EP0441879B1 - Verfahren zur beschichtung auf einem glasbehälter - Google Patents
Verfahren zur beschichtung auf einem glasbehälter Download PDFInfo
- Publication number
- EP0441879B1 EP0441879B1 EP89912908A EP89912908A EP0441879B1 EP 0441879 B1 EP0441879 B1 EP 0441879B1 EP 89912908 A EP89912908 A EP 89912908A EP 89912908 A EP89912908 A EP 89912908A EP 0441879 B1 EP0441879 B1 EP 0441879B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- container
- glass
- coating
- coating layer
- acrylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000576 coating method Methods 0.000 title claims description 76
- 239000011521 glass Substances 0.000 title claims description 69
- 239000000463 material Substances 0.000 claims abstract description 43
- 239000011248 coating agent Substances 0.000 claims description 73
- 238000000034 method Methods 0.000 claims description 32
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 23
- 239000011247 coating layer Substances 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 238000000137 annealing Methods 0.000 claims description 9
- 229940088990 ammonium stearate Drugs 0.000 claims description 5
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical compound [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 239000002981 blocking agent Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 230000000903 blocking effect Effects 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- 239000002131 composite material Substances 0.000 abstract 1
- 239000003086 colorant Substances 0.000 description 7
- 238000004040 coloring Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 7
- 229910001887 tin oxide Inorganic materials 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 238000011049 filling Methods 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 4
- 238000009500 colour coating Methods 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 4
- 230000001050 lubricating effect Effects 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- 235000013405 beer Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000009928 pasteurization Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000006066 glass batch Substances 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 235000014171 carbonated beverage Nutrition 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000005308 flint glass Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000156 glass melt Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
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- G—PHYSICS
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- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/08—Fastening or securing by means not forming part of the material of the label itself
- G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
- B65C3/00—Labelling other than flat surfaces
- B65C3/06—Affixing labels to short rigid containers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
- B65C3/00—Labelling other than flat surfaces
- B65C3/06—Affixing labels to short rigid containers
- B65C3/08—Affixing labels to short rigid containers to container bodies
- B65C3/14—Affixing labels to short rigid containers to container bodies the container being positioned for labelling with its centre-line vertical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
- B65C3/00—Labelling other than flat surfaces
- B65C3/06—Affixing labels to short rigid containers
- B65C3/08—Affixing labels to short rigid containers to container bodies
- B65C3/14—Affixing labels to short rigid containers to container bodies the container being positioned for labelling with its centre-line vertical
- B65C3/16—Affixing labels to short rigid containers to container bodies the container being positioned for labelling with its centre-line vertical by rolling the labels onto cylindrical containers, e.g. bottles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
- B65C9/00—Details of labelling machines or apparatus
- B65C9/08—Label feeding
- B65C9/18—Label feeding from strips, e.g. from rolls
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
- B65C9/00—Details of labelling machines or apparatus
- B65C9/08—Label feeding
- B65C9/18—Label feeding from strips, e.g. from rolls
- B65C9/1865—Label feeding from strips, e.g. from rolls the labels adhering on a backing strip
- B65C9/1869—Label feeding from strips, e.g. from rolls the labels adhering on a backing strip and being transferred directly from the backing strip onto the article
- B65C9/1873—Label feeding from strips, e.g. from rolls the labels adhering on a backing strip and being transferred directly from the backing strip onto the article the transfer involving heating means, e.g. for decals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
- B65C9/00—Details of labelling machines or apparatus
- B65C9/20—Gluing the labels or articles
- B65C9/24—Gluing the labels or articles by heat
- B65C9/25—Gluing the labels or articles by heat by thermo-activating the glue
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
- B65C9/00—Details of labelling machines or apparatus
- B65C9/40—Controls; Safety devices
- B65C9/42—Label feed control
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D23/00—Details of bottles or jars not otherwise provided for
- B65D23/08—Coverings or external coatings
- B65D23/0807—Coatings
- B65D23/0814—Coatings characterised by the composition of the material
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
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- G09F3/02—Forms or constructions
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- G—PHYSICS
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- G09F3/02—Forms or constructions
- G09F3/0286—Forms or constructions provided with adaptations for labelling machines
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- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
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- G09F3/02—Forms or constructions
- G09F2003/0257—Multilayer
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- G—PHYSICS
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- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/0257—Multilayer
- G09F2003/0258—Multilayer without carrier
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/0257—Multilayer
- G09F2003/0261—Multilayer encapsulated in polymer
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/027—Forms or constructions used to hang up an item, e.g. a perfusion bottle
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/0272—Labels for containers
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/0272—Labels for containers
- G09F2003/0273—Labels for bottles, flasks
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- G—PHYSICS
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- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/0272—Labels for containers
- G09F2003/0275—Shock absorbing labels
Definitions
- the invention relates to a method of coating glass containers, and more particularly to a technique for applying colour coatings that singularly or together may be coloured, block ultra-violet light, and offer a range of surface textures.
- the glass container industry limits itself to three primary colours for containers; clear glass (commonly called flint glass), amber and green.
- the green and amber are melted in several hues for both product differentiation and protection of the contents from the adverse effects of transmitted visual light as well as the ultra-violet component of natural and artificial light.
- Significant cost resulting from lost production when a glass melting unit changes from one colour to another is experienced throughout the industry as well as the cost to carry inventory of containers made of a specific color during a run of a few weeks that will satisfy many months of need.
- extra fuel is required to melt colored glass batch.
- the melting furnace life is reduced by the corrosive action of colored glass batches.
- Patent Abstracts of Japan, Vol. 12, No. 382 discloses the painting of a bottle surface for shielding ultra-violet rays following a method according to the preambles of claims 1 and 13.
- World Patent Index Latest, Week 8644, Derwent Publications Ltd., London, GB, AN 86-28759 discloses a UV shielding covering composition for glass.
- Yet another aim of this invention is to foster continued further reduction in container weight.
- the present invention provides a method of coating a glass container, comprising the steps of: providing a container of glass, said glass having an inside surface directed toward an interior of said container and an outer surface directed toward an exterior of said container; annealing said glass container; coating said container with at least a final acrylic coating layer applied in liquid form; and curing said acrylic coating; said method being characterized by the steps of applying a first coating material to said container at a first location in a container fabrication line subsequent to said annealing step; conveying said container to a second location with said first coating material providing surface lubricity; and applying an acrylic coating layer which is compatible with said first coating material over said glass on said outer surface of said container while at least some of said first coating material remains on said outer surface, said acrylic coating layer having a cured thickness of no greater than 0.0152 mm (0.0006 inch).
- the present invention further provides a method of coating a glass container, comprising the steps of: providing a container of glass, said glass having an inside surface directed toward an interior of said container and an outer surface directed toward an exterior of said container; annealing said glass container; coating said glass container with at least a final acrylic coating layer applied in liquid form; and curing said acrylic coating; said method being characterized by the steps of applying a first coating material to said container at a first location in a container fabrication line subsequent to said annealing step; conveying said container to a second location with said first coating material providing surface lubricity; exposing said first coating material to an oxidizing flame whereby first coating material is burnt off; and applying an acrylic coating layer over said glass on said outer surface of said container subsequent to said oxidizing flame step, said acrylic coating layer having a cured thickness of no greater than 0.0152 mm (0.0006 inch).
- the aims and advantages of the invention are achieved by coating the glass containers with a material, preferably heat-curable or UV-curable acrylic, which provides impact resistance and durability, such that it is no longer necessary to provide the tin oxide film prior to container lehring.
- the coating material is selected to have a colour corresponding to the desired container colour, and/or can be selected to have a composition which will block certain wavelengths of light which are considered harmful to the contents of the bottle.
- the coating material also provides sufficient impact and abrasion resistance to permit the tin oxide film to be dispensed with, with merely a token amount of the lubricating film being applied after annealing.
- This lubricating film is one which is compatible with the coating, such as ammonium stearate.
- the lubicating flim is sufficient to enable damage-free conveying from the lehr, through the inspection stations and into the colour coat machine staging area.
- the present invention resides in applying to a clear glass container a coating which may have a number of properties. There are a great number of properties which may be considered significant in any given case, but the properties discussed herein are color, light blocking for protection of the container contents from irradiation, abrasion resistance and impact resistance.
- the coating material is preferably a urethane coating, with appropriate additives as will be described below.
- the first significant property of the coating material is the color.
- it is sometimes desirable to color the bottle e.g., to amber or green, and this has heretofore been achieved by specific formulation of the glass batch introduced into the melters.
- an acrylic coating e.g., urethane
- heat-curable or UV-curable could be made to provide the desired coloring of the container.
- the coloring technique would provide any color desired to suit the particular product, from light tints to fully opaque colors.
- the particular additives to be used for this purpose would depend on the colors desired, with a number of suitable organic dyes being well-known to those of skill in the art.
- the cured color coat is formulated to withstand the wash and pasteurization processes associated with non-returnable containers, and with chemical modifications to the color coat, returnable containers will be able to survive the alkali wash required prior to refilling. Nor will the color coat be adversely affected by water, alcohol or organic materials used in the filling operations.
- the color coatings on adjacent containers will not abrade each other during the filling and packaging operations associated with transport, store display and consumer purchasing, and the color coat will also be chemically and physically stable.
- a preferred technique for providing irradiation protection for the container contents is to determine, e.g., via spectrographic analysis, which wavelengths of light are absorbed by the container contents, and to then include additives in the topcoat which will block light in these regions.
- the additives to be used would be known to those of skill in the art after determining the wavelengths of light to be blocked.
- the damaging ultra-violet component may be largely blocked by a clear additive, either to a clear or colored coating.
- Variations in color coating texture and appearance may also be desirable. It has been demonstrated that with changes in coating composition the surface may be altered from gloss finish, to matte, to frosted. This is done without sacrificing physical properties.
- a further aim of the invention to eliminate the cost of tin oxide coating. Because the acrylic coating of this invention provides impact resistance and durability, it is no longer necessary to provide the tin oxide film prior to container lehring.
- a lubricating film is sufficient to enable damage-free conveying from the lehr, through the inspection stations and into the color coat machine staging area. It should be a lubricating film compatible with the coating, such as ammonium stearate.
- ammonium stearate is comaptible with the coating material and allows the bonding of the coating to the glass so that burning off of residual lubricant may not be necessary.
- a coupling agent to promote adhesion of the color coat material to the container surface to meet certain container processing and use requirements, specifically, but not limited to the typical beer industry pasteurization process. While the coupling agent can be mixed with the color coat before application, it may be desirable to apply the coupling agent to the container surface before the color coat is applied for economic reasons as well as technical reasons.
- the containers are conveyed into a multi-station spray system which has been designed to address the needs of uniform coverage of the container and recovery of the overspray.
- the gripper devices are attached to a conveyor network whose design allows for spacing of the glass containers to optimize the coating and curing of the coating materials.
- the grippers should also be designed for rotating the container at the spraying and curing positions to insure uniform coating and processing.
- the application of the coating solution could be accomplished by belt or roller coating as described in WO-A-90/05088.
- Alternative methods of applying the topcoat include, but are not limited to, the use of a roller shaped to conform to the contour of the container, a belt flexible enough to conform to the container contour, or flowing the coating over the container while it is slowly rotated. Dipping may also be advantageous. Each option has its own merits and must be weighed against economics, quality and production rates.
- the containers are then conveyed to a circulating hot air cure chamber designed to provide the necessary exposure to hot air to completely cure the topcoat. It has been demonstrated that air moving at 457.2 m (1500 feet) per minute and at a temperature of 287.8°C (550°F) will insure a complete cure in 1.5 minutes.
- the container can be packaged for shipment and subsequent wash, filling and pasteurization, if required, by the various food and beverage packaging operations.
- the single figure herein illustrates one example of a system for applying the coating of this invention.
- the coating with ammonium stearate would be performed before the bottles are received at the upper right of the figure along a conveyor 100.
- the bottles would then be transferred to a loading station 104 one at a time by a star wheel control device 102.
- the bottles are then moved downwardly onto an indexing table 106 by means of a suitable placement device.
- the indexing table 106 will include container holders, e.g., suction holders or the like, and there may be supports at the neck of each container to absorb pressure during the container transfer.
- the indexing table is then rotated counterclockwise from the loading station to a container orienting station generally designated at reference character 108.
- the container may here be rotated to a particular orientation, although this will be unnecessary in many container systems.
- the rotating of the container would preferably be performed by rotation of individual container holder suction cups on the indexing table 106 until the correct position is detected, e.g., by suitable photo-electric means, at which point the holders would be locked in their correct positions.
- the indexing table 106 is further rotated to bring the bottles to the coating station 114 where the coating of this invention is applied.
- the indexing table 106 is then further rotated to bring the coated bottles to an unloading station where each container is off-loaded onto a container conveyor.
- the bottles could be removed. All bottles could be removed from the indexing table 106 to a single conveyor 120, taking care to ensure that the coatings are not disturbed. It may, be necessary, with suitable care taken, to use an air knife. It may, however, be necessary to move the bottles by clamping them at their "finish" and carrying them onto the conveyor 120 in a known manner.
- the bottles are held in groups of three on the indexing table 106.
- the coating on the bottles is cured in a suitable manner, e.g., by heat in the case of heat-curable coating or by U-V energy in the case of UV-curable coating.
- the conveyor 120 carries the bottles to a further container processing stage, e.g., labelling, inspection, packing and/or filling.
- a topcoating material as described herein will impart a desired color to a bottle, will increase abrasion and impact resistance of the glass container, will be waterproof and unaffected by the contents of any food or beverage, will be glossy and will not be abraded by like material, and will cover flaws and irregularities on the surface of glass containers such as to render them nearly invisible.
- the heat-curable color coating material can be cured quickly with hot convective air, easily achieved with commercial equipment. It is necessary to achieve a glass substrate temperature of 148.9°C (300°F) to achieve all of the desired properties of the color coat. Other curing processes are available.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Theoretical Computer Science (AREA)
- Mechanical Engineering (AREA)
- Details Of Rigid Or Semi-Rigid Containers (AREA)
- Labeling Devices (AREA)
- Surface Treatment Of Glass (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Claims (13)
- Verfahren zum Beschichten eines Glasbehälters, das die folgenden Schritte aufweist:Bereitstellen eines Behälters aus Glas, wobei das Glas eine innere Oberfläche, die zu der Innenseite des Behälters gerichtet ist, und eine äußere Oberfläche hat, die zu der Außenseite des Behälters gerichtet ist;Tempern des Glasbehälters;Beschichten des Behälters mit wenigstens einer letzten Acrylüberzugsschicht, die in flüssiger Form aufgebracht wird; undAushärten des Acrylüberzugs;
wobei das Verfahren durch die folgenden Schritte gekennzeichnet ist:Aufbringen eines ersten Überzugsmaterials auf den Behälter an einem ersten Ort in einer Behälterfertigungsstraße anschließend an den Temperschritt;Transportieren des Behälters zu einem zweiten Ort, wobei das erste Überzugsmaterial eine Oberflächenlubrizität bietet; undAufbringen einer Acrylüberzugsschicht, die mit dem ersten Überzugsmaterial kompatibel ist, über dem Glas auf der äußeren Oberfläche des Behälters, während gleichzeitig wenigstens ein Teil des ersten Überzugsmaterials an der äußeren Oberfläche verbleibt, wobei die Acrylüberzugsschicht eine ausgehärtete Dicke von nicht mehr als 0,0152 mm (0,0006 inch) hat. - Verfahren nach Anspruch 1,
wobei das Glas im wesentlichen klar ist. - Verfahren nach Anspruch 1 oder 2,
wobei die Acrylüberzugsschicht klar ist. - Verfahren nach Anspruch 1 oder 2,
wobei die Acrylüberzugsschicht farbig ist. - Verfahren nach einem der Ansprüche 1 bis 4,
wobei die Überzugsschicht wärmehärtbar ist. - Verfahren nach Anspruch 5,
wobei der Schritt des Aufbringens des Acrylüberzugs den Schritt des Aushärtens des Überzugs in nicht mehr als 1,5 Minuten durch Aufbringen von Wärme aufweist. - Verfahren nach einem der Ansprüche 1 bis 4,
wobei die Überzugsschicht UV-härtbar ist. - Verfahren nach einem der vorhergehenden Ansprüche,
wobei das erste Überzugsmaterial Ammoniumstearat ist. - Verfahren nach einem der vorhergehenden Ansprüche,
wobei die Schlagfestigkeit des anfänglich bereitgestellten Glasbehälters nach dem Aufbringen der Acrylüberzugsschicht um wenigstens 30 % erhöht wird. - Verfahren nach einem der vorhergehenden Ansprüche,
wobei die Überzugsschicht ein Lichtblockiermittel enthält, um wenigstens eine vorbestimmte Lichtwellenlänge zusätzlich zu dem durch eine Farbe des Überzugs blockierten Licht zu blockieren. - Verfahren nach Anspruch 10,
wobei die vorbestimmte Wellenlänge Ultraviolett ist. - Verfahren nach Anspruch 10,
wobei die vorbestimmte Wellenlänge außerhalb des UV-Bereichs ist. - Verfahren zum Beschichten eines Glasbehälters, das die folgenden Schritte aufweist:Bereitstellen eines Behälters aus Glas, wobei das Glas eine innere Oberfläche, die zu der Innenseite des Behälters gerichtet ist, und eine äußere Oberfläche hat, die zu der Außenseite des Behälters gerichtet ist;Tempern des Glasbehälters;Beschichten des Glasbehälters mit wenigstens einer letzten Acrylüberzugsschicht, die in flüssiger Form aufgebracht wird; undAushärten des Acrylüberzugs;
wobei das Verfahren durch die folgenden Schritte gekennzeichnet ist:Aufbringen eines ersten Überzugsmaterials auf den Behälter an einem ersten Ort in einer Behälterfertigungsstraße anschließend an den Temperschritt;Transportieren des Behälters zu einem zweiten Ort, wobei das erste Überzugsmaterial eine Oberflächenlubrizität bietet;Beaufschlagen des ersten Überzugsmaterials mit einer oxidierenden Flamme, so daß dadurch erstes Überzugsmaterial abgebrannt wird; undAufbringen einer Acrylüberzugsschicht über dem Glas auf der äußeren Oberfläche des Behälters anschließend an den Schritt der Behandlung mit der oxidierenden Flamme, wobei die Acrylüberzugsschicht eine ausgehärtete Dicke von nicht mehr als 0,0152 mm (0,0006 inch) hat.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26787788A | 1988-11-07 | 1988-11-07 | |
| US267877 | 1988-11-07 | ||
| PCT/US1989/004886 WO1990005667A1 (en) | 1988-11-07 | 1989-11-07 | Glass container color coating process |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0441879A1 EP0441879A1 (de) | 1991-08-21 |
| EP0441879A4 EP0441879A4 (en) | 1992-02-26 |
| EP0441879B1 true EP0441879B1 (de) | 1998-07-15 |
Family
ID=23020505
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP99201674A Expired - Lifetime EP0945842B1 (de) | 1988-11-07 | 1989-11-07 | Anbringen eines Etikettmehrschichtenverbunds an einen Behälter |
| EP96200911A Expired - Lifetime EP0737954B1 (de) | 1988-11-07 | 1989-11-07 | Etikett und Etikettmehrschichtenverbund |
| EP89912908A Expired - Lifetime EP0441879B1 (de) | 1988-11-07 | 1989-11-07 | Verfahren zur beschichtung auf einem glasbehälter |
| EP89912549A Expired - Lifetime EP0441858B1 (de) | 1988-11-07 | 1989-11-07 | Verfahren zum anbringen eines etiketts auf einen behälter |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP99201674A Expired - Lifetime EP0945842B1 (de) | 1988-11-07 | 1989-11-07 | Anbringen eines Etikettmehrschichtenverbunds an einen Behälter |
| EP96200911A Expired - Lifetime EP0737954B1 (de) | 1988-11-07 | 1989-11-07 | Etikett und Etikettmehrschichtenverbund |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89912549A Expired - Lifetime EP0441858B1 (de) | 1988-11-07 | 1989-11-07 | Verfahren zum anbringen eines etiketts auf einen behälter |
Country Status (5)
| Country | Link |
|---|---|
| EP (4) | EP0945842B1 (de) |
| JP (2) | JPH04503260A (de) |
| AT (4) | ATE195193T1 (de) |
| DE (4) | DE68928268T2 (de) |
| WO (4) | WO1990005031A1 (de) |
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| CA2002288C (en) * | 1988-11-07 | 2002-11-05 | Thomas L. Brandt | Glass container color coating process |
| US5085903A (en) * | 1990-06-11 | 1992-02-04 | Ppg Industries, Inc. | Coatings for the protection of products in light-transmitting containers |
| EP0529399A3 (en) * | 1991-08-23 | 1993-03-31 | Eastman Kodak Company | A laminator apparatus for making image proofs |
| DE4130682A1 (de) * | 1991-09-14 | 1993-03-18 | Herberts Gmbh | Verfahren, ueberzugsmittel und vorrichtung zur herstellung von beschichteten glashohlkoerpern |
| GB9200095D0 (en) * | 1992-01-04 | 1992-02-26 | Automated Transfers Limited | Improved decal applying apparatus |
| DE4302123A1 (de) * | 1993-01-27 | 1994-07-28 | Herberts Gmbh | Verfahren zum Bedrucken von Glashohlkörpern |
| DE29602430U1 (de) * | 1996-02-12 | 1997-07-03 | Steinbeis PPL GmbH, 83098 Brannenburg | Transferetikett |
| CA2250142A1 (en) | 1996-03-20 | 1997-09-25 | Heineken Technical Services B.V. | Transfer label comprising a backing layer and a transfer layer, container comprising such a transfer layer and method of removing a transfer layer from a container |
| US6616786B2 (en) | 1996-03-20 | 2003-09-09 | Heineken Technical Services B.V. | Process for applying an ink-only label to a polymeric surface |
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| CA2250140C (en) | 1996-03-20 | 2007-11-20 | Heineken Technical Services B.V. | Transfer label having ink containment layers, container comprising a transfer layer and method of washing such a container |
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| US6306242B1 (en) * | 1997-10-10 | 2001-10-23 | Peter J. Dronzek | Techniques for labeling of plastic, glass or metal containers or surfaces with polymeric labels |
| NL1009473C2 (nl) | 1998-06-24 | 1999-12-27 | Heineken Tech Services | Inrichting voor het aanbrengen van een decoratie op houders. |
| EP1046593A1 (de) | 1999-04-12 | 2000-10-25 | Heineken Technical Services B.V. | Behälterverschluss |
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| HU224455B1 (hu) | 1999-08-27 | 2005-09-28 | Heineken Technical Services B.V. | Átvivőcímke, valamint az átvitt címkével ellátott alakos tárgy |
| DE10014466A1 (de) * | 1999-12-24 | 2001-07-05 | Gerd Stoffel | Verfahren und Vorrichtung zum Herstellen von mit einem Aufdruck versehenen Behälter |
| EP1124213A1 (de) | 2000-02-08 | 2001-08-16 | Heineken Technical Services B.V. | Etikettenmaterial |
| DE10019355A1 (de) * | 2000-04-18 | 2001-10-31 | Schott Glas | Glaskörper mit erhöhter Festigkeit |
| EP1193185A1 (de) | 2000-10-02 | 2002-04-03 | Heineken Technical Services B.V. | Glasbehälter mit verbesserter Beschichtung |
| DE20214560U1 (de) | 2002-09-20 | 2002-11-21 | KHS Maschinen- und Anlagenbau AG, 44143 Dortmund | Einzelblattetikett für die Etikettierung von Behältern |
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| US11497681B2 (en) | 2012-02-28 | 2022-11-15 | Corning Incorporated | Glass articles with low-friction coatings |
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| US10273048B2 (en) | 2012-06-07 | 2019-04-30 | Corning Incorporated | Delamination resistant glass containers with heat-tolerant coatings |
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| US10117806B2 (en) | 2012-11-30 | 2018-11-06 | Corning Incorporated | Strengthened glass containers resistant to delamination and damage |
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| MX2020013796A (es) | 2018-07-02 | 2021-05-27 | Actega North America Tech Inc | Sistemas y metodos para decorar sustratos. |
| CN110379298B (zh) * | 2019-07-19 | 2021-06-01 | 深圳市华星光电半导体显示技术有限公司 | 框胶结构和显示面板的制作方法 |
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- 1989-11-07 DE DE68928268T patent/DE68928268T2/de not_active Expired - Lifetime
- 1989-11-07 AT AT96200911T patent/ATE195193T1/de not_active IP Right Cessation
- 1989-11-07 EP EP99201674A patent/EP0945842B1/de not_active Expired - Lifetime
- 1989-11-07 WO PCT/US1989/004887 patent/WO1990005031A1/en not_active Ceased
- 1989-11-07 JP JP1511817A patent/JPH04503260A/ja active Pending
- 1989-11-07 WO PCT/US1989/004888 patent/WO1990005353A1/en not_active Ceased
- 1989-11-07 EP EP96200911A patent/EP0737954B1/de not_active Expired - Lifetime
- 1989-11-07 EP EP89912908A patent/EP0441879B1/de not_active Expired - Lifetime
- 1989-11-07 AT AT99201674T patent/ATE293825T1/de not_active IP Right Cessation
- 1989-11-07 AT AT89912549T patent/ATE157059T1/de not_active IP Right Cessation
- 1989-11-07 EP EP89912549A patent/EP0441858B1/de not_active Expired - Lifetime
- 1989-11-07 DE DE68929534T patent/DE68929534T2/de not_active Expired - Fee Related
- 1989-11-07 WO PCT/US1989/004885 patent/WO1990005088A1/en not_active Ceased
- 1989-11-07 DE DE68928740T patent/DE68928740T2/de not_active Expired - Lifetime
- 1989-11-07 AT AT89912908T patent/ATE168344T1/de not_active IP Right Cessation
- 1989-11-07 WO PCT/US1989/004886 patent/WO1990005667A1/en not_active Ceased
- 1989-11-07 JP JP2500340A patent/JPH04501694A/ja active Pending
- 1989-11-07 DE DE68929237T patent/DE68929237T2/de not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| DE68928268T2 (de) | 1998-03-19 |
| WO1990005353A1 (en) | 1990-05-17 |
| WO1990005031A1 (en) | 1990-05-17 |
| EP0737954A3 (de) | 1996-10-23 |
| ATE293825T1 (de) | 2005-05-15 |
| ATE157059T1 (de) | 1997-09-15 |
| EP0441858B1 (de) | 1997-08-20 |
| WO1990005667A1 (en) | 1990-05-31 |
| EP0945842A2 (de) | 1999-09-29 |
| EP0441879A1 (de) | 1991-08-21 |
| DE68929534D1 (de) | 2005-05-25 |
| JPH04501694A (ja) | 1992-03-26 |
| ATE195193T1 (de) | 2000-08-15 |
| DE68929237T2 (de) | 2000-12-14 |
| EP0441879A4 (en) | 1992-02-26 |
| ATE168344T1 (de) | 1998-08-15 |
| EP0737954A2 (de) | 1996-10-16 |
| DE68928740T2 (de) | 1999-04-22 |
| DE68929237D1 (de) | 2000-09-07 |
| EP0945842B1 (de) | 2005-04-20 |
| EP0737954B1 (de) | 2000-08-02 |
| DE68929534T2 (de) | 2006-02-23 |
| WO1990005088A1 (en) | 1990-05-17 |
| JPH04503260A (ja) | 1992-06-11 |
| EP0441858A4 (en) | 1992-05-27 |
| DE68928268D1 (de) | 1997-09-25 |
| DE68928740D1 (de) | 1998-08-20 |
| EP0441858A1 (de) | 1991-08-21 |
| EP0945842A3 (de) | 2000-03-22 |
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