EP0844320B1 - Monofilament extrudé à l'état fondu - Google Patents
Monofilament extrudé à l'état fondu Download PDFInfo
- Publication number
- EP0844320B1 EP0844320B1 EP19970118497 EP97118497A EP0844320B1 EP 0844320 B1 EP0844320 B1 EP 0844320B1 EP 19970118497 EP19970118497 EP 19970118497 EP 97118497 A EP97118497 A EP 97118497A EP 0844320 B1 EP0844320 B1 EP 0844320B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- monofilament
- polyurethane
- cross
- melt
- section
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000004814 polyurethane Substances 0.000 claims abstract description 13
- 229920002635 polyurethane Polymers 0.000 claims abstract description 10
- 229920003023 plastic Polymers 0.000 claims abstract description 7
- 239000004033 plastic Substances 0.000 claims abstract description 7
- 230000007062 hydrolysis Effects 0.000 claims abstract description 4
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 4
- 239000003381 stabilizer Substances 0.000 claims abstract description 4
- 210000000988 bone and bone Anatomy 0.000 claims abstract 2
- 229920002215 polytrimethylene terephthalate Polymers 0.000 claims description 14
- -1 polytrimethylene terephthalate Polymers 0.000 claims description 9
- 239000004744 fabric Substances 0.000 claims description 4
- 239000004753 textile Substances 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims 2
- 239000000470 constituent Substances 0.000 claims 1
- 238000005299 abrasion Methods 0.000 abstract description 3
- NMYFVWYGKGVPIW-UHFFFAOYSA-N 3,7-dioxabicyclo[7.2.2]trideca-1(11),9,12-triene-2,8-dione Chemical compound O=C1OCCCOC(=O)C2=CC=C1C=C2 NMYFVWYGKGVPIW-UHFFFAOYSA-N 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- 101000738322 Homo sapiens Prothymosin alpha Proteins 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 102100037925 Prothymosin alpha Human genes 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/94—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of other polycondensation products
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
Definitions
- the invention relates to a melt-extruded monofilament for use in technical textiles, especially in paper machine clothing, essentially made of a plastic material consists.
- melt-extruded monofilaments have high strength and are therefore preferred in strength-bearing Structures such as technical fabrics and knitted fabrics and in particular used in clothing for paper machines.
- the object of the invention is therefore a monofilament for textile To create materials of the type mentioned, the extrudable in a simple manner and at lower temperatures and can be fixed later.
- PTMT polytrimethylene terephthalate
- a preferred Embodiment has the plastic material to increase the Abrasion resistance, especially elastomeric polyurethane (PU) up to a proportion of 45 wt .-%.
- PU elastomeric polyurethane
- this Case has the use of PTMT materials according to the invention the further advantage that the in the manufacture and treatment occurring temperatures are so low that they do not damage the polyurethane and, in so far, the state of the art Technology provided protective measures can be omitted, which also contributes to cost reduction.
- the plastic material contains a hydrolysis stabilizer in a manner known per se, preferably up to a proportion of 5% by weight.
- the melt-extruded monofilaments according to the invention can have any cross-sectional shape, ie they can be, for example, rectangular, cloverleaf-shaped, dog-bone-shaped, star-shaped, round, oval or the like and in particular also have a hollow cross-section.
- the cross-sectional area of the monofilaments is preferably between 0.02 mm 2 and 3.5 mm 2 , which corresponds to a diameter of 0.08 to 1 mm for a round cross section.
- the PTMT material can, for example, by condensation of Terephthalic acid and 1,3-propanediol.
- PTMT materials are already known per se and also have already been used for the production of fibers. The one there However, the specific strength achieved was for the area of application in strength-bearing structures such as technical fabrics and knitted too little. It was all the more surprising, that the honofilaments of the invention based on PTMT for use in such technical textiles and in particular Paper machine clothing has sufficient strength.
- melt-extruded according to the invention could Monofilaments also significantly higher degrees of stretching be achieved than in the literature for fibers PTMT base is specified.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Artificial Filaments (AREA)
- Paper (AREA)
- Woven Fabrics (AREA)
Claims (8)
- Monofilament extrudé à l'état fondu pour l'utilisation dans des textiles techniques, en particulier dans des toiles pour machines à papier, qui se compose essentiellement d'un matériau synthétique,qui présente en tant que composant principal du téréphtalate de polytriméthylène (PTMT),qui présente une fraction de polyuréthane allant jusqu'à 45 % en masse,qui se compose au moins à 95 % en masse de la combinaison du téréphtalate de polytriméthylène et du polyuréthane.
- Monofilament selon la revendication 1, caractérisé en ce que le polyuréthane est un polyuréthane élastomère.
- Monofilament selon la revendication 1 ou 2, caractérisé en ce que le matériau synthétique présente un stabilisant d'hydrolyse.
- Monofilament selon la revendication 3, caractérisé en ce que la fraction du stabilisant d'hydrolyse peut atteindre 5 % en masse.
- Monofilament selon l'une des revendications 1 à 4, caractérisé en ce que la surface de section du monofilament est comprise entre 0,02 mm2 et 3,5 mm2.
- Monofilament selon la revendication 5, caractérisé en ce que le monofilament présente une section circulaire ayant un diamètre compris entre 0,08 et 1 mm.
- Monofilament selon l'une des revendications 1 à 6, caractérisé en ce qu'il présente une section carrée, rectangulaire, ovale, trilobée ou en forme d'os.
- Toile pour machine à papier, caractérisé en ce qu'elle présente des monofilaments extrudés à l'état fondu selon l'une des revendications 1 à 7.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19648092 | 1996-11-20 | ||
| DE19648092 | 1996-11-20 | ||
| DE19648884 | 1996-11-26 | ||
| DE19648884A DE19648884A1 (de) | 1996-11-20 | 1996-11-26 | Schmelzextrudiertes Monofilament |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0844320A2 EP0844320A2 (fr) | 1998-05-27 |
| EP0844320A3 EP0844320A3 (fr) | 1999-01-13 |
| EP0844320B1 true EP0844320B1 (fr) | 2001-09-12 |
Family
ID=26031475
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19970118497 Expired - Lifetime EP0844320B1 (fr) | 1996-11-20 | 1997-10-24 | Monofilament extrudé à l'état fondu |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6033777A (fr) |
| EP (1) | EP0844320B1 (fr) |
| AT (1) | ATE205558T1 (fr) |
| CA (1) | CA2221532C (fr) |
| ES (1) | ES2163700T3 (fr) |
| PT (1) | PT844320E (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102877143A (zh) * | 2012-10-23 | 2013-01-16 | 江苏中润纤维科技股份有限公司 | 高仿棉多孔超细异形聚酯纤维的制备工艺及工艺设备 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0965665B1 (fr) * | 1998-06-18 | 2002-11-27 | Thomas Josef Heimbach Gesellschaft mit beschränkter Haftung & Co. | Monofilament et toile pour machine à papier à partir de celui-ci |
| CA2313867A1 (fr) | 1999-07-19 | 2001-01-19 | Paul C. Fleri | Melanges de polymeres composes de poly(trimethylene terephtalate) et d'un polyester elastomere |
| EP1183409B1 (fr) | 2000-03-03 | 2005-11-16 | E.I. Du Pont De Nemours And Company | Fil poly(trimethylene terephthalate) |
| US6287688B1 (en) | 2000-03-03 | 2001-09-11 | E. I. Du Pont De Nemours And Company | Partially oriented poly(trimethylene terephthalate) yarn |
| US6663806B2 (en) | 2000-03-03 | 2003-12-16 | E. I. Du Pont De Nemours And Company | Processes for making poly (trimethylene terephthalate) yarns |
| US20050075479A1 (en) * | 2003-10-03 | 2005-04-07 | Blackbourn Robert Lawrence | Process for increasing the toughness of solid state polymerized poly (trimethylene terephthalate) pellets |
| US20080254264A1 (en) * | 2007-04-11 | 2008-10-16 | Hiroki Yamaguchi | Textile sleeve for protecting elongate members and method of construction |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4436877A (en) * | 1982-11-08 | 1984-03-13 | Polyplastics Co., Ltd. | Thermoplastic polyester composition |
| US5169711A (en) * | 1988-08-05 | 1992-12-08 | Jwi Ltd. | Paper makers forming fabric |
| US5319039A (en) * | 1992-04-30 | 1994-06-07 | The Dow Chemical Company | Thermally processable blends of aromatic polyesters and high modulus polyurethanes |
| EP0387395B1 (fr) * | 1989-03-17 | 1994-12-07 | Jwi Limited | Toile stabilisée pour machine de fabrication de papier en polyester modifié avec le polyuréthane |
| DE4410399A1 (de) * | 1994-03-25 | 1995-09-28 | Hoechst Ag | Abriebfeste Polyestermischung mit erhöhter Verarbeitungssicherheit, Monofilamente daraus und deren Herstellung und Verwendung |
| WO1996000808A1 (fr) * | 1994-06-30 | 1996-01-11 | E.I. Du Pont De Nemours And Company | Procede de fabrication de fils continus, gonflants, de poly(trimethylene terephtalate), fils et tapis obtenus a partir de ce procede |
| US5763040A (en) * | 1995-04-18 | 1998-06-09 | E. I. Du Pont De Nemours And Company | Rug and carpet underlays substantially impervious to liquids |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5281973A (en) * | 1975-12-27 | 1977-07-08 | Kawase Gijiyutsu Kenkiyuushiyo | Illuminating apparatus |
| US5502120A (en) * | 1988-08-05 | 1996-03-26 | Jwi Ltd. | Melt-extruded monofilament comprised of a blend of polyethylene terephthalate and a thermoplastic polyurethane |
| US5137601A (en) * | 1991-06-26 | 1992-08-11 | Wangner Systems Corporation | Paper forming fabric for use with a papermaking machine made of PPT fibers |
| JPH08120521A (ja) * | 1994-10-24 | 1996-05-14 | Nippon Ester Co Ltd | ポリエステルフィラメント |
| EP0745711B1 (fr) * | 1995-05-08 | 2001-11-28 | Shell Internationale Researchmaatschappij B.V. | Procédé pour la fabrication de fils en polypropylène-téréphtalate |
| JPH0981427A (ja) * | 1995-09-18 | 1997-03-28 | Nippon Telegr & Teleph Corp <Ntt> | 更新差分データ抽出プログラム作成方法およびそのための装置 |
-
1997
- 1997-10-24 ES ES97118497T patent/ES2163700T3/es not_active Expired - Lifetime
- 1997-10-24 AT AT97118497T patent/ATE205558T1/de not_active IP Right Cessation
- 1997-10-24 PT PT97118497T patent/PT844320E/pt unknown
- 1997-10-24 EP EP19970118497 patent/EP0844320B1/fr not_active Expired - Lifetime
- 1997-11-19 CA CA 2221532 patent/CA2221532C/fr not_active Expired - Fee Related
- 1997-11-19 US US08/974,316 patent/US6033777A/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4436877A (en) * | 1982-11-08 | 1984-03-13 | Polyplastics Co., Ltd. | Thermoplastic polyester composition |
| US5169711A (en) * | 1988-08-05 | 1992-12-08 | Jwi Ltd. | Paper makers forming fabric |
| EP0387395B1 (fr) * | 1989-03-17 | 1994-12-07 | Jwi Limited | Toile stabilisée pour machine de fabrication de papier en polyester modifié avec le polyuréthane |
| US5319039A (en) * | 1992-04-30 | 1994-06-07 | The Dow Chemical Company | Thermally processable blends of aromatic polyesters and high modulus polyurethanes |
| DE4410399A1 (de) * | 1994-03-25 | 1995-09-28 | Hoechst Ag | Abriebfeste Polyestermischung mit erhöhter Verarbeitungssicherheit, Monofilamente daraus und deren Herstellung und Verwendung |
| US5700881A (en) * | 1994-03-25 | 1997-12-23 | Hoechst Aktiengesellschaft | Abrasion-resistant polyester mixture with enhanced consistency of processing, monofilaments therefrom, and production and use thereof |
| WO1996000808A1 (fr) * | 1994-06-30 | 1996-01-11 | E.I. Du Pont De Nemours And Company | Procede de fabrication de fils continus, gonflants, de poly(trimethylene terephtalate), fils et tapis obtenus a partir de ce procede |
| US5763040A (en) * | 1995-04-18 | 1998-06-09 | E. I. Du Pont De Nemours And Company | Rug and carpet underlays substantially impervious to liquids |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102877143A (zh) * | 2012-10-23 | 2013-01-16 | 江苏中润纤维科技股份有限公司 | 高仿棉多孔超细异形聚酯纤维的制备工艺及工艺设备 |
| CN102877143B (zh) * | 2012-10-23 | 2014-12-17 | 江苏中润纤维科技股份有限公司 | 高仿棉多孔超细异形聚酯纤维的制备工艺及工艺设备 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2221532A1 (fr) | 1998-05-20 |
| ATE205558T1 (de) | 2001-09-15 |
| CA2221532C (fr) | 2000-11-07 |
| EP0844320A2 (fr) | 1998-05-27 |
| EP0844320A3 (fr) | 1999-01-13 |
| US6033777A (en) | 2000-03-07 |
| ES2163700T3 (es) | 2002-02-01 |
| PT844320E (pt) | 2002-02-28 |
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