EP0475967A1 - Alkylsulfates gras et alkylpolyalkylene-glycolethersulfates gras; leur procede de production et leur utilisation - Google Patents

Alkylsulfates gras et alkylpolyalkylene-glycolethersulfates gras; leur procede de production et leur utilisation

Info

Publication number
EP0475967A1
EP0475967A1 EP90908223A EP90908223A EP0475967A1 EP 0475967 A1 EP0475967 A1 EP 0475967A1 EP 90908223 A EP90908223 A EP 90908223A EP 90908223 A EP90908223 A EP 90908223A EP 0475967 A1 EP0475967 A1 EP 0475967A1
Authority
EP
European Patent Office
Prior art keywords
isostearyl
polyalkylene glycol
sulfates
glycol ethers
sulfation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP90908223A
Other languages
German (de)
English (en)
Inventor
Bernd Fabry
Brigitte Giesen
Alfred Westfechtel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0475967A1 publication Critical patent/EP0475967A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/24—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfuric acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C305/00—Esters of sulfuric acids
    • C07C305/02—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton
    • C07C305/04—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated
    • C07C305/06—Hydrogenosulfates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C305/00—Esters of sulfuric acids
    • C07C305/02—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton
    • C07C305/04—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated
    • C07C305/10—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated being further substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers

Definitions

  • Fatty alkyl sulfates and fatty alkyl polyalkylene glycol ether sulfates which are generally referred to in short as alkyl sulfates or ether sulfates, can be obtained by sulfating fatty alcohols or by sulfating adducts of ethylene oxide and / or propylene oxide with fatty alcohols and then neutralizing the sulfuric acid semiesters formed with suitable bases, e.g. Soda lye, accessible.
  • suitable sulfating agents are e.g. Sulfuric acid, oleum, sulfamic acid, but especially chlorosulfonic acid or gaseous sulfur trioxide into consideration [J.Am.Oil.Che. Soc. 36 (1959) 208-210].
  • the starting materials for the preparation of the compounds according to the invention are known substances which can be obtained by customary methods in organic chemistry.
  • isostearyl alcohol Cosm.Perf. 89.7 (1974) 45-47 and soap-oil-fat waxes 114.7 (1988) 231-233] are appropriately used Isostearic acid, which in turn is obtained from the cis monomer fraction of the dimerization, for example of tall oil fatty acid, after hardening and separation of the network.
  • Example 2 Sulfation of isostearyl alcohol-2E0.
  • isostearyl sulfates or isostearyl ether sulfates according to the invention have better wetting properties than the comparative examples.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
  • Cosmetics (AREA)

Abstract

On obtient des alkylsulfates ou des éthersulfates à bonnes propriétés d'écoulement et de mouillabilité en sulfatant des isostéarylalcools ou des isostéarylpolyalkylène-glycoléthers puis en les neutralisant avec des bases appropriées.
EP90908223A 1989-06-05 1990-05-28 Alkylsulfates gras et alkylpolyalkylene-glycolethersulfates gras; leur procede de production et leur utilisation Withdrawn EP0475967A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3918252 1989-06-05
DE3918252A DE3918252A1 (de) 1989-06-05 1989-06-05 Fettalkylsulfate und fettalkyl-polyalkylenglycolethersulfate, verfahren zu ihrer herstellung und ihre verwendung

Publications (1)

Publication Number Publication Date
EP0475967A1 true EP0475967A1 (fr) 1992-03-25

Family

ID=6382071

Family Applications (2)

Application Number Title Priority Date Filing Date
EP90110111A Withdrawn EP0401642A1 (fr) 1989-06-05 1990-05-28 Sulfates d'alkyle gras et sulfates d'éthers alkyliques gras du polyalkylène glycol, procédé pour leur préparation et leur utilisation
EP90908223A Withdrawn EP0475967A1 (fr) 1989-06-05 1990-05-28 Alkylsulfates gras et alkylpolyalkylene-glycolethersulfates gras; leur procede de production et leur utilisation

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP90110111A Withdrawn EP0401642A1 (fr) 1989-06-05 1990-05-28 Sulfates d'alkyle gras et sulfates d'éthers alkyliques gras du polyalkylène glycol, procédé pour leur préparation et leur utilisation

Country Status (5)

Country Link
EP (2) EP0401642A1 (fr)
JP (1) JPH04505916A (fr)
DE (1) DE3918252A1 (fr)
PT (1) PT94260A (fr)
WO (1) WO1990015049A1 (fr)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4109250A1 (de) * 1991-03-21 1992-09-24 Henkel Kgaa Verfahren zur herstellung von hochkonzentrierten fettalkoholsulfat-pasten
DE4114243A1 (de) * 1991-05-02 1992-11-05 Henkel Kgaa Verfahren zur herstellung von glycerinethersulfaten
DE4218075A1 (de) * 1992-06-01 1993-12-02 Henkel Kgaa Verfahren zur Herstellung geruchsarmer Fettalkoholethersulfat-Salze
EP0609574B1 (fr) * 1993-02-04 1997-06-18 The Procter & Gamble Company Solutions de sulfate d'alkyle hautement concentrées
DE4322968A1 (de) * 1993-07-09 1995-01-12 Henkel Kgaa Verfahren zur Herstellung von Alkylsulfaten
GB9410678D0 (en) * 1994-05-27 1994-07-13 Unilever Plc Surfactant composition and cleaning composition comprising the same
DE19503061A1 (de) * 1995-02-01 1996-08-08 Henkel Kgaa Dimeralkohol-bis- und Trimeralkohol-tris-sulfate und -ethersulfate
DE19540295A1 (de) * 1995-10-28 1997-04-30 Henkel Kgaa Verfahren zur Herstellung kurzkettiger Alkylsulfate
EG21623A (en) * 1996-04-16 2001-12-31 Procter & Gamble Mid-chain branced surfactants
PH11997056158B1 (en) * 1996-04-16 2001-10-15 Procter & Gamble Mid-chain branched primary alkyl sulphates as surfactants
EG21174A (en) * 1996-04-16 2000-12-31 Procter & Gamble Surfactant manufacture
JP3043434B2 (ja) * 1996-04-16 2000-05-22 ザ、プロクター、エンド、ギャンブル、カンパニー 長鎖の枝分れしたアルカノールおよびアルコキシル化アルカノールの硫酸塩の製造方法
EG22088A (en) * 1996-04-16 2002-07-31 Procter & Gamble Alkoxylated sulfates
JP4509223B2 (ja) * 1996-04-16 2010-07-21 ザ、プロクター、エンド、ギャンブル、カンパニー 選択された中間鎖分岐界面活性剤を含有する洗剤組成物
WO1997039089A1 (fr) * 1996-04-16 1997-10-23 The Procter & Gamble Company Compositions liquides nettoyantes contenant des tensioactifs ramifies en milieu de chaine selectionnes
MA24137A1 (fr) * 1996-04-16 1997-12-31 Procter & Gamble Fabrication d'agents de surface ramifies .
US6150322A (en) 1998-08-12 2000-11-21 Shell Oil Company Highly branched primary alcohol compositions and biodegradable detergents made therefrom
US6093856A (en) * 1996-11-26 2000-07-25 The Procter & Gamble Company Polyoxyalkylene surfactants
DE19714043C2 (de) * 1997-04-05 2002-09-26 Cognis Deutschland Gmbh Verwendung von Glycerinsulfaten als Viskositätsregulatoren für konzentrierte wäßrige Alkyl(ether)sulfatpasten
ZA989155B (en) 1997-10-10 1999-04-12 Procter & Gamble Mixed surfactant system
CN1281500A (zh) 1997-10-14 2001-01-24 普罗格特-甘布尔公司 含有中链支链表面活性剂的轻垢液体或凝胶餐具洗涤剂组合物
JP2001519376A (ja) 1997-10-14 2001-10-23 ザ、プロクター、エンド、ギャンブル、カンパニー 中間鎖分岐界面活性剤を含んでなるパーソナルクレンジング組成物
WO1999019435A1 (fr) 1997-10-14 1999-04-22 The Procter & Gamble Company Compositions detergentes granuleuses comprenant des tensioactifs ramifies en milieu de chaine
DE19929511C2 (de) * 1999-06-29 2003-04-10 Cognis Deutschland Gmbh Hochkonzentriert fließfähige Aniontensidmischungen
DE102007032670A1 (de) * 2007-07-13 2009-01-15 Clariant International Ltd. Wässrige Zusammensetzungen enthaltend Alkylpolyethylenglykolethersulfate
US20130023687A1 (en) * 2010-03-04 2013-01-24 Hirosaki University Surfactant for stabilizing water/supercritical carbon dioxide microemulsion

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2654772A (en) * 1950-05-06 1953-10-06 Du Pont 2-(1, 3, 3-trimethylbutyl)-5, 7, 7-trimethyl octanol-1-sulfate
US2644831A (en) * 1951-04-16 1953-07-07 Monsanto Chemicals Alkali metal and ammonium sulfates of hydroxy ethers
US3338949A (en) * 1962-11-13 1967-08-29 Eastman Kodak Co 2, 2-dimethylalkyl sulfates and salts thereof
US3376333A (en) * 1964-11-16 1968-04-02 Textilana Corp Sulfuric acid esters of linear secondary alcohol ethoxylates and salts thereof and method of producing same
GB1159112A (en) * 1966-01-12 1969-07-23 Ici Ltd Process for the Production of Synthetic Detergents
US3647851A (en) * 1967-06-29 1972-03-07 Chevron Res Secondary alcohol sulfation process in the presence of inorganic salts
GB1345533A (en) * 1970-06-04 1974-01-30 Agfa Gevaert Coating compositions for photographic materials
GB1445997A (en) * 1973-11-06 1976-08-11 Unilever Ltd Process for sulphating ethoxylated secondary alcohols
EP0024711B2 (fr) * 1979-09-01 1989-02-08 Henkel Kommanditgesellschaft auf Aktien Produits concentrés de tensides aqueux et procédé pour l'amélioration des propriétés d'écoulement de produits concentrés de tensides aqueux difficilement transportables

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9015049A1 *

Also Published As

Publication number Publication date
EP0401642A1 (fr) 1990-12-12
DE3918252A1 (de) 1990-12-13
PT94260A (pt) 1991-02-08
JPH04505916A (ja) 1992-10-15
WO1990015049A1 (fr) 1990-12-13

Similar Documents

Publication Publication Date Title
EP0475967A1 (fr) Alkylsulfates gras et alkylpolyalkylene-glycolethersulfates gras; leur procede de production et leur utilisation
EP0807103B1 (fr) Sulfates et ethers-sulfates d'alcools dimeres bis et d'alcools trimeres tris
DE4321022A1 (de) Sulfatierte Hydroxymischether
EP0137983B1 (fr) Sulfonates d'éthers et leur préparation
EP0532557A1 (fr) Procede de production de sulfates d'ethers glyceriques.
DE3933860A1 (de) Verfahren zur herstellung von alkyl-polyethoxyethersulfaten
DE4109250A1 (de) Verfahren zur herstellung von hochkonzentrierten fettalkoholsulfat-pasten
EP0513134B1 (fr) Ester d'acide hydroxycarboxylique sulfate
DE1568769A1 (de) Verfahren zur Herstellung hellfarbiger Sulfonierungsprodukte
EP0785918A1 (fr) Matieres grasses
EP0518881B1 (fr) Procede de sulfonation de melanges contenant des glucosides d'alkyle
WO1997018189A1 (fr) Sulfates (d'ether) d'alcool gras a comportement a froid ameliore
DE19714043C2 (de) Verwendung von Glycerinsulfaten als Viskositätsregulatoren für konzentrierte wäßrige Alkyl(ether)sulfatpasten
EP0553148A1 (fr) Procede de production de pates de sulfate d'alkyle a fluidite amelioree
DE4032910A1 (de) Verfahren zur herstellung von alkylsulfatpasten mit verbesserten fliesseigenschaften
DE4031268A1 (de) Sulfatierungsprodukte von 2-alkyl-2-hydroxymethyl-1,3-propandiolen und deren (poly)-alkylenglykolethern
WO1991006531A1 (fr) Procede de production d'agents tensio-actifs anioniques a structure sulfatee
WO1992019590A1 (fr) Procede de preparation de sulfates d'ethers de glycerine
DE4316214A1 (de) Sulfonierte Diester
DE4446362A1 (de) Verfahren zur Herstellung wäßriger Konzentrate von Fettalkoholethersulfat-Erdalkalisalzen
DE4136784A1 (de) Verfahren zur herstellung hellfarbiger alkenylsulfat-pasten
DE4331294A1 (de) Reinigungsmittel für harte Oberflächen
WO1992000274A1 (fr) Sulfates d'ether d'octadienyle
DE4409568A1 (de) Sulfonierte Acrylsäureester
DE4030092A1 (de) Sulfonierte octadienylarylether

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19911127

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): DE FR

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 19931201