Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
  • C08G18/72—Polyisocyanates or polyisothiocyanates
  • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
  • C08G18/78—Nitrogen
  • C08G18/7806—Nitrogen containing -N-C=0 groups
  • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
  • C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/08—Processes
  • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
  • C08G18/2805—Compounds having only one group containing active hydrogen
  • C08G18/2815—Monohydroxy compounds
  • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
  • C08G18/72—Polyisocyanates or polyisothiocyanates
  • C08G18/80—Masked polyisocyanates
  • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
  • C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
  • C08G18/8041—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3271
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
  • C08G18/72—Polyisocyanates or polyisothiocyanates
  • C08G18/80—Masked polyisocyanates
  • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
  • C08G18/8048—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/34
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
  • C08G18/72—Polyisocyanates or polyisothiocyanates
  • C08G18/80—Masked polyisocyanates
  • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
  • C08G18/8064—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
  • D06B11/00—Treatment of selected parts of textile materials, e.g. partial dyeing
  • D06B11/0079—Local modifications of the ability of the textile material to receive the treating materials, (e.g. its dyeability)
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
  • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
  • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
  • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
  • D06L4/30—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using reducing agents
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
  • D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
  • D06P1/228—Indigo
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
  • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
  • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
  • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
  • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
  • D06P1/5257—(Meth)acrylic acid
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
  • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
  • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
  • D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
  • D06P1/5285—Polyurethanes; Polyurea; Polyguanides
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
  • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
  • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
  • D06P1/54—Substances with reactive groups together with crosslinking agents
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
  • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
  • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
  • D06P1/607—Nitrogen-containing polyethers or their quaternary derivatives
  • D06P1/6073—Nitrogen-containing polyethers or their quaternary derivatives containing CON=, OCON=, SO2N=, OSO2N= groups
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
  • D06P5/15—Locally discharging the dyes
  • D06P5/158—Locally discharging the dyes with other compounds

Definitions

• the present invention relates to an improved process for the production of patterned textiles and the use of hydrophilically modified polyisocyanates together with suitable binders in this process.
• the usual procedure is to produce the pattern either by printing a reservation agent before dyeing (the reserved areas cannot be stained) or by etching out with an etching paste after dyeing and then washing out the etching paste .
• Printing pastes are used as reservation agents, which have to be thermally fixed and normally contain formaldehyde.
• Etching pastes are also disadvantageous, especially because they usually react strongly alkaline.
• the object of the present application was to provide a process for the production of patterned textiles which, for reasons of process simplification, textile protection, energy saving and ecology, dispenses with the reservation agents and etching agents customary for textile printing and does not require any additional dye.
• a process has been found for the production of patterned textiles, which is characterized in that colored textile material is printed with a suitable ink-holding agent and then the pattern is produced by washing out the dye at the non-printed areas.
• the process according to the invention gives particularly excellent results when hydrophilic modified polyisocyanates are used together with suitable binders as the color holding agent.
• DE-A 42 17 716 describes the use of polyisocyanate mixtures with an average NCO functionality of 1.8 to 4.2 and a content of (cyclo) aliphatically bound isocyanate groups of 12.0 to 21.5% by weight, where these polyisocyanates can also be hydrophilically modified, recommended as a crosslinking agent for binders used in textile printing pastes.
• hydrophilically modified polyisocyanates used according to the invention are customary diisocyanates and / or customary higher-functionality polyisocyanates with an average NCO functionality of 2.0 to 4.5. These components can be present alone or in a mixture.
• customary diisocyanates are aliphatic diisocyanates such as tetramethylene diisocyanate, hexamethylene diisocyanate (1,6-diisocyanatohexane), octamethylene diisocyanate, decamethylene diisocyanate, dodecamethylene diisocyanate, tetradecamethylene diisocyanate, trimethylhexane diisocyanate or tetramethylhexalodipane diisocyanate, 1,3-diisocyanate, 1,4-diisocyanate, 1,4-diisocyanate, 1,4-diisocyanate, 4,4'-di (isocyanatocyclohexyl) methane, 1-isocyanato-3,3,5-trimethyl-5- (isocyanatomethyl) cyclohexane (isophorone diisocyanate) or 2,4'- or 2,6-diisocyanato-1-methyl
• Suitable customary higher-functional polyisocyanates are, for example, triisocyanates such as 2 - 4,6-triisocyanatotoluene or 2,4,4-triisocyanatodiphenyl ether or the mixtures of di-, tri- and higher polyisocyanates which are obtained by phosgenation of corresponding aniline / formaldehyde condensates and represent polyphenyl polyisocyanates having methylene bridges.
• Aliphatic diisocyanates and aliphatic higher-functional polyisocyanates are particularly preferred for the use according to the invention.
• the described diisocyanates and / or higher functionalized polyisocyanates are converted into non-ionically hydrophilically modified polyisocyanates, which are particularly preferred for the use according to the invention, with NCO-reactive compounds, the hydrophilic structural elements with nonionic groups or with polar groups that are not can be converted into ion groups.
• the diisocyanate or polyisocyanate is in a stoichiometric excess so that the resulting hydrophilically modified polyisocyanate still has free NCO groups.
• ethylene oxide or propylene oxide polyethers started on C 1 to C 4 alkanol with average molecular weights of 250 to 7000, in particular 450 to 1500.
• the diisocyanates and / or higher functionalized polyisocyanates described can also be obtained first by reaction with a deficit of hydroxyl-terminated polyesters, on other hydroxyl-terminated polyethers or on polyols, e.g. Generate ethylene glycol, trimethylolpropane or butanediol, prepolymers and then implement these prepolymers subsequently or simultaneously with the polyethers I in deficit to the hydrophilically modified polyisocyanates with free NCO groups.
• non-ionically hydrophilically modified polyisocyanates from diisocyanate or polyisocyanate and polyalkylene glycols of the formula HO- (AO) nH, in which A and n have the meanings given above. Both terminal OH groups of the polyalkylene glycol react with isocyanate.
• non-ionically hydrophilically modified polyisocyanates are in the documents DE-A 24 47 135, DE-A 26 10 552, DE-A 29 08 844, EP-A 013 112, EP-A 019 844, DE-A 40 36 927, DE-A 41 36 618, EP-B 206 059, EP-A 464 781 and EP-A 516 361.
• the described diisocyanates and / or higher functionalized polyisocyanates are converted into NCO-reactive compounds for conversion into anionically hydrophilically modified polyisocyanates which contain hydrophilic anionic groups, in particular acid groups such as carboxyl groups, sulfonic acid groups or phosphonic acid groups.
• the diisocyanate or polyisocyanate is present in a stoichiometric excess so that the resulting hydrophilically modified polyisocyanate still has free NCO groups.
• NCO-reactive compounds with anionic groups come especially hydroxycarboxylic acids such as 2-hydroxyacetic acid, 3-hydroxypropionic acid, 4-hydroxybutyric acid or hydroxypivalic acid and 2,2,2-tris and 2,2-bis (hydroxymethyl) alkanoic acids, e.g. 2,2-bis (hydroxymethyl) acetic acid, 2,2-bis (hydroxymethyl) propionic acid, 2,2-bis (hydroxymethyl) butyric acid or 2,2,2-tris (hydroxymethyl) acetic acid.
• the carboxyl groups can be partially or completely neutralized by a base in order to be in a water-soluble or water-dispersible form.
• the base used here is preferably a tertiary amine, which is known to be inert to isocyanate.
• the described diisocyanates and / or more highly functionalized polyisocyanates can also be reacted with a mixture of nonionically hydrophilically modifying and anionically hydrophilically modifying compounds which are added in succession or simultaneously, for example with a deficit of the polyethers I and the described hydroxycarboxylic acids.
• anionically hydrophilically modified polyisocyanates are described in more detail in the documents DE-A 40 01 783, DE-A 41 13 160 and DE-A 41 42 275.
• the described diisocyanates and / or higher functionalized polyisocyanates are converted to NCO-reactive compounds for conversion into cationically hydrophilically modified polyisocyanates which contain chemically incorporated alkylatable or protonatable functions with the formation of a cationic center.
• such functions are tertiary nitrogen atoms, which are known to be inert to isocyanate and can be easily quaternized or protonated.
• Particularly suitable amino alcohols II are N-methyldiethanolamine, N-methyldi (iso) propanolamine, N-butyldiethanolamine, N-butyldi (iso) propanolamine, N-stearyldiethanolamine, N-stearyldi (iso) propanolamine, N, N-dimethylethanolamine, N , N-dimethyl (iso) propanolamine, N, N-diethylethanolamine, N, N-diethyl (iso) propanolamine, N, N-dibutylethanolamine, N, N-dibutyl (iso) propanolamine, triethanolamine, tri (iso) propanolamine, N - (2-Hydroxyethyl) morpholine, N- (2-hydroxylpropyl) morpholine, N- (2-hydroxyethyl) piperidine, N- (2-hydroxypropyl) piperidine, N-methyl-
• NCO-reactive compounds with tertiary nitrogen atoms are preferably diamines of the general formula IIIa or IIIb in which R 2 to R 4 have the meanings given above and R 5 denotes C 1 to C 5 alkyl or forms a five- or six-membered ring, in particular a piperazine ring, with R 2 .
• Particularly suitable diamines IIIa are N, N-dimethylethylenediamine, N, N-diethylethylenediamine, N, N-dimethyl-1,3-diamino-2,2-dimethylpropane, N, N-diethyl-1,3 -propylenediamine, N- (3-aminopropyl) morpholine, N- (2-aminopropyl) morpholine, N- (3-aminopropyl) piperidine, N- (2-aminopropyl) piperidine, 4-amino-1- (N, N- diethylamino) pentane, 2-amino-1- (N, N-dimethylamino) propane, 2-amino-1- (N, N-diethylamino) propane or 2-amino-1- (N, N-dimethylamino) -2- methyl propane.
• Particularly suitable diamines IIIb are N, N, N'-trimethylethylenediamine, N, N, N'-triethylethylenediamine, N-methylpiperazine or N-ethylpiperazine.
• polyether (poly) ols with built-in tertiary nitrogen atoms which can be prepared by propoxylation and / or ethoxylation of starter molecules containing amine nitrogen, can also be used as NCO-reactive compounds.
• Such polyether (poly) oles are, for example, the propoxylation and ethoxylation products of ammonia, ethanolamine, diethanolamine, ethylenediamine or N-methylaniline.
• NCO-reactive compounds which can be used are polyester and polyamide resins having tertiary nitrogen atoms, polyols containing urethane groups and tertiary nitrogen atoms, and polyhydroxy polyacrylates having tertiary nitrogen atoms.
• the described diisocyanates and / or higher functionalized polyisocyanates can also be mixed with a mixture of non-ionically hydrophilically modifying and cationically hydrophilically modifying Compounds which are added in succession or simultaneously are reacted, for example with a deficit of the polyethers I and the amino alcohols II or the diamines IIIa or IIIb. Mixtures of nonionically hydrophilically modifying and anionically hydrophilically modifying compounds are also possible.
• hydrophilically modified polyisocyanates described can be incorporated into the printing pastes to be used according to the invention in undiluted form or dissolved in inert organic solvents.
• Solvents suitable for this are described, for example, in DE-A 35 21 618 and in German patent application P 44 29 446.8.
• inert organic solvents are ethyl acetate, acetone, methyl ethyl ketone, carbonic acid esters such as diethyl carbonate, 1,2-ethylene carbonate or 1,2-propylene carbonate, and lactones such as ⁇ -propiolactone, ⁇ -butyrolactone or ⁇ -caprolactone.
• Polyacrylates or polyurethanes or mixtures thereof are particularly suitable as binders.
• suitable polyacrylates are polyacrylic acids, polymethacrylic acids, copolymers of acrylic or methacrylic acid and acrylic or methacrylic acid esters, copolymers of acrylamide and acrylic acid and copolymers of acrylamide and hydroxyalkyl acrylates.
• Suitable polyurethanes here are, for example, those as described in DE-A 26 45 779 and US-A 4 092 286.
• the binders used are usually used as aqueous dispersions.
• the color-retaining agents to be used according to the invention can also contain auxiliaries customary for printing pastes, in particular thickeners, wetting agents or preservatives.
• the thickeners used are preferably those which are stable to electrolytes and are easy to wash out. Both natural-based thickeners, e.g. Alginates, as well as those used on a synthetic basis.
• Textiles or textile material are understood to mean both fabrics and items of clothing made from them.
• the method according to the invention is applied to textile material dyed with indigo. These are usually cotton textiles (denim). But even on textiles made of cotton or cotton-containing material dyed with other vat dyes, the method according to the invention can be used to produce patterns with excellent results.
• the dye is washed out at the non-printed areas completely or partially, i.e. in the latter case there is a lightening of the color compared to the printed areas, so that the pattern clearly stands out. Depending on the degree of washing out, this lightening is more or less strong.
• the unprinted areas are brightened, for example, by washing with stones or sand.
• the dye can also be washed out by treatment with enzymes or with reducing agents, it being possible for the dye to be completely removed at the non-printed areas.
• the method according to the invention allows patterned textiles, in particular cotton textiles dyed with indigo, to be produced by a simple, material-saving and energy-saving method of operation, since no thermal fixing steps are necessary.
• the textile material only needs to be dyed once, an additional dye application, for example after printing with the dye-holding agent, is not necessary. It was surprising that the mixtures of hydrophilically modified polyisocyanates and binders which are preferably used have such a washing resistance even when washing under drastic mechanical stress (stones, sand) and hold the dye on the printed areas practically without loss of authenticity.
• a biuret polyisocyanate based on hexamethylene diisocyanate which consisted essentially of N, N ', N "-Tris (6-isocyanatohexyl) biuret and its higher homologues, with an NCO content of 21.9%, a content of monomeric hexamethylene diisocyanate of less than 0.5% by weight, a viscosity at 23 ° C. of 2.9 Pa ⁇ s and an average NCO functionality of 3.3, which was obtained after cooling a clear resin with an NCO content of 18.1 wt .-% and a viscosity at 23 ° C of 3900 mPa ⁇ s.

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• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Organic Chemistry (AREA)
• Polymers & Plastics (AREA)
• Health & Medical Sciences (AREA)
• Manufacturing & Machinery (AREA)
• Materials Engineering (AREA)
• Polyurethanes Or Polyureas (AREA)
• Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
• Coloring (AREA)

Applications Claiming Priority (2)

Publications (3)

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• 1995
  • 1995-01-16 DE DE19501055A patent/DE19501055A1/de not_active Withdrawn
• 1996
  • 1996-01-09 EP EP96100202A patent/EP0726352B1/fr not_active Expired - Lifetime
  • 1996-01-09 ES ES96100202T patent/ES2199263T3/es not_active Expired - Lifetime
  • 1996-01-09 PT PT96100202T patent/PT726352E/pt unknown
  • 1996-01-09 DE DE59610411T patent/DE59610411D1/de not_active Expired - Lifetime

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