EP0227687A1 - Composition insecticide en poudre contenant du gel de silice - Google Patents
Composition insecticide en poudre contenant du gel de siliceInfo
- Publication number
- EP0227687A1 EP0227687A1 EP85905736A EP85905736A EP0227687A1 EP 0227687 A1 EP0227687 A1 EP 0227687A1 EP 85905736 A EP85905736 A EP 85905736A EP 85905736 A EP85905736 A EP 85905736A EP 0227687 A1 EP0227687 A1 EP 0227687A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- particles
- mix
- metal silicate
- ammonium
- sorptive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims description 48
- 239000000741 silica gel Substances 0.000 title claims description 29
- 229910002027 silica gel Inorganic materials 0.000 title claims description 29
- 239000002245 particle Substances 0.000 claims abstract description 55
- 238000000034 method Methods 0.000 claims abstract description 30
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 22
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 16
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000005507 spraying Methods 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000012216 bentonite Nutrition 0.000 claims abstract description 4
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 4
- 235000013312 flour Nutrition 0.000 claims abstract description 4
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 4
- 239000010451 perlite Substances 0.000 claims abstract description 4
- 235000019362 perlite Nutrition 0.000 claims abstract description 4
- 239000011248 coating agent Substances 0.000 claims description 17
- 238000000576 coating method Methods 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000499 gel Substances 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 241000238631 Hexapoda Species 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 239000005909 Kieselgur Substances 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 2
- 239000003456 ion exchange resin Substances 0.000 claims description 2
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- -1 pyrophiUite Inorganic materials 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 5
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims 5
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 claims 5
- 150000007522 mineralic acids Chemical class 0.000 claims 2
- 150000007524 organic acids Chemical class 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 229910000286 fullers earth Inorganic materials 0.000 claims 1
- 230000003019 stabilising effect Effects 0.000 claims 1
- 230000002745 absorbent Effects 0.000 abstract description 6
- 239000002250 absorbent Substances 0.000 abstract description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229940104869 fluorosilicate Drugs 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 12
- 239000010954 inorganic particle Substances 0.000 description 11
- 239000002917 insecticide Substances 0.000 description 10
- 239000000017 hydrogel Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 7
- 239000004964 aerogel Substances 0.000 description 5
- 239000004115 Sodium Silicate Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004965 Silica aerogel Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Definitions
- Australian Patent 476508 discloses an insecticidal powdered composition useful as a sorptive dust, insecticide which is effective on contact with the insect's waxy epicuticle.
- the inorganic sorptive particles are sized in the range of about 100 to about 500 Tyler screen mesh and are selected from such materials as diatomaceous earth, bentonites, sub-bentonites, montmorillonites, pyrophiUite, Fuller's earth, silica flour carbon and perlite.
- Adhered to the surface of such particles is a coating of sorptive silica gel, this gel ranging from about 0.1% to 10% by weight of the total weight of the coated particles after drying.
- the composition preferably has a packed bulk density from about 15 to about 100 lbs per cubic foot.
- Australian Patent 476508 calls for in-situ gelling of the silica gel onto the inert carrier, the inert carriers suitable in the practice of the invention of the said patent being specified in the body and claims thereof.
- the silica gel and inert carrier mix In the preparation of the product of the said patent the silica gel and inert carrier mix must be washed and decanted several times to remove the sodium sulphate produced during the in-situ gellation. After washing, the product is filtered and dried.
- the water content of a typical formulation, after filtration, is about 70%, that is for each tonne of dry product made, 2.3 or so tonnes of water must be dried off. Obviously the cost of this drying is a significant factor in production costs and any saving in energy costs is advantageous.
- inorganic particles may be coated with an adherent coating of a sorptive silica gel composition, especially hydrogels, and that the particles thus coated are highly effective as insecticides.
- the particles used preferably should have a sorptive surface, that is the particles themselves should be of a sorptive character.
- a compound such as ammonium fluosilicate is included, which is considered to aid in attracting and/or holding the particles to naturally occurring objects including plants and insects.
- the preferred particles for use with the present process are diatomaceous earth (diatoraite) , si'rice it has-been found that such particles are quite effective and also are of comparatively low cost and are readily available.
- diatomaceous earth diatomaceous earth
- si'rice it has-been found that such particles are quite effective and also are of comparatively low cost and are readily available.
- various other sorptive materials may be used, including various bentonites, sub-bentonites, montmorillonites, pyrophyllite, fuller's earths, silica flour, carbon, perlite, and other natural or synthetic substantial equivalents.
- the size of the inorganic particles can be varied to a considerable extent, although the size of the particles is important with regard to the ease with which the insecticide can be distributed.
- the particles should be sufficiently large and/or heavy so that they are capable of settling from "normal” or reasonably quiet air, that is at least about 400 mesh (Tyler screen size) or greater. Because the particles must, however, be sufficiently fine so that they can be easily distributed, they should pass a 100 mesh standard Tyler screen and preferably all or substantially all pass a 200 mesh standard Tyler screen.
- the inorganic particles are coated with an adherent coating of a silica gel, normally a hydrogel.
- Silica aerogels and hydrogels are well known and are used for many purposes such as in the paper and protective coating fields. These aerogels and hydrogels are considered to be highly absorbent for various materials such as water, oils, waxes, and the like. In general, hydrogels tend to be more absorbent toward water and various compositions which are similar to water than aerogels. Conversely, aerogels tend to absorb waxes and various other related compounds characterized by having comparatively long aliphatic hydrocarbon chains to a greater extent than the hydrogels.
- the sorptive characteristics of a hydrogel may be changed by various known expedients so as to produce properties which tend to approximate the sorptive properties of an aerogel.
- the thickness of the silica gel coating on the inorganic particles may be varied considerably and may be either a continuous or discontinuous coating, that is, the inorganic particles may or may not be completely coated.
- the surface of the inorganic particles must have sufficient silica gel coated thereon, however, to impart the necessary sorptive insecticidal properties to the composition. Since the lipid layer of insects is very thin, only a small amount of sorptive silica gel is necessary to kill the insects, and hence only a small quantity of silica gel coating on the inorganic particles is necessary.
- the silica gel coating will be at least 0.1 percent by weight of the total weight of the dry coated particles, and preferably at least about 0.2 percent. Insofar as the effectiveness of the insecticidal composition is concerned, there does not appear to be an upper limit on the quantity of the silica gel coating. For economic reasons, however, the quantity of such coating will be kept to a inumum, generally not exceeding approximately 10 percent by weight of the total weight of the coated particles. It should also be noted that the silica gel coated inorganic particles, of course, are applied in powder form as a batch of the finely divided coated particles rather than as single particles. Consequently, it is not essential that every particle in such batch have the same quantity of silica gel coating, as it is the effect of the total batch which is significant.
- the total batch must contain a sufficient quantity of the sorptive silica gel to provide the necessary insecticidal properties rather than the individual particles. Accordingly, based on the total weight of such a batch, the sorptive silica gel should comprise at least about 0.1 percent by weight and preferably at least 0.2 percent.
- individual particles of the composition may contain little or no silica gel coating. Since the coated particles are used as a batch, however, this will not affect the effectiveness of the composition as an insecticide, so long as the composition as a whole contains the indicated minimum quantity of sorptive silica gel.
- the composition of coated particles for effective results, will normally have a packed bulk density of about 15 to about 100 pounds/cubic foot, preferably about 20 to about 30 pounds/cubic foot, since the composition may be used in unenclosed areas where the effect of wind must be taken into consideration.
- the packed bulk density is the weight/unit volume of the powder when packed in a standard cubic foot container and may be determined simply by filling such a container with the powder and weighing the same.
- the requirement for fresh water is reduced from about 16 tonnes per tonne of product to 3 tonnes per tonne of product.
- the water content of t-he end product, prior to drying is reduced from 2.3 tonnes or so per tonne of product to about 1 tonne per tonne of product.
- the drying heat load is reduced from about 10 gigo-joules per tonne of product to about 5 gigo-joules per tonne of product.
- a process for preparing a powdered insecticidal composition comprising the steps of: forming a silicic acid mix, spraying said mix onto carrier particles of size range 100 to 500 Tyler mesh thereby producing damp sorptive particles coated with said mix in a gel form.
- an insecticidal composition when prepared by the above process.
- a method for erradicating insects at a locus by use of an effective amount of an insecticidal composition prepared according to the method above described.
- sorptive silica gel should be intimately adhered to the inorganic particles as a coating rather than in the form of a mixture of the aerogel or hydrogel and such particles since the degree of adherence produced by mixing is not sufficient because the silica gel and the inorganic particles may be readily separated as, for example, in handling. Further, for reasons which are not clear, the insecticide is not as effective as when a direct, intimate bond is achieved between the silica gel and the inorganic particles.
- ammonium fluosilicate it has been found advantageous to add ammonium fluosilicate to the silicic acid composition prior to dispersal upon the inorganic sorptive particles. This is in contrast with the method of AU 476508 wherein it was disclosed to add the ammonium fluosilicate to the particles after they had been coated with the silica gel.
- the ammonium fluosilicate can be sprayed onto the carrier particles prior to spraying the silicic acid mix onto the carrier particles.
- the ammonium fluosilicate can be sprayed onto the damp sorptive particles coated with the silicic acid mix in a gel form. That is, the ammonium fluosilicate can be added after formation of the silicic acid gel coating and prior to the drying step.
- ammonium fluosilicate reacts in some manner with the sorptive silica gel to provide the desired electrostatic properties to the particles. It should be used in a quantity of at least about 5% by weight based on the weight of the sorptive silica gel.
- a dilute sodium silicate solution (equivalent to a 6% Si0 2 by weight solution) was passed through an ion exchange resin and converted to silicic acid., also of 6% content by weight Si0 2 .
- Ammonium fluosilicate was dissolved in the silicic acid thus produced at a rate of 13.7g per 400g of silicic acid.
- the resulting mixture was sprayed onto 302g of dry diatomaceous earth to give a 7% silica gel coating.
- the resulting damp powder was stabilised with ammonia gas and dried in accordance with the process of Australian Patent No 476508.
- the damp powder contained only 53% water, i.e. 1.1 tonne of water per tonne of product to be removed.
- Example 2 250g of sodium silicate (at a 6% Si0 2 equivalent content in solution) was gelled with sulfuric acid. The resulting gel was cut into small pieces and washed three times using four volumes of water for each wash. After the last decantation, water was added to make up a total weight of 250g. To this was added 13.2g of ammonium fluosilicate and the mixture was dispersed with a high speed mixer then sprayed onto 272g of dry diatomaceous earth to give a 5% silica gel coating. The resulting damp powder contained only 0.75 tonne of water per tonne of product.
- test results were as follows:
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Inorganic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Un procédé de préparation d'une composition insecticide en poudre comprend les étapes de formation d'un mélange d'acide silicique et de fluorosilicate et la pulvérisation du mélange sur des particules porteuses de dimensions comprises entre 100 et 500 mailles de Tyler, produisant ainsi des particules absorbantes humides enduites du mélange sous une forme colloïdale. Les particules absorbantes humides sont de préférence des particules absorbantes inorganiques sélectionnées parmi des diatomites, bentonites, sub-bentonites, montmorillonites, pyrophillites, terre à foulon, farine silicieuse, carbone ou perlite. Les particules absorbantes humides sont stabilisées avec du gaz d'ammonium puis séchées.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU8157/84 | 1984-11-16 | ||
| AUPG815784 | 1984-11-16 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0227687A1 true EP0227687A1 (fr) | 1987-07-08 |
| EP0227687A4 EP0227687A4 (fr) | 1989-07-25 |
Family
ID=3770843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19850905736 Withdrawn EP0227687A4 (fr) | 1984-11-16 | 1985-11-15 | Composition insecticide en poudre contenant du gel de silice. |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0227687A4 (fr) |
| AU (1) | AU582200B2 (fr) |
| BR (1) | BR8507280A (fr) |
| IN (1) | IN164454B (fr) |
| WO (1) | WO1986002807A1 (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU594539B2 (en) * | 1986-12-04 | 1990-03-08 | Dryacide Pty. Ltd. | Insecticidal composition |
| CA2149164C (fr) * | 1995-05-11 | 2009-03-03 | Zlatko Korunic | Compose insecticide a base de diatomite |
| WO1996036220A2 (fr) * | 1995-05-11 | 1996-11-21 | Her Majesty In Right Of Canada, Represented By The Minister Of Agriculture | Composition insecticide contenant de la terre a diatomees et de la silice |
| GB2399501B (en) * | 2000-11-03 | 2005-05-11 | Second Nature Uk Ltd | Protection of fibres from attack by insects |
| CN101343452B (zh) * | 2008-08-12 | 2010-09-29 | 无锡市虎皇漆业有限公司 | 高效杀虫环保涂料及其制备方法 |
| CN104430323A (zh) * | 2014-11-26 | 2015-03-25 | 北京农学院 | 一种缓释农药颗粒剂 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1267974A (en) * | 1968-10-09 | 1972-03-22 | Leonard Roger Lyons | Insecticide |
| US3917814A (en) * | 1969-10-29 | 1975-11-04 | Kenneth B Hedges | Insecticidal composition and method of preparing the same |
| AU476508B2 (en) * | 1975-10-30 | 1976-09-23 | Clough, A. | Insecticidal composition and method of preparing the same |
-
1985
- 1985-11-15 IN IN958/DEL/85A patent/IN164454B/en unknown
- 1985-11-15 AU AU50917/85A patent/AU582200B2/en not_active Ceased
- 1985-11-15 WO PCT/AU1985/000283 patent/WO1986002807A1/fr not_active Ceased
- 1985-11-15 BR BR8507280A patent/BR8507280A/pt unknown
- 1985-11-15 EP EP19850905736 patent/EP0227687A4/fr not_active Withdrawn
Non-Patent Citations (2)
| Title |
|---|
| No relevant documents have been disclosed. * |
| See also references of WO8602807A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| IN164454B (fr) | 1989-03-18 |
| WO1986002807A1 (fr) | 1986-05-22 |
| BR8507280A (pt) | 1987-10-27 |
| AU5091785A (en) | 1986-06-03 |
| EP0227687A4 (fr) | 1989-07-25 |
| AU582200B2 (en) | 1989-03-16 |
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Legal Events
| Date | Code | Title | Description |
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| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
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| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE FR GB IT LI LU NL SE |
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| 17P | Request for examination filed |
Effective date: 19870515 |
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| R17P | Request for examination filed (corrected) |
Effective date: 19870515 |
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| R17P | Request for examination filed (corrected) |
Effective date: 19870515 |
|
| A4 | Supplementary search report drawn up and despatched |
Effective date: 19890725 |
|
| 17Q | First examination report despatched |
Effective date: 19901206 |
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| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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| 18D | Application deemed to be withdrawn |
Effective date: 19910417 |
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| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: HEDGES, KENNETH, BLAKE |