EP0340704A2 - Compositions détergentes aqueuses acides - Google Patents

Compositions détergentes aqueuses acides Download PDF

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Publication number
EP0340704A2
EP0340704A2 EP89107879A EP89107879A EP0340704A2 EP 0340704 A2 EP0340704 A2 EP 0340704A2 EP 89107879 A EP89107879 A EP 89107879A EP 89107879 A EP89107879 A EP 89107879A EP 0340704 A2 EP0340704 A2 EP 0340704A2
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EP
European Patent Office
Prior art keywords
bis
weight
fatty
atoms
reacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP89107879A
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German (de)
English (en)
Other versions
EP0340704B1 (fr
EP0340704A3 (en
Inventor
Richard Dr. Baur
Dieter Stoeckigt
Hans-Werner Neumann
Hans-Helmut Dr. Goertz
Norbert Dr. Wagner
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BASF SE
Original Assignee
BASF SE
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Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to AT89107879T priority Critical patent/ATE98293T1/de
Publication of EP0340704A2 publication Critical patent/EP0340704A2/fr
Publication of EP0340704A3 publication Critical patent/EP0340704A3/de
Application granted granted Critical
Publication of EP0340704B1 publication Critical patent/EP0340704B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/042—Acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides

Definitions

  • Aqueous acidic cleaner formulations are known. They contain tensides and acids as essential components.
  • the known acidic technical cleaners are used, for example, in dairies to remove deposits of lactic acid. They are also used to clean pipelines in which deposits of calcium and magnesium carbonates have formed.
  • the cleaning agent formulations In order to extend the exposure time of these technical cleaning systems when cleaning hard surfaces and thus to ensure optimal cleaning performance, the cleaning agent formulations must have a minimum viscosity so that the formulation cannot run off too quickly from the surface to be cleaned.
  • the viscosity of the known cleaner formulations is adjusted by using mixtures of different alkylphenol ethoxylates with different degrees of ethoxylation.
  • nonionic surfactants based on alkoxylated fatty alcohols, fatty acids, fatty amines, fatty acid amides or alkanesulfonamides are now used. However, the viscosity of such aqueous acidic cleaning formulations is not yet sufficient.
  • the present invention has for its object to provide aqueous acidic cleaner formulations which have an increased viscosity compared to the known acidic technical cleaners.
  • the cleaner formulations should also be stable in storage.
  • the detergent formulations can optionally contain further, conventional constituents, such as solubilizers, corrosion inhibitors and builders.
  • the aqueous acidic cleaning formulations contain, as an essential component (a), at least one nonionic surfactant based on alkoxylated fatty alcohols, fatty acids, fatty amines, fatty acid amides or alkanesulfonamides. These compounds are addition products of 3 to 40 moles of ethylene oxide with 1 mole of fatty alcohols, fatty acids, fatty amines, fatty acid amides or alkanesulfonamides each containing at least 8 carbon atoms.
  • the adducts of 3 to 20 moles of ethylene oxide with 1 mole of at least one alcohol having 10 to 18 carbon atoms are particularly preferred for use in the preparation of the aqueous acidic cleaner formulations.
  • Suitable alcohols are preferably coconut oil or tallow fatty alcohols, oleyl alcohol or synthetically produced alcohols with 8 to 18 carbon atoms.
  • the synthetic alcohols are produced, for example, by the Oxo process or the Ziegler process.
  • Preferred alcohols are, for example, isodecanol, decanol, isotridekanol and mixtures of C13 / C15 fatty alcohol mixtures and C16 / C16 fatty alcohol mixtures.
  • the ethoxylated fatty alcohols used with particular preference contain 3 to 16 moles of ethylene oxide per mole of alcohol.
  • the amount of nonionic surfactants in the aqueous acidic cleaning formulations is 1 to 20, preferably 5 to 15% by weight.
  • the aqueous acidic cleaning formulations contain, as a further essential component, at least one polyether polyol which can be obtained by reacting 2 to 6-valent alcohols which have 2 to 10 C atoms with alkylene oxides containing 2 to 4 C atoms and reacting these reaction products with 8 up to 30 carbon atoms containing 1,2-alkylene oxides, alkyl or alkenyl glycidyl ethers.
  • polyether polyols of component (b) are prepared in an at least two-stage process.
  • ethylene oxide or first ethylene oxide and then an alkylene oxide with 3 or 4 carbon atoms are added to a polyfunctional alcohol with 2 to 10 carbon atoms and 2 to 6 hydroxyl groups.
  • at least 1 alkylene oxide having 8 to 30 carbon atoms or an alkyl or alkenyl glycidyl ether having 8 to 30 carbon atoms in the alkyl or alkylene radical is added to the reaction product thus obtained. If mixtures of alkylene oxides with 2 to 4 carbon atoms are used in the first reaction stage, either statistical copolymers can be used (ie the reaction is carried out with mixtures of alkylene oxides carried out) or block copolymers.
  • the block copolymers are formed by first reacting the compounds to be alkoxylated, for example, with ethylene oxide and then with propylene oxide or a butylene oxide.
  • the alkylene oxides are added in a known manner to 2- to 6-valent alcohols.
  • These polyfunctional alcohols can be alkane polyols, alkene polyols, alkyne polyols or oxialkylene polyols.
  • alkane polyols are ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, trimethylolpropane, pentaerythritol, glycerol, 2,3,4,5- Hexantetrol, glucose and similarly structured sugars.
  • alkene polyols are 2-butene-1,4-diol, 2-hexene-1,4,6-triol, 1,5-hexadiene-3,4-diol, 3-heptene-1,2,6,7- tetrol.
  • alkyne polyols examples include 2-butyne-1,4-diol, 2-hexyne-1,4,6-triol and 4-octyne-1,2,7,8-tetrol.
  • oxyalkylene glycols are said to include diethylene glycol, triethylene glycol, tetraethylene glycol, dipropylene glycol and the like. Connections are understood.
  • trimethylolpropane, pentaerythritol, ethylene glycol and diethylene glycol are preferably suitable for the preparation of the polyether polyols according to (b).
  • At least one sufficient amount of an alkylene oxide with 2 to 4 carbon atoms is added to 1 mol of the polyhydric alcohol to produce products which contain up to 90% by weight of oxyalkylene units of alkylene oxides containing 2 to 4 carbon atoms.
  • the alkylene oxide addition product produced in the first stage of the reaction can also consist entirely of oxyethylene units.
  • those reaction products of the polyhydric alcohols with ethylene oxide and propylene oxide which contain ethylene oxide and propylene oxide in a weight ratio of 70:30 to 95: 5 added to a polyhydric alcohol are of interest. This can be either statistical polymers or block copolymers.
  • the polyhydric alcohols prepared in the first process stage and reacted with C2- to C4-alkylene oxides are reacted with 1,2-alkylene oxides containing 8 to 30 C atoms.
  • 1,2-alkylene oxides 1,2-alkyl or 1,2-alkenyl glycidyl ether can also be used.
  • the preparation of such glycidyl ethers is known, for example, from US Pat. No. 4,086,279.
  • Suitable long-chain alkylene oxides are, for example, 1,2-epoxyoctane, 1,2-epoxydodecane, 1,2-epoxyhexadecane, 1,2-epoxyoctacosane as well as mixtures of the epoxides mentioned and the commercially available mixtures of epoxides which have 10 to 20 carbon atoms.
  • alkyl glycidyl ethers examples include dodecyl, tetradecyl, hexadecyl, octadecyl, eicosyl, 2-methyldodecyl and 2-methyl tetradecyl, 2-methylpentadecyl, 2-hexyldecyl or 2-octyldodecylglycidyl ether.
  • Alkenyl glycidyl ether is preferably oleyl glycidyl ether.
  • the alkoxylations in the first and second reaction stages for the preparation of the polyether polyols are preferably carried out in the presence of bases such as sodium hydroxide solution or potassium hydroxide solution, at higher temperatures, e.g. up to temperatures of 160 ° C.
  • the reaction products obtained in the second stage contain the long-chain 1,2-alkylene oxide or the long-chain glycidyl ether in an amount of 0.5 to 75, preferably 1 to 20% by weight in the attached form.
  • Amounts of 1,2-alkylene oxides having 8 to 30 carbon atoms or the corresponding glycidyl ethers in the polyether polyol are particularly preferred such that the average molar ratio of longer-chain epoxide or glycidyl ether to each individual hydroxyl group of the polyhydric alcohol is preferably between 0.5 and 5 0.5 to 1.5.
  • the molecular weight of the polyether polyols of component (b) of the detergent formulations is 1000 to 75,000 and is preferably in the range from 5000 to 25,000.
  • the polyether polyols described are used in amounts of 0.1 to 15, preferably 0.15 to 10,% by weight in aqueous acidic cleaner formulations. In such formulations, together with the nonionic surfactants specified under (a), they produce a synergistic effect with regard to the increase in viscosity.
  • the viscosities of the aqueous acidic cleaning formulations are 100 to 19000 mPa.s.
  • inorganic or organic acids are suitable, e.g. Hydrochloric acid, sulfuric acid, phosphoric acid, formic acid, oxalic acid and citric acid or dicarboxylic acid mixtures (e.g. from succinic acid, glutaric acid and adipic acid). Acidic phosphoric acid esters as well as amidosulfonic acid and propanesulfonic acid are also suitable.
  • the cleaning formulations contain 1 to 40, preferably 5 to 20% by weight of at least one acid.
  • the acidic cleaning formulations contain water to make up to 100% by weight.
  • the cleaner formulations may also contain other constituents, such as solubilizers, corrosion inhibitors or builders.
  • Solubilizers are, for example, compounds such as isopropanol, glycol ether, cumene sulfonic acid or their alkali salts.
  • the solubilizers are used in an amount of up to 10% by weight, based on the overall formulation.
  • the cleaner formulations can also contain corrosion inhibitors, which may be used in amounts of up to 1% by weight. Suitable corrosion inhibitors are, for example, for HCl / H2SO4, 1,4-butynediol with application amounts of 0.1 to 0.2% for 10% effectively present acid or for H3PO4 methylphenylthiourea with 0.5%, based on 20% effectively present acid.
  • the cleaner formulations may also contain builders if necessary. These are, for example, compounds such as acidic salts of phosphoric acid, sulfuric acid etc. (sodium hydrophosphate, sodium bisulfate).
  • the amount of builders in the detergent formulation is up to 20% by weight.
  • aqueous acidic cleaner formulations described above are used to clean hard surfaces.
  • the removal of calcium and magnesium carbonate deposits from pipelines or heat exchangers which are operated with hard water may be mentioned as an example.
  • the acidic cleaner formulations are also used in dairies, for example to remove lactic acid deposits from objects made of metal, porcelain or ceramics.
  • the parts given in the following examples are parts by weight, the data in% relate to the weight of the substances.
  • the viscosities were measured in a Couette rotary viscometer at 20 ° C and a shear of 150 seconds ⁇ 1.
  • the molecular weights of the substances are average molecular weights after the number average.
  • polyether polyols were used as thickeners (component (b)):
  • Polyether polyol with a molecular weight of approx. 17,000 which can be obtained by reacting 1 mol of trimethylolpropane with a mixture of 102 mol of ethylene oxide and 19 mol of propylene oxide and then further reacting the alkoxylation product with 3 mol of a 1,2-alkylene oxide with 16 carbon atoms.
  • the proportion of long-chain alkylene oxide was 4.06% by weight.
  • the proportion of longer-chain bound alkylene oxide was 4.18% by weight.
  • the built-in C18 alkylene oxide content was 4.55% by weight.
  • surfactant I Addition product of 7 moles of ethylene oxide with 1 mole of isodecanol.
  • Surfactant II Addition product of 8 moles of ethylene oxide with 1 mole of isotridecanol.
  • Surfactant III Addition product of 7 moles of ethylene oxide with 1 mole of a C13 / C15 fatty alcohol mixture.
  • Surfactant IV Addition product of 3 moles of ethylene oxide with 1 mole of a C13 / C15 fatty alcohol mixture.
  • surfactant V Addition product of 5 moles of ethylene oxide with 1 mole of a C13 / C15 fatty alcohol mixture.
  • Surfactant VI Addition product of 11 moles of ethylene oxide with 1 mole of a C13 / C15 fatty alcohol mixture.
  • Surfactant VII Addition product of 11 moles of ethylene oxide with 1 mole of a C16 / C18 fatty alcohol mixture.
  • Surfactant VIII Addition product of 5 moles of ethylene oxide with 1 mole of isotridecanol.
  • Surfactant IX Addition product of 10 moles of ethylene oxide with 1 mole of C9-alkylphenol.
  • Surfactant X Addition product of 8 moles of ethylene oxide with 1 mole of a C13- / C15 fatty alcohol.
  • aqueous acidic cleaner formulations were prepared by mixing the surfactant, thickener, acid and water: 10% surfactant X% thickener 20% acid 70-X% water.
  • a thickener-free formulation of the following composition was examined as a comparison: 15% surfactant 20% acid and 65% water.
  • composition of the aqueous acidic cleaner formulations produced in each case and the viscosity of these formulations is given in Table 1.
  • aqueous acidic cleaner formulations are obtained according to the invention which have greatly increased viscosities compared to the corresponding thickener-free cleaner formulations.
  • Aqueous acidic cleaner formulations were prepared in accordance with the standard formulation given in Example 1. The table also provides information about the viscosity of the detergent formulations.
  • Table 2 No. Surfactant (a) Concentration of surfactant [%] Thickener (b) Concentration of thickener [%] Acid 20% (c) Viscosity of the detergent formulation [mPa.s] 1 (compare) IX 10th - - H3PO4 18th 2 (compare) IX 10th A 1 " 40 3 (compare) III 10th - - " 90 4th III 10th A 1 " 2598 5 (compare) X 10th - - " 15 6 X 10th A 1 " 1082 7 VII 10th - - " 12 8th VII 10th A 1 " 865
  • compositions given in Table 2 under Nos. 4, 6 and 8 are examples according to the invention, the other compositions are used for comparison.
  • Table 2 the selection of the surfactant plays a decisive role for the desired high viscosity of a detergent formulation.
  • An ethoxylated alkylphenol as a surfactant does not give the desired increase in viscosity, while the surfactants III, X and VII on the other hand lead to a surprisingly increased viscosity of the detergent formulation.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP89107879A 1988-05-05 1989-04-29 Compositions détergentes aqueuses acides Expired - Lifetime EP0340704B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT89107879T ATE98293T1 (de) 1988-05-05 1989-04-29 Waessrige saure reinigerformulierungen.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3815291 1988-05-05
DE3815291A DE3815291A1 (de) 1988-05-05 1988-05-05 Waessrige saure reinigerformulierungen

Publications (3)

Publication Number Publication Date
EP0340704A2 true EP0340704A2 (fr) 1989-11-08
EP0340704A3 EP0340704A3 (en) 1990-05-02
EP0340704B1 EP0340704B1 (fr) 1993-12-08

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EP89107879A Expired - Lifetime EP0340704B1 (fr) 1988-05-05 1989-04-29 Compositions détergentes aqueuses acides

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US (1) US4965009A (fr)
EP (1) EP0340704B1 (fr)
AT (1) ATE98293T1 (fr)
DE (2) DE3815291A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0523681A3 (en) * 1991-07-17 1993-05-05 Johannes Dr. Behrensdorf Automatic dishwashing detergent composition and method for producing the same
EP0598692A1 (fr) * 1992-11-16 1994-05-25 The Procter & Gamble Company Compositions de nettoyage pseudoplastiques et thixotropiques
EP0616028A1 (fr) * 1993-03-19 1994-09-21 The Procter & Gamble Company Compositions de nettoyage comprenant des agents tensioactifs non-ioniques à chaînes courtes
TR26294A (tr) * 1991-11-20 1995-03-15 Alsthom Gec ORTA GERILIMLI OTOMATIK KESICI SALTER VE BIR HüCRE ILE ORTA GERILIMLI AYGITLARDA KULLANIMI.
WO1998003243A1 (fr) * 1996-07-19 1998-01-29 Henkel Kommanditgesellschaft Auf Aktien Utilisation comme agents antimousse de composes d'addition oxyde d'ethylene/oxyde de propylene de glycerine ou de polyglycerine mis a reagir avec des alpha-epoxydes d'olefine
EP0875554A1 (fr) * 1997-04-30 1998-11-04 The Procter & Gamble Company Compositions acides pour enlever le tartre
EP0894849A1 (fr) * 1997-07-29 1999-02-03 Basf Corporation Composition détergente à base de l'eau sans solvant contenant deux dérivés tensioactifs nonioniques

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DE4028138A1 (de) * 1990-09-05 1992-03-12 Huels Chemische Werke Ag Viskose saeurehaltige reinigungsmittel
WO1993014181A1 (fr) * 1992-01-06 1993-07-22 Olin Corporation Composition nettoyante, aqueuse et biodegradable pour filtres contenant un agent tensioactif ethoxyle/propoxyle, de l'acide carboxylique et un solvant
US5279707A (en) * 1992-10-23 1994-01-18 Time Savers Die discoloration remover solution and method
US5851979A (en) * 1992-11-16 1998-12-22 The Procter & Gamble Company Pseudoplastic and thixotropic cleaning compositions with specifically defined viscosity profile
US5981455A (en) * 1993-03-19 1999-11-09 The Procter & Gamble Company Cleaning compositions with short chain nonionic surfactants
US5384063A (en) * 1993-03-19 1995-01-24 The Procter & Gamble Company Acidic liquid detergent compositions for bathrooms
JP2947695B2 (ja) * 1993-07-30 1999-09-13 日本ペイント株式会社 アルミニウム系金属の酸性洗浄水溶液及びその洗浄方法
US5736174A (en) * 1994-03-14 1998-04-07 Arco Chemical Technology, L.P. Alkoxylated alcohol fat substitutes
US5801133A (en) * 1995-05-08 1998-09-01 Buckman Laboratories International Inc. Effective alternative filter cleaner for biguanide treated recreational water systems
DE19525604C2 (de) * 1995-07-16 1998-09-03 Yankee Polish Lueth Gmbh & Co Flüssiger Reiniger und dessen Verwendung
DE29511365U1 (de) * 1995-07-16 1995-11-23 Yankee Polish Lüth GmbH + Co, 21465 Reinbek Flüssiger Reiniger
DE19545808C2 (de) * 1995-12-08 1999-03-11 Harald Baumgaertner Verfahren zur Vorbehandlung von einer mit einer Silikonbeschichtung zu versehenden Glasscheibe
US5776876A (en) * 1996-07-18 1998-07-07 Bio-Lab, Inc. Aqueous acidic filter cleaning composition for removing organic biguanide deposits
US5880078A (en) * 1997-09-04 1999-03-09 The United States Of America As Represented By The Secretary Of The Navy Non-solvent, general use exterior aircraft cleaner
DE60124906T2 (de) 2000-06-05 2007-05-24 S.C. Johnson & Son, Inc., Racine Biozide reinigungsmittel
DE102005034752A1 (de) * 2005-07-21 2007-01-25 Henkel Kgaa Reinigungs- und Pflegemittel mit verbesserter Emulgierfähigkeit
US7741265B2 (en) * 2007-08-14 2010-06-22 S.C. Johnson & Son, Inc. Hard surface cleaner with extended residual cleaning benefit
US8993502B2 (en) 2008-02-21 2015-03-31 S. C. Johnson & Son, Inc. Cleaning composition having high self-adhesion to a vertical hard surface and providing residual benefits
US8980813B2 (en) 2008-02-21 2015-03-17 S. C. Johnson & Son, Inc. Cleaning composition having high self-adhesion on a vertical hard surface and providing residual benefits
US9481854B2 (en) 2008-02-21 2016-11-01 S. C. Johnson & Son, Inc. Cleaning composition that provides residual benefits
US8143206B2 (en) 2008-02-21 2012-03-27 S.C. Johnson & Son, Inc. Cleaning composition having high self-adhesion and providing residual benefits
US9410111B2 (en) 2008-02-21 2016-08-09 S.C. Johnson & Son, Inc. Cleaning composition that provides residual benefits
BRPI0908179A2 (pt) 2008-02-21 2015-11-24 Johnson & Son Inc S C composição de limpeza possuindo alta auto-adesão e provendo benefícios residuais
US9404069B1 (en) 2015-06-12 2016-08-02 Crossford International, Llc Systems and methods for cooling tower fill cleaning with a chemical gel
US10030216B2 (en) 2015-06-12 2018-07-24 Crossford International, Llc Systems and methods for cooling tower fill cleaning with a chemical gel
US11421191B1 (en) 2018-11-15 2022-08-23 Ecolab Usa Inc. Acidic cleaner

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DE2224992A1 (de) * 1972-05-23 1973-12-06 Henkel & Cie Gmbh Klarspuelmittel fuer das maschinelle spuelen von geschirr
FR2407979A1 (fr) * 1977-11-04 1979-06-01 Basf Wyandotte Corp Derives de polyglycerols a proprietes tensio-actives et procede pour leur preparation
US4709099A (en) * 1979-10-22 1987-11-24 Basf Corporation Polyethers modified with alpha olefin oxides
US4665239A (en) * 1979-10-22 1987-05-12 Basf Corporation Polyethers modified with alpha olefin oxides
US4649224A (en) * 1979-10-22 1987-03-10 Basf Corporation Polyethers modified with alpha olefin oxides
US4587030A (en) * 1983-07-05 1986-05-06 Economics Laboratory, Inc. Foamable, acidic cleaning compositions
US4759867A (en) * 1983-07-07 1988-07-26 The Clorox Company Hard surface acid cleaner
US4501680A (en) * 1983-11-09 1985-02-26 Colgate-Palmolive Company Acidic liquid detergent composition for cleaning ceramic tiles without eroding grout
GB8511305D0 (en) * 1985-05-03 1985-06-12 Procter & Gamble Liquid detergent compositions
DE3607193A1 (de) * 1986-03-05 1987-10-01 Henkel Kgaa Fluessige tensidmischungen
JP2710052B2 (ja) * 1988-06-23 1998-02-10 東和化成工業株式会社 コードファクター関連化合物及びその製造法並びに該化合物を含有する免疫増強剤

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0523681A3 (en) * 1991-07-17 1993-05-05 Johannes Dr. Behrensdorf Automatic dishwashing detergent composition and method for producing the same
TR26294A (tr) * 1991-11-20 1995-03-15 Alsthom Gec ORTA GERILIMLI OTOMATIK KESICI SALTER VE BIR HüCRE ILE ORTA GERILIMLI AYGITLARDA KULLANIMI.
EP0598692A1 (fr) * 1992-11-16 1994-05-25 The Procter & Gamble Company Compositions de nettoyage pseudoplastiques et thixotropiques
EP0616028A1 (fr) * 1993-03-19 1994-09-21 The Procter & Gamble Company Compositions de nettoyage comprenant des agents tensioactifs non-ioniques à chaînes courtes
WO1998003243A1 (fr) * 1996-07-19 1998-01-29 Henkel Kommanditgesellschaft Auf Aktien Utilisation comme agents antimousse de composes d'addition oxyde d'ethylene/oxyde de propylene de glycerine ou de polyglycerine mis a reagir avec des alpha-epoxydes d'olefine
EP0875554A1 (fr) * 1997-04-30 1998-11-04 The Procter & Gamble Company Compositions acides pour enlever le tartre
EP0894849A1 (fr) * 1997-07-29 1999-02-03 Basf Corporation Composition détergente à base de l'eau sans solvant contenant deux dérivés tensioactifs nonioniques

Also Published As

Publication number Publication date
EP0340704B1 (fr) 1993-12-08
EP0340704A3 (en) 1990-05-02
DE3815291A1 (de) 1989-11-23
US4965009A (en) 1990-10-23
ATE98293T1 (de) 1993-12-15
DE58906336D1 (de) 1994-01-20

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