EP0523169A1 - Agent de blanchiment peroxygene - Google Patents

Agent de blanchiment peroxygene

Info

Publication number
EP0523169A1
EP0523169A1 EP91908049A EP91908049A EP0523169A1 EP 0523169 A1 EP0523169 A1 EP 0523169A1 EP 91908049 A EP91908049 A EP 91908049A EP 91908049 A EP91908049 A EP 91908049A EP 0523169 A1 EP0523169 A1 EP 0523169A1
Authority
EP
European Patent Office
Prior art keywords
sodium
particles
coating
weight
sodium carbonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP91908049A
Other languages
German (de)
English (en)
Other versions
EP0523169A4 (en
Inventor
William Clark Copenhafer
Basil Anthony Guiliano
William Avery Hills
Charles Vincent Juelke
Stephen Tomko
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FMC Corp
Original Assignee
FMC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FMC Corp filed Critical FMC Corp
Publication of EP0523169A1 publication Critical patent/EP0523169A1/fr
Publication of EP0523169A4 publication Critical patent/EP0523169A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
    • C01B15/10—Peroxyhydrates; Peroxyacids or salts thereof containing carbon
    • C01B15/106—Stabilisation of the solid compounds, subsequent to the preparation or to the crystallisation, by additives or by coating
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules

Definitions

  • the present invention is a solid composition which releases hydrogen peroxide in the presence of water and is stable when incorporated into solid household and laundry detergents.
  • peroxygenated compounds can be used as bleaching compounds in detergent powder mixtures.
  • sodium perborate tetrahydrate is generally used as a bleaching compound even though it is phytotoxic, as it is relatively stable to decomposition in a powdered detergent medium.
  • sodium perborate tetrahydrate has the disadvantage of dissolving too slowly, particularly in cold water.
  • Sodium perborate monohydrate dissolves rapidly, however, the particles are very fragile and generally break down to a dust. Both forms are environmentally undesirable because they add 1 mole of boron compound to the environment for each mole of active oxygen.
  • powdered detergents be used in a mixture with other peroxygen compounds, notably alkali metal percarbonates, perphosphate ⁇ and peroxymonosulfates, which have suitable dissolution rates.
  • these peroxygen compounds particularly percarbonates, decompose too quickly in the powdered state, especially if they are stored in a humid atmosphere. Furthermore, the moisture and other constituents in the cleaning compounds accelerate this decomposition.
  • particles of peroxygen compounds be coated by various compounds, such as trona (U.S. Patent No. 4,105,827); sodium silicate (U.S. Patent No. 3,951,838); sodium perborate plus sodium silicate (U.S. Patent No. 4,194,025); boric acid (U.S. Patent No. 4,321,301); wax (U.S. Patent No. 4,421,669); a polymer latex (U.S. Patent No.
  • these processes are based on either 1) physically coating the sodium carbonate peroxide with a compound, such as, trona, boric acid and the like to prevent the peroxygen compound (for example, sodium carbonate perhydrate) from physically contacting the other compounds in the detergent composition as a spacer, or 2) coating the peroxygen compound with a vapor barrier such as a wax or a polymer.
  • a compound such as, trona, boric acid and the like to prevent the peroxygen compound (for example, sodium carbonate perhydrate) from physically contacting the other compounds in the detergent composition as a spacer
  • a vapor barrier such as a wax or a polymer
  • substantially dry particles comprising a sodium carbonate perhydrate containing between 0.1% and 3% by weight diphosphonic acid or salt and between 1 and 5 moles of anhydrous sodium carbonate for each mole of available water contained therein sufficiently to substantially eliminate solid-solid contact between particles,
  • coated dry particles as a free- flowing peroxygen compound stable when incorporated into a solid detergent formulation.
  • the coated particles may be recycled to step a) and thereby be provided with two or more coatings.
  • the scope of the present invention is intended to include the product made by said process.
  • composition containing dry particles comprising sodium carbonate perhydrate, with from 1 to 5 moles excess sodium carbonate (anhydrous) and 0.1% to 3% diphosphonic acid may be employed.
  • SAPC Soda Ash Peroxygen Carrier
  • Diphosphonic acid appears to slow the rate of hydration of anhydrous sodium carbonate so that water preferentially evaporated.
  • the anhydrous sodium carbonate appears to be able to form a hydrate with any water formed by the decomposition of the peroxygen.
  • SAPC soda ash peroxygen carrier
  • the sodium carbonate perhydrate decomposition process produces 1.5 moles of water for each mole of. sodium carbonate perhydrate, and the coating, if impervious to vapor, prevents the water from evaporating. Consequently, the retained water accelerates the decomposition of the sodium carbonate perhydrate.
  • the coating is not impervious to water vapor, the moisture in the detergent formulation is able to contact the sodium carbonate perhydrate and initiate decomposition.
  • the present invention can be carried out in a fluid bed by suspending the dry particles by the fluidizing gas and applying the coating by a spray.
  • "suspending ... to eliminate solid-solid contact” would include permitting particles to be separately lifted by a stream of air or to fall separately as in a tower.
  • the invention can be carried out in a tower and applying the coating in a countercurrent, cocurrent or radial spray.
  • Other alternative processes will be apparent to one skilled in the art, such as a spray dryer with both liquid and solids injection, or the like.
  • the drops of aqueous solution be much smaller in diameter than the solid particles to avoid agglomerating the particles caused by wetting the surface of the dry particles, or of hydrating either the sodium carbonate perhydrate (SPC) or any sodium carbonate in the dry particles thereby forming the hydrate of SPC, 2Na 2 CO 3 .3H 2 O.2H 2 O 2 , a sodium carbonate hydrate or other hydrate.
  • SPC sodium carbonate perhydrate
  • the Quick Test is a method for determining the relative stability of similar samples (decomposition) in only eight hours. Sufficient sample is added to a closed container connected to a manometer to provide a constant volume to sample weight ratio. The temperature is maintained at 50°C and the oxygen evolved (the increase in pressure is measured hourly by the and the slope of the line is reported as cm/Hg). The test can be employed for samples formulated in a detergent base or for unformulated samples of a peroxygen compound ("neat stability").
  • the 80/80 Open Box Test simulates the storage of an open box of a detergent formulation. Unless otherwise specified sufficient peroxygen compound to be evaluated is blended in a commercial detergent formulation to provide 0.7% active oxygen by weight. The box containing 0.45 kilograms of formulation is stored with an open lid at 26.7°C (80°F) and 80% relative humidity for six weeks. At two week intervals samples are selected by riffling the contents of the box. Active oxygen is determined in triplicate.
  • the apparatus used for coating the dry particles was the Strea-1 Laboratory Fluid-Bed Coater, manufactured by Aeromatic, a division of Niro Industries.
  • the unit consists of a coating feed container, a tubing pump to dispense the coating solution and the fluid bed coater.
  • the fluid bed coater consists of a clear outer shell for easy viewing, a grid plate to introduce the fluidizing air, and a center draft tube containing an air atomizing spray nozzle.
  • the product introduced into the container is fluidized by a stream of preheated air from below the grid plate.
  • the particles to be coated are recycled through the draft tube until the desired amount of coating is applied.
  • uncoated SAPC having a bulk density of 1,025 kg/m 3 should have a bulk density after coating of at least 800 kg/m 3 (50 1b/cu.ft.), preferably at least 880 kg/m 3 (55 1b/cu.ft.).
  • the particles are coated with 2-10% of their weight of coating compound.
  • the single coating material may be applied or a combination either as a mixture or as multiple coats..
  • the effect of the coating is determined by how well the coated particles maintain active oxygen (hydrogen peroxide content) in the Quick Test and Open Box Test.
  • Solutions of the coating compound can vary in concentration over a large range. Preferably the solutions should contain about 15% to 25% solids. Higher concentrations than 25% can be used but usually must be preheated to prevent crystallization and to permit atomization into fine droplets. More dilute solutions require a greater heat input to evaporate the water sufficiently to prevent wetting the particles being coated. With care solutions can range from about 12% solids to about 35% solids.
  • Typical 25% solids solution preparation is illustrated as follows:
  • Sodium metaborate Add 261.8 g sodium metaborate tetrahydrate to 238.2 g water.
  • Sodium borosilicate A blend of above solutions (ratio 1:99 to 99:1).
  • the best mode of practicing the invention is exemplified employing the preferred SAPC because it will easily detect insufficient evaporation of water in step c) by the conversion of anhydrous sodium carbonate to a hydrate.
  • Soda Ash Peroxygen Carrier (SAPC) initially containing about 9.0% active oxygen was prepared using two commercial grades of sodium carbonate, FMC
  • coating the SAPC decreases the decomposition rate.
  • Coated and uncoated SAPC were evaluated by the Quick Test alone (neat stability) and formulated with a commercial detergent (P&G's nonphosphate Tide).
  • the Table shows particles coated according to the present invention are far more stable (less decom position) in detergent formulations than uncoated particles and comparable to the sodium perborate monohydrate of Tide with Bleach.
  • Samples of soda ash peroxygen carrier made by the process of U.S. Patent No. 4,966,762 and a commercial sodium carbonate perhydrate containing silicate and magne ⁇ ium stabilizer were coated with 2% and 10% borosilicate (about 50% sodium metaborate and 50% sodium silicate by weight). The samples were incorporated into non-phosphate Tide brand detergent to provide 0.7% active oxygen (A.O.). The stability was determined after storage for 6 weeks in the Open Box Test. Results are reported in Table IV and compared with commercial Tide with Bleach detergent and with a sample of Tide brand detergent made up with sodium perborate monohydrate.
  • the dissolution rate of coated peroxygen compounds was compared by measuring the change of active oxygen (A.O.) with time. Sufficient peroxygen compound was added to provide a final A.O. content of 0.2% by weight; the samples were stirred at 200 rpm.
  • Sodium perborate monohydrate (uncoated) which is known to dissolve very rapidly was substantially all in solution within 10 seconds, while uncoated sodium perborate tetrahydrate was only 50% dissolved by 120 seconds.
  • Samples of SAPC coated with 2% and 4% sodium borosilicate were both substantially dissolved (90%) within 40 seconds while samples of SAPC coated with 6%, 8% and 10% were all substantially dissolved (90%) within 60 seconds.
  • a sample of SAPC coated with 2% sodium silicate over an initial 2% sodium metaborate was only 80% dissolved after 120 seconds.
  • Borosil sodium borosilicate
  • SPBM sodium perborate monohydrate
  • SAPC soda ash peroxygen carrier

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention a trait à un procédé de revêtement de particules sèches comprenant un perhydrate de carbonate de sodium permettant d'obtenir un matière particulaire solide sèche et stable libérant du peroxyde d'hydrogène au contact d'une solution aqueuse. Les particules enrobées sont immédiatement solubles dans l'eau et/ou stables lorsqu'elles entrent dans la composition d'un détergent solide.
EP19910908049 1990-04-06 1991-04-03 Peroxygen laundry bleach Withdrawn EP0523169A4 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US50580090A 1990-04-06 1990-04-06
US505800 1990-04-06

Publications (2)

Publication Number Publication Date
EP0523169A1 true EP0523169A1 (fr) 1993-01-20
EP0523169A4 EP0523169A4 (en) 1993-02-03

Family

ID=24011897

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19910908049 Withdrawn EP0523169A4 (en) 1990-04-06 1991-04-03 Peroxygen laundry bleach

Country Status (7)

Country Link
EP (1) EP0523169A4 (fr)
JP (1) JPH0662998B2 (fr)
KR (1) KR960008939B1 (fr)
AU (1) AU7677291A (fr)
CA (1) CA2079915C (fr)
TR (1) TR25762A (fr)
WO (1) WO1991015423A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5328721A (en) * 1992-07-30 1994-07-12 Fmc Corporation Process for manufacturing sodium carbonate perhydrate particles and coating them with sodium borosilicate
DE4306399C2 (de) * 1993-03-02 1995-06-14 Degussa Verfahren zur Herstellung von stabilisiertem Natriumpercarbonat
GB9326522D0 (en) * 1993-12-29 1994-03-02 Solvay Interox Ltd Process for stabilising particulate alkali metal percarbonate
SE9400653D0 (sv) * 1994-02-25 1994-02-25 Eka Nobel Ab Blekmedel
DK0745664T3 (da) * 1994-02-25 1999-03-08 Eka Chemicals Ab Blegemiddel
IT1270000B (it) * 1994-09-22 1997-04-16 Solvay Interox Procedimento per la fabbricazione di particelle di persali
DE19600018A1 (de) 1996-01-03 1997-07-10 Henkel Kgaa Waschmittel mit bestimmten oxidierten Oligosacchariden
FI104634B (fi) 1997-01-24 2000-03-15 Kemira Chemicals Oy Stabiloitu natriumkarbonaattiperoksihydraatti

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB174891A (en) * 1920-07-26 1922-01-26 Adolf Welter Process for producing finely granulated compounds
US4156039A (en) * 1976-11-11 1979-05-22 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Sodium percarbonate particles (A)
LU76548A1 (fr) * 1977-01-10 1978-09-18
DE2748783C3 (de) * 1977-10-31 1985-07-11 Degussa Ag, 6000 Frankfurt Verfahren zum Stabilisieren von Natriumpercarbonat
CA1202854A (fr) * 1982-06-10 1986-04-08 Muthumi Kuroda Detergent blanchisseur
JPS58217599A (ja) * 1982-06-10 1983-12-17 花王株式会社 漂白洗浄剤組成物
US4759956A (en) * 1987-05-22 1988-07-26 Lever Brothers Company Process for encapsulating particles using polymer latex
US4966762A (en) * 1988-10-06 1990-10-30 Fmc Corporation Process for manufacturing a soda ash peroxygen carrier
US4970058A (en) * 1988-10-06 1990-11-13 Fmc Corporation Soda ash peroxygen carrier

Also Published As

Publication number Publication date
CA2079915C (fr) 1996-10-08
KR960008939B1 (ko) 1996-07-10
EP0523169A4 (en) 1993-02-03
CA2079915A1 (fr) 1991-10-07
TR25762A (tr) 1993-09-01
JPH0662998B2 (ja) 1994-08-17
AU7677291A (en) 1991-10-30
JPH05503729A (ja) 1993-06-17
WO1991015423A1 (fr) 1991-10-17

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