EP0301082A4 - Shampoo - Google Patents
ShampooInfo
- Publication number
- EP0301082A4 EP0301082A4 EP19880902294 EP88902294A EP0301082A4 EP 0301082 A4 EP0301082 A4 EP 0301082A4 EP 19880902294 EP19880902294 EP 19880902294 EP 88902294 A EP88902294 A EP 88902294A EP 0301082 A4 EP0301082 A4 EP 0301082A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- formula
- weight percent
- shampoo
- alk
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000002453 shampoo Substances 0.000 title claims abstract description 13
- 229940095673 shampoo product Drugs 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 18
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 4
- 229920003086 cellulose ether Polymers 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 3
- 229960003237 betaine Drugs 0.000 claims description 3
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 3
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 3
- 150000008282 halocarbons Chemical class 0.000 claims description 3
- 229940057950 sodium laureth sulfate Drugs 0.000 claims description 3
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 206010015946 Eye irritation Diseases 0.000 abstract description 2
- 231100000013 eye irritation Toxicity 0.000 abstract description 2
- 241000195940 Bryophyta Species 0.000 abstract 1
- 235000011929 mousse Nutrition 0.000 abstract 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000003380 propellant Substances 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 229960002216 methylparaben Drugs 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 2
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 2
- 229960003415 propylparaben Drugs 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- -1 polyoxyethylene Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Definitions
- the present invention relates to shampoo formulations. More particuarly, it relates to shampoos useful for washing the hair of children, who are particularly sensitive to eye irritation that can be caused by some known shampoo products.
- the invention relates in particular to a shampoo formulation that can be dispensed from a pressurized container as a mousse-type product.
- the present invention is a water-based shampoo product comprising
- R cell is the residue of an anhydroglucose unit; y is an integer having a value of from about
- each R independently represents a substituent group of the general formula (2):
- m is an integer having a value of 0 to 10
- n is 0, 1, 2 or 3
- p is an integer having a value of 0 to 10
- q is 0 or 1
- R is -H, -COOH, -COONa
- (ALK) is a C 10 -C 18 saturated or mono ⁇ unsaturated straight or branch-chain alkyl or alkylene group and i is 1-6;
- R (ALK) is a C 10 -C 18 saturated or monounsaturated straight or branched-chain alkyl or alkylene group/ and j is 1-5;
- the present invention contains as indicated several components which in combination provide a product having useful properties and free of undesirable side effects.
- the product includes water, typically in an amount comprising about 50 to about 75 weight percent.
- One component is a quaternary nitrogen-containing cellulose ether of the formula (1) disclosed hereinabove. Particularly preferred are derivatives of hydroxyethyl cellulose/ including the compound known generically as polyquaternium-10 available commercially from Union Carbide.
- the quaternary nitrogen-containing cellulose ether can be synthesized following the procedure described generally in U.S. Patent No. 3,472,840.
- the amount of this component can generally range from 0.01 to 1.0 weight percent.
- a preferred amount is 0.1 to 0.5 weight percent.
- anhydroglucose residue refers to a glucopyranose in which three of the hydroxy groups have been removed from three of its positions on the backbone of the glucose molecule and which is capable of being substituted to the OR group at these positions.
- Examples of anhydroglucose residue include:
- the preferred anhydroglucose residue is:
- Another component in the shampoo of the present invention is an anionic surfactant of the general formula (3) described above.
- the preferred embodiment of this ingredient is sodium laureth sulfate (3 EtO), that is, the sodium salt of sulfated ethoxylated lauryl alcohol in which, in the above formula (3), (Alk) is CH 3 (CH 2 ) 11 - and i is 3.
- EtO sodium laureth sulfate
- (Alk) is CH 3 (CH 2 ) 11 - and i is 3.
- the preferred component is available commercially. This component can be present in an amount ranging from about 5 to about 50 weight percent of the composition/ and more preferably about 10 to about 40 weight percent.
- Another component of the present invention is a betaine of the formula (4) given above.
- the preferred embodiment of this component is cocamidopropyl betaine, a commercially available product in which in formula (4) above the substitutent (ALK) is derived from coconut oil and j is 3.
- This component can be present generally in the amount ranging from about 2 to about 20 weight percent of the composition, and more preferably about 2 to about 10 weight percent.
- Another component of the present invention is 0.05 to 1.0 weight percent of a polyoxyethylene of the general formula (5) given above.
- a preferred range is 0.1 to 0.5 weight percent.
- the degree of polymerization d can be about 20,000 to about
- the preferred polymer in which the degree of polymerization is about 21,000 is available commercially and is known generically as PEG-21M.
- the composition of the present invention also preferably contains benzyl alcohol, in an amount ranging from about 0.1 to about 2.0 weight percent and more preferably about 0.3 to about 0.7 weight percent.
- composition of the present invention can also optionally contain preservatives, such as methyl paraben and/or propyl paraben. in an effective amount which will generally be up to about 0.5 weight percent of the composition.
- preservatives such as methyl paraben and/or propyl paraben.
- the composition can also optionally contain components to provide cosmetically and esthetically acceptable fragrance; examples of such components are numerous and well known to those skilled in this art.
- the amount of fragrance is generally up to about 0.5 weight percent or may range up to about 1.0 weight percent.
- composition of the present invention can be prepared by simply mixing together each of the above components in the water base.
- the resulting composition is packaged in a pressurized dispensing system, containing typically 75-99 percent by weight of the composition and. the balance a propellant such as any of the hydrocarbons or halogenated hydrocarbons well known for use in this type of application.
- the mixture and propellant are charged into a pressurized container fitted with an appropriate aerosol dispensing nozzle.
- One example of a satisfactory shampoo composition in accordance with the present invention is the following: Ingredient Amount (wt.%)
- This shampoo vehicle contains both anionic and cationic materials and is relatively mild upon contact with the eyes. It is superior in performance to known shampoos in mildness, cleaning, rinseability and conditioning properties.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US916787A | 1987-01-30 | 1987-01-30 | |
| US9167 | 1987-01-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0301082A1 EP0301082A1 (fr) | 1989-02-01 |
| EP0301082A4 true EP0301082A4 (en) | 1991-03-20 |
Family
ID=21735980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19880902294 Withdrawn EP0301082A4 (en) | 1987-01-30 | 1988-01-29 | Shampoo |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0301082A4 (fr) |
| JP (1) | JPH01502030A (fr) |
| AU (1) | AU600108B2 (fr) |
| BR (1) | BR8805088A (fr) |
| NZ (1) | NZ223355A (fr) |
| WO (1) | WO1988005812A1 (fr) |
| ZA (1) | ZA88646B (fr) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4992266A (en) * | 1989-08-14 | 1991-02-12 | S. C. Johnson & Son, Inc. | Reducing the ocular irritancy of anionic shampoos |
| FR2708276B1 (fr) * | 1993-07-28 | 1995-09-22 | Oreal | Composition de lavage des fibres kératiniques à base de polymères dérivés du chitosane. |
| JP3437637B2 (ja) * | 1994-05-12 | 2003-08-18 | 花王株式会社 | 泡状毛髪化粧料 |
| US5632978A (en) * | 1994-08-24 | 1997-05-27 | The Procter & Gamble Company | Mild shower gel composition comprising fatty alcohol which imparts improved lathering and thickening properties |
| US5681546A (en) * | 1996-03-18 | 1997-10-28 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Hair styling mousse |
| US5843875A (en) * | 1996-06-20 | 1998-12-01 | The Procter & Gamble Company | Perfume delivery systems in liquid personal cleansing |
| US5804538A (en) * | 1996-06-20 | 1998-09-08 | The Procter & Gamble Company | Perfume delivery systems in liquid personal cleansing compositions |
| GB9626551D0 (en) * | 1996-12-20 | 1997-02-05 | Procter & Gamble | Packaged personal cleansing product |
| GB9626552D0 (en) * | 1996-12-20 | 1997-02-05 | Procter & Gamble | Packaged personnal cleansing product |
| GB9828719D0 (en) | 1998-12-24 | 1999-02-17 | Unilever Plc | Detergent composition |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3816616A (en) * | 1971-11-30 | 1974-06-11 | Warner Lambert Co | Unitary shampoo and cream rinse compositions |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU464487B2 (en) * | 1971-06-16 | 1975-08-11 | Colgate-Palmolive Pty. Ltd. | Light duty detergent formulations |
| FR2382233A1 (fr) * | 1977-03-02 | 1978-09-29 | Oreal | Nouvelles compositions cosmetiques pour cheveux et procede d'application |
| FR2450105A1 (fr) * | 1979-02-27 | 1980-09-26 | Oreal | Composition et procede de traitement de matieres keratiniques a base de derives fluores |
| US4412944A (en) * | 1980-02-12 | 1983-11-01 | Alcolac, Inc. | High foaming, low eye irritation cleaning compositions containing ethoxylated anionic (C13-C30) sulphates |
| US4372869A (en) * | 1981-05-15 | 1983-02-08 | Johnson & Johnson Baby Products Company | Detergent compositions |
| LU83911A1 (fr) * | 1982-01-29 | 1983-09-02 | Oreal | Produit nettoyant des cheveux et de la peau a base d'acylise thionates et de polymeres cationiques |
-
1988
- 1988-01-29 JP JP63502136A patent/JPH01502030A/ja active Pending
- 1988-01-29 BR BR8805088A patent/BR8805088A/pt not_active Application Discontinuation
- 1988-01-29 WO PCT/US1988/000357 patent/WO1988005812A1/fr not_active Ceased
- 1988-01-29 AU AU13661/88A patent/AU600108B2/en not_active Ceased
- 1988-01-29 EP EP19880902294 patent/EP0301082A4/en not_active Withdrawn
- 1988-01-29 ZA ZA880646A patent/ZA88646B/xx unknown
- 1988-01-29 NZ NZ223355A patent/NZ223355A/en unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3816616A (en) * | 1971-11-30 | 1974-06-11 | Warner Lambert Co | Unitary shampoo and cream rinse compositions |
Non-Patent Citations (1)
| Title |
|---|
| See also references of WO8805812A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| NZ223355A (en) | 1990-11-27 |
| BR8805088A (pt) | 1989-08-15 |
| AU1366188A (en) | 1988-08-24 |
| ZA88646B (en) | 1988-08-03 |
| WO1988005812A1 (fr) | 1988-08-11 |
| JPH01502030A (ja) | 1989-07-13 |
| EP0301082A1 (fr) | 1989-02-01 |
| AU600108B2 (en) | 1990-08-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU602729B2 (en) | Personal skin care products containing dimethyl diallyl ammonium chloride/acrylic acid-type polymers | |
| US4963535A (en) | Nonirritant cosmetic compositions containing a foaming surfactant and a nonionic surfactant containing two fatty chains | |
| CA2398224C (fr) | Compositions detergentes hydratantes | |
| KR20190053886A (ko) | 컨디셔닝 특성을 갖는 클렌징 조성물 | |
| JP2002502807A (ja) | 起泡スキンクレンジング製品 | |
| AU1709997A (en) | Detergent compositions | |
| GB2087919A (en) | Anionic-amphoteric based antimicorbial shampoo | |
| MXPA01000659A (es) | Composicion para el lavado de materiales con queraitna a partir de ester de sorbitan debilmente etoxilado. | |
| US20050019299A1 (en) | Conditioning detergent compositions | |
| US6878379B2 (en) | Cosmetic preparations | |
| WO2004098558A1 (fr) | Composition detergente | |
| KR970001639B1 (ko) | 피부용 양이온 조성물 | |
| EP0160507B1 (fr) | Composition pour shampooing | |
| EP0301082A4 (en) | Shampoo | |
| EP1352644B1 (fr) | Composition détergente | |
| US20030069163A1 (en) | Detergent composition | |
| JP3526314B2 (ja) | シャンプー組成物 | |
| US20030068342A1 (en) | Cosmetic cream cleanser | |
| US20070202072A1 (en) | Ethoxylated Polyurethane Viscosity Enhancers | |
| JPH07304626A (ja) | 保湿性の改良された化粧料 | |
| JPS6284198A (ja) | 液体洗浄剤組成物 | |
| JPH0885800A (ja) | 低刺激性洗浄剤組成物 | |
| JPH05194157A (ja) | 洗浄剤組成物 | |
| JPH05310542A (ja) | 洗浄剤組成物 | |
| GB2197875A (en) | Surfactant composition for body application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 19880922 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): BE CH DE FR GB IT LI LU NL |
|
| A4 | Supplementary search report drawn up and despatched |
Effective date: 19910128 |
|
| AK | Designated contracting states |
Kind code of ref document: A4 Designated state(s): BE CH DE FR GB IT LI LU NL |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
| 18W | Application withdrawn |
Withdrawal date: 19920716 |