EP0268211A2 - Procédé d'application d'une poudre d'émail par projection électrostatique sur des pièces avec addition d'un gaz de protection - Google Patents

Procédé d'application d'une poudre d'émail par projection électrostatique sur des pièces avec addition d'un gaz de protection Download PDF

Info

Publication number
EP0268211A2
EP0268211A2 EP87116719A EP87116719A EP0268211A2 EP 0268211 A2 EP0268211 A2 EP 0268211A2 EP 87116719 A EP87116719 A EP 87116719A EP 87116719 A EP87116719 A EP 87116719A EP 0268211 A2 EP0268211 A2 EP 0268211A2
Authority
EP
European Patent Office
Prior art keywords
powder
addition
enamel powder
enamel
protective gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP87116719A
Other languages
German (de)
English (en)
Other versions
EP0268211B1 (fr
EP0268211A3 (en
Inventor
Berndpeter Dr.-Ing. Schumacher
Wilfried Dipl.-Phys. Galle
Christel Dipl.-Ing. Sickert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of EP0268211A2 publication Critical patent/EP0268211A2/fr
Publication of EP0268211A3 publication Critical patent/EP0268211A3/de
Application granted granted Critical
Publication of EP0268211B1 publication Critical patent/EP0268211B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D5/00Coating with enamels or vitreous layers
    • C23D5/04Coating with enamels or vitreous layers by dry methods

Definitions

  • the invention relates to a method for applying electrostatically sprayable enamel powder to workpieces with the addition of protective gas.
  • enamel powder i.e. powdered, hydrophobized enamel frits u. Suspend the like in air, in this form to a sprayer and spray there under the influence of an electric field, the electric field being generated by a high voltage.
  • DE-OS 27 15 128 describes a method for applying a glazed enamel to metallic workpieces by generating a strong, directed electrostatic field which directs the charged powder onto the workpiece.
  • the particles of enamel powder cannot initially be sprayed electrostatically without additional technological means, such as coating with silicone compounds, since they have an organic composition and the required high electrical surface resistances are not present.
  • enamel powder air mixtures are not explosive.
  • the enamel powders produced with the known preparation processes are subject to a high degree of negative influence by air humidity and temperature during the application process.
  • DE-AS 24 51 672 describes a process for the electrostatic spraying of powdery substances onto preheated metal pipes, in which, in addition to other technological features, the powdery substances are sprayed with intergas.
  • intergas is necessary for the purpose of preventing the oxidation of the workpiece and to reduce the risk of explosion of the plastic powder-air mixture.
  • the use of this solution for coating with enamel powder is not possible due to the structural design of the device used and the technological process sequence, since electrostatically sprayable enamel powders do not adhere to heated materials in accordance with quality.
  • the invention seeks to remedy this.
  • the invention as characterized in the claims, solves the problem of creating a method for applying electrostatically sprayable enamel powder to workpieces with the addition of gas, by means of which the layer thickness differences are reduced to a minimum by means of increased spraying and deposition rates and the dependency on temperature and humidity fluctuations is reduced.
  • electrostatic powder application is understood to mean the process of charging the enamel particles, their migration to the workpiece and the subsequent deposition of the particles on the workpiece.
  • the advantages achieved by the invention are essentially to be seen in the fact that the charging behavior of the enamel powder is improved by the addition of CO2, at the same time preventing the possibility of discharge, so that the spray yield is increased and the powder adhesion on the workpiece is increased. Furthermore, the dependency of the coating process on the temperature and humidity of the surrounding working atmosphere is reduced, the effectiveness of the electrostatic enamel powder coating significantly improved, while at the same time the investment costs by reducing the necessary facilities, such as air conditioning for the spray room, the number of sprayers required, and reducing the differences in layer thickness by generating a uniform layer thickness to a minimum.
  • a baking room of an electric oven with electrostatic enamel powder is using known devices, such as application booth with multiple spray guns, to which the processed enamel powder is fed, high voltage generator, conveyor chain for workpiece conveying and. Like., The powder application carried out.
  • the uncharged enamel powder intended for spraying is conveyed from the powder storage container by means of CO2-containing gas and fed to the spray guns, the electrostatic charging of the enamel powder taking place directly in the spray guns via electrodes.
  • the application booth can advantageously also be supplied through existing openings to improve the powder adhesion on the workpiece CO2.
  • the powder particles are applied to the workpiece being passed.
  • no air conditioning measures are generally carried out when individual coatings are necessary.
  • the layer thicknesses which occur during the application of enamel powder fluctuate very strongly as a function of room temperature and room air humidity.
  • the spraying and separation rate is increased by approx. 20%.
  • the amount of powder adhering to the workpiece increases by approx. 10%.
  • the coating result is constant under various external climatic conditions, which is not possible under the naturally changing conditions (temperature, air humidity) when using known methods.
  • a CO2-air mixture (1: 3) is used in a system in which the outer parts of the hearth are coated on a running conveyor chain by means of powder enamelling.
  • the spray yield increases by approx. 15%.
  • the spray booth is supplied with ambient air and CO2-containing, dewatered exhaust gas from an enamelling furnace.
  • the powder adhesion improves by approx. 15%.
  • the number of spray guns required can be reduced from 12 to 10 previously.
  • the more uniform layer thickness distribution achieved results in a 20% lower enamel powder consumption.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Electrostatic Spraying Apparatus (AREA)
  • Prostheses (AREA)
  • Materials For Medical Uses (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Paints Or Removers (AREA)
EP19870116719 1986-11-18 1987-11-12 Procédé d'application d'une poudre d'émail par projection électrostatique sur des pièces avec addition d'un gaz de protection Expired - Lifetime EP0268211B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DD29636886A DD253647B1 (de) 1986-11-18 1986-11-18 Verfahren zur pulver-emaillierung
DD296368 1986-11-18

Publications (3)

Publication Number Publication Date
EP0268211A2 true EP0268211A2 (fr) 1988-05-25
EP0268211A3 EP0268211A3 (en) 1990-01-31
EP0268211B1 EP0268211B1 (fr) 1992-05-13

Family

ID=5583947

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19870116719 Expired - Lifetime EP0268211B1 (fr) 1986-11-18 1987-11-12 Procédé d'application d'une poudre d'émail par projection électrostatique sur des pièces avec addition d'un gaz de protection

Country Status (6)

Country Link
EP (1) EP0268211B1 (fr)
CS (1) CS785487A1 (fr)
DD (1) DD253647B1 (fr)
DE (1) DE3779054D1 (fr)
ES (1) ES2031109T3 (fr)
SU (1) SU1581777A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0572358A1 (fr) * 1992-05-29 1993-12-01 Girolamo Barbieri Procédé et appareil pour revêtir électrostatiquement un objet avec de la peinture
EP3839099A4 (fr) * 2019-10-25 2022-01-26 Sohome Houseware (Nanjing) Co., Ltd Procédé de fabrication de récipient en émail et récipient en émail

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8715787B2 (en) * 2011-05-24 2014-05-06 Alfonz Morav{hacek over (c)}ík Method of making a compact layer of enamel coatings on moulded products

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1108722A (en) * 1966-10-26 1968-04-03 Shell Int Research A process for coating articles
GB1273159A (en) * 1968-09-19 1972-05-03 Head Wrightson & Co Ltd Method and apparatus for coating continuously moving surfaces

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0572358A1 (fr) * 1992-05-29 1993-12-01 Girolamo Barbieri Procédé et appareil pour revêtir électrostatiquement un objet avec de la peinture
US5397605A (en) * 1992-05-29 1995-03-14 Barbieri; Girolamo Method and apparatus for electrostatically coating a workpiece with paint
EP3839099A4 (fr) * 2019-10-25 2022-01-26 Sohome Houseware (Nanjing) Co., Ltd Procédé de fabrication de récipient en émail et récipient en émail

Also Published As

Publication number Publication date
EP0268211B1 (fr) 1992-05-13
DD253647A1 (de) 1988-01-27
EP0268211A3 (en) 1990-01-31
CS785487A1 (en) 1989-08-14
DE3779054D1 (de) 1992-06-17
DD253647B1 (de) 1988-12-14
ES2031109T3 (es) 1992-12-01
SU1581777A1 (ru) 1990-07-30

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