EP0284762A2 - Appareil pour refroidir un gaz de synthèse dans un refroidisseur à trempe - Google Patents

Appareil pour refroidir un gaz de synthèse dans un refroidisseur à trempe Download PDF

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Publication number
EP0284762A2
EP0284762A2 EP88102397A EP88102397A EP0284762A2 EP 0284762 A2 EP0284762 A2 EP 0284762A2 EP 88102397 A EP88102397 A EP 88102397A EP 88102397 A EP88102397 A EP 88102397A EP 0284762 A2 EP0284762 A2 EP 0284762A2
Authority
EP
European Patent Office
Prior art keywords
inner jacket
jacket
pressure
spray nozzles
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP88102397A
Other languages
German (de)
English (en)
Other versions
EP0284762B1 (fr
EP0284762A3 (en
Inventor
Arnold Dr. Tolle
Manfred Förster
Heinz Haacker
Helmut Wensing
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Deutsche Babcock Werke Energie und Umwelttechnik AG
MAN GHH Immobilien GmbH
Original Assignee
Deutsche Babcock Werke AG
MAN Gutehoffnungshutte GmbH
Deutsche Babcock Werke Energie und Umwelttechnik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deutsche Babcock Werke AG, MAN Gutehoffnungshutte GmbH, Deutsche Babcock Werke Energie und Umwelttechnik AG filed Critical Deutsche Babcock Werke AG
Priority to AT88102397T priority Critical patent/ATE64148T1/de
Publication of EP0284762A2 publication Critical patent/EP0284762A2/fr
Publication of EP0284762A3 publication Critical patent/EP0284762A3/de
Application granted granted Critical
Publication of EP0284762B1 publication Critical patent/EP0284762B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/74Construction of shells or jackets
    • C10J3/76Water jackets; Steam boiler-jackets
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/52Ash-removing devices
    • C10J3/526Ash-removing devices for entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • C10J3/845Quench rings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S48/00Gas: heating and illuminating
    • Y10S48/02Slagging producer

Definitions

  • the invention relates to a device for cooling a synthesis gas generated in a gasification reactor with the aid of a quench cooler according to the preamble of claim 1.
  • a known quench cooler (DE-C-2 940 933) the inner jacket is provided with trickle cooling.
  • the application of a water film on the surface of the inner jacket is difficult, since there is a risk that the water to be applied evaporates on the hot surface and thus the water film tears open.
  • the gas generated in the gasification reactor is passed through the water sump, where it is cooled, saturated with water and freed from liquid slag and fly ash.
  • a disadvantage of such quench cooling is that the water from the water sump also absorbs the halogen components of the synthesis gas and is heated by the gas. The water must therefore be subjected to treatment and cooling after the solids have been separated off.
  • the gas entrains water droplets in which fine dust particles are suspended when it exits the water sump. These dust particles can bake on the wall of the cooler and in the subsequent pipes and lead to blockages.
  • the invention has for its object to carry out the cooling of the synthesis gas in the generic device in such a way that the water sump remains free of halogen components and caking of dust is avoided.
  • the water vapor content in the synthesis gas is adjusted by spraying water into the gas stream and not when it passes through the water sump.
  • the surface temperature on the cooled inner jacket becomes approximately the same in normal operation Gasification operating pressure corresponding boiling temperature. The surface temperature is thus far above the saturation temperature corresponding to the water vapor pressure of the synthesis gas, so that undershoots on the inner jacket are reliably avoided.
  • the spray nozzles are arranged, the intermediate section between the reactor outlet and the inner jacket ensures that the reactor outlet is kept warm, so that the reactor outlet is not blocked by solidification of the liquid slag outflow.
  • a quench cooler which contains an outer pressure jacket 1, is flanged to the outlet of a pressure gasification reactor, not shown.
  • the gas inlet 2 of the quench cooler is lined fireproof and has the same diameter as the outlet of the gasification reactor.
  • An intermediate section 3 of enlarged diameter adjoins the gas inlet 2. The height of the intermediate section 3 corresponds to approximately half to a simple value of its diameter.
  • the gas inlet 2 and the intermediate section 3 are provided with refractory heat insulation.
  • the lower part of the inner jacket 5 receives a water sump 6, which is connected to an outlet nozzle 7 at the lower end of the pressure jacket 1.
  • the water sump 6 serves to quench the liquid slag contained in the synthesis gas.
  • the quenched slag is withdrawn from the outlet nozzle 7 together with the water from the water sump 6.
  • one or more gas outlet connections 8 are provided, which are passed through the inner jacket 5 and the pressure jacket 1.
  • guide surfaces 9 are arranged obliquely downwards in the form of a funnel and are led out of the course of the inner casing 5.
  • the lower edges of the guide surfaces 9 project into the interior of the inner casing 5 and are supported on the inner casing 5 by means of pipes 10.
  • the gas flowing through the inner jacket 5 is deflected in this way to improve dust separation before it exits through the gas outlet connection 8.
  • the inner jacket 5 consists of a steel wall, which is provided on the back with an open, pressure-free relative to the process pressure evaporative cooling.
  • the pressure jacket 1 is provided in the lower part with a nozzle 11 which opens into the annular space 4.
  • Treated feed water is fed into the annular space 4 through the nozzle 11.
  • a chamber 12 is formed at the upper end of the annular space 4.
  • Downpipes 13 are arranged in the annular space 4 and are welded into a perforated plate 14. The downpipes 13 are passed through the inner jacket 5 with the lower ends below the level of the gas outlet connection 8 and connect the chamber 12 to the interior of the inner jacket 5, so that there is pressure compensation.
  • the lower ends of the downpipes 13 can end above the water sump 6 or can dip into the water sump 6.
  • the water volume within the annular space 4 is selected so large that in the event of any malfunctions in the quench system over a certain time, which is sufficient to take countermeasures, the entire residual and storage heat accumulated can be dissipated through the open evaporation system. Via the downpipes 13, the water fed continuously through the nozzle 11 during operation and the accumulated saturated steam are passed into the water sump 6.
  • Spray nozzles 15 protrude into the interior of the inner jacket 5.
  • the spray nozzles 15 are installed in cooled lances 16, which are interchangeably passed through the pressure jacket 1 and the inner jacket 5.
  • the spray nozzles 15 can be aligned both axially and radially with respect to the lance 16 or can be inclined downwards.
  • the lances 16 can be horizontal or obliquely downwards directional installed in the quench cooler. A first row of such lances 16 is arranged immediately below the intermediate section 3. Additional lances can be provided below this upper row of lances 16.
  • the front edges of the lances 16 lie on a pitch circle, the diameter of which is larger than the diameter of the intermediate section 3. In this way, the lances 16 are protected against slag flowing off.
  • the intermediate section 3 serves to ensure that the cooled synthesis gas does not come into contact with the edge of the gas inlet 2 by an internal backflow and would cool it, so that freezing of the slag flowing away, which would lead to a blockage of the gas inlet 2, is avoided becomes.
  • the amount of water added via the spray nozzles 15 is dimensioned such that the water evaporates almost completely and the synthesis gas is cooled to about 300 to 600 degrees C. when it exits through the gas outlet connection 8. At this temperature, the water vapor contained in the synthesis gas does not yet condense out, so that no significant amounts of halogens can get into the water of the water sump 6. The water sump does not heat up, which makes handling of the sump contents easier when discharging the quenched slag.
  • the cooled gas is optionally fed to a further processing system after further cooling in a radiation or convection cooler via a gas scrubber.
  • the inner jacket 5 is designed as a gas-tight tube wall.
  • the tube wall also forms the intermediate section 3.
  • the tubes are laid in a spiral in the tube wall and water is applied to them via tubes 17.
  • the spray nozzles 15 are integrated into the tube wall of the inner jacket 5.
  • the annular space between the inner jacket 5 and the pressure jacket 1 can also be filled with thermal insulation 18. Cooling tubes 19 are guided through this thermal insulation 18.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Optical Couplings Of Light Guides (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Defrosting Systems (AREA)
EP88102397A 1987-04-03 1988-02-19 Appareil pour refroidir un gaz de synthèse dans un refroidisseur à trempe Expired - Lifetime EP0284762B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT88102397T ATE64148T1 (de) 1987-04-03 1988-02-19 Vorrichtung zum kuehlen eines synthesegases in einem quenchkuehler.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19873711314 DE3711314A1 (de) 1987-04-03 1987-04-03 Vorrichtung zum kuehlen eines synthesegases in einem quenchkuehler
DE3711314 1987-04-03

Publications (3)

Publication Number Publication Date
EP0284762A2 true EP0284762A2 (fr) 1988-10-05
EP0284762A3 EP0284762A3 (en) 1989-02-08
EP0284762B1 EP0284762B1 (fr) 1991-06-05

Family

ID=6324823

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88102397A Expired - Lifetime EP0284762B1 (fr) 1987-04-03 1988-02-19 Appareil pour refroidir un gaz de synthèse dans un refroidisseur à trempe

Country Status (8)

Country Link
US (1) US4848982A (fr)
EP (1) EP0284762B1 (fr)
JP (1) JPS63260986A (fr)
CN (1) CN1014071B (fr)
AT (1) ATE64148T1 (fr)
DE (2) DE3711314A1 (fr)
FI (1) FI88807C (fr)
ZA (1) ZA881409B (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0433579A1 (fr) * 1989-11-17 1991-06-26 Krupp Koppers GmbH Procédé et appareillage pour refroidir du gaz brut d'oxydation partielle
EP0586837A3 (en) * 1992-09-09 1994-05-18 Babcock Energie Umwelt Device for cooling hot gases
EP0870818A3 (fr) * 1997-04-08 1998-11-18 MAN Gutehoffnungshütte Aktiengesellschaft Gazogène pour gaz de synthèse avec chambre de combustion et de trempe
EP1939271A1 (fr) 2006-12-18 2008-07-02 Pratt & Whitney Rocketdyne Inc. Gazogène refroidi par fluide perdu
WO2009033543A1 (fr) * 2007-09-07 2009-03-19 Choren Industries Gmbh Procédé et dispositif de traitement de gaz chauds chargés
WO2012034700A2 (fr) 2010-09-16 2012-03-22 Choren Industries Gmbh Dispositif et procédé de traitement d'un courant de gaz chaud contenant un laitier
DE102010045482A1 (de) 2010-09-16 2012-03-22 Choren Industries Gmbh Vorrichtung und Verfahren zur Behandlung eines schlackehaltigen Heißgasstromes
EP2598615A4 (fr) * 2010-06-18 2014-03-19 Gasek Oy Procédé et appareil pour gazéifier un combustible solide

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4017219A1 (de) * 1990-05-29 1991-12-05 Babcock Werke Ag Vorrichtung zur vergasung von kohlenstoffhaltigen materialien
US5248483A (en) * 1991-03-28 1993-09-28 Phillips Petroleum Company Apparatus and methods for producing ceramic products
DK0616022T3 (da) * 1993-03-16 1996-01-15 Krupp Koppers Gmbh Fremgangsmåde til trykforgasning af partikelformige brændstoffer
DK0616023T3 (da) * 1993-03-16 1996-04-09 Krupp Koppers Gmbh Forgasningsapparat til trykforgasning af findelt brændstof
DE19654806C2 (de) * 1996-12-31 2001-06-13 Axiva Gmbh Optimierung des Kühlwassersystems einer Polyolefinanlage
DE19930051C2 (de) * 1999-06-30 2001-06-13 Daimler Chrysler Ag Vorrichtung und Verfahren zur Durchführung eines Wasser-Quenches
KR101347031B1 (ko) * 2005-05-02 2014-01-03 쉘 인터내셔날 리써취 마트샤피지 비.브이. 합성가스 생산 방법 및 시스템
CN1919980B (zh) * 2005-08-24 2012-07-04 未来能源有限公司 通过在加压下部分氧化含灰的燃料并且骤冷粗制气而生产合成气的气化方法和设备
DE202005021661U1 (de) * 2005-09-09 2009-03-12 Siemens Aktiengesellschaft Vorrichtung zur Erzeugung von Synthesegasen durch Partialoxidation von aus aschehaltigen Brennstoffen hergestellten Slurries und Vollquenchung des Rohgases
DE102006031816B4 (de) * 2006-07-07 2008-04-30 Siemens Fuel Gasification Technology Gmbh Verfahren und Vorrichtung zur Kühlung von heißen Gasen und verflüssigter Schlacke bei der Flugstromvergasung
DE102007006990B4 (de) * 2007-02-07 2016-03-10 Air Liquide Global E&C Solutions Germany Gmbh Verfahren und Vorrichtung zur Konvertierung von Rohgasen bei der Partialoxidation gasförmiger und flüssiger Kohlenwasserstoffe
CN101605877B (zh) * 2007-09-04 2013-08-21 国际壳牌研究有限公司 骤冷转炉
ATE554848T1 (de) * 2007-09-04 2012-05-15 Shell Int Research Sprühdüsenverteiler und verfahren zum abschrecken eines heissen gases unter verwendung einer derartigen anordnung
EP2321388B1 (fr) 2008-09-01 2015-09-30 Shell Internationale Research Maatschappij B.V. Élément auto-nettoyant
JP6394988B2 (ja) * 2015-08-21 2018-09-26 Jfeエンジニアリング株式会社 排ガス減温塔及び排ガス減温方法
DE102015216783A1 (de) * 2015-09-02 2017-03-02 Siemens Aktiengesellschaft Verblockungsfreier Wasserüberlauf aus dem Wassermantel eines Quenchers in den Quenchraum

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1217014B (de) * 1957-12-13 1966-05-18 Texaco Development Corp Vorrichtung zur Herstellung von Kohlenoxyd und Wasserstoff
US3223398A (en) * 1963-02-20 1965-12-14 Kaiser Ind Corp Lance for use in a basic oxygen conversion process
DE1501387A1 (de) * 1965-01-13 1969-05-29 Knapsack Ag Rohrfoermiger Einspritzkuehler zum Abschrecken von heissen,agressiven Gasen
DE2650512B2 (de) * 1976-11-04 1980-03-20 Gutehoffnungshuette Sterkrade Ag, 4200 Oberhausen Vorrichtung zum Reinigen von durch chemische Kohlevergasung erzeugtem Synthesegas
US4218423A (en) * 1978-11-06 1980-08-19 Texaco Inc. Quench ring and dip tube assembly for a reactor vessel
US4377132A (en) * 1981-02-12 1983-03-22 Texaco Development Corp. Synthesis gas cooler and waste heat boiler
CH661054A5 (de) * 1981-10-23 1987-06-30 Sulzer Ag Gaskuehler an synthesegasgenerator.
DE3205346C2 (de) * 1982-02-15 1983-12-15 L. & C. Steinmüller GmbH, 5270 Gummersbach Zweistufen-Vergaser
DE3248096C2 (de) * 1982-12-24 1985-01-31 M.A.N. Maschinenfabrik Augsburg-Nürnberg AG, 4200 Oberhausen Stehende Vorrichtung zum Kühlen von unter hohem Druck stehenden Gasen mit hohem Staubanteil

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0433579A1 (fr) * 1989-11-17 1991-06-26 Krupp Koppers GmbH Procédé et appareillage pour refroidir du gaz brut d'oxydation partielle
EP0586837A3 (en) * 1992-09-09 1994-05-18 Babcock Energie Umwelt Device for cooling hot gases
EP0870818A3 (fr) * 1997-04-08 1998-11-18 MAN Gutehoffnungshütte Aktiengesellschaft Gazogène pour gaz de synthèse avec chambre de combustion et de trempe
WO1998045388A3 (fr) * 1997-04-08 1999-01-07 Metallgesellschaft Ag Generateur de gaz de synthese comprenant des chambres de combustion et de refroidissement rapide
US5976203A (en) * 1997-04-08 1999-11-02 Metallgesellschaft Aktiengellschaft Synthesis gas generator with combustion and quench chambers
US7740671B2 (en) 2006-12-18 2010-06-22 Pratt & Whitney Rocketdyne, Inc. Dump cooled gasifier
EP1939271A1 (fr) 2006-12-18 2008-07-02 Pratt & Whitney Rocketdyne Inc. Gazogène refroidi par fluide perdu
WO2009033543A1 (fr) * 2007-09-07 2009-03-19 Choren Industries Gmbh Procédé et dispositif de traitement de gaz chauds chargés
CN101809125A (zh) * 2007-09-07 2010-08-18 科林工业有限公司 负载热气的处理方法和设备
EP2598615A4 (fr) * 2010-06-18 2014-03-19 Gasek Oy Procédé et appareil pour gazéifier un combustible solide
WO2012034700A2 (fr) 2010-09-16 2012-03-22 Choren Industries Gmbh Dispositif et procédé de traitement d'un courant de gaz chaud contenant un laitier
DE102010045482A1 (de) 2010-09-16 2012-03-22 Choren Industries Gmbh Vorrichtung und Verfahren zur Behandlung eines schlackehaltigen Heißgasstromes
US8945286B2 (en) 2010-09-16 2015-02-03 Ccg Energy Technology Company Ltd. Device and method for treating a hot gas flow containing slag

Also Published As

Publication number Publication date
FI88807C (fi) 1993-07-12
US4848982A (en) 1989-07-18
CN1014071B (zh) 1991-09-25
EP0284762B1 (fr) 1991-06-05
FI88807B (fi) 1993-03-31
DE3711314A1 (de) 1988-10-13
CN88101732A (zh) 1988-10-19
ATE64148T1 (de) 1991-06-15
EP0284762A3 (en) 1989-02-08
FI881329L (fi) 1988-10-04
DE3863104D1 (de) 1991-07-11
ZA881409B (en) 1988-09-15
FI881329A0 (fi) 1988-03-21
JPS63260986A (ja) 1988-10-27

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