EP0773840B1 - Procede de production et de refection de peintures multicouche permettant d'obtenir des effets multicolores - Google Patents

Procede de production et de refection de peintures multicouche permettant d'obtenir des effets multicolores Download PDF

Info

Publication number
EP0773840B1
EP0773840B1 EP95925869A EP95925869A EP0773840B1 EP 0773840 B1 EP0773840 B1 EP 0773840B1 EP 95925869 A EP95925869 A EP 95925869A EP 95925869 A EP95925869 A EP 95925869A EP 0773840 B1 EP0773840 B1 EP 0773840B1
Authority
EP
European Patent Office
Prior art keywords
coating
shear
shear rate
mpa
apparent viscosity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP95925869A
Other languages
German (de)
English (en)
Other versions
EP0773840A1 (fr
Inventor
Heinz TÖPFEL
Ewald Bischoff
Harry Libutzki
Jorge Wellmann
Dieter Herbst
Hans-Joachim Streitberger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Coatings GmbH
Original Assignee
BASF Coatings GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Coatings GmbH filed Critical BASF Coatings GmbH
Publication of EP0773840A1 publication Critical patent/EP0773840A1/fr
Application granted granted Critical
Publication of EP0773840B1 publication Critical patent/EP0773840B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/04—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B05D5/067—Metallic effect
    • B05D5/068—Metallic effect achieved by multilayers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]

Definitions

  • the invention relates to a method for manufacturing and repair of multi-layer effect paints.
  • Pneumatic application methods stand out disadvantageous in that a relatively large Part of the sprayed amount of paint does not cover the substrate reached, which has the consequence that the circulating air in the Spray booth must have high speeds, thus the relatively large amounts of overspray deposited and can be disposed of.
  • the basecoat film is preferably in only one spray cycle, exclusively made by electrostatic spraying.
  • electrostatic spraying the amount is of the sprayed paint material that the substrate achieved considerably larger than with pneumatic application processes.
  • the speed the circulating air in the spray booth is reduced can and that smaller amounts of paint overspray have to be processed and disposed of.
  • all of the platelet-shaped pigments containing platelet-shaped pigments suitable for the serial painting of automobile bodies can be used, provided they have a solids content of 18% by weight and a temperature of 23 ° C. at a shear rate of 1,000 s -1 after a shear time of 6 s an apparent viscosity of 40 to 200, preferably 60 to 150 mPa s, after a shear time of 300 s at a shear rate of 1000 s -1 an apparent viscosity of 40 to 200, preferably 60 to 150 mPa s, at a shear rate of 5 s -1 after a shear time of 10 s an apparent viscosity of 100 to 2000, preferably 200 to 800 mPa s and after a shear time of 300 s at a shear rate of 5 s -1 an apparent viscosity of 100 to 2000, preferably 500 to 1500 mPa s, the measurements carried out at the shear rate of 5 sec
  • rheology aids such as, for example, crosslinked polymer microparticles (cf. for example EP-A-38127), finely divided silica, anionic polyacrylate resins, layered silicates, etc.
  • the person skilled in the art can in principle apply any basecoat suitable for series coating to a viscosity behavior, that meet the above conditions.
  • the basecoats used in stage (1) of the process according to the invention can be either aqueous or non-aqueous.
  • Aqueous basecoats are described, for example, in EP-A-38127 and non-aqueous basecoats are described, for example, in US-A-4,220,679.
  • the method according to the invention is particularly suitable good for making and repairing multilayer Effect coatings with darker shades (e.g. Diamond Black) and for the production and repair of multi-layer effect paints with lighter ones Shades (e.g. silver).
  • darker shades e.g. Diamond Black
  • lighter ones Shades e.g. silver
  • Basecoat layer exclusively by electrostatic Syringes is made.
  • electrostatic Spraying is the amount of paint material sprayed, which reaches the substrate, much larger than with pneumatic application processes. That has as a result that the speed of the circulating air in the Spray booth can be reduced and that lower Amounts of paint overspray worked up and disposed of Need to become. It can also be used to manufacture multi-layer effect painting necessary painting system be significantly reduced if the basecoat layer exclusively by electrostatic Syringes is made.
  • the application of basecoats containing platelet-like pigments electrostatic spraying is good for the person skilled in the art known and therefore does not need any further details here to be explained
  • Spray application process in which the paint drops of the spray jet meet the above-mentioned conditions can, for example, with the help of HVLP (high volume, low pressure) fuel pistols that are commercially available are available.
  • the diameter, the speed and thus the impulse of the Drops of paint in the spray jet essentially depend on the paint flow rate, the amount of atomizing air or Atomizing air pressure, paint viscosity and Nozzle geometry.
  • a reduction in paint flow rate has, for example, a reduction in the paint drop diameter and an increase in speed the paint drops result.
  • An increase in atomizing air pressure also leads to a reduction the paint drop diameter and to an increase the speed of the paint drops.
  • phase Doppler anemometry method is used by W.D. Bachalo and M.J. Houser in OPTICAL ENGINEERING / September / October 1984 / Vol.23 No.5 on pages 583 to 590.
  • the basecoat film thus obtained is after an intermediate drying (10 min, 80 ° C) with a commercially available a polyacrylate resin as a binder and a melamine resin as a clearcoat containing crosslinking agents overcoated (dry film thickness of the clear coat: 50 ⁇ m) and then basecoat and clearcoat 20 Baked at 140 ° C for minutes.
  • half of the painted test board is taped with an adhesive strip and the remaining half is sanded with sandpaper (800). Then the basecoat used for the initial painting is applied with an HVLP spray gun (De Vilbiss GFHV-511, manufacturer: De Vilbiss; cap: air cap No. 152, nozzle EY 7; atomization pressure: 0.4 bar, measured at air cap; spraying distance: 30 cm to Substrate) in a first application (first cloister) sprayed in a dry layer thickness of 6-8 ⁇ m.
  • HVLP spray gun De Vilbiss GFHV-511, manufacturer: De Vilbiss; cap: air cap No. 152, nozzle EY 7; atomization pressure: 0.4 bar, measured at air cap; spraying distance: 30 cm to Substrate
  • the spray jet produced is characterized in that 25% of the drops of paint passing a measuring point located in the center of the spray jet and 300 mm from the nozzle have a diameter which is below 20 ⁇ m and 15% of the drops of paint which pass this measuring point happen, have a diameter that is over 60 microns. In addition, 33% of the drops of paint passing the measuring point have a speed which is below 6 m / s, and 17% of the drops of paint which pass the measuring point have a speed of more than 10 m / s.
  • the impulse of the paint drops that pass the measuring point is 6.8 ⁇ 10 -5 g cm s -1 .
  • the diameter and the speed of the paint drops were determined using the phase Doppler anemometry method.
  • the basecoat film thus obtained is after an intermediate drying (10 min, 80 ° C) with a commercially available a polyacrylate resin as a binder and a Clear varnish containing polyisocyanate as crosslinking agent overcoated (dry film thickness of the clear coat: 45 ⁇ m) and then basecoat and Clear coat baked at 140 ° C for 30 min.

Landscapes

  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Claims (3)

  1. Procédé de production et de réfecticn de peintures multicouches permettant d'obtenir des effets multicolores, lors duquel
    (1) l'on produit une couche de peinture de base sur une surface de substrat en utilisant au moins une peinture contenant un pigment sous forme de paillettes,
    (2) l'on procède à la réfection de cette couche de peinture de base, le cas échéant, à l'aide d'au moins une peinture contenant un pigment sous forme de paillettes,
    (3) l'on procède à la sur-peinture de la couche de peinture obtenue dans l'étape (1), ou l'étape (2), a l'aide d'une peinture transparente,
    (4) l'on procède à la cuisson de la peinture multicouche ainsi obtenue,
    (5) l'on procède à la réfection de la peinture multicouche ainsi soumise à cuisson, le cas échéant, a l'aide d'au moins une peinture contenant un pigment sous forme de paillettes,
    (6) l'on procède à la sur-peinture de la couche de peinture ainsi obtenue dans l'étape (5), à l'aide d'une peinture transparente, et
    (7) l'on procède à la cuisson de la peinture multicouche ainsi obtenue,
    le procédé se composant des étapes (1), (2), (3), (4), (5), (6) et (7) ou des étapes (1), (2), (3) et (4), ou des étapes (1), (3), (4), (5), (6), et (7), caracterise en ce que
    (i) dans l'étape (1), l'on utilise une peinture qui présente, pour une teneur en matières solides de 18 % en poids et pour une température de 23°C, pour une vitesse de cisaillement de 1 000 s-1 après une durée de cisaillement de 6 secondes une viscosité apparente de 40 à 200 mPas, pour une vitesse de cisaillement de 1 000 s-1 après une durée de cisaillement de 300 secondes une viscosité apparente de 40 à 200 mPas, pour une vitesse de cisaillement de 5 s-1 après une durée de cisaillement de 10 secondes une viscosité apparente de 100 à 2 000 mPas et pour une vitesse de cisaillement de 5 s-1 après une durée de cisaillement de 300 secondes une viscosité apparente de 100 à 2 000 mPas, les mesures effectuées pour une vitesse de cisaillement de 5 s-1 ayant été effectuées immédiatement après un cisaillement préalable d'une durée de 300 secondes pour une vitesse de cisaillement de 1000 s-1, et la viscosité apparente, mesurée pour une vitesse de cisaillement de 5 s-1 après une durée de cisaillement de 300 secondes, se situant à un niveau plus élevé de 0 à 1 000 mPas que la viscosité apparente mesurée pour une vitesse de cisaillement de 5 s-1 après une durée de cisaillement de 10 secondes,
    (ii) l'on produit la couche de peinture de base produite dans l'étape (1) exclusivement par pulvérisation électrostatique et
    (iii) l'on effectue la réfection effectuée dans l'étape (2), ou dans l'étape (5), à l'aide d'un procédé d'application par pulvérisation, lors duquel on produit un jet de pulvérisation se composant de gouttelettes de peinture qui se caractérise en ce que
    au plus 40 % des gouttelettes de peinture qui passent par un point de mesure, qui se situe au centre du jet de pulvérisation et à 300 mm de la buse, présentent un diamètre qui se situe en-dessous de 20 microns, et au moins 5 % des gouttelettes de peinture, qui passent par ce point de mesure, présentent un diamètre, qui se situe au-dessus de 60 microns,
    au moins 20 % des gouttelettes de peinture qui passent par un point de mesure, qui se situe au centre du jet de pulvérisation et à 300 mm de la buse, présentent une vitesse, qui se situe en-dessous de 6 m/s, et au plus 30 % des gouttelettes de peinture, qui passent par ce point de mesure, présentent une vitesse de plus de 10 m/s et
    les gouttelettes de peinture qui passent par un point de mesure, qui se situe au centre du jet de pulvérisation et à 300 mm de la buse, présentent une quantité de mouvement qui est d'au moins 4 x 10-5 g cm s-1,
    le diamètre et la vitesse des gouttelettes de peinture ayant été déterminés à l'aide de la méthode d'anémométrie Doppler à phases.
  2. Procédé selon la revendication 1, caractérisé en ce que la peinture utilisée dans l'étape (1) présente pour une vitesse de cisaillement de 1 000 s-1 après une durée de cisaillement de 6 secondes une viscosité apparente de 60 à 150 mPas, pour une vitesse de cisaillement de 1 000 s-1 après une durée de cisaillement de 300 secondes une viscosité apparente de 60 à 150 mPas, pour une vitesse de cisaillement de 5 s-1 après une durée de cisaillement de 10 secondes une viscosité apparente de 200 à 800 mPas, et pour une vitesse de cisaillement de 5 s-1 après une durée de cisaillement de 300 secondes une viscosité apparente de 500 à 1 500 mPas, la viscosité apparente mesurée pour une vitesse de cisaillement de 5 s-1 après une durée de cisaillement de 300 secondes se situant à un niveau plus élevé de 200 à 600 mPas que la viscosité apparente mesurée pour une vitesse de cisaillement de 5 s-1 après une durée de cisaillement de 10 secondes.
  3. Procédé selon la revendication 1 ou 2, caractérisé en ce que l'on effectue la réfection effectuée dans l'étape (2), ou l'étape (5) à l'aide d'un procédé d'application par pulvérisation, lors duquel on produit un jet de pulvérisation comportant des goutelettes de peinture, qui se caractérise par
    de 10 à 30 % des gouttelettes de peinture qui passent par un point de mesure, qui se situe au centre du jet de pulvérisation et à 300 mm de la buse, présentent un diamètre qui se situe en dessous de 20 microns, et 10 à 30 % des gouttelettes de peinture qui passent par ce point, présentent un diamètre qui se situe au dessus de 60 microns,
    de 30 à 50 % des gouttelettes de peinture, qui passent par un point de mesure, qui se situe au centre du jet de pulvérisation et à 300 mm de la buse, présentent une vitesse, qui se situe en dessous de 6 m/s, et de 0 à 20 % des gouttelettes de peinture qui passent par ce point de mesure, présentent une vitesse de plus de 10 m/s, et
    les gouttelettes de peinture , qui passent par un point de mesure, qui se situe au centre du jet de pulvérisation et à 300 mm de la buse, présentent une quantité de mouvement, qui va de 6 x 10-5 à 8 x 10-5 g cm s-1,
    le diamètre et la vitesse des gouttelettes de peinture ayant été déterminés à l'aide de la méthode d'anémométrie Doppler à phases.
EP95925869A 1994-07-22 1995-07-13 Procede de production et de refection de peintures multicouche permettant d'obtenir des effets multicolores Expired - Lifetime EP0773840B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4426039 1994-07-22
DE4426039A DE4426039A1 (de) 1994-07-22 1994-07-22 Verfahren zur Herstellung und Ausbesserung von mehrschichtigen Effektlackierungen
PCT/EP1995/002749 WO1996003221A1 (fr) 1994-07-22 1995-07-13 Procede de production et de refection de peintures multicouche permettant d'obtenir des effets multicolores

Publications (2)

Publication Number Publication Date
EP0773840A1 EP0773840A1 (fr) 1997-05-21
EP0773840B1 true EP0773840B1 (fr) 1998-09-23

Family

ID=6523917

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95925869A Expired - Lifetime EP0773840B1 (fr) 1994-07-22 1995-07-13 Procede de production et de refection de peintures multicouche permettant d'obtenir des effets multicolores

Country Status (12)

Country Link
US (1) US5820986A (fr)
EP (1) EP0773840B1 (fr)
JP (1) JP2891778B2 (fr)
KR (1) KR100208908B1 (fr)
CN (1) CN1152886A (fr)
AT (1) ATE171399T1 (fr)
CA (1) CA2191879A1 (fr)
DE (2) DE4426039A1 (fr)
DK (1) DK0773840T3 (fr)
ES (1) ES2125029T3 (fr)
TW (1) TW400255B (fr)
WO (1) WO1996003221A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE50111955D1 (de) * 2000-03-16 2007-03-15 Volkswagen Ag Verfahren zur kleinflächigen beseitigung von lackierungsfehlern
ATE294647T1 (de) * 2000-04-17 2005-05-15 Du Pont Verfahren zur reparaturbeschichtung von mehrschichtüberzügen auf substraten
US6777033B2 (en) 2002-03-18 2004-08-17 E. I. Du Pont De Nemours And Company Process for refinishing substrates
US9744559B2 (en) 2014-05-27 2017-08-29 Paul W Harrison High contrast surface marking using nanoparticle materials
CN106423805A (zh) * 2016-11-28 2017-02-22 中信戴卡股份有限公司 一种铝合金表面涂层及形成该涂层的方法
WO2020002252A1 (fr) * 2018-06-25 2020-01-02 Basf Coatings Gmbh Procédé pour réaliser un revêtement optimisé et revêtement pouvant être obtenu au moyen dudit procédé
CN112513611A (zh) * 2018-06-25 2021-03-16 巴斯夫涂料有限公司 油漆开发中的雾化期间液滴尺寸分布的测定方法和基于其的筛选方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5814266B2 (ja) * 1975-12-19 1983-03-18 三井東圧化学株式会社 メタリツクチヨウトマクノケイセイホウホウ
US4238387A (en) * 1978-11-20 1980-12-09 E. I. Du Pont De Nemours And Company Rheology control additive for paints
GB2073609B (en) * 1980-04-14 1984-05-02 Ici Ltd Coating process
US4477536A (en) * 1982-03-18 1984-10-16 Glasurit America, Inc. Process for preparing a multilayer coating
NL8500475A (nl) * 1985-02-20 1986-09-16 Akzo Nv Thixotrope bekledingssamenstelling.
DE3919028A1 (de) * 1989-06-10 1990-12-13 Hoechst Ag Ueberzugsmasse, verfahren zur herstellung von ueberzuegen und damit beschichtete substrate
JPH0312263A (ja) * 1989-06-12 1991-01-21 Nissan Motor Co Ltd うるし調塗膜の形成方法
US5204401A (en) * 1990-07-13 1993-04-20 Basf Corporation Metallic water borne base coat composition based on acrylic latex resins using acrylic resins derived from vinyl monomers having nonionic and urethane functionality for aluminum storage and a treated hextorie clay for rheology control - water base 9
US5413809A (en) * 1993-07-01 1995-05-09 E. I. Du Pont De Nemours And Company Method for achieving recoat adhesion over a silane topcoat
JP3208022B2 (ja) * 1994-10-21 2001-09-10 本田技研工業株式会社 メタリック塗料の塗装方法

Also Published As

Publication number Publication date
KR970704525A (ko) 1997-09-06
TW400255B (en) 2000-08-01
US5820986A (en) 1998-10-13
DE4426039A1 (de) 1996-01-25
JPH09509098A (ja) 1997-09-16
CA2191879A1 (fr) 1996-02-08
CN1152886A (zh) 1997-06-25
ATE171399T1 (de) 1998-10-15
DK0773840T3 (da) 1999-06-14
ES2125029T3 (es) 1999-02-16
WO1996003221A1 (fr) 1996-02-08
KR100208908B1 (ko) 1999-07-15
JP2891778B2 (ja) 1999-05-17
EP0773840A1 (fr) 1997-05-21
DE59503723D1 (de) 1998-10-29

Similar Documents

Publication Publication Date Title
DE19512017C1 (de) Verfahren zur Mehrschichtlackierung
DE60018598T2 (de) Verfahren und vorrichtung zur beschichtung eines substrates
DE102004010389B4 (de) Verfahren zum Naßlackieren von Fahrzeugkarosserien, zweifarbig lackierte Fahrzeugkarosserie und Zweifarben-Lackieranlage
DE102008054283A1 (de) Farb- und/oder effektgebende Mehrschichtlackierungen mit pigmentfreien Lackierungen als Füller-Ersatz, ihre Herstellung und Verwendung
EP0729390B1 (fr) Procede de reparation avec plusieurs couches de peinture
EP0048498A1 (fr) Procédé pour appliquer des vernis en plusieurs couches sur un véhicule automobile
EP0773840B1 (fr) Procede de production et de refection de peintures multicouche permettant d'obtenir des effets multicolores
EP0719185B1 (fr) Procede de production d'un revetement multicouche de peinture de reparation
EP0061165B1 (fr) Voiture automobile avec enduit de vernis multicouche et procédé pour vernir en multicouche
EP0666779B1 (fr) Laque transparente en poudre et procede de realisation d'un laquage multicouche
DE602005005628T2 (de) Verfahren zur herstellung von zweifarbig überzogenen substraten
DE60008228T2 (de) Elektrizitätsleitende beschichtungsmasse beschichtet durch intern geladene elektrostatische zerstäuber
EP1040875B1 (fr) Revêtement multicouche au toucher souple
EP0764475B1 (fr) Procédé pour faire une laque à effets sur un substrat en plastique grainé
DE19517277C1 (de) Verfahren zur Herstellung von Mehrschicht-Effektlackierungen
DE60110492T2 (de) Verfahren zur Reparaturbeschichtung von Mehrschichtüberzügen auf Substraten
US5849365A (en) Method for the production and repair of multicoat special-effect coating
DE19858175C2 (de) Verfahren zur Effektlackierung von Oberflächen und Teil-Oberflächen von Gegenständen
EP2976163B1 (fr) Procédé
DE4422287A1 (de) Verfahren zur Herstellung von Effektlackierungen
DE2159836A1 (de) Lackierverfahren
EP1169140A1 (fr) Procede de fabrication et d'amelioration de peintures
DE19735320A1 (de) Lackierung für Metallflächen
DE10017814A1 (de) Verfahren zur Herstellung effektgebender Mehrschichtlackierungen

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19961121

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB IT LI NL SE

17Q First examination report despatched

Effective date: 19970804

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: BASF COATINGS AKTIENGESELLSCHAFT

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES FR GB IT LI NL SE

REF Corresponds to:

Ref document number: 171399

Country of ref document: AT

Date of ref document: 19981015

Kind code of ref document: T

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REF Corresponds to:

Ref document number: 59503723

Country of ref document: DE

Date of ref document: 19981029

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: R. A. EGLI & CO. PATENTANWAELTE

ET Fr: translation filed
GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19981230

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2125029

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20010720

Year of fee payment: 7

Ref country code: AT

Payment date: 20010720

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20010723

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20010726

Year of fee payment: 7

Ref country code: DK

Payment date: 20010726

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20010807

Year of fee payment: 7

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20020713

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20020714

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20020731

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20020731

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20020731

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20020731

BERE Be: lapsed

Owner name: *BASF COATINGS A.G.

Effective date: 20020731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20030201

EUG Se: european patent has lapsed
REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 20030201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.

Effective date: 20050713

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20080821

Year of fee payment: 14

Ref country code: DE

Payment date: 20080717

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20080718

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20080716

Year of fee payment: 14

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20090713

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20100331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090713

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100202

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20090714

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090714