EP0575794B1 - Solutions de nettoyage contenant de l'isopropanol à point d'inflammation élevé - Google Patents

Solutions de nettoyage contenant de l'isopropanol à point d'inflammation élevé Download PDF

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Publication number
EP0575794B1
EP0575794B1 EP93108989A EP93108989A EP0575794B1 EP 0575794 B1 EP0575794 B1 EP 0575794B1 EP 93108989 A EP93108989 A EP 93108989A EP 93108989 A EP93108989 A EP 93108989A EP 0575794 B1 EP0575794 B1 EP 0575794B1
Authority
EP
European Patent Office
Prior art keywords
weight
mixtures
isopropanol
partially fluorinated
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP93108989A
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German (de)
English (en)
Other versions
EP0575794A1 (fr
Inventor
Wilfried Dr. Becker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay SA
Original Assignee
Solvay SA
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Filing date
Publication date
Application filed by Solvay SA filed Critical Solvay SA
Publication of EP0575794A1 publication Critical patent/EP0575794A1/fr
Application granted granted Critical
Publication of EP0575794B1 publication Critical patent/EP0575794B1/fr
Anticipated expiration legal-status Critical
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
    • C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50—Solvents
    • C11D7/5004—Organic solvents
    • C11D7/5018—Halogenated solvents

Definitions

  • EP-A 454 490 describes ternary mixtures Isopropanol, water and a perfluorocarbon with one Boiling point of 30 to 70 ° C known as Serve cleaning solutions.
  • Preferred compounds of the above formula are in which x is 1 to 3, w is 4 to 6 and y is 7 to 13.
  • Particularly preferred compounds are 3,4-dihydroperfluoro (2-methylpentane), 3,4,4-trihydroperfluoro (2-methylpentane), Mixtures of these two compounds by weight ratio from about 95: 5 to about 5: 95, preferably 90: 10 to 10:90, 2,2,2-trifluoroethyl-1,1,2,2-tetrafluoroethyl ether and especially 1H-perfluorohexane.
  • a mixture of 6.76 parts by weight of isopropanol is added and 1 part by weight of water 20% by weight, based on this Mixture, to one of the compounds mentioned, so obtained a flash point (according to DIN 51 758) of over 50 ° C.
  • a flash point (according to DIN 51 758) of over 50 ° C.
  • 1H-perfluorohexane already causes an addition of 10% by weight a flash point of 50 to 52 ° C and with a mixture about 90% by weight 3,4-dihydro-perfluoro (2-methyl-pentane) and 10 wt .-% 3,4,4-trihydro-perfluoro (2-methyl-pentane) a Flash point above 55 ° C.
  • the invention therefore relates in particular to mixtures of predominantly isopropanol and smaller, approximately equal amounts Water and fluorinated compound.
  • Preferred mixtures contain 70 to 80% by weight isopropanol, 10 to 12% by weight water and 9 to 18% by weight fluorinated compound.
  • a preferred mixture consists of, for example 72.6% by weight of isopropanol, 10.7% by weight of water and 16.7% by weight Trifluoroethyl tetrafluoroethyl ether.
  • Particularly preferred mixtures consist of 79.2% by weight Isopropanol, 11.7% by weight water and 9.1% by weight fluorinated Hydrocarbon.
  • the fluorinated hydrocarbons are known Links. You can, for example, by hydrogenation of the corresponding olefins [V.F. Snegirev et al., Izv. Akad. Nauk SSSR, Ser. Khim. (12), 2775 to 2781 (1983)].
  • the fluorinated ether is obtained one, for example, by the addition of alcohols fluorinated olefins (Houben-Weyl, 'Methods of Organic Chemie ', 4th edition, volume V / 3 (1962), halogen compounds, Page 280).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)

Claims (9)

  1. Utilisation, comme constituants d'un mélange à base d'isopropanol et d'eau, d'hydrocarbures ou d'éthers partiellement fluorés de formule CwHxFyOz, dans laquelle x < y, la somme de x + y = 2w +2 et z est égal à zéro ou 1, et qui présentent un point d'ébullition dans la gamme de 40 à 100°C.
  2. Mélanges à base principalement d'isopropanol et d'une quantité mineure d'eau et d'un ou de plusieurs hydrocarbures ou éthers partiellement fluorés de formule CwHxFyOz, dans laquelle x < y, la somme de x + y = 2w +2 et z est égal à zéro ou 1, et qui présentent un point d'ébullition dans la gamme de 40 à 100°C.
  3. Mélanges à base de 70 à 80 % en poids d'isopropanol, de 10 à 12 % en poids d'eau et de 9 à 18 % en poids d'un ou de plusieurs hydrocarbures ou éthers partiellement fluorés de formule CwHxFyOz, dans laquelle x < y, la somme de x + y = 2w +2 et z est égal à zéro ou 1, et qui présentent un point d'ébullition dans la gamme de 40 à 100°C.
  4. Mélanges selon la revendication 2 ou 3, caractérisés en ce que, dans la formule CwHxFyOz, x signifie 1 à 3.
  5. Mélanges selon les revendications 2 à 4, caractérisés en ce que, dans la formule CwHxFyOz, w signifie 4 à 6.
  6. Mélanges selon les revendications 2 à 5, caractérisés en ce que, dans la formule CwHxFyOz, y signifie 7 à 13.
  7. Mélanges selon les revendications 2 à 6, caractérisés en ce que les hydrocarbures ou éthers partiellement fluorés sont choisis parmi le 3,4-dihydro-perfluor-(2-méthyl-pentane), le 3,4,4-trihydro-perfluor-(2-méthyl-pentane), le 2,2,2-trifluoréthyl-1,1,2,2-tétrafluoroéthyl-éther, le 1H-perfluorhexane et leurs mélanges.
  8. Mélanges selon la revendication 7, caractérisés en ce que l'hydrocarbure ou l'éther partiellement fluoré est le 1H-perfluorhexane.
  9. Mélanges selon la revendication 7, caractérisés en ce que l'hydrocarbure ou l'éther partiellement fluoré est le 2,2,2-trifluoréthyl-1,1,2,2-tétrafluoroéthyl-éther.
EP93108989A 1992-06-10 1993-06-04 Solutions de nettoyage contenant de l'isopropanol à point d'inflammation élevé Expired - Lifetime EP0575794B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4218966A DE4218966A1 (de) 1992-06-10 1992-06-10 Isopropanolhaltige Reinigungslösungen mit erhöhtem Flammpunkt
DE4218966 1992-06-10

Publications (2)

Publication Number Publication Date
EP0575794A1 EP0575794A1 (fr) 1993-12-29
EP0575794B1 true EP0575794B1 (fr) 1998-10-14

Family

ID=6460703

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93108989A Expired - Lifetime EP0575794B1 (fr) 1992-06-10 1993-06-04 Solutions de nettoyage contenant de l'isopropanol à point d'inflammation élevé

Country Status (5)

Country Link
EP (1) EP0575794B1 (fr)
JP (1) JPH0657296A (fr)
AT (1) ATE172239T1 (fr)
CA (1) CA2098057A1 (fr)
DE (2) DE4218966A1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3123695B2 (ja) * 1993-01-22 2001-01-15 キヤノン株式会社 混合溶剤組成物、及びそれを利用する洗浄方法と洗浄処理装置
IT1271075B (it) 1994-11-21 1997-05-26 Ausimont Spa Miscele ternarie di solventi, e loro uso per la rimozione di sostanze oleose
US5814595A (en) 1995-05-16 1998-09-29 Minnesota Mining And Manufacturing Company Azeotrope-like compositions and their use
US6008179A (en) * 1995-05-16 1999-12-28 3M Innovative Properties Company Azeotrope-like compositions and their use
US5827446A (en) * 1996-01-31 1998-10-27 E. I. Du Pont De Nemours And Company Nonafluoromethoxybutane compositions
RU2107707C1 (ru) * 1996-07-15 1998-03-27 Воронежская государственная технологическая академия Акционерного общества "Туласпирт" "Лужковский спиртзавод" Жидкость для очистки замороженных поверхностей изделий от льда
US6030934A (en) * 1997-02-19 2000-02-29 3M Innovative Properties Company Azeotropic compositions of methoxy-perfluoropropane and their use
US6159917A (en) * 1998-12-16 2000-12-12 3M Innovative Properties Company Dry cleaning compositions containing hydrofluoroether
KR101002202B1 (ko) * 2002-07-03 2010-12-20 아사히 가라스 가부시키가이샤 용제 조성물

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2008882A1 (fr) * 1989-02-01 1990-08-01 Takamasa Tsumoto Agent et methode de lavage et processus de fabrication de dispositifs a semiconducteur a circuits integres utilisant cet agent et cette methode
GB9009504D0 (en) * 1990-04-27 1990-06-20 Isc Chemicals Ltd Reduced flammability mixture based on isopropanol

Also Published As

Publication number Publication date
DE59309054D1 (de) 1998-11-19
CA2098057A1 (fr) 1993-12-11
JPH0657296A (ja) 1994-03-01
DE4218966A1 (de) 1993-12-16
EP0575794A1 (fr) 1993-12-29
ATE172239T1 (de) 1998-10-15

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