EP0596830A1 - Appareil de pulvérisation par plasma - Google Patents

Appareil de pulvérisation par plasma Download PDF

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Publication number
EP0596830A1
EP0596830A1 EP93810729A EP93810729A EP0596830A1 EP 0596830 A1 EP0596830 A1 EP 0596830A1 EP 93810729 A EP93810729 A EP 93810729A EP 93810729 A EP93810729 A EP 93810729A EP 0596830 A1 EP0596830 A1 EP 0596830A1
Authority
EP
European Patent Office
Prior art keywords
plasma
anode
channel
cathode
arrangement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP93810729A
Other languages
German (de)
English (en)
Other versions
EP0596830B1 (fr
Inventor
Klaus Dr. Landes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oerlikon Metco AG
Original Assignee
Sulzer Metco AG
Plasma Tecknik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sulzer Metco AG, Plasma Tecknik AG filed Critical Sulzer Metco AG
Publication of EP0596830A1 publication Critical patent/EP0596830A1/fr
Application granted granted Critical
Publication of EP0596830B1 publication Critical patent/EP0596830B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00—Generating plasma; Handling plasma
    • H05H1/24—Generating plasma
    • H05H1/26—Plasma torches
    • H05H1/32—Plasma torches using an arc
    • H05H1/34—Details, e.g. electrodes, nozzles
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/134—Plasma spraying
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00—Generating plasma; Handling plasma
    • H05H1/24—Generating plasma
    • H05H1/26—Plasma torches
    • H05H1/32—Plasma torches using an arc
    • H05H1/34—Details, e.g. electrodes, nozzles
    • H05H1/3484—Convergent-divergent nozzles

Definitions

  • the present invention relates to a plasma spraying device with an indirect plasmatron for spraying powdery material, in particular for coating workpiece surfaces.
  • plasma sprayers For spraying powdery material in the molten state, plasma sprayers are used which work with an indirect plasmatron, i.e. a plasma generator with an electrically non-current-carrying plasma jet flowing out of a nozzle.
  • an indirect plasmatron i.e. a plasma generator with an electrically non-current-carrying plasma jet flowing out of a nozzle.
  • the plasma is generated by an arc and passed through a plasma channel to an outflow nozzle, a distinction being made between devices with a short arc and those with a long arc.
  • Foot migrations can be particularly pronounced in plasma cartridges that work with a short arc, a pin-shaped cathode being immersed in a one-piece, nozzle-shaped anode (for example in accordance with DE-GM 1 932 150), since anode nozzles with an axial extension with this electrode arrangement have both axial and peripheral Migration of the arc base can occur.
  • At least axial foot point hikes can also be expected in a similar plasma spraying device according to DE 33 12 232, which has several cathodes instead of one.
  • an axial base point migration results from the fact that an arc burning between a cathode and a nozzle-shaped anode is drawn out under the influence of the plasma flow to a point of the anode furthest from the cathode, then tears off at this point and at one of the Cathode at the closest point of the anode again starts.
  • this process is repeated more or less periodically with a repetition frequency in the order of several kilohertz.
  • the voltage changes associated with the changes in length of the arc can lead to strong power fluctuations (up to approximately ⁇ 30%) and corresponding intensity fluctuations in the free plasma beam.
  • the spray material supplied to the plasma jet is treated very unevenly.
  • the radial temperature profile of the free plasma jet also runs asymmetrically, i.e. that the hot core of the plasma jet experiences a certain deflection from the longitudinal axis of the plasma cartridge.
  • This effect is further supported by the fact that the plasma flowing out of the anode nozzle at the base of the arc, i.e. at an eccentric point in the arrangement, is additionally heated.
  • Such a deflection of the plasma core is particularly serious in connection with a peripheral migration of the base of the arc. This creates a kind of precession movement of the plasma jet, which usually runs irregularly and also results in an uneven thermal treatment of the spray material when the spray material is supplied externally from a stationary supply device.
  • a plasma spraying device the plasmatron of which works with a long arc and, for example according to EP 0 249 238 A2, one with an anode ring and has a number of annular, electrically isolated neutrodes formed from each other.
  • a plasmatron of this type still shows a pronounced peripheral migration of the arc base at the ring-shaped anode, provided the arc starts from a single cathode, as is the case, for example, with the plasma spraying device according to EP 0 249 238 A2.
  • the situation is similar to that of the example of a short-arc plasma platrons described above. In this case too, the result is an uneven treatment of the spray material supplied from the side.
  • the plasma spraying device shown in longitudinal section has three rod-shaped cathodes 1, which run parallel to one another and are evenly distributed in a circle around the central longitudinal axis 2 of the device, furthermore an annular anode 3 distanced from the cathodes 1 and a plasma guide channel 4 extending from the cathodes 1 to the anode 3.
  • the plasma guide channel 4 is isolated from one another by a number of annular, electrically insulated Neutrodes 6 to 12 and the annular anode 3 are formed.
  • the cathode rods 1 are anchored in a cathode support 13 made of insulating material.
  • a sleeve-shaped anode carrier 14 made of insulating material, which surrounds the neutrodes 6 to 12 and the anode 3.
  • the whole is held together by three metal sleeves 15, 16 and 17, the first sleeve 15 being screwed to the end on the end face and the second sleeve 16 being screwed to the first circumference, while the third sleeve 17 is loosely anchored on the one hand to the second sleeve 16 and on the other hand is screwed circumferentially to the anode carrier 14.
  • the third sleeve 17 also presses with an inwardly directed flange 18 against the anode ring 3 and thus holds the elements forming the plasma guide channel 4 together, the neutrode 6 closest to the cathodes being supported on an inner collar 19 of the anode carrier 4.
  • the free ends of the cathode rods 1 carry cathode pins 20, which are made of an electrically and thermally particularly conductive and also high-melting material, for example tungsten.
  • the cathode pins 20 are eccentric to the respective one Axis of the cathode rods 1 is arranged so that their longitudinal axes are closer to the central longitudinal axis 2 than those of the cathode rods 1.
  • a central insulating body 21 made of high-melting, in particular glass-ceramic material, from which the cathode pins 20 are made, is attached to the cathode carrier 13 on the side facing the plasma guide channel 4 protrude into the cavity 22 of the inlet nozzle formed by the first neutrode 6.
  • the exposed part of the outer lateral surface of the insulating body 21 is located radially opposite a part of the nozzle wall and forms with this wall part an annular channel 23 for the inlet of the plasma gas into the nozzle cavity 22.
  • the plasma gas PG is fed through a transverse channel 26 provided in the cathode carrier 13, which transitions into a longitudinal channel 27, from which the plasma gas reaches an annular space 28 and from there into the annular channel 23.
  • a distributor ring 29 is provided on the insulating body 20 and has a plurality of through bores 30 which connect the annular space 28 to the annular channel 23.
  • the elements forming the plasma guide channel 4, namely the anode 3 and the neutrodes 6 to 12, are electrically insulated from one another by ring disks 31 made of insulating material, for example boron nitride, and are connected to one another in a gastight manner by means of sealing rings 32.
  • the plasma guide channel 4 has a constriction zone 33 in the region near the cathode and widens after this Constriction zone 33 towards the anode 3 to a diameter which is at least 1.5 times as large as the channel diameter at the narrowest point of the constriction zone 33. After this expansion, the plasma guide channel 4 extends cylindrically to its anode-side end.
  • the anode 3 is composed of an outer ring 34, for example of copper, and an inner ring 35 of an electrically and thermally particularly conductive and also high-melting material, for example tungsten.
  • the neutrode 6 closest to the cathode rods 1 extends over the entire constriction zone 33, so that the channel wall 52 unites beyond the narrowest point of the constriction zone has a steady course.
  • the parts directly exposed to the arc and plasma heat are largely water-cooled.
  • various cavities for the circulation of the cooling water KW are provided in the cathode holder 13, in the cathode rods 1 and in the anode holder 14.
  • the cathode holder 13 has three annular spaces 36, 37 and 38, which are connected to connecting lines 39, 40 and 41, respectively, and the anode holder 14 has an annular space 42 in the area of the anode 3 and one surrounding all neutrodes in the area of the neutrodes 6 to 12 Cavity 43 on.
  • Cooling water KW is supplied via the connecting lines 39 and 41.
  • the cooling water of the connecting line 39 first passes through a longitudinal channel 44 to the annular space 42 surrounding the most thermally stressed anode 3.
  • the cooling water flows through the cavity 43 of the lateral surface of the neutrodes 6 to 12 back through a longitudinal channel 45 into the annular space 37
  • Connection line 41 flows into an annular space 38 and from this into a cavity 46 of the cathode rods 1, which is divided by a cylindrical partition 47.
  • the cooling water also arrives from the cathode rods 1 into the annular space 37, from which it flows out via the connecting line 40.
  • the approximate course of the individual arcs 50 (two visible) is also indicated schematically in the figure. Their anode-side base points are distributed evenly over the inner circumference of the anode ring 3. Furthermore, the beginning section of the free plasma jet PS emerging axially symmetrically from the plasma channel 4 is indicated by dashed lines.
  • the supply of the spray material, for example metal powder, into the free plasma jet PS takes place with the aid of a ring arrangement 51 made of temperature-resistant material placed on the anode-side metal sleeve 17, which is provided with channels 52 in the form of radial bores, to which the spray material SM is supplied with a carrier gas via connecting lines 53 is fed.
  • a ring arrangement 51 made of temperature-resistant material placed on the anode-side metal sleeve 17, which is provided with channels 52 in the form of radial bores, to which the spray material SM is supplied with a carrier gas via connecting lines 53 is fed.
  • two radial bores are diametrically opposite one another.
  • a ring arrangement with only one channel 52 or one with more than two, for example three, channels can also be present be in the latter case, the channels are preferably arranged evenly distributed over the circumference of the ring assembly 51.
  • the channels are preferably arranged evenly distributed over the circumference of the ring assembly 51.
  • the spray material SM on the anode side in the free plasma jet PS it may be expedient not only to provide the spray material SM on the anode side in the free plasma jet PS, but also to provide spray material at the cathode-side end of the plasma cartridge.
  • an axial guide tube can be provided which passes through the cathode holder 13 and the insulating body 21 centrally.
  • the entire arc energy that is to say not only the energy portion which passes from the arc into the free plasma jet, can be used in a known manner to melt the spray material.
  • the plasmatron could be operated simultaneously or alternately with anode-side and cathode-side supply of spray material.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical & Material Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Plasma Technology (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Nozzles (AREA)
  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
  • Electrostatic Spraying Apparatus (AREA)
EP93810729A 1992-11-06 1993-10-18 Appareil de pulvérisation par plasma Expired - Lifetime EP0596830B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE9215133U 1992-11-06
DE9215133U DE9215133U1 (de) 1992-11-06 1992-11-06 Plasmaspritzgerät

Publications (2)

Publication Number Publication Date
EP0596830A1 true EP0596830A1 (fr) 1994-05-11
EP0596830B1 EP0596830B1 (fr) 1996-05-08

Family

ID=6885751

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93810729A Expired - Lifetime EP0596830B1 (fr) 1992-11-06 1993-10-18 Appareil de pulvérisation par plasma

Country Status (6)

Country Link
US (1) US5406046A (fr)
EP (1) EP0596830B1 (fr)
JP (1) JP3287373B2 (fr)
AT (1) ATE137905T1 (fr)
CA (1) CA2102284C (fr)
DE (2) DE9215133U1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19610015C2 (de) * 1996-03-14 1999-12-02 Hoechst Ag Thermisches Auftragsverfahren für dünne keramische Schichten und Vorrichtung zum Auftragen
DE102011114406A1 (de) 2011-09-26 2013-03-28 Klaus Landes Plasmaspritzgerät

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE9215133U1 (de) * 1992-11-06 1993-01-28 Plasma-Technik Ag, Wohlen Plasmaspritzgerät
US5514848A (en) * 1994-10-14 1996-05-07 The University Of British Columbia Plasma torch electrode structure
DE19540587A1 (de) * 1995-10-31 1997-05-07 Bosch Gmbh Robert Plasmabrenner
US6213049B1 (en) 1997-06-26 2001-04-10 General Electric Company Nozzle-injector for arc plasma deposition apparatus
FR2779316B1 (fr) * 1998-05-29 2000-08-25 Aerospatiale Dispositif de melange de gaz froid en sortie de torche a plasma
US7662468B2 (en) * 2000-10-06 2010-02-16 Brock Usa, Llc Composite materials made from pretreated, adhesive coated beads
US6669106B2 (en) 2001-07-26 2003-12-30 Duran Technologies, Inc. Axial feedstock injector with single splitting arm
SE523135C2 (sv) * 2002-09-17 2004-03-30 Smatri Ab Plasmasprutningsanordning
SE525927C2 (sv) * 2002-09-18 2005-05-31 Volvo Aero Corp Anordning för termisk sprutning
US7557324B2 (en) * 2002-09-18 2009-07-07 Volvo Aero Corporation Backstream-preventing thermal spraying device
US20050089678A1 (en) * 2003-08-20 2005-04-28 Mead Steven R. Multi-layered floorig composite including an acoustic underlayment
US7244477B2 (en) * 2003-08-20 2007-07-17 Brock Usa, Llc Multi-layered sports playing field with a water draining, padding layer
US7759599B2 (en) * 2005-04-29 2010-07-20 Sulzer Metco (Us), Inc. Interchangeable plasma nozzle interface
SE529053C2 (sv) 2005-07-08 2007-04-17 Plasma Surgical Invest Ltd Plasmaalstrande anordning, plasmakirurgisk anordning och användning av en plasmakirurgisk anordning
SE529058C2 (sv) 2005-07-08 2007-04-17 Plasma Surgical Invest Ltd Plasmaalstrande anordning, plasmakirurgisk anordning, användning av en plasmakirurgisk anordning och förfarande för att bilda ett plasma
SE529056C2 (sv) 2005-07-08 2007-04-17 Plasma Surgical Invest Ltd Plasmaalstrande anordning, plasmakirurgisk anordning och användning av en plasmakirurgisk anordning
WO2007065252A1 (fr) * 2005-12-06 2007-06-14 Lucian Bogdan Delcea Systeme de buse de pulverisation plasma
USD545851S1 (en) 2006-03-30 2007-07-03 Dave Hawley Plasma gun nozzle holder
US7928338B2 (en) * 2007-02-02 2011-04-19 Plasma Surgical Investments Ltd. Plasma spraying device and method
CA2695902C (fr) * 2007-08-06 2016-01-05 Plasma Surgical Investments Limited Ensemble cathodique et procede de generation de plasma pulse
US8735766B2 (en) * 2007-08-06 2014-05-27 Plasma Surgical Investments Limited Cathode assembly and method for pulsed plasma generation
US7589473B2 (en) * 2007-08-06 2009-09-15 Plasma Surgical Investments, Ltd. Pulsed plasma device and method for generating pulsed plasma
FR2943209B1 (fr) 2009-03-12 2013-03-08 Saint Gobain Ct Recherches Torche a plasma avec injecteur lateral
US9315888B2 (en) 2009-09-01 2016-04-19 General Electric Company Nozzle insert for thermal spray gun apparatus
US8237079B2 (en) * 2009-09-01 2012-08-07 General Electric Company Adjustable plasma spray gun
FR2952786B1 (fr) 2009-11-17 2012-06-08 Centre Nat Rech Scient Torche a plasma et procede de stabilisation d'une torche a plasma
US8613742B2 (en) * 2010-01-29 2013-12-24 Plasma Surgical Investments Limited Methods of sealing vessels using plasma
US9089319B2 (en) 2010-07-22 2015-07-28 Plasma Surgical Investments Limited Volumetrically oscillating plasma flows
EP2535437A1 (fr) 2011-06-16 2012-12-19 RH Optronic ApS Procédé de revêtement au plasma de rouleaux et rouleau revêtu au plasma
AU2012371647B2 (en) * 2012-02-28 2015-05-07 Sulzer Metco (Us), Inc. Extended cascade plasma gun
US9272360B2 (en) 2013-03-12 2016-03-01 General Electric Company Universal plasma extension gun
CH712835A1 (de) * 2016-08-26 2018-02-28 Amt Ag Plasmaspritzvorrichtung.
RU2020129100A (ru) * 2018-02-20 2022-03-21 ЭРЛИКОН МЕТКО (ЮЭс) ИНК. Однодуговой каскадный плазмотрон низкого давления, использующий пакет нейтродов как способ контроля плазменной дуги
CN110315178A (zh) * 2019-07-03 2019-10-11 阳江市高功率激光应用实验室有限公司 焊枪结构及具有该焊枪结构的熔覆系统
EP4205515A2 (fr) 2020-08-28 2023-07-05 Plasma Surgical Investments Limited Systèmes, procédés et dispositifs pour générer un flux de plasma étendu principalement radialement
DE102024117476A1 (de) * 2024-06-20 2025-12-24 Sms Group Gmbh Kathodenteil, Anodenteil, Zuführeinrichtung, Vorrichtung zum thermischen Spritzen, Verfahren zum Herstellen eines derartigen Kathodenteils und/oder Anodenteils, Verfahren zum Betreiben einer Vorrichtung zum thermischen Spritzen, Verwendung eines Kathodenteils, Verwendung eines Anodenteils und Verwendung einer Zuführvorrichtung von Pulverpartikeln

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US3524962A (en) * 1967-06-02 1970-08-18 Air Reduction Aspirating plasma torch nozzle
FR2171469A5 (fr) * 1972-02-01 1973-09-21 Air Liquide
FR2341247A1 (fr) * 1976-02-16 1977-09-09 Muller Niklaus Torche a arc de plasma
US4122292A (en) * 1976-09-13 1978-10-24 Viktor Nikolaevich Karinsky Electric arc heating vacuum apparatus
EP0500491A1 (fr) * 1991-02-21 1992-08-26 Sulzer Metco AG Appareil de pulvérisation par plasma de matériaux en poudre ou gazeux
EP0500492A1 (fr) * 1991-02-21 1992-08-26 Sulzer Metco AG Appareil de pulvérisation par plasma de matériaux en poudre ou gazeux
DE9215133U1 (de) * 1992-11-06 1993-01-28 Plasma-Technik Ag, Wohlen Plasmaspritzgerät

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US4788408A (en) * 1987-05-08 1988-11-29 The Perkin-Elmer Corporation Arc device with adjustable cathode
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Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3524962A (en) * 1967-06-02 1970-08-18 Air Reduction Aspirating plasma torch nozzle
FR2171469A5 (fr) * 1972-02-01 1973-09-21 Air Liquide
FR2341247A1 (fr) * 1976-02-16 1977-09-09 Muller Niklaus Torche a arc de plasma
US4122292A (en) * 1976-09-13 1978-10-24 Viktor Nikolaevich Karinsky Electric arc heating vacuum apparatus
EP0500491A1 (fr) * 1991-02-21 1992-08-26 Sulzer Metco AG Appareil de pulvérisation par plasma de matériaux en poudre ou gazeux
EP0500492A1 (fr) * 1991-02-21 1992-08-26 Sulzer Metco AG Appareil de pulvérisation par plasma de matériaux en poudre ou gazeux
DE9215133U1 (de) * 1992-11-06 1993-01-28 Plasma-Technik Ag, Wohlen Plasmaspritzgerät

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19610015C2 (de) * 1996-03-14 1999-12-02 Hoechst Ag Thermisches Auftragsverfahren für dünne keramische Schichten und Vorrichtung zum Auftragen
DE102011114406A1 (de) 2011-09-26 2013-03-28 Klaus Landes Plasmaspritzgerät

Also Published As

Publication number Publication date
JPH06228730A (ja) 1994-08-16
CA2102284A1 (fr) 1994-05-07
US5406046A (en) 1995-04-11
ATE137905T1 (de) 1996-05-15
EP0596830B1 (fr) 1996-05-08
CA2102284C (fr) 1999-03-30
JP3287373B2 (ja) 2002-06-04
DE59302504D1 (de) 1996-06-13
DE9215133U1 (de) 1993-01-28

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