Verfahren zum Färben von Mischungen aus Cellulose- und Polyesterfasern
AT308044B (de)	1973-06-25	Verfahren zum einbadigen Färben von Mischungen aus Cellulose-, Polyester- und sauer modifizierten Polyesterfasern
DE3049170A1 (de)	1981-10-08	"verfahren zum faerben von polyester/cellulose mischgewebe"
DE4443639A1 (de)	1996-06-13	Phthalocyaninreaktivfarbstoffmischung
DE2816465B1 (de)	1979-10-18	Verfahren und Farbstoffzubereitungen zum Klotzfaerben von Mischungen aus Polyester- und Cellulosefasern
DE1261105B (de)	1968-02-15	Verfahren zum Faerben von Textilfasern oder -faeden aus hochmolekularen, hydrophoben, organischen Stoffen
DE1619467A1 (de)	1971-03-11	Verfahren zum Klotzfaerben und Bedrucken von Mischungen aus Cellulosefasern und Fasermaterialien aus linearen Polyestern
DE2227604B1 (de)	1974-03-21	Verfahren zur herstellung von denim-artikeln
DE2000688A1 (de)	1970-07-30	Verfahren zur Herstellung von Catalytic Fading-freier Faerbungen und Drucke auf textilen Materialien