EP0593809B1 - Déodorant comprenant une émulsion H/E et une phase constituée de microcapsules de parfum, et le procédé de préparation - Google Patents
Déodorant comprenant une émulsion H/E et une phase constituée de microcapsules de parfum, et le procédé de préparation Download PDFInfo
- Publication number
- EP0593809B1 EP0593809B1 EP92118067A EP92118067A EP0593809B1 EP 0593809 B1 EP0593809 B1 EP 0593809B1 EP 92118067 A EP92118067 A EP 92118067A EP 92118067 A EP92118067 A EP 92118067A EP 0593809 B1 EP0593809 B1 EP 0593809B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- perfume
- microcapsules
- deodorant
- emulsion
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 239000002304 perfume Substances 0.000 title claims abstract description 50
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 8
- 239000003094 microcapsule Substances 0.000 title claims description 20
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000007764 o/w emulsion Substances 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000839 emulsion Substances 0.000 claims abstract description 15
- 239000003995 emulsifying agent Substances 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 5
- 239000003755 preservative agent Substances 0.000 claims description 5
- 230000002335 preservative effect Effects 0.000 claims description 4
- 239000007791 liquid phase Substances 0.000 claims description 3
- 239000012071 phase Substances 0.000 claims description 3
- 239000007900 aqueous suspension Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 abstract description 5
- 239000000725 suspension Substances 0.000 abstract description 3
- 238000009472 formulation Methods 0.000 abstract description 2
- 239000002002 slurry Substances 0.000 description 4
- 230000005484 gravity Effects 0.000 description 3
- 239000001828 Gelatine Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 239000012729 immediate-release (IR) formulation Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical group CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 description 1
- 229920002690 Polyoxyl 40 HydrogenatedCastorOil Polymers 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
- A61L9/12—Apparatus, e.g. holders, therefor
Definitions
- the invention concerns a deodorant, consisting of a water emulsion of a perfume oil, and of a certain quantity of microcapsules, filled with the same perfume oil, and mixed with the water emulsion of the perfume.
- the invention also concerns the method of preparation of the deodorant.
- deodorants in which the perfume is mixed with other components in order to obtain a gel as well as deodorants made by plastic materials of various types.
- liquid deodorants which can be sprayed directly in the air or deodorants which release perfume through a porous surface, or else deodorants in granular form.
- deodorants with the exception of the liquids sprayed in the air, are capable of a slow, continuous release of perfume, once they are put in use for a certain period of time.
- instantaneous deodorants consisting of a liquid formula which is finely sprayed in the room to be deodorized.
- deodorants are sprayed either by means of a manual pump or, in the well-known aerosol form, by a compressed or liquified propellant gas.
- liquid deodorants are generally hydroalcoholic formulae, so that the sprayed product is effective for a limited length of time, depending on the volatility of the components of the formula and of the perfume itself. This time is always rather short, especially taking into account the fact that the products rapidly tend to deposit on the ground by gravity.
- WO-A-92 00 722 relates to a fragrance composition comprising a fragrant base in the microencapsulated form. This composition is specifically provided for topic use.
- the present invention proposes a deodorant composed of a liquid phase constitued by a water emulsion of a perfume oil and a phase constitued by microcapsules containing the same perfume oil.
- the invention also concerns the relevant method of preparation.
- the deodorant provides the advantage of a longer-lasting effect, as compared to the normal deodorants, as, beside the immediate release of perfume at the moment of its dispersion in the environment, a further effect is provided, owing to the release of perfume from the microcapsules, when, once deposited on various surfaces, they get broken when walking on them, or by other means.
- the scope of the invention is that of providing a deodorant which overcomes the limitations of the usual deodorants by immediately perfuming the air when sprayed, and then by mantaining for a relatively long time its capacity to release perfume.
- the invention provides a deodorant composed of a liquid phase, constitued by a water emulsion of perfume oil, and of a certain amount of microcapsules of the same perfume oil which are sprayed in the air mixed with the rest of the product, and which then tend to fall down by gravity.
- the water emulsion phase of the deodorant serves the purpose of immediately perfuming the air, while the microcapsules provide a longer-lasting action as they release their perfume when they are mechanically broken as they are walked on or by other means.
- the deodorant is constituted by a water emulsion of a perfume oil, to which a certain quantity of microencapsulated perfume has been added and held in suspension within the perfume emulsion in water.
- a formula suitable for the purpose of the invention is as follows: Preferred Composition Perfume 0.5% - 10% 3% Emulsifier 0.2% - 10% 2% Microencapsulated Perfume 0.2% - 10% 2% Preservative As needed Demineralized Water Balance to 100%
- This perfume will have to be chosen among those which are non-miscible with water.
- perfumes which more or less spontaneously become emulsified in water must be excluded.
- Such characteristic is mandatory because only non-emulsifible perfumes are suitable to be microencapsulated according to the usual techniques.
- the normally used emulsifiers which are useful to disperse perfumes in water can be used for the purpose of the present invention.
- This emulsion is usually a milky-white liquid, or in rarer rases, an opalescent liquid.
- emulsifier capable of providing a stable emulsion for a period of at least six months at room temperature.
- the preservative used must guarantee an effective protection of the product against a wide range of bacterial strains and yeasts.
- Kathon CG® produced by Sandoz, used at very low levels, between 3ppm and 10ppm, preferably 5ppm.
- microcapsules containing the perfume are constitued by the perfume itself, finely dispersed in microscopic droplets coated by gelatine.
- microencapsulation process is not described as it can be carried out through known techniques.
- microcapsules of perfume and gelatine contain between 50% and 90% perfume, preferably between 80% and 85% perfume, and have sizes ranging from 1 to 10 micron, preferably 5 micron.
- microcapsules are used under the form of a water suspension ("slurry"), containing between 10% and 30% microcapsules, preferably 20%.
- microcapsules in suspension in water tend to sediment it is necessary to keep them under moderate agitation during the preparation of the finished product.
- the finished product is prepared as follows:
- the deodorant product according to the present invention provides, as stated above, the dual advantage of an immediate deodorant/perfuming action and of a further continuous release of perfume, thanks to mechanical break-up of the microcapsules when they were walked on, etc.
- a further advantage is due to the fact that the product does not contain solvents, thus overcoming possible risks of flammability and other possible drawbacks related to the use of solvents.
Landscapes
- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Cosmetics (AREA)
Claims (3)
- Désodorisant ambiant caractérisé en ce qu'il est constitué d'une phase liquide, comprenant une émulsion dans l'eau d'une huile de parfum et d'une autre phase constituée de microcapsules contenant la même huile de parfum, qui sont mélangées à l'émulsion aqueuse ci-dessus.
- Désodorisant suivant la revendication 1, dans lequel le parfum est présent en des quantités allant entre 0,5 % et 10 %, avantageusement 3 %, l'émulsifiant est présent entre 0,2 % et 10 %, avantageusement 2 %, et le parfum dans les microcapsules entre 0,2 % et 10 %, avantageusement 2 %.
- Procédé de production d'un désodorisant suivant l'une ou l'autre des revendications 1 et 2, comprenant les étapes suivantes :mélanger du parfum et de l'émulsifiant;ajouter de l'eau sous une agitation modérée;préparer des microcapsules contenant du parfum;ajouter une suspension aqueuse de microcapsules de parfum à l'émulsion aqueuse de parfum sous une agitation modérée;ajouter un agent de conservation.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP92118067A EP0593809B1 (fr) | 1992-10-22 | 1992-10-22 | Déodorant comprenant une émulsion H/E et une phase constituée de microcapsules de parfum, et le procédé de préparation |
| ES92118067T ES2142810T3 (es) | 1992-10-22 | 1992-10-22 | Desodorante que comprende una emulsion de aceite/agua y una fase constituida por microcapsulas de perfume, y metodo de preparacion. |
| PT92118067T PT593809E (pt) | 1992-10-22 | 1992-10-22 | Desodorizante compreendendo uma emulsao o/a e uma fase constituida por microcapsulas de perfume e processo de preparacao |
| DE69230793T DE69230793T2 (de) | 1992-10-22 | 1992-10-22 | Deodorant enthaltend eine O/W Emulsion und eine Parfummikrokapseln enthaltende Phase, und Verfahren zu ihrer Herstellung |
| AT92118067T ATE190506T1 (de) | 1992-10-22 | 1992-10-22 | Deodorant enthaltend eine o/w emulsion und eine parfummikrokapseln enthaltende phase, und verfahren zu ihrer herstellung |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP92118067A EP0593809B1 (fr) | 1992-10-22 | 1992-10-22 | Déodorant comprenant une émulsion H/E et une phase constituée de microcapsules de parfum, et le procédé de préparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0593809A1 EP0593809A1 (fr) | 1994-04-27 |
| EP0593809B1 true EP0593809B1 (fr) | 2000-03-15 |
Family
ID=8210162
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP92118067A Revoked EP0593809B1 (fr) | 1992-10-22 | 1992-10-22 | Déodorant comprenant une émulsion H/E et une phase constituée de microcapsules de parfum, et le procédé de préparation |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0593809B1 (fr) |
| AT (1) | ATE190506T1 (fr) |
| DE (1) | DE69230793T2 (fr) |
| ES (1) | ES2142810T3 (fr) |
| PT (1) | PT593809E (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110038392A (zh) * | 2019-04-10 | 2019-07-23 | 佛山市高明绿化纳新材料有限公司 | 一种新型抗菌除臭空气清新剂及其制备方法和应用 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL142981A0 (en) * | 1998-11-25 | 2002-04-21 | Procter & Gamble | Improved uncomplexed cyclodextrin compositions for odor control |
| GB0109754D0 (en) * | 2001-04-20 | 2001-06-13 | Quest Int | Floor treatment compositions |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2032425T3 (es) * | 1987-11-24 | 1993-02-16 | Pictoris Beta | Desodorante solido de tipo granular y su paquete correspondiente. |
| CN1045599A (zh) * | 1989-03-15 | 1990-09-26 | 王英 | 长效微粒香乳及制造方法 |
| WO1992000722A1 (fr) * | 1990-07-13 | 1992-01-23 | Firmenich S.A. | Composition parfumante alcoolique |
-
1992
- 1992-10-22 EP EP92118067A patent/EP0593809B1/fr not_active Revoked
- 1992-10-22 ES ES92118067T patent/ES2142810T3/es not_active Expired - Lifetime
- 1992-10-22 AT AT92118067T patent/ATE190506T1/de not_active IP Right Cessation
- 1992-10-22 DE DE69230793T patent/DE69230793T2/de not_active Revoked
- 1992-10-22 PT PT92118067T patent/PT593809E/pt unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110038392A (zh) * | 2019-04-10 | 2019-07-23 | 佛山市高明绿化纳新材料有限公司 | 一种新型抗菌除臭空气清新剂及其制备方法和应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69230793D1 (de) | 2000-04-20 |
| EP0593809A1 (fr) | 1994-04-27 |
| ES2142810T3 (es) | 2000-05-01 |
| DE69230793T2 (de) | 2000-06-29 |
| ATE190506T1 (de) | 2000-04-15 |
| PT593809E (pt) | 2000-06-30 |
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