EP0761809A3 - Bleichmittelzusammensetzung enthaltend Polyoxometallate als Bleichmittelkatalysator - Google Patents

Bleichmittelzusammensetzung enthaltend Polyoxometallate als Bleichmittelkatalysator Download PDF

Info

Publication number
EP0761809A3
EP0761809A3 EP96113058A EP96113058A EP0761809A3 EP 0761809 A3 EP0761809 A3 EP 0761809A3 EP 96113058 A EP96113058 A EP 96113058A EP 96113058 A EP96113058 A EP 96113058A EP 0761809 A3 EP0761809 A3 EP 0761809A3
Authority
EP
European Patent Office
Prior art keywords
polyoxometalates
bleaching composition
bleach catalyst
bleaching
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP96113058A
Other languages
English (en)
French (fr)
Other versions
EP0761809B1 (de
EP0761809A2 (de
Inventor
Gerd Dr. Reinhardt
Vera Friderichs
Bernd Dr. Scharbert
Rolf Peter Dr. Schulz
Bernt Prof. Dr. Krebs
Rainer Dl. Böhner
Christian Dl. Thülig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Produkte Deutschland GmbH
Original Assignee
Hoechst AG
Clariant GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Clariant GmbH filed Critical Hoechst AG
Publication of EP0761809A2 publication Critical patent/EP0761809A2/de
Publication of EP0761809A3 publication Critical patent/EP0761809A3/de
Application granted granted Critical
Publication of EP0761809B1 publication Critical patent/EP0761809B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

Bleichmittelzusammensetzung enthaltend ein oder mehrere Bleichmittel und einen oder mehrere Polyoxometallate der Formel (Q)q (AaXxMmOyZz(H2O)b·cH2O als Bleichkatalysator, wobei die Symbole Q, A, X, M, Z, q, a, x, m, y, z, b und c die in der Beschreibung genannten Bedeutung haben.
EP96113058A 1995-08-22 1996-08-14 Bleichmittelzusammensetzung enthaltend Polyoxometallate als Bleichmittelkatalysator Expired - Lifetime EP0761809B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19530786 1995-08-22
DE19530786A DE19530786A1 (de) 1995-08-22 1995-08-22 Bleichmittelzusammensetzung enthaltend Polyoxometallate als Bleichkatalysator

Publications (3)

Publication Number Publication Date
EP0761809A2 EP0761809A2 (de) 1997-03-12
EP0761809A3 true EP0761809A3 (de) 1998-09-02
EP0761809B1 EP0761809B1 (de) 2004-11-03

Family

ID=7770053

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96113058A Expired - Lifetime EP0761809B1 (de) 1995-08-22 1996-08-14 Bleichmittelzusammensetzung enthaltend Polyoxometallate als Bleichmittelkatalysator

Country Status (8)

Country Link
US (1) US5928382A (de)
EP (1) EP0761809B1 (de)
JP (1) JP4107690B2 (de)
KR (1) KR970010940A (de)
BR (1) BR9603491A (de)
CA (1) CA2183814C (de)
DE (2) DE19530786A1 (de)
ES (1) ES2231796T3 (de)

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19530787A1 (de) * 1995-08-22 1997-02-27 Hoechst Ag Mangan enthaltende Polyoxometallate, Synthese und Verwendung
GB9725614D0 (en) * 1997-12-03 1998-02-04 United States Borax Inc Bleaching compositions
US6713076B1 (en) * 1998-04-13 2004-03-30 Emory University Methods for removing a contaminant by a polyoxometalate-modified fabric or a polyoxometalate-modified cellulosic fiber and fabrics thereof
US6074437A (en) * 1998-12-23 2000-06-13 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Bleaching with polyoxometalates and air or molecular oxygen
US6723349B1 (en) 1999-10-12 2004-04-20 Emory University Polyoxometalate materials, metal-containing materials, and methods of use thereof
JP4570196B2 (ja) * 2000-03-31 2010-10-27 小林製薬株式会社 義歯洗浄剤
KR100680055B1 (ko) * 2000-04-19 2007-02-07 엘지전자 주식회사 플라즈마 디스플레이 패널의 구동장치
GB0207430D0 (en) * 2002-03-28 2002-05-08 Unilever Plc Liquid cleaning compositionsand their use
DE10304131A1 (de) 2003-02-03 2004-08-05 Clariant Gmbh Verwendung von Übergangsmetallkomplexen als Bleichkatalysatoren
WO2005021435A2 (en) * 2003-02-25 2005-03-10 Emory University Compositions materials incorporating the compositions, and methods of using the compositions and materials
US7504372B2 (en) * 2004-09-08 2009-03-17 Clariant Produkte (Deutschland) Gmbh Mixtures of bleaching agents
JPWO2006075618A1 (ja) * 2005-01-12 2008-06-12 株式会社日本触媒 漂白活性化剤及び該化合物を含有する洗浄用組成物
JP4870970B2 (ja) * 2005-11-04 2012-02-08 ライオン株式会社 ベンゾイルオキシベンゼンスルホネートの製造方法、並びに漂白剤組成物及び洗浄剤組成物
KR100655378B1 (ko) * 2005-12-29 2006-12-08 포항공과대학교 산학협력단 미생물 광감응 살균제 및 이를 이용한 미생물 살균 방법
US7514577B2 (en) * 2006-05-31 2009-04-07 Exxonmobil Chemical Patents Inc. Pd- and Pt-substituted polyoxometalates and process for their preparation
DE102007039651A1 (de) * 2006-11-27 2009-02-26 Henkel Ag & Co. Kgaa Bleichkatalysatorgranulat
KR100792012B1 (ko) * 2006-12-28 2008-01-04 (재)대구경북과학기술연구원 폴리옥소메탈레이트 광촉매를 이용한 염료 및 중금속의동시 제거 방법
US7820868B2 (en) * 2007-01-19 2010-10-26 Exxonmobil Chemical Patents Inc. Transition metal substituted polyoxometalates and process for their preparation
US8183195B2 (en) * 2007-02-14 2012-05-22 Avantor Performance Materials, Inc. Peroxide activated oxometalate based formulations for removal of etch residue
US7645907B2 (en) * 2007-03-23 2010-01-12 Exxonmobil Chemical Patents Inc. Transition metal substituted polyoxometalates and process for their preparation
CA2680363A1 (en) * 2007-03-23 2008-10-02 Mitsubishi Gas Chemical Company, Inc. Tooth-bleaching material and method of bleaching tooth
US8871807B2 (en) 2008-03-28 2014-10-28 Ecolab Usa Inc. Detergents capable of cleaning, bleaching, sanitizing and/or disinfecting textiles including sulfoperoxycarboxylic acids
US8809392B2 (en) 2008-03-28 2014-08-19 Ecolab Usa Inc. Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
US12203056B2 (en) 2008-03-28 2025-01-21 Ecolab Usa Inc. Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
US8492324B2 (en) 2008-04-09 2013-07-23 Basf Se Use of metal hydrazide complex compounds as oxidation catalysts
WO2012000846A1 (en) 2010-06-28 2012-01-05 Basf Se Metal free bleaching composition
GB201021541D0 (en) * 2010-12-21 2011-02-02 Reckitt Benckiser Nv Bleach catalyst particle
WO2013028035A2 (ko) * 2011-08-25 2013-02-28 Kook Seung Won 신규 금속다중산화물과 금속다중산화물을 이용하여 제조된 기능성 섬유 또는 직물
KR101304296B1 (ko) * 2011-09-01 2013-09-11 인제나노헬스주식회사 재활용이 가능한 환경친화형 퍼옥소폴리옥소메탈레이트 표백 조성물 및 이의 용도
DE102011083572A1 (de) 2011-09-28 2013-03-28 BSH Bosch und Siemens Hausgeräte GmbH Wasserführendes Haushaltsgerät mit einer katalytisch wirksamen inneren Oberfläche sowie Verfahren zu seinem Betrieb
WO2013060708A1 (en) 2011-10-25 2013-05-02 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
IN2014CN03742A (de) 2011-10-25 2015-09-04 Basf Se
US9321664B2 (en) 2011-12-20 2016-04-26 Ecolab Usa Inc. Stable percarboxylic acid compositions and uses thereof
US9752105B2 (en) 2012-09-13 2017-09-05 Ecolab Usa Inc. Two step method of cleaning, sanitizing, and rinsing a surface
US8822719B1 (en) 2013-03-05 2014-09-02 Ecolab Usa Inc. Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring
US20140256811A1 (en) 2013-03-05 2014-09-11 Ecolab Usa Inc. Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids
US10165774B2 (en) 2013-03-05 2019-01-01 Ecolab Usa Inc. Defoamer useful in a peracid composition with anionic surfactants
DE102013205302A1 (de) 2013-03-26 2014-10-16 BSH Bosch und Siemens Hausgeräte GmbH Hausgerät mit einer katalytisch wirksamen Oberfläche sowie Verfahren zu seinem Betrieb
US9790452B2 (en) 2013-03-27 2017-10-17 Basf Se Block copolymers as soil release agents in laundry processes
CN103503921B (zh) * 2013-09-07 2015-04-22 宁波市雨辰环保科技有限公司 多聚金属氧酸盐在制备用于杀菌或去除甲醛的消毒剂中的应用
KR20160105790A (ko) 2013-11-27 2016-09-07 바스프 에스이 세탁 방법에서 오염물 방출제로서의 랜덤 공중합체
EP3766523A1 (de) 2014-12-18 2021-01-20 Ecolab USA Inc. Erzeugung von perameisensäure durch polyhydrisches alkoholformiat
EP3232781A4 (de) 2014-12-18 2018-08-22 Ecolab USA Inc. Verfahren zur formung von peroxyformsäure und verwendungen davon
US10172351B2 (en) 2015-09-04 2019-01-08 Ecolab Usa Inc. Performic acid on-site generator and formulator
EP3904526B1 (de) 2015-09-10 2024-07-10 Ecolab USA Inc. Selbstanzeigende antimikrobielle chemie
DE102015224832A1 (de) 2015-12-10 2017-06-14 BSH Hausgeräte GmbH Flüssigkeitsspeichersystem für ein flüssigkeitsführendes Haushaltsgerät
WO2017186480A1 (en) 2016-04-26 2017-11-02 Basf Se Metal free bleaching composition
DE102016008185A1 (de) 2016-07-04 2018-01-04 Sven Herrmann Salz zur Reinigung von einer Flüssigkeit und/oder einem Gas
DE102017209335A1 (de) 2017-06-01 2018-12-06 Henkel Ag & Co. Kgaa Bleichverstärkung beim Waschen und Reinigen
DE102017209332A1 (de) 2017-06-01 2018-12-06 Henkel Ag & Co. Kgaa Bleichendes Wasch- oder Reinigungsmittel
DE102017209336A1 (de) 2017-06-01 2018-12-06 Henkel Ag & Co. Kgaa Bleichverstärkung beim Waschen und Reinigen
DE102017209333A1 (de) 2017-06-01 2018-12-06 Henkel Ag & Co. Kgaa Bleichendes Wasch- oder Reinigungsmittel
WO2019241635A1 (en) 2018-06-15 2019-12-19 Ecolab Usa Inc. On site generated performic acid compositions for teat treatment
EP3677663A1 (de) * 2019-01-07 2020-07-08 Henkel AG & Co. KGaA Nichtenzymatische entfernung von eiweisshaltigen anschmutzungen
CN113811762A (zh) 2019-05-31 2021-12-17 埃科莱布美国股份有限公司 通过电导率测量和过酸组合物监测过酸浓度的方法
WO2021026410A1 (en) 2019-08-07 2021-02-11 Ecolab Usa Inc. Polymeric and solid-supported chelators for stabilization of peracid-containing compositions
CN110804853A (zh) * 2019-11-14 2020-02-18 南通大学 一种使用多金属氧酸盐的棉织物漂白方法
CN115104631A (zh) * 2021-08-18 2022-09-27 上海康迈新材料有限公司 一种过氧羧酸金属化合物的预制组合物及应用
CN114737401A (zh) * 2022-05-18 2022-07-12 江苏金秋弹性织物有限公司 一种棉类织带基于POMs原位催化降解杂质的低碱前处理工艺

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986002674A1 (fr) * 1984-10-31 1986-05-09 Manufacture De Produits Chimiques Protex Procede de blanchiment oxydant en milieu acide
US5041142A (en) * 1990-03-23 1991-08-20 Lever Brothers Company, Division Of Conopco Inc. Peroxymetallates and their use as bleach activating catalysts
JPH0641593A (ja) * 1992-07-27 1994-02-15 Central Glass Co Ltd 漂白活性剤および漂白剤組成物
WO1994005849A1 (en) * 1992-08-28 1994-03-17 THE UNITED STATES OF AMERICA as represented by THE SECRETARY, U.S. DEPARTMENT OF AGRICULTURE Oxidative bleaching of wood pulp by vanadium-substituted polyoxometalates

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB855735A (en) 1958-05-09 1960-12-07 Unilever Ltd Bleaching processes and compositions
NL252798A (de) 1959-06-19 1900-01-01
DE2038106A1 (de) 1970-07-31 1972-02-10 Henkel & Cie Gmbh Aktivatoren fuer Perverbindungen
US4803187A (en) 1987-07-20 1989-02-07 Sun Refining And Marketing Company Alkane oxidation catalysts
GB8908416D0 (en) * 1989-04-13 1989-06-01 Unilever Plc Bleach activation
ES2084783T3 (es) * 1990-11-02 1996-05-16 Clorox Co Detergente liquido no acuoso con peracido solubilizado estable.
GB9108136D0 (en) * 1991-04-17 1991-06-05 Unilever Plc Concentrated detergent powder compositions
US5208369A (en) * 1991-05-31 1993-05-04 The Dow Chemical Company Degradable chelants having sulfonate groups, uses and compositions thereof
GB9304513D0 (en) * 1993-03-05 1993-04-21 Unilever Plc Bleaching agents
US5360568A (en) * 1993-11-12 1994-11-01 Lever Brothers Company, Division Of Conopco, Inc. Imine quaternary salts as bleach catalysts
JP2941430B2 (ja) * 1994-04-07 1999-08-25 ザ、プロクター、エンド、ギャンブル、カンパニー 金属含有漂白触媒を含む漂白組成物
DE19530787A1 (de) * 1995-08-22 1997-02-27 Hoechst Ag Mangan enthaltende Polyoxometallate, Synthese und Verwendung

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986002674A1 (fr) * 1984-10-31 1986-05-09 Manufacture De Produits Chimiques Protex Procede de blanchiment oxydant en milieu acide
US5041142A (en) * 1990-03-23 1991-08-20 Lever Brothers Company, Division Of Conopco Inc. Peroxymetallates and their use as bleach activating catalysts
JPH0641593A (ja) * 1992-07-27 1994-02-15 Central Glass Co Ltd 漂白活性剤および漂白剤組成物
WO1994005849A1 (en) * 1992-08-28 1994-03-17 THE UNITED STATES OF AMERICA as represented by THE SECRETARY, U.S. DEPARTMENT OF AGRICULTURE Oxidative bleaching of wood pulp by vanadium-substituted polyoxometalates

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 018, no. 268 (C - 1202) 23 May 1994 (1994-05-23) *

Also Published As

Publication number Publication date
BR9603491A (pt) 1998-05-12
KR970010940A (ko) 1997-03-27
CA2183814C (en) 2008-12-23
JP4107690B2 (ja) 2008-06-25
JPH09118899A (ja) 1997-05-06
ES2231796T3 (es) 2005-05-16
EP0761809B1 (de) 2004-11-03
US5928382A (en) 1999-07-27
DE59611133D1 (de) 2004-12-09
CA2183814A1 (en) 1997-02-23
EP0761809A2 (de) 1997-03-12
DE19530786A1 (de) 1997-02-27

Similar Documents

Publication Publication Date Title
EP0761809A3 (de) Bleichmittelzusammensetzung enthaltend Polyoxometallate als Bleichmittelkatalysator
TR28055A (tr) Agartma katalizör bilesimi, bu bilesimin imali ve deterjan ve/veya agartma bilesimleri icinde kullanimi.
CA2219987A1 (en) Aqueous detergent compositions containing chelants which remain undissolved under acidic conditions
DE3763725D1 (de) Einen persaeureaktivator enthaltende fluessige wasserstoffperoxidbleiche.
DE69105836D1 (de) Bleichmittelzusammensetzung.
CA2037800A1 (en) Bleach catalysts and compositions containing the same
DE69418332D1 (de) Kosmetische zusammensetzung, die hydroxysaeuren enthaelt
FI973808L (fi) Aktivoituja nestemäisiä valkaisukoostumuksia
TR28154A (tr) Azaltilmis agartici kokusuna sahip koyulastirilmis hipoklorit cözeltileri ve üretim ve kullanim yöntemleri.
ATE128726T1 (de) Stabilisierte, bleichmittel enthaltende, flüssige waschmittelzusammensetzungen.
MA22947A1 (fr) Compositions de blanchiment stabilisees.
DE69300710D1 (de) Waschmittelzusammensetzungen.
TR28071A (tr) Aktif agartma katalizörü olarak bir manganez kompleksini iceren bir agartma katalizör bilesimi.
DE69019781D1 (de) Bleichmittelzusammensetzung.
DE68918561D1 (de) Bleichzusammensetzung.
MX9805303A (es) Composiciones colorantes para el cabello.
DE68921181D1 (de) Bleichmittelzusammensetzung.
DE68928037D1 (de) Waschmittelzusammensetzungen, die Peroxysäure-Bleiche und Riechstoff enthalten
FR2690690B1 (fr) Composition et solution de blanchiment.
DE69600871D1 (de) Filtrierende kosmetische oder dermatologische Zusammensetzung enthaltend einen Eisen-Chelat-Bildner
DE68919518D1 (de) Eingekapselte, flüssige Detergenszusammensetzung.
FR2713086B1 (fr) Nouvelles compositions cosmétiques contenant des polyols simples.
CA2096254A1 (en) Granular detergent or bleaching compositions containing amidoperoxyacid bleach and perfume
FI943069L (fi) Kloorittomia, mahdollisesti vetypitoisia fluorihiilivetyjä sisältävät koostumukset
DE69632166D1 (de) Bleichende Waschmittelzusammensetzung

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH DE DK ES FR GB IT LI NL

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: CLARIANT GMBH

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE CH DE DK ES FR GB IT LI NL

17P Request for examination filed

Effective date: 19990302

17Q First examination report despatched

Effective date: 20000724

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RBV Designated contracting states (corrected)

Designated state(s): BE DE ES FR GB IT

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): BE DE ES FR GB IT

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REF Corresponds to:

Ref document number: 59611133

Country of ref document: DE

Date of ref document: 20041209

Kind code of ref document: P

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20050420

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2231796

Country of ref document: ES

Kind code of ref document: T3

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

ET Fr: translation filed
26N No opposition filed

Effective date: 20050804

REG Reference to a national code

Ref country code: FR

Ref legal event code: CD

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20080709

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20080729

Year of fee payment: 13

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20090430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080901

REG Reference to a national code

Ref country code: FR

Ref legal event code: RN

REG Reference to a national code

Ref country code: FR

Ref legal event code: FC

BERE Be: lapsed

Owner name: *CLARIANT PRODUKTE DEUTSCHLAND G.M.B.H.

Effective date: 20090831

PGRI Patent reinstated in contracting state [announced from national office to epo]

Ref country code: FR

Effective date: 20091204

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090831

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20090817

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090815

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 59611133

Country of ref document: DE

Representative=s name: ACKERMANN, JOACHIM KARL WILHELM, DIPL.-CHEM. D, DE

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 59611133

Country of ref document: DE

Representative=s name: ACKERMANN, JOACHIM KARL WILHELM, DIPL.-CHEM. D, DE

Effective date: 20140902

Ref country code: DE

Ref legal event code: R081

Ref document number: 59611133

Country of ref document: DE

Owner name: WEYLCHEM WIESBADEN GMBH, DE

Free format text: FORMER OWNER: CLARIANT PRODUKTE (DEUTSCHLAND) GMBH, 65929 FRANKFURT, DE

Effective date: 20140902

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20140821

Year of fee payment: 19

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20140821

Year of fee payment: 19

Ref country code: GB

Payment date: 20140820

Year of fee payment: 19

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20140828

Year of fee payment: 19

REG Reference to a national code

Ref country code: FR

Ref legal event code: TP

Owner name: WEYLCHEM WIESBADEN GMBH, DE

Effective date: 20150908

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 59611133

Country of ref document: DE

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20150814

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150814

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20160429

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160301

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150814

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150831