EP0312080B1 - Tragbare, automatische Vorrichtung zum Anreichern von Wasser mit Kohlensäure ohne elektrische Bauteile - Google Patents
Tragbare, automatische Vorrichtung zum Anreichern von Wasser mit Kohlensäure ohne elektrische Bauteile Download PDFInfo
- Publication number
- EP0312080B1 EP0312080B1 EP88117098A EP88117098A EP0312080B1 EP 0312080 B1 EP0312080 B1 EP 0312080B1 EP 88117098 A EP88117098 A EP 88117098A EP 88117098 A EP88117098 A EP 88117098A EP 0312080 B1 EP0312080 B1 EP 0312080B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- chamber
- gas
- reagent
- carbonator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 78
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 30
- 239000002253 acid Substances 0.000 claims description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims 5
- 230000001105 regulatory effect Effects 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 38
- 229910002092 carbon dioxide Inorganic materials 0.000 description 19
- 239000000126 substance Substances 0.000 description 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Substances OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 206010019233 Headaches Diseases 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002991 molded plastic Substances 0.000 description 2
- 239000011973 solid acid Substances 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 235000014171 carbonated beverage Nutrition 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67D—DISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
- B67D1/00—Apparatus or devices for dispensing beverages on draught
- B67D1/04—Apparatus utilising compressed air or other gas acting directly or indirectly on beverages in storage containers
- B67D1/0412—Apparatus utilising compressed air or other gas acting directly or indirectly on beverages in storage containers the whole dispensing unit being fixed to the container
- B67D1/0443—Apparatus utilising compressed air or other gas acting directly or indirectly on beverages in storage containers the whole dispensing unit being fixed to the container comprising a gas generator
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/236—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids specially adapted for aerating or carbonating beverages
Definitions
- the present invention relates to a carbonator which requires no electrical components and includes a CO2 gas generator module which generates the gas by a chemical reaction.
- the water carbonator in combination with the conventional CO2-cylinder, comprises a system, which is an essential part of those beverage dispensers which use syrup and water to produce a finished carbonated beverage.
- Conventional carbonator systems require complex controls firstly to ensure the correct degree of carbonation and secondly to provide a constant water pressure while dispensing. The latter is essential for providing good control of the water-syrup dispensing ratio and a constant carbonation level while water is being drawn.
- the conventional CO2 supply comprises heavy, high pressure CO2 cylinders, which are necessarily returnable, refillable packages, are inconvenient in use, and require pressure controls and safety devices.
- a non-pressurized or low-pressure CO2 package is important, since it simplifies distribution through normal retail channels and provides greater convenience for the non-professional user.
- a convenient design of carbonator for home-dispensing is one which is portable, can be filled at the user's sink, and be replaced into the dispenser after filling.
- Home dispensers are essentially simple devices, with few controls, and in the future some may be fitted into refrigerators, eliminating the need for separate cooling. This in turn implies the need for simple mechanical controls of the carbonation process.
- both the actual carbonation and the generation of gas for dispensing purposes should occur automatically, with minimum user manipulation. Otherwise, the advantages of simplicity and cost-effectiveness are counter-balanced by the lack of essential convenience.
- US-A-4,040,342 discloses an apparatus for the generation of CO2 gas and the carbonation of water wherein the CO2-releasing substance is immersed into the water only after closing the gas generating chamber.
- the whole mass of the CO2-releasing substance is immersed into water so that the CO2 pressure is very high at the beginning and decreases gradually with the delivery of carbonated water.
- the carbonation level of the water decreases concommittantly.
- DE-C-45 734 discloses an apparatus for the generation of CO2 gas at constant pressure in the same way as a Kipp generator.
- the invention as claimed in claim 1 solves the problem of how to provide a non-electric carbonator which delivers carbonated water at a substantially constant pressure and with a substantially constant carbonation level.
- the carbonator of the present invention uses a substance, such as sodium bicarbonate, which in contact with an acid, such as citric or phosphoric acid, releases carbon dioxide.
- the two components can be mixed as powders, so that carbon dioxide is generated when water is added. Alternatively, one or both components can be dissolved in water and thereafter gas generation occurs when the two solutions are mixed together. Details of a suitable CO2 gas generator are also fully disclosed in EP-A-312,078.
- Chemical generation of CO2 gas is generally known. Also known are devices, which use this form of gas-generation to carbonate water to a pre-determined degree. These are mostly inconvenient, because they often involve the user in an unacceptable degree of manipulation. Also they are not useable in place of the conventional carbonator/CO2 cylinder system found in beverage dispensers, since they have no means of maintaining a constant pressure within the carbonator once water is being drawn to feed the dispenser.
- the carbonator of the present invention is portable and complete with a built-in CO2-supply system, which operates on disposable gas generating cartridges. It requires no electrical connections and is self-sufficient, and automatic. It demands a minimum amount of manipulation by the user and requires him simply to fill the carbonator, insert the cartridge and replace the cartridge cover and carbonator lid. Nonetheless, once the carbonator is closed, it proceeds to carbonate the water to the correct level, and whenever water is drawn, it reacts by generating more CO2 so as to maintain a constant pressure.
- the carbonator consists of a lid 20, a main body 22, an intermediate section 24(which houses the pressure-regulating "memory" and the internal channels) and a base 26 into which the CO2-generating cartridge is inserted. These three sections are shown apart in an "exploded" view in the flow-diagram in Figure 1 to simplify the description.
- the CO2-generating cartridge 28 in the particular example shown, comprises two separate parts. Each of these two parts consists of pellets of a mixture of sodium bicarbonate and citric acid (or another suitable solid acid) in a perforated outer package. An air-gap is present between the two parts and one is mounted above the other. In the lower part, reagent R c has the correct proportions for securing the necessary level of water carbonation. In the upper part reagent R p , is proportioned so as to provide adequate gas quantities for propulsion and displacing the entire contents of the carbonator to the dispensing point, while maintaining the required pressure.
- the main body consists of a large chamber W, which contains the carbonated water and two small chambers A and B, which contain reagent water. All three chambers are filled simultaneously, when the correct water level is reached in the carbonator.
- the lid 20 simply screws down and seals onto the top of the main vessel and seals the chambers A and B separating them from each other and from W, once the lid is secured.
- valve V3 is normally open to Vent 3 (leading to the top of chamber 24) this position being ensured by spring pressure.
- a third vertical rod 30, also running down inside the walls of the main body fits into a ratchet ( Figure 1D) and prevents the spring from returning the valve V3, once the valve is set in another position. The user can thus change the position of valve V3 during operation and it springs back to its normal position only when the lid is removed.
- the base section 26 can be unscrewed from the central section 22, so that the cartridge 28 comprising reagents R c and R p can be inserted. The user inserts the cartridge 28 before closing the lid 20 of the main chamber W.
- the system described can be constructed of moulded plastic parts, with in-built channels for the various flows shown and the three valve-actuating rods.
- the three valves V2, V3, V4 consist of simple plug-cocks and are inserted in prepared borings in the side of the central casting which also contains chamber C.
- valve V1 opens and the water in chamber A discharges into chamber D flooding the lower part R c of the reagent cartridge 28, Simultaneously, the water in chamber B flows into chamber C.
- the reagent R c gradually releases CO2 through the diffuser 32 to effect the required carbonation level in the water in chamber W.
- the head-pressure in chamber C at the end of the carbonation cycle is equal to that in chamber D and the whole system now reaches pressure equilibrium.
- the carbonator can be placed into the dispenser either while carbonating or at the end of the carbonation cycle.
- a simple, self-sealing push-in connector at the base fits onto the dispenser. Once dispensing can begin, the user simply switches valve V3 to the dispensing position. From that moment, whenever water is drawn out of the carbonator and the pressure in the carbonator drops, the pressure in chamber D also drops and water enters chamber D from chamber C, since this chamber is now at a higher pressure. The water floods the cartridge R p and generates CO2 until the pressure in chambers W and D have attained equilibrium with the reference pressure in chamber C. When pressure equilibrium has been reached, the water is pushed back into chamber C and the reaction stops. The process repeats itself whenever the pressure in W drops below the reference pressure in C. This reference pressure acts as a pressure "memory” and the pressure "memory” is set by the system itself after carbonation is complete.
- FIGS. 2A, 2B and 3 illustrate such a system, using the principles already described.
- a suitable gas-generating cartridge 40 is shown.
- the cartridge 40 consists of a moulded plastic shell 42.
- the top-section is filled with bicarbonate pellets 44, the middle section with pellets containing a mixture of bicarbonate and powdered acid 46 and the lower section contains a liquid acid 48.
- the top and bottom sections are connected by a tube 50, which is sealed with foil 52 at the bottom and filter paper 54 at the top.
- the top and bottom of cartridge 40 are closed by sealing foil 56.
- FIG 3 shows a sectional view of the carbonator tank.
- Lid 1 is removed and the tank filled with water up to a pre-determined mark.
- the reagent water tank 14 is filled at the same time, as soon as the water reaches the required level.
- valve 4 is opened by the pressure which lid 1 exerts on a spring valve actuator.
- the water in the reagent tank cannot as yet flow out, since it is restrained by a second valve 5.
- Lid 2 is removed and the gas generating cartridge 40 inserted. The cartridge 40 does not reach its lowest position, being restrained by an o-ring 6.
- the cartridge is punctured on the top foil 56 and forced to its lowest position.
- the cartridge 40 In its lowest position, the cartridge 40 seals its base 9 against o-ring 7 and its top section 10 against a seal 8.
- a spring bellows 13 enters the base 3 of the cartridge displacing the acid into the top section.
- the spike 11 in the center of the bellows opens the channel to the top section through foil 52.
- valve 5 opens automatically and water from the reagent water chamber flows into the carbonating reagent section 12 of the cartridge. CO2 gas is released and flows to sparge tubes 60, carbonating the water to the level pre-determined by the quantity of chemicals.
- the spring bellows 13 has forced acid in contact with bicarbonate and this also generates CO2, pressurizing the head-space of the tank. As soon as the head-space pressure has reached equilibrium with the spring pressure in the bellows, the spring contracts, the acid returns to the lower chamber and the reaction stops. Thereafter, the process repeats itself, whenever water is drawn out of the carbonator and the head-pressure drops.
- FIGS. 4A and 4B show a typical installation of a horizontal carbonator tank in a refrigerator.
- the tank can now be connected to a dispensing point within or outside the refrigerator.
- the above principles can also be applied to a vertical carbonator. They also illustrate how a liquid acid may also be used, in place of a solid acid, and how an external fixed pressure reference may be applied in place of the self-generated internal reference as described in Figure 1.
- the external pressure reference can be by spring pressure (as above), or by an air-cushion or by a membrane or by a piston or by some other similar pressure-exerting device.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Non-Alcoholic Beverages (AREA)
- Devices For Dispensing Beverages (AREA)
- Water Treatment By Sorption (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- External Artificial Organs (AREA)
Claims (5)
- Karbonisator mit
einer Wasservorratskammer (W) mit einer ersten benachbarten Reagenzwasser-Kammer (A), wobei die Wasserkammern gleichzeitig mit Wasser gefüllt werden können;
einer Abdeckung (20) zum gleichzeitigen verschließen der Wasserkammern (W, A);
einer Gaserzeugungskammer (D), die Reagenzien (Rc, Rp) zur Erzeugung von CO₂-Gas bei chemischer Reaktion der Reagenzien enthält;
einer Einrichtung zum selektiven In-Kontakt-Bringen des Wassers in der ersten Reagenzwasser-Kammer (A) mit der Gaserzeugungskammer (D);
einer Leitung zur Einführung einer ersten Stufe von CO₂-Gas von der Gaserzeugungskammer (D) in die Wasservorratskammer (W), wodurch stilles Wasser innerhalb der Wasservorratskammer (W) karbonisiert wird;
Ventileinrichtungen, die im offenen Zustand die Strömung von karbonisiertem Wasser aus dem Karbonisator zulassen, und im geschlossenen Zustand die Strömung daraus verhindern;
gekennzeichnet
durch eine zweite Reagenzwasser-Kammer (B), die gleichzeitig mit der Wasservorratskammer (W) und der ersten Reagenzwasser-Kammer (A) gefüllt werden kann und gleichzeitig mit diesen Kammern (W, A) durch die Abdeckung (20) verschlossen werden kann;
dadurch, daß die Einrichtung zum selektiven In-Kontakt-Bringen ein erstes Ventil (V₁) zur Herstellung einer selektiven Fluid-Verbindung der ersten Reagenzwasser-Kammer (A) mit der Gaserzeugungskammer (D) ist, wobei eine Betätigung des ersten Ventils (V₁) Reagenzwasser aus der Reagenzwasser-Kammer (A) in die Gaserzeugungskammer (D) einleitet, wodurch CO₂-Gas in einer ersten Stufe erzeugt wird;
durch ein Druckreguliersystem (24) zur Aufrechterhaltung eines vorgegebenen Luftraumdruckes in der Wasservorratskammer (W), wobei das Druckreguliersystem (24) eine Wasserkammer (C) in Fluidverbindung mit dem Luftraum in der Wasservorratskammer (W) aufweist;
durch ein zweites Ventil (V₂) zur Schaffung einer selektiven Fluidverbindung der zweiten Reagenzwasser-Kammer (D) mit der Wasserkammer (C) des Druckreguliersystems (24), wobei eine Betätigung des zweiten Ventils (V₂) Reagenzwasser aus der zweiten Reagenzwasser-Kammer (D) in die Wasserkammer (C) einleitet;
durch ein drittes Ventil (V₃) zur Schaffung einer selektiven Fluidverbindung der Wasserkammer (C) mit der Gaserzeugungskammer (D), wodurch anschließend an die Karbonisierung des Wassers in der Wasservorratskammer (W) das dritte Ventil (V₃) zur Einleitung von Wasser aus der Wasserkammer (C) in die Gaserzeugungskammer (D) betätigbar ist, wodurch CO₂-Gas in einer zweiten Stufe erzeugt wird; und
durch ein viertes Ventil (V₄) zur selektiven Zuführung wenigstens eines Teils der zweiten Stufe des CO₂-Gases in den Luftraum der Wasservorratskammer (W) nur bei Entleerung wenigstens eines entsprechenden Teils von karbonisiertem Wasser aus der Wasservorratskammer (W), wodurch der Druck in dem Luftraum der Wasservorratskammer (W) in einem ausgeglichenen Gleichgewicht mit dem Druck in der Gaserzeugungskammer (D) steht. - Karbonisator nach Anspruch 1, wobei die Gaserzeugungskammer (26) eine Patrone (28) mit einem ersten Reagenz (Rc) zur Erzeugung der ersten Stufe von CO₂-Gas und ein zweites Reagenz (Rp) zur Erzeugung der zweiten Stufe des CO₂-Gases enthält, wobei das erste und das zweite Reagenz durch einen Luftspalt getrennt sind.
- Karbonisator nach Anspruch 2, wobei das erste und das zweite Reagenz Bikarbonat und pulverförmige Säure enthalten.
- Karbonisator nach Anspruch 1, wobei die selektive Betätigung des ersten und des zweiten Ventils (V₁, V₂) das Festmachen der Abdeckung (20) an der Wasservorrats- und der ersten und der zweiten Reagenzwasser-Kammer (W, A, B) umfaßt, wobei das erste und das zweite Ventil (V₁, V₂) jeweils ein Federelement (30) aufweisen, das beim Anbringen der Abdeckung (20) zusammengedrückt und beim Entfernen der Abdeckung (20) entspannt wird.
- Karbonisator nach Anspruch 1, wobei die Leitung zur Zuführung der ersten Stufe von CO₂-Gas in den Wasservorrat ferner wenigstens einen CO₂-Diffusor (32) aufweist, der am inneren Boden der Wasservorratskammer (W) angeordnet ist, und wobei die Leitung in Fluidverbindung mit der Gaserzeugungskammer (D) steht.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT88117098T ATE92363T1 (de) | 1987-10-15 | 1988-10-14 | Tragbare, automatische vorrichtung zum anreichern von wasser mit kohlensaeure ohne elektrische bauteile. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10868487A | 1987-10-15 | 1987-10-15 | |
| US108684 | 1987-10-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0312080A1 EP0312080A1 (de) | 1989-04-19 |
| EP0312080B1 true EP0312080B1 (de) | 1993-08-04 |
Family
ID=22323528
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP88117098A Expired - Lifetime EP0312080B1 (de) | 1987-10-15 | 1988-10-14 | Tragbare, automatische Vorrichtung zum Anreichern von Wasser mit Kohlensäure ohne elektrische Bauteile |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0312080B1 (de) |
| JP (1) | JPH01139128A (de) |
| CN (1) | CN1019172B (de) |
| AT (1) | ATE92363T1 (de) |
| AU (1) | AU606220B2 (de) |
| DE (1) | DE3882879T2 (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2012008857A (es) | 2010-02-01 | 2012-12-05 | Green Mountain Coffee Roasters Inc | Metodo y aparato para carbonatacion de bebidas a basadas en cartuchos. |
| US9936834B2 (en) | 2010-02-01 | 2018-04-10 | Bedford Systems Llc | Method and apparatus for cartridge-based carbonation of beverages |
| US9700852B2 (en) * | 2012-08-28 | 2017-07-11 | So Spark Ltd. | System, method and capsules for producing sparkling drinks |
| US9382119B2 (en) | 2014-01-27 | 2016-07-05 | So Spark Ltd. | Rapid high-pressure microwave thermal decomposition system, capsule and method for using same |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE7114C (de) * | O. ZWIETUSCH in Mihvaukee im Staate Wisconsin, N.-A | Automatische Kohlensäure - Entwickelungs-Apparat für hohen Druck | ||
| DE45734C (de) * | G. F. GRAF in Hanau a. Main | Kohlensäure-Entwickler mit selbsttätiger Druckregulirung | ||
| JPS5825053B2 (ja) * | 1979-07-24 | 1983-05-25 | 工業技術院長 | 高圧高温印加によるチオ・ニツケル・フエライト(NiFe↓2S↓4)の製造方法 |
| US4304736A (en) * | 1980-01-29 | 1981-12-08 | The Coca-Cola Company | Method of and apparatus for making and dispensing a carbonated beverage utilizing propellant carbon dioxide gas for carbonating |
| GB2139910B (en) * | 1983-05-17 | 1987-04-29 | Thorn Emi Domestic Appliances | Carbonating apparatus |
| GB8417772D0 (en) * | 1984-07-12 | 1984-08-15 | Thorn Emi Domestic Appliances | Carbonating apparatus |
-
1988
- 1988-10-14 EP EP88117098A patent/EP0312080B1/de not_active Expired - Lifetime
- 1988-10-14 CN CN88108527A patent/CN1019172B/zh not_active Expired
- 1988-10-14 AT AT88117098T patent/ATE92363T1/de not_active IP Right Cessation
- 1988-10-14 JP JP63257386A patent/JPH01139128A/ja active Granted
- 1988-10-14 DE DE88117098T patent/DE3882879T2/de not_active Expired - Fee Related
- 1988-10-17 AU AU23918/88A patent/AU606220B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CN1033751A (zh) | 1989-07-12 |
| DE3882879D1 (de) | 1993-09-09 |
| AU2391888A (en) | 1989-06-08 |
| CN1019172B (zh) | 1992-11-25 |
| JPH01139128A (ja) | 1989-05-31 |
| EP0312080A1 (de) | 1989-04-19 |
| JPH0446610B2 (de) | 1992-07-30 |
| ATE92363T1 (de) | 1993-08-15 |
| AU606220B2 (en) | 1991-01-31 |
| DE3882879T2 (de) | 1994-03-17 |
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