EP0337860A2 - Isolier-Container mit Kältemittelbehälter und Verwendung beim Transport von frischen Produkten - Google Patents
Isolier-Container mit Kältemittelbehälter und Verwendung beim Transport von frischen Produkten Download PDFInfo
- Publication number
- EP0337860A2 EP0337860A2 EP89400968A EP89400968A EP0337860A2 EP 0337860 A2 EP0337860 A2 EP 0337860A2 EP 89400968 A EP89400968 A EP 89400968A EP 89400968 A EP89400968 A EP 89400968A EP 0337860 A2 EP0337860 A2 EP 0337860A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- container
- screen
- tank
- container according
- slides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003507 refrigerant Substances 0.000 title claims description 6
- 235000013305 food Nutrition 0.000 claims abstract description 9
- 239000002826 coolant Substances 0.000 claims abstract description 7
- 239000011810 insulating material Substances 0.000 claims abstract description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 5
- -1 polyethylene Polymers 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 4
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims 1
- 239000010935 stainless steel Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 description 8
- 239000000725 suspension Substances 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 3
- 235000012054 meals Nutrition 0.000 description 3
- 239000010964 304L stainless steel Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- 240000000528 Ricinus communis Species 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D3/00—Devices using other cold materials; Devices using cold-storage bodies
- F25D3/12—Devices using other cold materials; Devices using cold-storage bodies using solidified gases, e.g. carbon-dioxide snow
- F25D3/125—Movable containers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/18—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
Definitions
- the present invention relates to an insulated container, in particular an itinerant trolley intended for the transport of fresh products, usable for example for the transport of meal trays.
- the present invention relates in particular to trolleys for the transport of fresh products which can be used in particular for storing and transporting fresh products and for example meals before their distribution in planes, trains or hospitals and this at temperatures specific to the conservation of fresh products, that is to say close to 0 ° C.
- the insulated containers are in this case slightly insulated, of light structure, for example only have a double wall, and are disposed or mounted integrally on displacement means, such as carts or castors or trains of casters for example.
- the Applicant has demonstrated that in order to be able to carry out, for example long-term transport (30 hours) without freezing the products taking into account the doses of solid CO2 to be used, an additional device is necessary.
- a container in particular an itinerant trolley, for the transport of fresh products, with isothermal walls of the type comprising a reservoir for refrigerant product in which the reservoir is arranged in the upper part of the container, and where a screen made of thermally insulating material, of dimensions slightly smaller than the internal section of the container and leaving at its periphery an annular space suitable for the free passage of gas is disposed horizontally below the tank, at a sufficient distance to delimit in the upper part of the container an area suitable for exchange by natural convection, and where the tank and the screen comprise means of attachment and / or support in the container, characterized in that it comprises at least one food compartment disposed in the container, below the screen plate, of dimensions substantially smaller than the internal volume of the container, a space remaining free around the co
- solid carbon dioxide stored in the tank is used as the refrigerant.
- the invention has the following advantages: . the products stored near the tank are protected from radiation and therefore from too low temperatures by the screen which forms a thermal barrier; . the sublimation gases can flow along the walls of the container, in the free space left between the screen and the vertical internal walls. During the initial sublimation, the cold gases descend to the bottom of the container, exchanging their frigories as they go. The hot atmosphere of the container rises by natural convection and passes into the area suitable for exchange by natural convection, in particular between the screen and the coolant tank where it cools.
- the refrigerant is then a cooling agent for a radiant heat-conducting exchange surface which enables permanent cooling of the atmosphere by natural convection.
- the food compartment may or may not be removable. There is free space around the compartment in the container.
- the cold gas flowing along the walls of the container also flows along the walls of the compartment and cools it homogeneously.
- the double envelope formed plays the role of a new thermal barrier with low insulation power, but compensated by the fact that the gas / solid exchange (without circulation) provides a low coefficient of thermal transfer.
- the fresh products can optionally be stored on several trays arranged in the food compartment.
- the food compartment can be opened, for example, at the front and / or rear to allow easy loading and unloading of fresh products, and in this case the refrigerant gases are in contact with fresh products during storage . It can also be airtight.
- Carbon dioxide is however detrimental to the good conservation of certain fresh products. Therefore, in this case, the food compartment must be airtight.
- cleats made of food-grade polyethylene permanently fixed to the walls of the container.
- This internal structure makes it possible to load the products to be transported without particular precautions, its role being essentially to ensure the circulation of gaseous CO2 around the product whether or not the container is equipped with a double envelope.
- the double envelope formed by a watertight metal box made of thin sheet metal will be deposited on the internal structure of the insulated container, that is to say on the lower battens and between the lateral battens, and its watertightness guaranteed on the front, loading side, by a metal door secured to the insulated door of the container.
- the door can also be equipped with a plate fixed on its internal face, the plate being spaced from the internal face of the door to ensure the double envelope, the tightness of the compartment then being guaranteed by a seal at lips.
- This seal makes it possible to seal the compartment even when the excess CO2 escapes through the door away from the container.
- the containers according to the invention perfectly meet the conditions of temperature, temperature stability during storage and temperature uniformity for the preservation of fresh products.
- the present invention also relates to the application of these containers to the storage of product at temperatures close to 0 ° C.
- the rectangular container 1 consists of walls provided with insulating material 2.
- a polyethylene plate 3 forming a screen is suspended by four suspension columns 4 from the upper wall 5 of the container 1.
- This screen forming plate 3 delimits an area 6 suitable for exchange by natural convection where the hot gases which rise from the lower part of the container through the free space 8 between the screen 3 and the vertical walls 9 of the container cool in passing between the screen 3 and the reservoir 10 of coolant.
- the containers further include in their lower part a grating 11 or cleats made of plastic material, for example polyethylene on which are arranged the fresh products to be transported.
- FIG. 2 appears in section, and seen from the side, the same container 1 provided with the screen 3 suspended by the columns 4 and with the reservoir 10 placed in the zone 6.
- Figure 3 appear in perspective the screen 3 and the tank 10 as they are arranged in the upper part of the container to form the natural convection zone.
- the screen forming plate 3 is provided as described above with four suspension columns 4.
- the reservoir 10 is a drawer made of 304L stainless steel provided with slides 12 capable of sliding in translation on slides 13 parallel to the drawer and themselves provided with pads of suspension 14 on the upper wall 5 of the container 1.
- the studs 15 located at the end of the slides 13 on the side of the bottom 16 of the drawer 10 form a stop.
- the drawer 10 is equipped, on the side opposite the bottom 16, with a handle 17 allowing the user to handle the drawer in translation when filling or checking the level of coolant.
- the bottom 18 of the reservoir 10 is at a distance of a few centimeters from the screen 3.
- a suitable convection zone is defined in the upper part of the container, for example if the bottom 18 of the drawer 10 is approximately halfway between the screen 3 and the upper wall of the container where the studs and suspension columns are fixed (4, 14, 15).
- two superimposed plates can be provided, separated by washers.
- expanded PVC is suitable as a material for the plate (s).
- the tank 10 is a 304L stainless steel drawer with internal dimensions (in mm) 500 x 420 x 50 (thickness 12/10).
- the screen 3 a 10 mm thick polyethylene plate, is suspended from 100 mm and the drawer is suspended from 10 mm from the wall 5.
- the free space 8 is 30 mm at the front and at the rear and 55 mm on the sides.
- the temperature between the reserve drawer provided with solid CO2 and the thermal barrier formed by the screen plate is at an average of -18 ° C. the temperatures measured in the container outside this zone have remained above -5 ° C., with a gap between the bottom and the top of the container of around 2 ° C. The tests lasted more than 5 hours at ambient temperatures of around 15 ° C. The products stored in the container remained between 0.5 and 2 ° C.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Packages (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8804659 | 1988-04-08 | ||
| FR8804659A FR2629799B2 (fr) | 1988-02-01 | 1988-04-08 | Trolley ambulant pour le transport de produits frais |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0337860A2 true EP0337860A2 (de) | 1989-10-18 |
| EP0337860A3 EP0337860A3 (de) | 1991-05-29 |
| EP0337860B1 EP0337860B1 (de) | 1996-05-22 |
Family
ID=9365110
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89400968A Expired - Lifetime EP0337860B1 (de) | 1988-04-08 | 1989-04-07 | Isolier-Container mit Kältemittelbehälter und Verwendung beim Transport von frischen Produkten |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4964283A (de) |
| EP (1) | EP0337860B1 (de) |
| CA (1) | CA1319347C (de) |
| DE (1) | DE68926520T2 (de) |
| ES (1) | ES2088391T3 (de) |
| GR (1) | GR3020303T3 (de) |
| PT (1) | PT90228B (de) |
| TR (1) | TR27507A (de) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1993004949A1 (en) * | 1991-09-04 | 1993-03-18 | Weyerhaeuser Company | A method of packaging perishable food or horticultural products |
| US5290580A (en) * | 1990-09-05 | 1994-03-01 | Weyerhaeuser Company | Cooling process for perishable food and horticultural products |
| FR2696158A1 (fr) * | 1992-09-29 | 1994-04-01 | Carboxyque Francaise | Conteneur isotherme, notamment pour le transport de produits frais ou surgelés. |
| EP0631096A1 (de) * | 1993-06-23 | 1994-12-28 | Carboxyque Francaise | Verfahren zur Konservierung von Waren bei niedrigen Temperaturen in einem isolierten Gehäuse, Vorrichtung zur Durchführung des Verfahrens, isoliertes Gehäuse und Behälter für solch ein Gehäuse |
| FR2726353A1 (fr) * | 1994-10-26 | 1996-05-03 | Carboxyque Francaise | Procede de dosage automatique pour conserver a basse temperature des produits dans une enceinte isolee comprenant un volume de chargement et au moins un bac a neige carbonique |
| US5747082A (en) * | 1990-09-05 | 1998-05-05 | Weyerhaeuser Co | Package for perishable food and horticultural products |
| FR2758620A1 (fr) | 1997-01-20 | 1998-07-24 | Carboxyque Francaise | Bac de reception de neige carbonique, et son application a une enceinte et une installation de conservation de produits |
| EP0863374A2 (de) | 1997-03-05 | 1998-09-09 | MONETTI S.p.A. | Gefäss mit festem Kältemittel für isothermische Behälter, insbesondere für den Warentransport mit überwachter Temperatur |
| US5908649A (en) * | 1990-09-05 | 1999-06-01 | Weyerhaeuser Company | Package for perishable food and horticultural products |
| NL1016535C2 (nl) * | 2000-07-24 | 2002-01-25 | Willem Cornelis Schuddebeurs | Koelinrichting. |
| FR2891354A1 (fr) * | 2005-09-28 | 2007-03-30 | Air Liquide | Receptacle de neige carbonique a double compartiment pour conteneurs isothermes |
| FR2891899A1 (fr) * | 2005-10-12 | 2007-04-13 | Air Liquide | Systeme d'injection de neige carbonique dans des conteneurs isothermes et conteneurs associes |
| EP2604956A1 (de) | 2011-12-15 | 2013-06-19 | ACP Belgium N.V. | Verfahren zur Konservierung von Produkten in isolierten Gehäusen bei niedriger Temperatur |
| EP3244144A1 (de) | 2016-05-10 | 2017-11-15 | Bonetto S.r.l. | Isothermischer behälter für den transport von verderblichen nahrungsmitteln |
| RU175886U1 (ru) * | 2015-06-17 | 2017-12-21 | Акционерное общество "Информационные спутниковые системы" имени академика М.Ф. Решетнева" | Изотермический контейнер |
| FR3058206A1 (fr) * | 2016-10-31 | 2018-05-04 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Echangeur air/neige carbonique et procede de regulation d'un tel echangeur |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NO982971A (no) * | 1998-06-26 | 1999-12-27 | H&R Ind Inc | Fremgangsmåte for transport og lagring av varer, samt container egnet for samme |
| DE19919934A1 (de) * | 1999-04-30 | 2000-11-02 | Tv Kohlensaeure Technik & Vert | Vorrichtung und Verfahren zur Temperaturhaltung von Lebensmitteln |
| US6898892B2 (en) * | 2002-08-14 | 2005-05-31 | John F. Senckowski | Apparatus and method for fishing utilizing the jig fishing system |
| WO2013024448A1 (en) * | 2011-08-16 | 2013-02-21 | SEARLE, John Peter | Delivery container for temperature sensitive goods |
| JP6191207B2 (ja) * | 2013-04-10 | 2017-09-06 | 富士電機株式会社 | 収容庫 |
| JP6255698B2 (ja) * | 2013-04-10 | 2018-01-10 | 富士電機株式会社 | 収容庫 |
| CN105758046A (zh) * | 2016-04-28 | 2016-07-13 | 浙江和利制冷设备有限公司 | 超低温触摸屏拆分装置及其工作原理 |
| FR3090599B1 (fr) * | 2018-12-20 | 2021-01-15 | Cold & Co | Conteneur réfrigérant amélioré |
| JP2022110869A (ja) * | 2021-01-19 | 2022-07-29 | Agc株式会社 | 断熱容器 |
| KR20230104418A (ko) * | 2021-12-31 | 2023-07-10 | 오씨아이 주식회사 | 단열 컨테이너 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE20215E (en) * | 1936-12-22 | Refbigekated package | ||
| US1998681A (en) * | 1932-07-29 | 1935-04-23 | Littleford Brothers | Refrigerating container |
| US1997936A (en) * | 1932-10-10 | 1935-04-16 | Pennsylvania Railroad Co | Refrigerator container |
| US2057058A (en) * | 1934-06-20 | 1936-10-13 | Internat Carbonic Inc | Refrigerator shipping container for container cars |
| FR2178437A5 (de) * | 1972-03-31 | 1973-11-09 | Air France | |
| NL7306577A (de) * | 1972-06-05 | 1973-12-07 | ||
| DE2731858A1 (de) * | 1977-07-14 | 1979-02-01 | Martin A Dipl Ing Frank | Verfahren zur kuehlhaltung von guetern in kuehlcontainern und kuehlcontainer |
| US4498306A (en) * | 1982-11-09 | 1985-02-12 | Lewis Tyree Jr | Refrigerated transport |
| DE3420256A1 (de) * | 1984-05-30 | 1985-12-05 | Martin A. Prof. Dipl.-Ing. 5060 Bergisch Gladbach Frank | Verfahren und vorrichtung zur kuehlung in containern |
-
1989
- 1989-04-07 DE DE68926520T patent/DE68926520T2/de not_active Expired - Lifetime
- 1989-04-07 PT PT90228A patent/PT90228B/pt not_active IP Right Cessation
- 1989-04-07 CA CA000596074A patent/CA1319347C/fr not_active Expired - Fee Related
- 1989-04-07 EP EP89400968A patent/EP0337860B1/de not_active Expired - Lifetime
- 1989-04-07 ES ES89400968T patent/ES2088391T3/es not_active Expired - Lifetime
- 1989-04-10 TR TR00285/89A patent/TR27507A/xx unknown
- 1989-04-10 US US07/335,677 patent/US4964283A/en not_active Expired - Lifetime
-
1996
- 1996-06-20 GR GR960401672T patent/GR3020303T3/el unknown
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5747082A (en) * | 1990-09-05 | 1998-05-05 | Weyerhaeuser Co | Package for perishable food and horticultural products |
| US5290580A (en) * | 1990-09-05 | 1994-03-01 | Weyerhaeuser Company | Cooling process for perishable food and horticultural products |
| US5908649A (en) * | 1990-09-05 | 1999-06-01 | Weyerhaeuser Company | Package for perishable food and horticultural products |
| WO1993004949A1 (en) * | 1991-09-04 | 1993-03-18 | Weyerhaeuser Company | A method of packaging perishable food or horticultural products |
| FR2696158A1 (fr) * | 1992-09-29 | 1994-04-01 | Carboxyque Francaise | Conteneur isotherme, notamment pour le transport de produits frais ou surgelés. |
| EP0591047A1 (de) * | 1992-09-29 | 1994-04-06 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Isothermischer Behälter, insbesondere für den Transport von frischen oder tiefgefrorenen Waren |
| US5397010A (en) * | 1992-09-29 | 1995-03-14 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Isothermal container, particularly for transporting fresh or frozen products |
| FR2706990A1 (de) * | 1993-06-23 | 1994-12-30 | Carboxyque Francaise | |
| US5566553A (en) * | 1993-06-23 | 1996-10-22 | Carboxyque Francaise | Process for the preservation of products at low temperature in an insulated chamber, installation for practicing the process, insulated chamber and container for such a chamber |
| US5511379A (en) * | 1993-06-23 | 1996-04-30 | Carboxyque Francaise | Process for the preservation of products at low temperature in an insulated chamber, installation for practicing the process, insulated chamber and container for such a chamber |
| EP0631096A1 (de) * | 1993-06-23 | 1994-12-28 | Carboxyque Francaise | Verfahren zur Konservierung von Waren bei niedrigen Temperaturen in einem isolierten Gehäuse, Vorrichtung zur Durchführung des Verfahrens, isoliertes Gehäuse und Behälter für solch ein Gehäuse |
| FR2726353A1 (fr) * | 1994-10-26 | 1996-05-03 | Carboxyque Francaise | Procede de dosage automatique pour conserver a basse temperature des produits dans une enceinte isolee comprenant un volume de chargement et au moins un bac a neige carbonique |
| FR2758620A1 (fr) | 1997-01-20 | 1998-07-24 | Carboxyque Francaise | Bac de reception de neige carbonique, et son application a une enceinte et une installation de conservation de produits |
| EP0863374A2 (de) | 1997-03-05 | 1998-09-09 | MONETTI S.p.A. | Gefäss mit festem Kältemittel für isothermische Behälter, insbesondere für den Warentransport mit überwachter Temperatur |
| NL1016535C2 (nl) * | 2000-07-24 | 2002-01-25 | Willem Cornelis Schuddebeurs | Koelinrichting. |
| FR2891354A1 (fr) * | 2005-09-28 | 2007-03-30 | Air Liquide | Receptacle de neige carbonique a double compartiment pour conteneurs isothermes |
| WO2007036656A1 (fr) * | 2005-09-28 | 2007-04-05 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Receptacle de neige carbonique a double compartiment pour conteneurs isothermes |
| FR2891899A1 (fr) * | 2005-10-12 | 2007-04-13 | Air Liquide | Systeme d'injection de neige carbonique dans des conteneurs isothermes et conteneurs associes |
| WO2007042727A1 (fr) * | 2005-10-12 | 2007-04-19 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Systeme d'injection de neige carbonique dans des conteneurs isothermes et conteneurs associes |
| EP2604956A1 (de) | 2011-12-15 | 2013-06-19 | ACP Belgium N.V. | Verfahren zur Konservierung von Produkten in isolierten Gehäusen bei niedriger Temperatur |
| RU175886U1 (ru) * | 2015-06-17 | 2017-12-21 | Акционерное общество "Информационные спутниковые системы" имени академика М.Ф. Решетнева" | Изотермический контейнер |
| EP3244144A1 (de) | 2016-05-10 | 2017-11-15 | Bonetto S.r.l. | Isothermischer behälter für den transport von verderblichen nahrungsmitteln |
| FR3058206A1 (fr) * | 2016-10-31 | 2018-05-04 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Echangeur air/neige carbonique et procede de regulation d'un tel echangeur |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0337860B1 (de) | 1996-05-22 |
| ES2088391T3 (es) | 1996-08-16 |
| EP0337860A3 (de) | 1991-05-29 |
| GR3020303T3 (en) | 1996-09-30 |
| US4964283A (en) | 1990-10-23 |
| DE68926520D1 (de) | 1996-06-27 |
| CA1319347C (fr) | 1993-06-22 |
| DE68926520T2 (de) | 1996-09-26 |
| PT90228B (pt) | 1995-05-31 |
| PT90228A (pt) | 1989-11-10 |
| TR27507A (tr) | 1995-06-07 |
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