EP0380630B1 - Anwendung von einer zweiphasigen eisen-mangan-aluminium-kohlenstofflegierung mit hoher dämpfungsfähigkeit - Google Patents
Anwendung von einer zweiphasigen eisen-mangan-aluminium-kohlenstofflegierung mit hoher dämpfungsfähigkeit Download PDFInfo
- Publication number
- EP0380630B1 EP0380630B1 EP89908610A EP89908610A EP0380630B1 EP 0380630 B1 EP0380630 B1 EP 0380630B1 EP 89908610 A EP89908610 A EP 89908610A EP 89908610 A EP89908610 A EP 89908610A EP 0380630 B1 EP0380630 B1 EP 0380630B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- cast iron
- phase
- damping capacity
- alloys
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 32
- 239000000956 alloy Substances 0.000 title claims abstract description 32
- 238000013016 damping Methods 0.000 title claims abstract description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 12
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 11
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910001141 Ductile iron Inorganic materials 0.000 claims abstract description 6
- 239000011651 chromium Substances 0.000 claims abstract description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 229910001566 austenite Inorganic materials 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 239000010955 niobium Substances 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 235000000396 iron Nutrition 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 229910002804 graphite Inorganic materials 0.000 abstract description 2
- 239000010439 graphite Substances 0.000 abstract description 2
- 229910001018 Cast iron Inorganic materials 0.000 abstract 2
- 229910000851 Alloy steel Inorganic materials 0.000 abstract 1
- 229910000975 Carbon steel Inorganic materials 0.000 abstract 1
- 229910000640 Fe alloy Inorganic materials 0.000 abstract 1
- 229910001060 Gray iron Inorganic materials 0.000 abstract 1
- 229910001296 Malleable iron Inorganic materials 0.000 abstract 1
- 230000001276 controlling effect Effects 0.000 abstract 1
- 230000002596 correlated effect Effects 0.000 abstract 1
- 239000011572 manganese Substances 0.000 description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- 229910052748 manganese Inorganic materials 0.000 description 5
- 229910001339 C alloy Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
Definitions
- This invention relates to a high damping capacity, two-phase Fe-Mn-Al-C alloy.
- alpha-gamma two-phase alloys have been developed by adding molybdenum and cobalt to the Fe-Ni-Cr alloy system for the purpose of making alloys having both better stress corrosion and hydrogen embrittlement resistance.
- the iron-based materials that have been used for high damping capacity are the cast irons.
- the graphite in gray cast irons is the most important factor for absorbing the high frequency vibration wave. But cast irons generally are not workable, making them of limited value in high damping applications.
- a ferrite-austenite two-phase alloy for high damping capacity applications, said alloy having a composition comprising of 10 to 45 wt% manganese, 4 to 15 wt% aluminum, up to 12 wt% chromium, 0.01 to 0.7 wt% carbon and optionally containing 0 to 4.0 wt% molybdenum, 0 to 4.0 wt% copper, 0 to 2.0 wt% nickel, 0 to 3.5 wt% niobium, up to 500 ppm boron, up to 0.2 wt% nitrogen, 0 to 3.5 wt% titanium, 0 to 2.0 wt% cobalt, 0 to 3.5 wt% vanadium, 0 to 3.5 wt% tungsten, 0 to 2.0 wt% zirconium, up to 2.5 wt% silicon, the balance iron and impurities, the composition being such that the ferrite phase of said alloy comprises 25% to 75%
- Fe-Mn-Al-C alloys manganese and carbon are gamma-phase formers and aluminum is an alpha-phase former.
- Fe-Mn-Al-C alloys can be designed to be fully gamma phase, such as Fe-29Mn-7A1-1C. Reduction of the manganese or carbon or both of them and the increase of aluminum can promote the appearance of alpha phase, and make the alloy an alpha+gamma two-phase steel.
- the volume fraction of alpha phase can be controlled by changing the amount of manganese or aluminum or carbon or other ferrite-forming elements.
- This example illustrates the effect of the element compositions on the change of a volume fraction in the Fe-Mn-Al-C based alloys.
- Manganese and carbon are austenite phase stabilizers and aluminum is a ferrite phase former.
- the effect of the carbon content on the ferrite fraction of the Fe-Mn-Al-C based alloys is shown in Table I, in which the chemical composition of aluminum and manganese are essentially constant and the carbon content decreases from 0.5 wt% to 0.11 wt%. With the decreasing of carbon content, the ferrite phase volume fractions of the alloys increases from 0% to 36%. With the change of manganese, carbon and aluminum contents, the volume fractions of ferrite phase and balanced ⁇ phase is controlled to be from 25% to 75%.
- This example illustrates the good damping capacity of the said ⁇ + ⁇ two-phase Fe-Mn-Al-C based alloys which have been measured and determined with comparison to ductile cast iron.
- the test sample of the invention contained 19.7Mn-5.84Al-5.74Cr-0.19C.
- the ferrite volume fraction is about 65% balanced with ⁇ phase.
- the damping capacity curves of the damping capacity tests of the Fe-Mn-Al-C based alloy and ductile cast iron are shown in Fig. 1 and Fig. 2. It is seen that the damping capacities of the two alloys are almost equivalent.
- This example illustrates the good workability of ⁇ + ⁇ two-phase Fe-Mn-Al-C based alloys.
- the alloys listed in Table II were cast into ingot; homogenized at 1200°C; cut and hot forged at 1200°C; further annealed at 1150°C and descaled.
- the alloys were cold rolled into 2.0 mm thick strip and annealed.
- the ferrite volume percentages of these strips were measured and are listed in Table III.
- the mechanical properties of these annealed strips are also listed in Table III. It is seen that the alloys of the invention have good workability and excellent mechanical properties. Table II alloy no.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Laminated Bodies (AREA)
Claims (1)
- Verwendung einer Ferrit-Austenit-Zweiphasenlegierung in Anwendungen, die ein hohes Dämpfungsvermögen verlangen, wobei diese Legierung eine Zusammensetzung aufweist, die 10 bis 45 Gew.% Mangan, 4 bis 15 Gew.% Aluminium, bis zu 12 Gew.% Chrom und 0,01 bis 0,7 Gew.% Kohlenstoff umfaßt und gegebenenfalls 0 bis 4,0 Gew.% Molybdän, 0 bis 4,0 Gew.% Kupfer, 0 bis 2,0 Gew.% Nickel, 0 bis 3,5 Gew.% Niob, bis zu 500 ppm Bor, bis zu 0,2 Gew.% Stickstoff, 0 bis 3,5 Gew.% Titan, 0 bis 2,0 Gew.% Cobalt, 0 bis 3,5 Gew.% Vanadium, 0 bis 3,5 Gew.% Wolfram, 0 bis 2,0 Gew.% Zirkon und bis zu 2,5 Gew.% Silicium enthält, wobei der Rest Eisen und Verunreinigungen ist und die Zusammensetzung derart ist, daß die Ferritphase der Legierung 25 bis 75 Vol.% der Legierung umfaßt, der Rest im wesentlichen Austenit ist und die Legierung ein Dämpfungsvermögen mit etwa dem gleichen Wert wie duktiles Eisen hat.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US218695 | 1988-07-08 | ||
| US07/218,695 US4875933A (en) | 1988-07-08 | 1988-07-08 | Melting method for producing low chromium corrosion resistant and high damping capacity Fe-Mn-Al-C based alloys |
| US341117 | 1989-04-20 | ||
| US07/341,117 US4966636A (en) | 1988-07-08 | 1989-04-20 | Two-phase high damping capacity F3-Mn-Al-C based alloy |
| PCT/US1989/002950 WO1990000629A1 (en) | 1988-07-08 | 1989-07-06 | High damping capacity, two-phase fe-mn-al-c alloy |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0380630A1 EP0380630A1 (de) | 1990-08-08 |
| EP0380630A4 EP0380630A4 (en) | 1990-12-27 |
| EP0380630B1 true EP0380630B1 (de) | 1994-11-30 |
Family
ID=26913151
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89908610A Expired - Lifetime EP0380630B1 (de) | 1988-07-08 | 1989-07-06 | Anwendung von einer zweiphasigen eisen-mangan-aluminium-kohlenstofflegierung mit hoher dämpfungsfähigkeit |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0380630B1 (de) |
| JP (1) | JPH03500305A (de) |
| AT (1) | ATE114736T1 (de) |
| AU (1) | AU610429B2 (de) |
| CA (1) | CA1336364C (de) |
| DE (1) | DE68919672T2 (de) |
| WO (1) | WO1990000629A1 (de) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR960006453B1 (ko) * | 1993-10-22 | 1996-05-16 | 최종술 | Fe-Mn계 진동 감쇠 합금강과 그 제조 방법 |
| CN1043253C (zh) * | 1995-08-18 | 1999-05-05 | 赵学胜 | 铝锰硅氮系奥氏体不锈耐酸钢 |
| DE10259230B4 (de) * | 2002-12-17 | 2005-04-14 | Thyssenkrupp Stahl Ag | Verfahren zum Herstellen eines Stahlprodukts |
| RU2401877C2 (ru) * | 2005-02-02 | 2010-10-20 | Корус Стал Бв | Аустенитная сталь, имеющая высокую прочность и формуемость, способ получения упомянутой стали и ее применение |
| EP2008971A4 (de) | 2006-04-20 | 2010-08-04 | Asahi Glass Co Ltd | Kern-schale-siliciumdioxid und herstellungsverfahren dafür |
| WO2013064202A1 (en) * | 2011-11-03 | 2013-05-10 | Tata Steel Nederland Technology B.V. | Method of manufacturing a duplex steel sheet having enhanced formability |
| WO2013178887A1 (fr) * | 2012-05-31 | 2013-12-05 | Arcelormittal Investigación Desarrollo Sl | Acier laminé a chaud ou a froid a faible densite, son procede de mise en oeuvre et son utilisation |
| FI3265102T3 (fi) | 2015-03-06 | 2025-10-31 | Atea Pharmaceuticals Inc | Beta-d-2'-deoksi-2'-alfa-fluori-2'-beta-c-substituoituja-2-modifioituja-n6-substituoituja puriininukleotideja hcv-hoitoa varten |
| CN104674109B (zh) * | 2015-03-11 | 2017-01-18 | 北京科技大学 | 一种低密度Fe‑Mn‑Al‑C系冷轧汽车用钢板及制备方法 |
| KR101910744B1 (ko) * | 2017-07-26 | 2018-10-22 | 포항공과대학교 산학협력단 | 극저온 특성이 우수한 중엔트로피 합금 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA655825A (en) * | 1963-01-15 | Ciba Limited | Unsaturated aliphatic amino-diols and process for their manufacture | |
| DE1239857B (de) * | 1959-06-23 | 1967-05-03 | United States Steel Corp | Verwendung einer austenitischen Stahllegierung fuer schmiedbare Bauteile |
| AU8261182A (en) * | 1981-04-22 | 1982-10-28 | Unisearch Limited | Oxidation and corrosion-resistant febase-al-mn alloys |
| JPS60248866A (ja) * | 1984-05-24 | 1985-12-09 | Yamato Metal Kogyo Kk | 耐海水性に優れる極低温用ステンレス鋼 |
-
1989
- 1989-07-06 WO PCT/US1989/002950 patent/WO1990000629A1/en not_active Ceased
- 1989-07-06 AT AT89908610T patent/ATE114736T1/de not_active IP Right Cessation
- 1989-07-06 JP JP1508050A patent/JPH03500305A/ja active Pending
- 1989-07-06 EP EP89908610A patent/EP0380630B1/de not_active Expired - Lifetime
- 1989-07-06 AU AU39815/89A patent/AU610429B2/en not_active Ceased
- 1989-07-06 DE DE68919672T patent/DE68919672T2/de not_active Expired - Fee Related
- 1989-07-07 CA CA000605033A patent/CA1336364C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA1336364C (en) | 1995-07-25 |
| JPH03500305A (ja) | 1991-01-24 |
| EP0380630A1 (de) | 1990-08-08 |
| WO1990000629A1 (en) | 1990-01-25 |
| AU610429B2 (en) | 1991-05-16 |
| DE68919672T2 (de) | 1995-04-06 |
| EP0380630A4 (en) | 1990-12-27 |
| ATE114736T1 (de) | 1994-12-15 |
| DE68919672D1 (de) | 1995-01-12 |
| AU3981589A (en) | 1990-02-05 |
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