EP0745005A1 - Procede de stockage de dechets heterogenes - Google Patents

Procede de stockage de dechets heterogenes

Info

Publication number
EP0745005A1
EP0745005A1 EP95909632A EP95909632A EP0745005A1 EP 0745005 A1 EP0745005 A1 EP 0745005A1 EP 95909632 A EP95909632 A EP 95909632A EP 95909632 A EP95909632 A EP 95909632A EP 0745005 A1 EP0745005 A1 EP 0745005A1
Authority
EP
European Patent Office
Prior art keywords
waste
inert gas
bunker
atmosphere
carbon dioxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP95909632A
Other languages
German (de)
English (en)
Other versions
EP0745005B1 (fr
Inventor
Günter H. KISS
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Thermoselect AG
Original Assignee
Thermoselect AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thermoselect AG filed Critical Thermoselect AG
Publication of EP0745005A1 publication Critical patent/EP0745005A1/fr
Application granted granted Critical
Publication of EP0745005B1 publication Critical patent/EP0745005B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F13/00—Illuminated signs; Luminous advertising
    • G09F13/16—Signs formed of or incorporating reflecting elements or surfaces, e.g. warning signs having triangular or other geometrical shape
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00—Component parts, details or accessories for large containers
    • B65D90/22—Safety features
    • B65D90/38—Means for reducing the vapour space or for reducing the formation of vapour within containers
    • B65D90/44—Means for reducing the vapour space or for reducing the formation of vapour within containers by use of inert gas for filling space above liquid or between contents
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F13/00—Illuminated signs; Luminous advertising
    • G09F13/04—Signs, boards or panels, illuminated from behind the insignia
    • G09F13/0418—Constructional details
    • G09F13/0472—Traffic signs
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S220/00—Receptacles
    • Y10S220/908—Trash container

Definitions

  • the invention relates to a method for storing heterogeneous waste in intermediate or storage facilities according to the preamble of claim 1.
  • Ignition sources such as furnace ash, chemicals and metal parts are introduced in an uncontrolled manner.
  • aerobic and anaerobic processes take place in the bunker, which can cause, among other things, increases in temperature up to self-ignition.
  • Garbage bins are therefore potential hazards within the meaning of the Accident Ordinance.
  • Significant and extremely negative effects are to be expected in the event of accidents.
  • the plant areas mentioned here are exemplary plant areas in which the obvious dangers can lead to completely different types of accidents (J. Look, TÜV invention / Saxony, safety technology in waste incineration plants with regard to the Accident Ordinance, conference thermal disposal of waste and residues, December 9 and 10, 1993, Cologne).
  • the essential dangerous substances released in the event of fire are - heavy metal compounds, acid gases,
  • Another, resulting from the temporary or storage storage of the garbage represents the methane formation resulting from possible decomposition processes. Mixed with air, an ignitable gas mixture can result which can lead to a gross risk of explosion.
  • Garbage bunkers only in the event of a fire, so far there have been no specific measures to prevent fire.
  • Garbage bunkers that meet existing fire protection requirements must among other things have firewalls, temperature-resistant suction devices, smoke and heat flaps, emergency power-supplied safety devices, fire monitoring systems, extinguishing systems, charging options for bunker fires and infrared cameras for possible localization of the source of the fire. Since garbage bunker fires do not generally occur on the surface but within the stored garbage, the fire protection equipment required is insufficiently suitable, despite infrared cameras, to locate the source of the fire precisely and to combat it, and certainly not suitable, to prevent it from occurring.
  • the disposal security is to be increased significantly, while reducing the operating costs at the same time.
  • the inert gas atmosphere in the refuse bunker deviates from the outside pressure, there is no odor nuisance in the bunker environment in the event of a slight negative pressure in the bunker.
  • suitable ter pressure locks By means of suitable ter pressure locks, the inert gas atmosphere can be safely sealed off from the outside air.
  • the garbage introduced into the inert atmosphere generally contains only small amounts of oxygen. During its subsequent degassing in the case of thermal treatment, the formation of organic pollutants, such as Dioxins and furans, largely suppressed.
  • the gasification of the carbon components present in the heterogeneous mixture is carried out with the aid of more or less pure oxygen.
  • the waste is first compressed, thermally pretreated in this state with the exclusion of air, and the carbon thus obtained is subsequently processed with the aid of oxygen. guest.
  • Metal components in the garbage can be melted out, non-metallic garbage components can be mineralized in a leach-proof manner.
  • the disposal material to be advantageously processed by this method is stored in the presence of atmospheric oxygen before it is compressed.
  • the formation of fire nests in the upstream garbage bunker, for example by introducing embers or the like. is ultimately not to be prevented there.
  • the oxygen required in the known method in the high temperature stage is obtained by air separation.
  • the waste product is the nitrogen required for the inert gas atmosphere in the storage bunker in a form that can be used directly.
  • the inert gas loading of the garbage with this atmospheric nitrogen therefore does not cause any additional costs, rather it considerably reduces investment and operating costs.
  • the carbon dioxide component if it can be used in the system for this purpose, can also be used as an inert gas atmosphere.
  • exhaust gases contain, after thermal use of the synthesis gas, carbon dioxide, which is separated by means of conventional processes and used as an inert gas for storing the waste, i.e. can be used for specifying the inert atmosphere.
  • the waste heat from the system can be used to separate carbon dioxide.
  • synthesis gas is generated in a thermal waste treatment using the aforementioned method, this can contain up to 30% carbon dioxide, which then can be separated and used as an inert gas for storing the waste in this inert atmosphere.
  • the waste heat from the system itself can advantageously be used to separate carbon dioxide.
  • the method according to the invention can also be used in any other conventional waste incineration plant, since the flue gases of these waste incineration plants contain carbon dioxide, which can be separated using standard processes and used as inert gases for the permanent storage of the waste in an inert atmosphere, with carbon dioxide separation Waste heat from the system is usable.
  • Carbon dioxide as an inert gas has the additional advantage that the inert gas drawn off from the bunker can be fed from the high-temperature range to a thermal treatment plant, detoxified there and, if necessary, included in the gasification process.
  • the inert gas atmosphere is monitored for residual gas components, especially for oxygen residues and methane components.
  • Such monitoring is desirable not only in the actual bunker area, but also in the area of the pressure locks.
  • the method according to the invention guarantees the greatest possible availability of the respective system with correspondingly improved disposal security. Since active and passive fire protection measures can be dispensed with, considerable cost savings can be achieved. Due to the lack of fire risk, considerably lower fire insurance premiums are payable.

Landscapes

  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Geometry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Fire-Extinguishing Compositions (AREA)

Abstract

La présente invention concerne un procédé de stockage de déchets hétérogènes dans des zones de dépôt intermédiaire ou de réserve, tels que silos ou conteneurs à déchets appropriés, avant leur prélèvement, leur traitement thermique ou tout autre traitement ultérieur. Ce procédé doit pratiquement exclure tout danger d'incendie et d'explosion de gaz, supprimer les processus de décomposition aérobie, ralentir la décomposition aérobie, éviter, dans la mesure du possible, la formation ultérieure de dioxines et de furannes lors de traitements thermiques ultérieures et exclure de façon fiable l'attaque des stocks par de la vermine. En évitant ou au moins en réduisant les perturbations aux alentours du silo, la sécurité de l'élimination des déchets doit être notablement améliorée. A cet effet, le stockage des déchets se fait en atmosphère essentiellement inerte, empêchant les incendies.
EP95909632A 1994-02-15 1995-02-15 Procede de stockage de dechets heterogenes Expired - Lifetime EP0745005B1 (fr)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
DE4404679 1994-02-15
DE4404679 1994-02-15
DE4407107 1994-03-01
DE4407107 1994-03-01
DE4420449 1994-06-10
DE4420449A DE4420449C5 (de) 1994-02-15 1994-06-10 Verfahren zum Lagern von heterogenem Müll
PCT/DE1995/000191 WO1995021708A1 (fr) 1994-02-15 1995-02-15 Procede de stockage de dechets heterogenes

Publications (2)

Publication Number Publication Date
EP0745005A1 true EP0745005A1 (fr) 1996-12-04
EP0745005B1 EP0745005B1 (fr) 1998-06-24

Family

ID=27206081

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95909632A Expired - Lifetime EP0745005B1 (fr) 1994-02-15 1995-02-15 Procede de stockage de dechets heterogenes

Country Status (8)

Country Link
US (1) US6199493B1 (fr)
EP (1) EP0745005B1 (fr)
JP (1) JP3115327B2 (fr)
AT (1) ATE167644T1 (fr)
DE (2) DE4420449C5 (fr)
DK (1) DK0745005T3 (fr)
ES (1) ES2118570T3 (fr)
WO (1) WO1995021708A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE230789T1 (de) * 1996-10-29 2003-01-15 Thermoselect Ag Verfahren zur vollständigen stofflichen, emissionslosen nutzung durch hochtemperatur- recycling und durch fraktionierte stofflich spezifische konvertierung des entstehenden synthese-rohgases
US6196765B1 (en) * 1998-11-06 2001-03-06 Joseph G. Harrington Inhibiting acid mine drainage by displacing oxygen in rock heap
US6991405B2 (en) 2002-09-03 2006-01-31 Terraquest Technologies, Ltd. Application of inert gas mixtures to prevent and/or to control sulfide mineral oxidation and the generation of acid rock drainage
DE102005004585A1 (de) * 2005-02-01 2006-08-10 Linde Ag Verfahren zur Brandbekämpfung
US20090020296A1 (en) * 2007-07-19 2009-01-22 Lee Ron C Method for extinguishing a fire in a silo
US20090178814A1 (en) * 2008-01-11 2009-07-16 Michael Heisel Method for extinguishing a smouldering fire in a silo
CN102161047B (zh) * 2010-12-08 2012-12-12 沈阳大学 一种用于固体废弃物厌氧生物修复的实验装置
GB2493460A (en) * 2012-08-02 2013-02-06 Linde Ag Fire Prevention in Storage Silos
GB201415623D0 (en) * 2014-09-04 2014-10-22 Linde Ag Prevention of combustion in storage silos
US9428310B2 (en) * 2014-10-27 2016-08-30 White Donna M Cover for open top food containers
CN112520205A (zh) * 2020-12-22 2021-03-19 广州市净水有限公司 活性污泥保鲜运输装置

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1803460A (en) * 1926-12-15 1931-05-05 Brooks Engineering Corp Fire prevention system for tanks
GB301413A (en) * 1927-06-25 1928-11-26 James John Cantley Brand Improvements in or relating to the storage and handling of powdered fuel and to the potection of bunkers or like storage apparatus against spontaneous combustion
US1849932A (en) * 1928-07-25 1932-03-15 Sidney P Johnson Method and apparatus for preventing fire hazards in operating upon and cleaning containers of inflammable liquids or gases
US2551216A (en) * 1945-06-07 1951-05-01 Smith Corp A O Silo
US2964916A (en) * 1957-10-14 1960-12-20 British Oxygen Co Ltd Production of inert atmospheres in storage vessels, fuel tanks and the like
DE2046452C3 (de) * 1970-09-21 1979-10-11 Liquid Gas International Gmbh, 5480 Remagen Verfahren und Vorrichtung zum Gasbzw. Luftfreimachen von Flüssiggasbehältern auf Tankschiffen
US3691730A (en) * 1971-05-18 1972-09-19 Parker Hannifin Corp Fuel tank inerting system
US3820687A (en) * 1973-03-05 1974-06-28 Astec Ind Apparatus for providing a non-reacting atmosphere within a storage bin
DD147188A3 (de) * 1977-09-19 1981-03-25 Lutz Barchmann Verfahren und vorrichtung zur druckvergasung staubfoermiger brennstoffe
US4384536A (en) * 1981-03-31 1983-05-24 Foster Wheeler Energy Corporation Desulfurization and improvement of combustion and gasification characteristics of coals
JPS5943736A (ja) * 1982-09-03 1984-03-10 Hitachi Zosen Corp 微粉炭の貯蔵方法
GB8824276D0 (en) * 1988-10-17 1988-11-23 Telektron Ltd Pressuring & purging apparatus
WO1990005098A1 (fr) * 1988-11-08 1990-05-17 Bon Bon Plastic Products Pty. Ltd. Conteneur a ordures
DE3906006C1 (fr) * 1989-02-27 1990-08-30 Kali Und Salz Ag, 3500 Kassel, De
US4934286A (en) * 1989-08-24 1990-06-19 Fowler Benjamin P Apparatus and method for the disposal of waste
DE9104259U1 (de) * 1991-04-09 1991-06-06 Schönmackers Umweltdienste Sonderabfall GmbH & Co. KG, 4152 Kempen Vorrichtung zum Zerkleinern von Abfallstoffen oder Abfallgebinden
DE4130416C1 (fr) * 1991-09-10 1992-12-10 Thermoselect Ag, Vaduz, Li
US5282931A (en) * 1992-07-08 1994-02-01 Pulp And Paper Research Institute Of Canada Determination and control of effective alkali in kraft liquors by IR spectroscopy
DE4315193A1 (de) * 1993-05-07 1994-11-10 Aicher Max Verfahren zur Behandlung von Abfällen, insbesondere Hausmüll
TW201526943A (zh) 2013-10-09 2015-07-16 Yasuhiro Nagaoka 化妝料用套件、毛髮處理劑用套件以及毛髮處理方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9521708A1 *

Also Published As

Publication number Publication date
JP3115327B2 (ja) 2000-12-04
DE4420449C5 (de) 2004-02-05
ES2118570T3 (es) 1998-09-16
DK0745005T3 (da) 1998-11-16
EP0745005B1 (fr) 1998-06-24
JPH09506033A (ja) 1997-06-17
ATE167644T1 (de) 1998-07-15
DE4420449C2 (de) 1996-05-30
DE59502652D1 (de) 1998-07-30
US6199493B1 (en) 2001-03-13
WO1995021708A1 (fr) 1995-08-17
DE4420449A1 (de) 1995-08-17

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