EP0295454A2 - Procédé et dispositif pour la destruction orientée (craquage) de polychlorodibenzodioxines et/ou dibenzofuranes polychlorés et pour le traitement non polluant de matières craquées - Google Patents

Procédé et dispositif pour la destruction orientée (craquage) de polychlorodibenzodioxines et/ou dibenzofuranes polychlorés et pour le traitement non polluant de matières craquées Download PDF

Info

Publication number
EP0295454A2
EP0295454A2 EP88108074A EP88108074A EP0295454A2 EP 0295454 A2 EP0295454 A2 EP 0295454A2 EP 88108074 A EP88108074 A EP 88108074A EP 88108074 A EP88108074 A EP 88108074A EP 0295454 A2 EP0295454 A2 EP 0295454A2
Authority
EP
European Patent Office
Prior art keywords
fluid mixture
substances
fluid
mixture
cracking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP88108074A
Other languages
German (de)
English (en)
Other versions
EP0295454B1 (fr
EP0295454A3 (en
Inventor
Henner Dipl.-Ing. Otromke
Uwe Dipl.-Ing. Theerkorn
Gerd Hedemann
Wolfgang Dr. Rer.Nat. Meiners
Lothar Dipl.-Ing. Hartung
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dipl-Ing Lothar Hartung Te Kreuztal-Buschhuetten
Original Assignee
Felten and Guilleaume Energietechnik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6329667&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0295454(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Felten and Guilleaume Energietechnik AG filed Critical Felten and Guilleaume Energietechnik AG
Priority to AT88108074T priority Critical patent/ATE60347T1/de
Publication of EP0295454A2 publication Critical patent/EP0295454A2/fr
Publication of EP0295454A3 publication Critical patent/EP0295454A3/de
Application granted granted Critical
Publication of EP0295454B1 publication Critical patent/EP0295454B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/40—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by heating to effect chemical change, e.g. pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/20—Organic substances
    • A62D2101/22—Organic substances containing halogen
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/20—Organic substances
    • A62D2101/28—Organic substances containing oxygen, sulfur, selenium or tellurium, i.e. chalcogen
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2203/00—Aspects of processes for making harmful chemical substances harmless, or less harmful, by effecting chemical change in the substances
    • A62D2203/10—Apparatus specially adapted for treating harmful chemical agents; Details thereof

Definitions

  • the invention relates to a method for the targeted decomposition (cracking) of organic-chemical substances in the production and for the environmentally friendly preparation of the cracked substances according to the preamble of claim 1.
  • a further embodiment of the method is specified in claim 2.
  • Devices for carrying out the method are characterized in the subclaims.
  • PCDD Polychlorodibenzodioxins
  • PCDF polychlorinated dibenzofurans
  • PCDD and PCDF arise as trace products in the chemical synthesis of chlorinated hydrocarbons, especially in the synthesis of more chlorinated aromatic hydrocarbons, and can also arise when aromatic chlorinated hydrocarbons are used as intermediates in chemical syntheses.
  • Preferred reaction conditions for the formation of PCDD and PCDF are high temperatures and alkaline medium.
  • PCDD and PCDF can also arise in all types of combustion processes if organic chlorine compounds are present.
  • a well-known example is waste incineration plants. Even when burning wood and fuel, small amounts of PCDD and PCDF must be expected.
  • PCDD and PCDF can today be detected as ubiquitous in nature as predominantly anthropogenic environmental contamination.
  • identification and especially the quantification of this class of substances, which is characterized by a large number of isomers - often referred to simply as "dioxins" by the public - was only possible through modern instrumental analysis.
  • PCDD and PCDf-containing waste The main requirement in the disposal of PCDD and PCDf-containing waste is the removal of this material from the natural cycle. However, the conditions of the applicable laws must be observed.
  • the yardstick for assessing which disposal path to take is the content of PCDD and PCDF in the waste on the one hand, and the level of the disposal facilities on the other.
  • the invention is therefore based on the object of finding a method which makes it possible to carry out an environmentally friendly removal of waste containing PCDD and PCDf and to provide an apparatus for using this method.
  • a further embodiment of the method is specified in claim 2, for which a device is specified in subclaims.
  • the main advantage of the process described in claims 1 and 2 is the treatment of organic chemical substances under defined reductive conditions with a very constant temperature over the entire reaction scheme. This means e.g. created the possibility of eliminating PCDD and PCDF-containing waste in an anaerobic atmosphere. A high reduction potential is built up through a high hydrogen content.
  • the reaction temperature can be kept very precisely at better than +/- 2 ° C for a long period of time.
  • Technical and chemical parameters are selected so that e.g. the formation or destruction of PCDD and PCDF is not only influenced kinetically, but also via the existing reaction partners.
  • the first part of the device is used to generate an anaerobic atmosphere.
  • a fluid mixture of nitrogen, hydrogen and residual gases is processed in a gas cracking plant 1.
  • the fluid mixture prepared in this way is further refined in a fine control stage 2 downstream of the gas gap system 1 with the aid of hydrogen and / or nitrogen, a manipulated variable from a computer-controlled gas analysis system 6 influencing the fine control.
  • the fluid mixture is preheated and enters a fluid bed 3 through gas inlet nozzles 32 below a nozzle plate 31.
  • solid substances in a defined sphere size, here aluminum oxide spheres 34.
  • a container 4 for the organic chemical substances to be treated which are injected into the fluid bed 3 via an injection pump 5 through injection nozzles 33.
  • a fluid mixture that is always processed is guided past the surfaces of the aluminum oxide spheres 34.
  • other elements such as chlorine and possibly existing oxygen are bound by the hydrogen of the fluid mixture.
  • the cracked low molecular weight substances are carried out of the fluid bed 3 according to the flow rate of the fluid mixture and sucked off or blown out.
  • the fluid mixture can also be fed to a piston compressor 11 via a charger 10.
  • the loader has the task of compressing and conveying the fluid mixture from a low initial pressure to a higher final pressure.
  • the piston compressor consists of a cylindrical compression chamber 12 as a working space with a piston reciprocating in a straight line.
  • the organic chemical substances to be treated in liquid form are initially in a container 4, from which they are injected into the piston compressor by means of an injection pump 5.
  • the fluid mixture passes from the charger 10 via inlet valves 14 into the piston compressor 11.
  • the mixture consisting of the fluid mixture and the cracked products leaves the piston compressor 11 via outlet valves 15, previously passing through a catalytic converter 16.
  • the mixture consisting of the fluid mixture and the cracking products is then analyzed in the gas analysis system 6.
  • This system consists of a gas chromatograph and other analysis systems, from which control values are transmitted to fine control level 2.
  • a subsequent one Filtering the mixture consisting of fluid mixture and cracking products in a washing system 7 has the result that the hydrochloric acid contained in the mixture is washed out.
  • a decision is then made as to whether the remainder is washed back to new substances 9 by recycling measures or is fed to a thermal afterburning 8.
  • manipulated variables of the gas analysis system 6 can influence the process sequence in the final stage. 2, the charger is influenced by manipulated variables of the gas analysis system 6.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Business, Economics & Management (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Emergency Management (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Processing Of Solid Wastes (AREA)
EP19880108074 1987-06-13 1988-05-20 Procédé et dispositif pour la destruction orientée (craquage) de polychlorodibenzodioxines et/ou dibenzofuranes polychlorés et pour le traitement non polluant de matières craquées Expired - Lifetime EP0295454B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT88108074T ATE60347T1 (de) 1987-06-13 1988-05-20 Verfahren und vorrichtung zur gezielten zerlegung (cracken) von polychlordibenzodioxinen und/oder polychlorierten dibenzofuranen und zur umweltfreundlichen aufbereitung der gecrackten stoffe.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3719824A DE3719824C1 (de) 1987-06-13 1987-06-13 Verfahren und Vorrichtung zur gezielten Zerlegung (Cracken) von Halogenkohlenwasserstoffen mit anschliessender umweltfreundlicher Aufbereitung der gecrackten Stoffe
DE3719824 1987-06-13

Publications (3)

Publication Number Publication Date
EP0295454A2 true EP0295454A2 (fr) 1988-12-21
EP0295454A3 EP0295454A3 (en) 1989-03-15
EP0295454B1 EP0295454B1 (fr) 1991-01-23

Family

ID=6329667

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19880108074 Expired - Lifetime EP0295454B1 (fr) 1987-06-13 1988-05-20 Procédé et dispositif pour la destruction orientée (craquage) de polychlorodibenzodioxines et/ou dibenzofuranes polychlorés et pour le traitement non polluant de matières craquées

Country Status (4)

Country Link
EP (1) EP0295454B1 (fr)
AT (1) ATE60347T1 (fr)
DE (2) DE3719824C1 (fr)
ES (1) ES2021113B3 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2671990A1 (fr) * 1991-01-24 1992-07-31 Chaussonnet Pierre Systeme pour le traitement par thermolyse sous vide des produits liquides ou gazeux dont le rejet est prejudiciable pour l'environnement.
EP0570645A1 (fr) * 1992-05-20 1993-11-24 Societe Francaise De Thermolyse Système et procédé de traitement par thermolyse sous vide des produits liquides ou gazeux dont le rejet est préjudiciable pour l'environnement
WO1993023497A1 (fr) * 1992-05-20 1993-11-25 Societe Francaise De Thermolyse Systeme et procede de traitement par thermolyse sous vide des produits liquides ou gazeux dont le rejet est prejudiciable pour l'environnement
US5730947A (en) * 1991-01-24 1998-03-24 Societe Francaise De Thermolyse System and process for vacuum thermolysis treatment of liquid or gas products the disposal of which is detrimental to the environment

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2886605A (en) * 1954-10-11 1959-05-12 Dow Chemical Co Method of reducing the halogen content of halohydrocarbons
US3542532A (en) * 1968-01-11 1970-11-24 Exxon Research Engineering Co Process for the production of hydrogen from petroleum coke
US3597327A (en) * 1969-04-02 1971-08-03 Arthur M Squires Process for pyrolyzing a solid or liquid hydrocarbonaceous fuel in a fluidized bed
AU533902B2 (en) * 1979-09-21 1983-12-15 Monsanto Company Oxidants for gasifying carbon - containing materials
CA1260959A (fr) * 1984-05-21 1989-09-26 Sidney W. Benson Conversion de substances toxiques halogenees
DE3616785A1 (de) * 1986-05-17 1987-11-19 Union Rheinische Braunkohlen Verfahren zur aufarbeitung von kohlenstoff enthaltenden abfaellen und biomassen
CA1294111C (fr) * 1986-08-08 1992-01-14 Douglas J. Hallett Procede de destruction de rebuts organiques

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2671990A1 (fr) * 1991-01-24 1992-07-31 Chaussonnet Pierre Systeme pour le traitement par thermolyse sous vide des produits liquides ou gazeux dont le rejet est prejudiciable pour l'environnement.
US5730947A (en) * 1991-01-24 1998-03-24 Societe Francaise De Thermolyse System and process for vacuum thermolysis treatment of liquid or gas products the disposal of which is detrimental to the environment
EP0570645A1 (fr) * 1992-05-20 1993-11-24 Societe Francaise De Thermolyse Système et procédé de traitement par thermolyse sous vide des produits liquides ou gazeux dont le rejet est préjudiciable pour l'environnement
WO1993023497A1 (fr) * 1992-05-20 1993-11-25 Societe Francaise De Thermolyse Systeme et procede de traitement par thermolyse sous vide des produits liquides ou gazeux dont le rejet est prejudiciable pour l'environnement

Also Published As

Publication number Publication date
DE3719824C1 (de) 1989-03-09
EP0295454B1 (fr) 1991-01-23
EP0295454A3 (en) 1989-03-15
ES2021113B3 (es) 1991-10-16
ATE60347T1 (de) 1991-02-15
DE3861632D1 (de) 1991-02-28

Similar Documents

Publication Publication Date Title
DE2330591C2 (de) Verfahren zur Beseitigung von organischen Schädlingsbekämpfungsmitteln
EP0044991B1 (fr) Procédé et installation pour la destruction pyrolytique de substances organiques contenant des halogènes et/ou du phosphore
DE69209152T2 (de) Verfahren und Vorrichtung zur Verringerung der Freilassung toxischer Verbindungen in die Umwelt bei der Verbrennung von Abfallstoffen
DE3830812A1 (de) Verfahren zur entfernung von schadstoffen aus einem abgasstrom
DE3224328A1 (de) Verfahren und anlage zur umwandlung von abfallstoffen in bestaendige endprodukte
DE69311368T2 (de) Verfahren zur chemischen zersetzung von halogenierten organischen verbindungen
DE69707361T2 (de) Verfahren und Apparat zur Konvertierung von Kunststoffabfällen in Öl
DE2705229C2 (de) Verfahren zum Behandeln eines Gasstromes
DE69220673T2 (de) Verfahren und Anlage zur Behandlung und Verwertung von Abfallstoffen durch Veränderung dieser in wiederverwertbare, nicht verunreinigte Materialien
DE10304641A1 (de) System zur Entgiftung toxischer chlorierter organischer Verbindungen und Verfahren zum Rezyklieren des entgifteten Abfalls
EP0295454B1 (fr) Procédé et dispositif pour la destruction orientée (craquage) de polychlorodibenzodioxines et/ou dibenzofuranes polychlorés et pour le traitement non polluant de matières craquées
DE19508322C2 (de) Verfahren und Anlage zur umweltschonenden Entsorgung von Spreng- und Giftstoffe enthaltendem Gefahrengut
DE102008016519B4 (de) Verfahren zur Reinigung von Rauchgas in einer Müllverbrennungsanlage sowie eine Vorrichtung zur Durchführung des Verfahrens
DE2331156B2 (de) Vorrichtung zum Beseitigen von in Abgasen enthaltenen gasförmigen Schadstoffen
EP1537905B1 (fr) Procédé et installation pour la sorption de polluants de fumées de combustion au moyen d'un lit fluidisé
WO1989012482A1 (fr) Procede et dispositif de separation de substances nocives
DE2362920A1 (de) Verfahren zur kontinuierlichen hydrolyse von polyurethanschaum in einer begrenzten rohrfoermigen reaktionszone und gewinnung von produkten daraus
DE3744765C1 (en) Process and device for the controlled cracking of halogenated hydrocarbons which are present in waste products from the manufacture of workpieces, with environmentally sound processing of the cracked substances
DE69624721T2 (de) Verfahren zur dekontamination und behandlung einer flüssigen, gasförmigen oder festen matrix mit oxidativem gegenstrom
EP4208282B1 (fr) Recirculation des matières valorisables de la purification de gaz d'échappement
DE69809310T2 (de) Verfahren und System zur Entfernung von Schadstoffen
DE69902168T2 (de) Verfahren zum behandeln einer flüssigkeit, die flüchtige bestandteile enthält
DE3815507A1 (de) Verfahren und anlage zum dekontaminieren von mit toxischen organischen verbindungen verseuchtem material
EP2911985A1 (fr) Décontamination par carbonisation hydrothermique de matériau contaminé
EP0343672A1 (fr) Méthode et dispositif pour purifier des mélanges de gaz d'hydrocarbures lourds et de leurs dérivés

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH DE ES FR GB IT LI NL SE

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

17P Request for examination filed

Effective date: 19881208

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE CH DE ES FR GB IT LI NL SE

17Q First examination report despatched

Effective date: 19891129

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE ES FR GB IT LI NL SE

REF Corresponds to:

Ref document number: 60347

Country of ref document: AT

Date of ref document: 19910215

Kind code of ref document: T

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)
REF Corresponds to:

Ref document number: 3861632

Country of ref document: DE

Date of ref document: 19910228

ET Fr: translation filed
RIN2 Information on inventor provided after grant (corrected)

Free format text: OTROMKE, HENNER, DIPL.-ING. * THEERKORN, UWE, DIPL.-ING. * HEDEMANN, GERD * MEINERS, WOLFGANG, DR. RER.NAT. * HARTUNG, LOTHAR, DIPL.-ING.

ITF It: translation for a ep patent filed
RAP2 Party data changed (patent owner data changed or rights of a patent transferred)

Owner name: HARTUNG, LOTHAR, DIPL.-ING.

Owner name: FELTEN & GUILLEAUME ENERGIETECHNIK AG

REG Reference to a national code

Ref country code: CH

Ref legal event code: PUE

Owner name: FELTEN & GUILLEAUME ENERGIETECHNIK AG

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 19910509

Year of fee payment: 4

NLT2 Nl: modifications (of names), taken from the european patent patent bulletin

Owner name: FELTEN & GUILLEAUME ENERGIETECHNIK AG TE KEULEN EN

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

26 Opposition filed

Opponent name: RWE-ENTSORGUNG AKTIENGESELLSCHAFT

Effective date: 19911016

BECN Be: change of holder's name

Effective date: 19910123

NLR1 Nl: opposition has been filed with the epo

Opponent name: RWE-ENTSORGUNG AG

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 19920217

Year of fee payment: 5

REG Reference to a national code

Ref country code: CH

Ref legal event code: PUE

Owner name: DIPL.-ING. LOTHAR HARTUNG

ITPR It: changes in ownership of a european patent

Owner name: CESSIONE;HARTUNG, LOTHAR, DIPL. - ING.

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19920402

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19920410

Year of fee payment: 5

REG Reference to a national code

Ref country code: GB

Ref legal event code: 732

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19920429

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 19920508

Year of fee payment: 5

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19920521

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19920527

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19920531

Year of fee payment: 5

REG Reference to a national code

Ref country code: FR

Ref legal event code: CL

NLS Nl: assignments of ep-patents

Owner name: DIPL.-ING. LOTHAR HARTUNG TE KREUZTAL-BUSCHHUETTEN

PLBN Opposition rejected

Free format text: ORIGINAL CODE: 0009273

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: OPPOSITION REJECTED

27O Opposition rejected

Effective date: 19921102

NLR2 Nl: decision of opposition
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Effective date: 19930520

Ref country code: AT

Effective date: 19930520

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Effective date: 19930521

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Effective date: 19930531

Ref country code: CH

Effective date: 19930531

Ref country code: BE

Effective date: 19930531

REG Reference to a national code

Ref country code: ES

Ref legal event code: PC2A

Owner name: LOTHAR HARTUNG

BERE Be: lapsed

Owner name: HARTUNG LOTHAR

Effective date: 19930531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19931201

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19940110

Year of fee payment: 6

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee
GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19930520

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Effective date: 19940131

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

EUG Se: european patent has lapsed

Ref document number: 88108074.1

Effective date: 19931210

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Effective date: 19950201

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 19990405

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050520

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO