EP0604973A1 - Pillingarmes Mischgarn aus Polyester - Google Patents
Pillingarmes Mischgarn aus Polyester Download PDFInfo
- Publication number
- EP0604973A1 EP0604973A1 EP93121003A EP93121003A EP0604973A1 EP 0604973 A1 EP0604973 A1 EP 0604973A1 EP 93121003 A EP93121003 A EP 93121003A EP 93121003 A EP93121003 A EP 93121003A EP 0604973 A1 EP0604973 A1 EP 0604973A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fiber
- polyester
- weight
- staple
- sheath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 71
- 239000000835 fiber Substances 0.000 claims abstract description 110
- 239000004744 fabric Substances 0.000 claims abstract description 54
- 229920001634 Copolyester Polymers 0.000 claims abstract description 14
- 239000011159 matrix material Substances 0.000 claims abstract description 14
- 230000000295 complement effect Effects 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 25
- 229920000742 Cotton Polymers 0.000 claims description 24
- -1 polypropylene Polymers 0.000 claims description 20
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 15
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 14
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 claims description 5
- 229920002994 synthetic fiber Polymers 0.000 claims description 4
- 239000012209 synthetic fiber Substances 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 229920000297 Rayon Polymers 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 239000002964 rayon Substances 0.000 claims description 3
- 210000002268 wool Anatomy 0.000 claims description 3
- QQVIHTHCMHWDBS-UHFFFAOYSA-L isophthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC(C([O-])=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-L 0.000 claims 4
- 238000009960 carding Methods 0.000 claims 2
- 238000009987 spinning Methods 0.000 claims 2
- 239000006187 pill Substances 0.000 description 12
- 238000005299 abrasion Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- 229920013683 Celanese Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000007383 open-end spinning Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
Definitions
- the present invention relates to polyester blended yarn and the use of bicomponent polyester fiber in the polyester blended yarn.
- the fabrics comprising synthetic polymer fibers such as poly(ethylene terephthalate) (PET) fibers, and blends of natural and synthetic fibers have an undesirable propensity upon prolonged use to exhibit small, compact groupings of entangled fibers (i.e., fuzz balls) on the fabric surface.
- Such fiber groupings commonly are termed "pills" and tend to form and to tenaciously adhere to the surface of the fabric as the fabric encounters surface abrasion during normal use.
- the aesthetic appearance of fabric accordingly may be adversely influenced by these relatively compact groupings of entangled fibers which are retained on the surface of the fabrics.
- the pills can be traced to the relatively high strength of the synthetic fibers present in the fabric.
- the pills may be more or less permanently attached to the fabric surface by one or a few synthetic polymer fibers extending out of the fabric which will resist breakage as surface abrasion continues.
- Pills commonly are observed on the fabric formed from blends of cotton and staple poly(ethylene terephthalate) fibers following extended use. While pills may be observed in fabrics having wider variety of constructions, they are frequently observed on loosely constructed fabrics, particularly knitted fabrics using spun yarns of polyester staple fiber and cotton.
- One approach heretofore proposed is to reduce the tendency of the poly(ethylene terephthalate) fibers to pill initially by limiting the molecular weight (measured as the intrinsic viscosity) of the poly(ethylene terephthalate) polymer prior to fiber formation.
- Such reduced intrinsic viscosity provides a general indication of reduced polymeric chain length and leads to fibers having a lesser strength. Accordingly, when such entangled fibers become free on the surface of the fabric following abrasion, they tend to cleanly break away more readily and do not serve as a secure length which retains a fuzz ball at the surface of the fabric.
- polyester fiberfill blends can be made of polyester fibers and binder fibers such as bicomponent fibers.
- binder fibers such as bicomponent fibers.
- such fibers are blended and formed into an unbonded back of the desired weight that is heat treated to melt the chief material of the bicomponent fiber and then cooled to result in a bonded nonwoven fabric.
- a polyester blended yarn consisting essentially of from about 40% to about 70% by weight of matrix staple fiber, from about 1% to 20% by weight of crimped staple bicomponent fiber having a polyester core and a sheath of polyester or a copolyester having a melting point lower than that of the polyester core and complementary to total 100% by weight from about 59% to about 10% of crimped polyester staple fiber of a denier of about 0.5 to less than 10 dpf.
- the instant product overcomes the disadvantages of the prior art because of its simplicity and ease of control. Accordingly, the instant product fulfills a need for a product to render polyester blended yarn, low pilling, which is simple to use, easy to control and readily commercializable.
- the instant invention is directed to a polyester blended yarn consisting of 1% to 20% bicomponent fibers so that the resulting polyester fabric does not pill.
- the polyester blended yarn consists essentially of 40% to 70% by weight of matrix staple fibers and from about 1% to 20% by weight of crimped staple bicomponent fibers and complementary up to a total 100% by weight from about 59% to about 10% of crimped polyester staple fiber.
- the staple fibers used in here are textile fibers having a linear density suitable for wearing apparel, i.e., less than 10 dpf per fiber, preferably less than 6 dpf per fiber in lengths from 0.75 to 2.5 inches. Crimped fibers are particularly preferred for textile aesthetics and processability.
- the matrix staple fiber used in the present invention may be any fiber whether synthetic or natural, used in conjunction with polyester fibers to make fabric.
- Such fibers may be made from cotton, wool, rayon, acrylic, nylon and polypropylene.
- cotton fibers are used in the present invention.
- the next ingredient is a polyester, in particular, poly (ethylene terephthalate) (PET).
- PET polymer can be made by either terephthalic acid or dimethyl terephthalate or copolymer processes, which are well known to those of ordinary skill in the art.
- the third essential ingredient in the blend is bicomponent fiber which is a sheath core fiber, the sheath of which comprises the lower melting binder polymer as suggested in U.S. Patent No. 4,068,036.
- the bicomponent fiber is made up of a polyester core and a sheath of a polyester or a copolyester having a melting point lower than that of the polyester core the polyester staple fibers.
- a preferred sheath material is an ethylene terephthalate/isothalate copolyester.
- the matrix staple fiber is cotton fiber.
- the process for making the fabric involves steps of first preparing a blend of about 40% to about 70% by weight of cotton fibers, from about 1 to about 20% by weight of bicomponent fibers and complementary to total 100% by weight of polyester staple fibers.
- a continuous yarn is spun from the blend.
- the spun yarn should have sufficient twist or entanglement for uses in fabric.
- the presence of cotton in the yarn provides added softness and moisture absorption.
- the fabrics made according to the process are low pill, i.e. they are low pilling fabrics.
- low pill or it's equivalent, means herein that the tested material obtains a value of 4 to 5 as defined by ASTMD3512-82 entitled "Standard Test Method for Pilling Resistance In Other Related Surface Changes Of Textile Fabrics: Random Tumble Pilling Tester Method.”
- the values of 4 or 5 indicates low pill formation whereas values between 1 and 3 indicate various levels of pilling.
- a polyester blended yarn was prepared from a 50/50 blend of a polyester staple fiber having a denier of 0.9 dpf and a length of 1.25 inch, and standard cotton staple fiber.
- the blend was carded to produce a 65 grain/yard sliver intimately blended with the mixture of fibers shown above.
- the sliver was then drawn twice to produce a 56 grain/yard sliver.
- the yarn was then spun on an open-end spinning machine to deliver a 28 singles cotton count yarn.
- the yarn was knitted to produce standard fleece circular knit fabric wherein the yarn was used for face and tie yarns with a normal 15 singles cotton count used as backing yarn.
- the fabric was dyed and finished to produce standard fleece fabric.
- the fabric was tested for pilling by being washed for 60 minutes and rated 1, 2 and 2, unacceptable levels of pilling.
- a polyester blended yarn was prepared from a blend of 10% bicomponent fiber, 40% polyester staple fiber and 50% cotton staple fiber.
- the bicomponent fiber has a polyester core and a copolyester sheath having a denier of 2.0 dpf and a length of 1.5 inch.
- the bicomponent fiber is available as Celbond® K-54 fiber from the Hoechst Celanese Corporation.
- the fabric was tested for pilling by being washed for 60 minutes and rated 5, 5 and 5 indicating low pill formation.
- the bicomponent fiber tends to soften, mill and bind to the contiguous fibers thus producing fiber locking, contributing to the low pilling.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US99977492A | 1992-12-31 | 1992-12-31 | |
| US999774 | 1992-12-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0604973A1 true EP0604973A1 (de) | 1994-07-06 |
| EP0604973B1 EP0604973B1 (de) | 1997-02-26 |
Family
ID=25546668
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP93121003A Expired - Lifetime EP0604973B1 (de) | 1992-12-31 | 1993-12-28 | Pillingarmes Mischgarn aus Polyester |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0604973B1 (de) |
| AT (1) | ATE149215T1 (de) |
| DE (1) | DE69308279T2 (de) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0768406A1 (de) * | 1995-10-11 | 1997-04-16 | Hoechst Trevira GmbH & Co. KG | Textile Flächengebilde hoher Dichte aus Polyesterhybridgarnen, Verfahren zur Herstellung von Verbundwerkstoffen und Verwendung der textilen Flächengebilde |
| WO2000003078A1 (en) * | 1998-07-09 | 2000-01-20 | Wellman, Inc. | Method of producing improved knit fabrics from blended fibers |
| US6221488B1 (en) | 1997-10-14 | 2001-04-24 | Wellman, Inc. | Modified polyester with high intrinsic viscosity at moderate strength |
| WO2003062511A1 (en) * | 2001-12-21 | 2003-07-31 | Invista Technologies S.À.R.L. | Stretch polyester/cotton spun yarn |
| WO2004033772A1 (en) * | 2002-10-04 | 2004-04-22 | Invista Technologies S.À.R.L. | Stretch polyester and acrylic spun yarn |
| EP1956121A1 (de) * | 2001-12-21 | 2008-08-13 | INVISTA Technologies S.à.r.l. | Elastisches gesponnenes Garn aus Polyester/Baumwolle |
| US8513146B2 (en) | 2005-09-29 | 2013-08-20 | Invista North America S.ár.l. | Scalloped oval bicomponent fibers with good wicking, and high uniformity spun yarns comprising such fibers |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102019104834A1 (de) * | 2019-02-26 | 2020-08-27 | W.F. Gözze Frottierweberei GmbH | Verfahren zur rohstofflichen Verwertung kurzfaseriger Baumwollfaserreste |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3104450A (en) * | 1958-01-08 | 1963-09-24 | Du Pont | Textile material |
| CA808866A (en) * | 1969-03-25 | Kenneth C. Mcalister, Jr. | Pill resistant polyester fabrics | |
| US3576773A (en) * | 1968-06-04 | 1971-04-27 | Rhodiaceta | Polyester based fibers comprising a non-linear branched ethylene terephthalate polymers |
| GB1524857A (en) * | 1974-10-30 | 1978-09-13 | Du Pont | Flame-resistant textile fibre blends |
| US4270913A (en) * | 1979-07-06 | 1981-06-02 | Celanese Corporation | Pill-resistant polyester fabrics |
| EP0086630A2 (de) * | 1982-02-11 | 1983-08-24 | E.I. Du Pont De Nemours And Company | Polyestergarn |
-
1993
- 1993-12-28 AT AT93121003T patent/ATE149215T1/de not_active IP Right Cessation
- 1993-12-28 DE DE69308279T patent/DE69308279T2/de not_active Expired - Fee Related
- 1993-12-28 EP EP93121003A patent/EP0604973B1/de not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA808866A (en) * | 1969-03-25 | Kenneth C. Mcalister, Jr. | Pill resistant polyester fabrics | |
| US3104450A (en) * | 1958-01-08 | 1963-09-24 | Du Pont | Textile material |
| US3576773A (en) * | 1968-06-04 | 1971-04-27 | Rhodiaceta | Polyester based fibers comprising a non-linear branched ethylene terephthalate polymers |
| GB1524857A (en) * | 1974-10-30 | 1978-09-13 | Du Pont | Flame-resistant textile fibre blends |
| US4270913A (en) * | 1979-07-06 | 1981-06-02 | Celanese Corporation | Pill-resistant polyester fabrics |
| EP0086630A2 (de) * | 1982-02-11 | 1983-08-24 | E.I. Du Pont De Nemours And Company | Polyestergarn |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0768406A1 (de) * | 1995-10-11 | 1997-04-16 | Hoechst Trevira GmbH & Co. KG | Textile Flächengebilde hoher Dichte aus Polyesterhybridgarnen, Verfahren zur Herstellung von Verbundwerkstoffen und Verwendung der textilen Flächengebilde |
| US6250060B1 (en) | 1997-04-18 | 2001-06-26 | Wellman, Inc. | Method of producing improved knit fabrics from blended fibers |
| US6221488B1 (en) | 1997-10-14 | 2001-04-24 | Wellman, Inc. | Modified polyester with high intrinsic viscosity at moderate strength |
| WO2000003078A1 (en) * | 1998-07-09 | 2000-01-20 | Wellman, Inc. | Method of producing improved knit fabrics from blended fibers |
| WO2003062511A1 (en) * | 2001-12-21 | 2003-07-31 | Invista Technologies S.À.R.L. | Stretch polyester/cotton spun yarn |
| US7036299B2 (en) | 2001-12-21 | 2006-05-02 | Invista North America S.A.R.L. | Stretch polyster/cotton spun yarn |
| US7240476B2 (en) | 2001-12-21 | 2007-07-10 | Invista North America S.àr.l. | Stretch polyester/cotton spun yarn |
| EP1956121A1 (de) * | 2001-12-21 | 2008-08-13 | INVISTA Technologies S.à.r.l. | Elastisches gesponnenes Garn aus Polyester/Baumwolle |
| CN100467686C (zh) * | 2001-12-21 | 2009-03-11 | 因维斯塔技术有限公司 | 弹力聚酯/棉纱 |
| WO2004033772A1 (en) * | 2002-10-04 | 2004-04-22 | Invista Technologies S.À.R.L. | Stretch polyester and acrylic spun yarn |
| US8513146B2 (en) | 2005-09-29 | 2013-08-20 | Invista North America S.ár.l. | Scalloped oval bicomponent fibers with good wicking, and high uniformity spun yarns comprising such fibers |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0604973B1 (de) | 1997-02-26 |
| DE69308279T2 (de) | 1997-07-10 |
| ATE149215T1 (de) | 1997-03-15 |
| DE69308279D1 (de) | 1997-04-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR112020026622A2 (pt) | Fio fiado, tecido e artigo | |
| EP0604973B1 (de) | Pillingarmes Mischgarn aus Polyester | |
| JP2000303283A (ja) | 長短複合糸 | |
| JP2543624B2 (ja) | 熱接着性繊維 | |
| JPH03227408A (ja) | 芯鞘型複合繊維 | |
| JP3238828B2 (ja) | ダンボールニット | |
| JP2001295164A (ja) | 起毛編地およびその縫製品 | |
| JPS62184119A (ja) | 熱接着性長繊維 | |
| JP4663186B2 (ja) | ポリ乳酸ステレオコンプレックス繊維の製造方法 | |
| JP4922232B2 (ja) | ポリ乳酸繊維およびそれを用いてなる繊維製品 | |
| JPH07292547A (ja) | ダンボールニット | |
| JP2003055848A (ja) | 抗ピル性および伸縮性に優れた長短複合糸 | |
| JP3173311B2 (ja) | 不織布用芯鞘複合短繊維 | |
| JP7284882B1 (ja) | 編地、その製造方法及びそれを含む衣料 | |
| JPH02264016A (ja) | 熱接着性複合繊維 | |
| JP3499919B2 (ja) | ウールタフトカーペット | |
| JP3307383B2 (ja) | ポリエステル中空短繊維 | |
| JP2000034636A (ja) | モップ用芯鞘型長短複合紡績糸およびそれを用いてなるモップ | |
| JPS62117869A (ja) | カ−ペツトおよびその製造法 | |
| JPH09302526A (ja) | 紡毛糸および紡毛布帛 | |
| JPH0593356A (ja) | タフテツドカーペツト用基布 | |
| JPH09241949A (ja) | 編地の製造方法 | |
| Lulay | Apparel end uses | |
| JPH0147569B2 (de) | ||
| JP2000220055A (ja) | 嵩高織編物の製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU NL PT SE |
|
| 17P | Request for examination filed |
Effective date: 19940803 |
|
| GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
| GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
| 17Q | First examination report despatched |
Effective date: 19960531 |
|
| GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU NL PT SE |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 19970226 Ref country code: LI Effective date: 19970226 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRE;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.SCRIBED TIME-LIMIT Effective date: 19970226 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 19970226 Ref country code: FR Effective date: 19970226 Ref country code: ES Free format text: THE PATENT HAS BEEN ANNULLED BY A DECISION OF A NATIONAL AUTHORITY Effective date: 19970226 Ref country code: DK Effective date: 19970226 Ref country code: CH Effective date: 19970226 Ref country code: BE Effective date: 19970226 Ref country code: AT Effective date: 19970226 |
|
| REF | Corresponds to: |
Ref document number: 149215 Country of ref document: AT Date of ref document: 19970315 Kind code of ref document: T |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
| REF | Corresponds to: |
Ref document number: 69308279 Country of ref document: DE Date of ref document: 19970403 |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: 72247 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Effective date: 19970526 Ref country code: PT Effective date: 19970526 |
|
| EN | Fr: translation not filed | ||
| NLV1 | Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act | ||
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19971228 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19971228 Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19971228 |
|
| 26N | No opposition filed | ||
| GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 19971228 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19980901 |