EP0228001A2 - Procédé pour éliminer les formation de salpêtre, pour le séchage et pour maintenir à sec la maçonnerie - Google Patents

Procédé pour éliminer les formation de salpêtre, pour le séchage et pour maintenir à sec la maçonnerie Download PDF

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Publication number
EP0228001A2
EP0228001A2 EP86117283A EP86117283A EP0228001A2 EP 0228001 A2 EP0228001 A2 EP 0228001A2 EP 86117283 A EP86117283 A EP 86117283A EP 86117283 A EP86117283 A EP 86117283A EP 0228001 A2 EP0228001 A2 EP 0228001A2
Authority
EP
European Patent Office
Prior art keywords
masonry
electrodes
desalination
mortar
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86117283A
Other languages
German (de)
English (en)
Other versions
EP0228001B1 (fr
EP0228001A3 (en
Inventor
Manfred Dr. Ing. Hübler
Peter Dr. Rer. Nat. Friese
Klaus Dipl.-Jur. Krüger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bauakademie der DDR
Original Assignee
Bauakademie der DDR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bauakademie der DDR filed Critical Bauakademie der DDR
Priority to AT86117283T priority Critical patent/ATE50306T1/de
Publication of EP0228001A2 publication Critical patent/EP0228001A2/fr
Publication of EP0228001A3 publication Critical patent/EP0228001A3/de
Application granted granted Critical
Publication of EP0228001B1 publication Critical patent/EP0228001B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/70Drying or keeping dry, e.g. by air vents
    • E04B1/7007Drying or keeping dry, e.g. by air vents by using electricity, e.g. electro-osmosis

Definitions

  • the invention relates to a method for desalination, drainage and keeping masonry dry. This is often a necessary prerequisite for the complete renovation of old buildings in which water rises from the ground, which transports soluble salts into the masonry and accumulates in the evaporation zone.
  • DD-PS 200 398 proposes combining active electroosmotic drying with prior desalination of the masonry.
  • this invention has the disadvantage that corrosion-resistant electrodes made of graphite or platinized titanium are used. For their To enable reuse, it is proposed to replace these expensive electrodes with cheaper ones after desalting, but it has been found that the electrodes are subject to severe corrosion even after desalting. With electrodes made of iron, their volume increases many times as a result of the anodic oxidation, as a result of which the electrodes can be pressed out of the masonry and the electrokinetic permanent lock can be interrupted.
  • DE-OS 3430449 and 3430450 only anodic chloride hydrates can be removed from the masonry.
  • Adaptation to the moisture content in the masonry is desirable in order to prevent the masonry from drying out before the end of the desalination process and interrupting the desalination process.
  • the aim of the invention is a method with which masonry in which water rises can be desalinated and drained in a simple manner and can be kept permanently dry.
  • the invention has for its object to find a method with which moisture-damaged masonry with any moisture and salt content first desalted, then drained and then kept dry without the electrodes having to be replaced and without this process being interrupted by premature drying out or by the salts and iron oxides deposited on the electrode.
  • this object is achieved in that one or more mortar bridges are placed between the electrodes arranged in or on the masonry, preferably made of iron, and the masonry depending on the measured moisture and salt content of the masonry Connect the masonry, but so that there is enough space between the electrodes and the masonry to absorb the soluble salts and iron oxides deposited on the electrodes.
  • the invention is based inter alia on the knowledge that the direction of the water flow in the masonry is determined exclusively by the sign of the zeta potential. This results from the formation of a double layer of electrically charged ions at the phase boundary between solid and liquid. The charge carriers in the immediate vicinity of the solid are compensated for by ions that are in a rigid and a diffuse double layer. The potential measured at the boundary between the rigid and diffuse double layer is called the zeta potential. Its sign and size depend on the one hand on the structure and chemical composition of the solid, i.e. the masonry, and on the other hand on the properties of the adjacent liquid.
  • Negative zeta potentials are very likely to be found in brick masonry.
  • the electrodes arranged in or on the masonry are switched as an anode, the earth electrodes as cathodes.
  • additives are added to the mortar according to the invention which keep the zeta potential small and prevent premature electrokinetic outflow of the water from the anode compartment.
  • additives can be calcium or barium salts. This effect can be further enhanced according to the invention by admixing cationic surfactants, such as cetyltrimethylammonium bromide, because they reverse the sign of the zeta potential and cause a weak water flow towards the anode, which promotes desalination.
  • cationic surfactants such as cetyltrimethylammonium bromide
  • the electrodes connected to the masonry via the mortar bridges are connected to each other in an electrically conductive manner, and the highest possible DC voltage is applied to a system of earth rods, taking occupational health and safety into account. This is maintained until the current has dropped to a constant limit and thus indicates that desalination is complete.
  • the salts and iron oxides that have accumulated in the anode compartments are then removed mechanically and by rinsing with water, and then the anode compartments are neutralized with a solution of barium hydroxide. If necessary, damaged mortar bridges are replaced. Then a direct voltage is applied again, so that the electrodes now act as a permanent electrokinetic barrier against rising moisture.
  • a building is to be renovated against rising damp, the masonry contains less than 8% water, 1 x 10 -4 mol / g chloride and little sulfate.
  • liquid-impermeable channels are arranged between the mortar bridges, which drain the dripping salt solutions to the outside. After desalination, which is indicated by a decrease in the current to a constant value, After the voltage source has been disconnected, the salts and iron oxides that have accumulated in the anode compartment are removed, and then the anode compartment is neutralized with a solution of barium hydroxide. Then a direct voltage is applied again in order to prevent the water from rising again by means of an electrokinetic permanent lock.
  • the following mortar composition is selected in percent by mass:
  • a DC voltage of 5o V was applied for desalination and a DC voltage of 1o V for establishing the permanent electrokinetic barrier.

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electromagnetism (AREA)
  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Drying Of Solid Materials (AREA)
  • Working Measures On Existing Buildindgs (AREA)
  • Processing Of Solid Wastes (AREA)
  • Prevention Of Electric Corrosion (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
EP86117283A 1985-12-30 1986-12-11 Procédé pour éliminer les formation de salpêtre, pour le séchage et pour maintenir à sec la maçonnerie Expired - Lifetime EP0228001B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT86117283T ATE50306T1 (de) 1985-12-30 1986-12-11 Verfahren zur entsalzung, trockenlegung und trockenhaltung von mauerwerk.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DD285727 1985-12-30
DD85285727A DD246334B1 (de) 1985-12-30 1985-12-30 Verfahren zur entsalzung, trockenlegung und trockenenthaltung von mauerwerk

Publications (3)

Publication Number Publication Date
EP0228001A2 true EP0228001A2 (fr) 1987-07-08
EP0228001A3 EP0228001A3 (en) 1987-08-26
EP0228001B1 EP0228001B1 (fr) 1990-02-07

Family

ID=5575503

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86117283A Expired - Lifetime EP0228001B1 (fr) 1985-12-30 1986-12-11 Procédé pour éliminer les formation de salpêtre, pour le séchage et pour maintenir à sec la maçonnerie

Country Status (6)

Country Link
EP (1) EP0228001B1 (fr)
AT (1) ATE50306T1 (fr)
DD (1) DD246334B1 (fr)
DE (1) DE3668932D1 (fr)
GR (1) GR3000149T3 (fr)
HU (1) HUT49182A (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989006299A1 (fr) * 1988-01-04 1989-07-13 Miller John B Procede servant a stopper les reactions agregats-alcalis, par exemple dans du beton, et moyen de realisation dudit procede
WO1993025773A1 (fr) * 1992-06-15 1993-12-23 Ortlieb, Mathieu Procede et dispositif pour eliminer l'humidite des murs d'une construction
FR2736075A1 (fr) * 1995-06-30 1997-01-03 Stumpp Bernard Procede d'assechement et de consolidation de murs ou analogues, dispositif et lot pour la mise en oeuvre de ce procede

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4102612A1 (de) * 1991-01-25 1991-12-12 Peter Dr Friese Verfahren zur entsalzung von mauerwerk und anderen poroesen koerpern ueber konvektiven wassertransport durch das poroese medium

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3856646A (en) * 1967-09-19 1974-12-24 D Morarau Methods and electrodes for the drying of damp buildings
DD231236A3 (de) * 1983-10-04 1985-12-24 Bauakademie Ddr Vorrichtung zur trocknung von naessegeschaedigtem mauerwerk
DD234997A3 (de) * 1983-10-04 1986-04-23 Adw Ddr Elektrodenanordnung zur elektrochemischen entsalzung undtrocknung von mauerwerk

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989006299A1 (fr) * 1988-01-04 1989-07-13 Miller John B Procede servant a stopper les reactions agregats-alcalis, par exemple dans du beton, et moyen de realisation dudit procede
GB2223526A (en) * 1988-01-04 1990-04-11 John B Miller Method to stop alkali-aggregate reactions in concrete etc.,and means to carry out this method
GB2223526B (en) * 1988-01-04 1992-02-19 John B Miller Method to stop alkali-aggregate reactions in concrete.
WO1993025773A1 (fr) * 1992-06-15 1993-12-23 Ortlieb, Mathieu Procede et dispositif pour eliminer l'humidite des murs d'une construction
FR2736075A1 (fr) * 1995-06-30 1997-01-03 Stumpp Bernard Procede d'assechement et de consolidation de murs ou analogues, dispositif et lot pour la mise en oeuvre de ce procede

Also Published As

Publication number Publication date
HUT49182A (en) 1989-08-28
EP0228001B1 (fr) 1990-02-07
DE3668932D1 (de) 1990-03-15
ATE50306T1 (de) 1990-02-15
DD246334B1 (de) 1989-09-20
DD246334A1 (de) 1987-06-03
GR3000149T3 (en) 1991-03-15
EP0228001A3 (en) 1987-08-26

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