EP0860183B1 - Verfahren und System zur Entfernung von Schadstoffen - Google Patents
Verfahren und System zur Entfernung von Schadstoffen Download PDFInfo
- Publication number
- EP0860183B1 EP0860183B1 EP98102829A EP98102829A EP0860183B1 EP 0860183 B1 EP0860183 B1 EP 0860183B1 EP 98102829 A EP98102829 A EP 98102829A EP 98102829 A EP98102829 A EP 98102829A EP 0860183 B1 EP0860183 B1 EP 0860183B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- chlorine
- treatable material
- removal agent
- sulfur
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 55
- 230000001473 noxious effect Effects 0.000 title description 120
- 239000000460 chlorine Substances 0.000 claims abstract description 167
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 166
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 165
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 107
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000011593 sulfur Substances 0.000 claims abstract description 68
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 68
- 238000010438 heat treatment Methods 0.000 claims abstract description 56
- 239000000126 substance Substances 0.000 claims abstract description 51
- 239000000203 mixture Substances 0.000 claims abstract description 50
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 26
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000002156 mixing Methods 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims description 191
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 102
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 93
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 82
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 59
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 51
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 36
- 150000001875 compounds Chemical group 0.000 claims description 32
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 30
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 27
- 239000011736 potassium bicarbonate Substances 0.000 claims description 24
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 24
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 24
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 20
- 229910052760 oxygen Inorganic materials 0.000 claims description 20
- 239000001301 oxygen Substances 0.000 claims description 20
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 18
- 229940086066 potassium hydrogencarbonate Drugs 0.000 claims description 18
- 235000011118 potassium hydroxide Nutrition 0.000 claims description 18
- 235000017550 sodium carbonate Nutrition 0.000 claims description 14
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 claims description 14
- 235000018341 sodium sesquicarbonate Nutrition 0.000 claims description 14
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 claims description 14
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 13
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 12
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 235000011181 potassium carbonates Nutrition 0.000 claims description 10
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 9
- 239000004800 polyvinyl chloride Substances 0.000 claims description 9
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 9
- 239000005033 polyvinylidene chloride Substances 0.000 claims description 9
- 238000000197 pyrolysis Methods 0.000 claims description 9
- 150000003112 potassium compounds Chemical class 0.000 claims description 8
- 229920001971 elastomer Polymers 0.000 claims description 7
- VLYFRFHWUBBLRR-UHFFFAOYSA-L potassium;sodium;carbonate Chemical compound [Na+].[K+].[O-]C([O-])=O VLYFRFHWUBBLRR-UHFFFAOYSA-L 0.000 claims description 7
- 239000005060 rubber Substances 0.000 claims description 7
- 229920003002 synthetic resin Polymers 0.000 claims description 6
- 239000000057 synthetic resin Substances 0.000 claims description 6
- 150000003388 sodium compounds Chemical class 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 3
- 229940093956 potassium carbonate Drugs 0.000 claims description 3
- 229940093932 potassium hydroxide Drugs 0.000 claims description 3
- 235000015424 sodium Nutrition 0.000 claims description 3
- 229940083608 sodium hydroxide Drugs 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 239000002699 waste material Substances 0.000 abstract description 22
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 abstract description 11
- 150000001339 alkali metal compounds Chemical class 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 138
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 64
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 57
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 51
- 229910001868 water Inorganic materials 0.000 description 51
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 40
- 238000011282 treatment Methods 0.000 description 40
- 238000007669 thermal treatment Methods 0.000 description 36
- 238000006243 chemical reaction Methods 0.000 description 31
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 30
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 27
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 27
- 229910002092 carbon dioxide Inorganic materials 0.000 description 25
- 235000011164 potassium chloride Nutrition 0.000 description 19
- 239000001103 potassium chloride Substances 0.000 description 18
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 17
- 239000000446 fuel Substances 0.000 description 15
- -1 power Substances 0.000 description 14
- 239000005539 carbonized material Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 12
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 12
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 12
- 239000011343 solid material Substances 0.000 description 12
- 229910052783 alkali metal Inorganic materials 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 11
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 10
- 239000000920 calcium hydroxide Substances 0.000 description 10
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 10
- 239000010813 municipal solid waste Substances 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- 239000011780 sodium chloride Substances 0.000 description 9
- 235000002639 sodium chloride Nutrition 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 238000000354 decomposition reaction Methods 0.000 description 8
- 235000011116 calcium hydroxide Nutrition 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000003513 alkali Substances 0.000 description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 description 6
- 150000001805 chlorine compounds Chemical class 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- NEAPKZHDYMQZCB-UHFFFAOYSA-N N-[2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]ethyl]-2-oxo-3H-1,3-benzoxazole-6-carboxamide Chemical compound C1CN(CCN1CCNC(=O)C2=CC3=C(C=C2)NC(=O)O3)C4=CN=C(N=C4)NC5CC6=CC=CC=C6C5 NEAPKZHDYMQZCB-UHFFFAOYSA-N 0.000 description 5
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 5
- 150000008041 alkali metal carbonates Chemical class 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 5
- 239000004568 cement Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000011835 investigation Methods 0.000 description 4
- 231100000614 poison Toxicity 0.000 description 4
- 230000007096 poisonous effect Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 230000000630 rising effect Effects 0.000 description 4
- DFGKGUXTPFWHIX-UHFFFAOYSA-N 6-[2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]acetyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)C1=CC2=C(NC(O2)=O)C=C1 DFGKGUXTPFWHIX-UHFFFAOYSA-N 0.000 description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002440 industrial waste Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- JQMFQLVAJGZSQS-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-N-(2-oxo-3H-1,3-benzoxazol-6-yl)acetamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)NC1=CC2=C(NC(O2)=O)C=C1 JQMFQLVAJGZSQS-UHFFFAOYSA-N 0.000 description 2
- CONKBQPVFMXDOV-QHCPKHFHSA-N 6-[(5S)-5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-2-oxo-1,3-oxazolidin-3-yl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C[C@H]1CN(C(O1)=O)C1=CC2=C(NC(O2)=O)C=C1 CONKBQPVFMXDOV-QHCPKHFHSA-N 0.000 description 2
- WTFUTSCZYYCBAY-SXBRIOAWSA-N 6-[(E)-C-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-N-hydroxycarbonimidoyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C/C(=N/O)/C1=CC2=C(NC(O2)=O)C=C1 WTFUTSCZYYCBAY-SXBRIOAWSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 241001625808 Trona Species 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 229910052925 anhydrite Inorganic materials 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 239000010849 combustible waste Substances 0.000 description 2
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- LLQHSBBZNDXTIV-UHFFFAOYSA-N 6-[5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-4,5-dihydro-1,2-oxazol-3-yl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC1CC(=NO1)C1=CC2=C(NC(O2)=O)C=C1 LLQHSBBZNDXTIV-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- MPONAPFARZGDTH-UHFFFAOYSA-N Cl.OS(O)=O Chemical compound Cl.OS(O)=O MPONAPFARZGDTH-UHFFFAOYSA-N 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 210000003278 egg shell Anatomy 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 238000011328 necessary treatment Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000013502 plastic waste Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/34—Dehalogenation using reactive chemical agents able to degrade
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/40—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by heating to effect chemical change, e.g. pyrolysis
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
- F23G5/0276—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using direct heating
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/22—Organic substances containing halogen
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/40—Inorganic substances
- A62D2101/47—Inorganic substances containing oxygen, sulfur, selenium or tellurium, i.e. chalcogen
Definitions
- chlorine-containing compound and chlorine component in the treatable material can be converted into sodium or potassium chloride and water, and therefore hydrogen chloride forming part of a source of dioxin cannot be formed thereby realizing the unexpected results of making both emitted gas and residue harmless.
- the thermal treatment or heating of the mixture in the thermal treatment furnace 2 is accomplished within temperature and time ranges to cover the temperature and time of generation of HCl gas and SOx gas from the treatable material, the temperature (for example, 600 °C) and time (for example, 1 hour) having been determined under a previous investigation.
- These temperature and time are in relation to a condition (such as the size and the heating coil) of the thermal treatment furnace, the treatment amount of the treatable material, the treatment time of the thermal treatment of the treatable material, the treatment temperature of the thermal treatment of the treatable material. Therefore, the above temperature and time are required to be previously determined under a sufficient investigation and to accumulate the data to be taken for the temperature and time.
- the chlorine removal agent sodium hydrogen carbonate
- the chlorine removal agent was in the form of powder having an average particle size of 100 ⁇ m, in all Examples
- the thus sealed tank was stepwise heated with a heating coil, in which heating was made at eight temperature steps of 250 °C, 300 °C, 350 °C, 400 °C, 450 °C, 500 °C, 550 °C, 600 °C.
- the temperature at each of the eight steps was kept for 5 minutes, in which a concentration of HCl gas and a concentration of SO 2 in the tank was measured at each temperature rising time (at which the temperature was rising from one temperature step to the next temperature step) and at each temperature keeping time (at which the temperature at each temperature step was keeping).
- the temperature rising time is indicated as "Rising time” while the temperature keeping time is indicated as "Keeping time” in Tables 1 and 2.
- the temperature for heating the mixture of the treatable material and the chlorine removal agent may be selected according to form of facilities for accomplish the thermal treatment, time of the thermal treatment, amount of the treatable material and the like.
- sodium hydrogen carbonate (NaHCO 3 ), sodium carbonate (Na 2 CO 3 ), sodium sesqui carbonate (Na 2 CO 3 • NaHCO 3 • 2H 2 O), natural soda (containing Na 2 CO 3 • NaHCO 3 • 2H 2 O), sodium hydroxide (NaOH), potassium hydroxide (KOH), potassium carbonate (K 2 CO 3 ), and potassium hydrogen carbonate (KHCO 3 ) can react with noxious HCl thereby to convert HCl into harmless chloride (NaCl and KCl) according to reaction formulae discussed before. It will be understood that sodium potassium carbonate and sodium carbonate hydrate can also react with noxious HCl similarly to the above.
- chlorine-containing compound and chlorine component in the treatable material can be converted into sodium chloride (NaCl), potassium chloride (KCl), water (H 2 O) and carbon dioxide gas (CO 2 ), and therefore hydrogen chloride forming part of a source of dioxin cannot be formed thereby realizing the unexpected result of making both emitted gas and residue harmless.
- NaOH or KOH smoothly reacts with SO2 thereby to newly form harmless sulfite (Na 2 SO 3 , K 2 SO 3 ).
- sulfur-containing compound and sulfur component in the treatable material can be converted into sodium sulfite (Na 2 SO 3 ) in powder form, and potassium sulfite (K 2 SO 3 ) in powder form, water (H 2 O) and carbon dioxide gas (CO 2 ), and therefore SOx gas can be prevented from generation thus realizing the unexpected result of making both emitted gas and residue harmless.
- noxious hydrogen chloride and/or sulfur oxide are converted into harmless chloride (NaCl, KCl) and/or sulfite (Na 2 SO 3 , K 2 SO 3 ), thereby making it possible to remove noxious components (hydrogen chloride and/or sulfur oxide) from the decomposition gas generated from the treatable material upon heating.
- the decomposition gas or emitted gas from the furnace can be effectively made harmless.
- the chloride and/or sulfite form part of the residue and can be effectively removed under a rinsing or dissolving treatment with water or the like.
- the residual materials can be separated into respective materials which are different in characteristics by any separating means.
- the separated respective materials are dried and massed to be usable as fuel or the like.
- liquid (such as water) used for the above rinsing treatment hardly contains no noxious substances and therefore can be discharged as it is to a river and the sea.
Landscapes
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Treating Waste Gases (AREA)
- Processing Of Solid Wastes (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Fire-Extinguishing Compositions (AREA)
- Removal Of Specific Substances (AREA)
- Hardware Redundancy (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Claims (19)
- Verfahren zum Entfernen von Chlor oder Schwefel oder beiden aus einem zu behandelnden Material, das Chlor oder Schwefel oder beide enthält, wobei das Verfahren die folgenden Schritte in der angegebenen Reihenfolge aufweist:Mischen des zu behandelnden Materials und eines Mittels zum Entfernen von Chlor und Schwefel unter Bildung einer Mischung, wobei das Mittel zum Entfernen von Chlor und Schwefel wenigstens eine Verbindung aus der Gruppe enthält, die aus einer Natriumverbindung und einer Kaliumverbindung besteht; undZuführen der Mischung in einen Ofen;Rühren und Erhitzen der Mischung in einer Atmosphäre mit niedriger Sauerstoffkonzentration in dem Ofen, um das zu behandelnde Material thermisch zu zersetzen, um eine chlor- oder schwefelhaltige Substanz oder beide zu erzeugen und die chlor- oder schwefelhaltige Substanz oder beide mit dem Mittel zum Entfernen von Chlor und Schwefel in Kontakt kommen und reagieren zu lassen, um unschädliches Chlorid oder Sulfit oder beides zu bilden.
- Verfahren nach Anspruch 1, bei dem Chlor aus einem zu behandelnden, chlorhaltigen Material entfernt wird.
- Verfahren nach Anspruch 1 oder 2, bei dem das Mittel zum Entfernen wenigstens eine Verbindung aus der Gruppe enthält, die aus Natrium- und Kaliumcarbonat, -hydrogencarbonat und -hydroxid besteht.
- Verfahren nach Anspruch 1 oder 2, bei dem das Mittel zum Entfernen wenigstens eine Verbindung aus der Gruppe enthält, die aus Natriumhydrogencarbonat, Natriumcarbonat, Natriumsesquicarbonat, Natursoda, Natriumhydroxid, Kaliumhydroxid, Kaliumcarbonat, Kaliumhydrogencarbonat und Kaliumnatriumcarbonat besteht.
- Verfahren nach Anspruch 2, bei dem der Heizschritt den Schritt des Erhitzens der Mischung in einem Ofen einschließt, der im wesentlichen abgedichtet ist, um zu verhindern, daß Frischluft dem Ofen zugeführt wird, indem ein Druck im Ofen aus dem Ofen austritt.
- Verfahren nach Anspruch 2, bei dem der Heizschritt den Schritt des Erhitzens der Mischung einschließt, um das zu behandelnde Material zu dessen Trockendestillation zu veranlassen.
- Verfahren nach Anspruch 2, bei dem das Material zum Entfernen wenigstens eine der Formen aus der Gruppe aufweist, die aus Masse, Platte, porösem Körper, Teilchen, Lösung und Suspension besteht.
- Verfahren nach Anspruch 2, bei dem das zu behandelnde Material wenigstens eines aus der Gruppe ist, die aus Polyvinylchlorid, Polyvinylidenchlorid, einem synthetischen, chlorhaltigen Harz und einem chlorhaltigen Kautschuk besteht.
- Verfahren nach Anspruch 2, bei dem das Material zum Entfernen in dem Mischschritt in einer Menge im Bereich von 0,05 bis 10 Gew.-% vorliegt, bezogen auf das zu behandelnde Material zum Zeitpunkt vor dem Mischschritt.
- Verfahren nach Anspruch 2, bei dem das Mittel zum Entfernen in dem Mischschritt in einer Menge im Bereich von 10 bis 70 Gew.-% vorliegt, bezogen auf das zu behandelnde Material, sofern das zu behandelnde Material wenigstens eines aus der Gruppe ist, die aus Polyvinylchlorid, Polyvinylidenchlorid, einem synthetischen, chlorhaltigen Harz und einem chlorhaltigen Kautschuk besteht.
- Verfahren nach Anspruch 2, bei dem das Mittel zum Entfernen in dem Mischschritt in einer Menge nicht unter einem chemischen Äquivalent des Chlors vorliegt, das aus dem zu behandelnden Material freizusetzen ist.
- Verfahren nach Anspruch 2, das außerdem den Schritt der Zugabe des Mittels zum Entfernen zu der Mischung in dem Heizschritt aufweist.
- Verfahren nach Anspruch 12, bei dem die Zugabe des Mittels zum Entfernen zu der Mischung erfolgt, bevor die Temperatur des zu behandelnden Materials eine Höhe erreicht, bei der eine thermische Zersetzung des zu behandelnden Materials stattfindet.
- Verfahren nach Anspruch 12, bei dem die Zugabe des Mittels zum Entfernen zu der Mischung erfolgt, nachdem die Temperatur des zu behandelnden Materials eine Höhe erreicht hat, bei der eine thermische Zersetzung des zu behandelnden Materials stattfindet.
- Verfahren nach Anspruch 2, bei dem außerdem die Zuführung des Mittels zum Entfernen zu dem zu behandelnden Material in einem Ofen durch Gießen und/oder Sprühen erfolgt.
- Verfahren nach Anspruch 2, bei dem im Heizschritt das Erhitzen des zu behandelnden Materials auf eine Temperatur im Bereich von 200 bis 1000°C erfolgt.
- System zum Entfernen von Chlor oder Schwefel oder beiden aus einem zu behandelnden Material, das Chlor oder Schwefel oder beide enthält, mit:einer Vorrichtung zum Mischen des zu behandelnden Materials und eines Mittels zum Entfernen von Chlor und Schwefel unter Bildung einer Mischung, wobei das Mittel zum Entfernen von Chlor und Schwefel wenigstens eine Verbindung aus der Gruppe enthält, die aus einer Natriumverbindung und einer Kaliumverbindung besteht;einem Ofen, dem die Mischung aus dem zu behandelnden Material und dem Mittel zum Entfernen von Chlor und Schwefel zugeführt wird, wobei der Ofen so angepaßt ist, um eine Atmosphäre mit niedriger Sauerstoffkonzentration darin zu bilden, und mit einem rotierenden Transportmittel ausgestattet ist; undeiner Heizeinrichtung zum Heizen der Mischung in der Atmosphäre mit niedriger Sauerstoffkonzentration in dem Ofen, um das zu behandelnde Material thermisch zu zersetzen, so daß eine Trockendestillation des zu behandelnden Materials durchgeführt wird, bei der die Mischung eine chlor- oder schwefelhaltige Substanz oder beide erzeugt und die chlor- oder schwefelhaltige Substanz oder beide mit dem Mittel zum Entfernen von Chlor und Schwefel in Kontakt und zur Reaktion gebracht wird, um unschädliches Chlorid oder Sulfit oder beides zu bilden.
- System nach Anspruch 17, bei dem das Mittel zum Entfernen von Chlor und Schwefel wenigstens eine Verbindung aus der Gruppe enthält, die aus Natrium- und Kaliumcarbonat, -hydrogencarbonat und -hydroxid besteht.
- System nach Anspruch 17, bei dem das Mittel zum Entfernen von Chlor und Schwefel wenigstens eine Verbindung aus der Gruppe enthält, die aus Natriumhydrogencarbonat, Natriumcarbonat, Natriumsesquicarbonat, Natursoda, Natriumhydroxid, Kaliumhydroxid, Kaliumcarbonat, Kaliumhydrogencarbonat und Kaliumnatriumcarbonat besteht.
Applications Claiming Priority (21)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9038729A JPH10235149A (ja) | 1997-02-24 | 1997-02-24 | 塩化ビニル系物質の脱塩素処理方法 |
| JP3872897 | 1997-02-24 | ||
| JP3873797 | 1997-02-24 | ||
| JP3872997 | 1997-02-24 | ||
| JP9038728A JPH10235148A (ja) | 1997-02-24 | 1997-02-24 | 脱塩素処理方法 |
| JP38726/97 | 1997-02-24 | ||
| JP9038726A JPH10235147A (ja) | 1997-02-24 | 1997-02-24 | 脱塩素処理方法 |
| JP3872697 | 1997-02-24 | ||
| JP38729/97 | 1997-02-24 | ||
| JP38737/97 | 1997-02-24 | ||
| JP9038737A JPH10235311A (ja) | 1997-02-24 | 1997-02-24 | 塩化ビニル系物質の脱塩素処理方法 |
| JP38728/97 | 1997-02-24 | ||
| JP9160911A JPH119938A (ja) | 1997-06-18 | 1997-06-18 | 脱塩素処理方法 |
| JP16091197 | 1997-06-18 | ||
| JP160911/97 | 1997-06-18 | ||
| JP160914/97 | 1997-06-18 | ||
| JP16091497 | 1997-06-18 | ||
| JP9160914A JPH119939A (ja) | 1997-06-18 | 1997-06-18 | 塩化ビニル系物質の脱塩素処理方法 |
| JP26599397 | 1997-09-30 | ||
| JP9265993A JPH11101417A (ja) | 1997-09-30 | 1997-09-30 | 有害ガスの発生防止方法 |
| JP265993/97 | 1997-09-30 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0860183A2 EP0860183A2 (de) | 1998-08-26 |
| EP0860183A3 EP0860183A3 (de) | 1999-01-20 |
| EP0860183B1 true EP0860183B1 (de) | 2002-11-13 |
Family
ID=27564474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP98102829A Expired - Lifetime EP0860183B1 (de) | 1997-02-24 | 1998-02-18 | Verfahren und System zur Entfernung von Schadstoffen |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0860183B1 (de) |
| KR (1) | KR100341551B1 (de) |
| CN (1) | CN1095687C (de) |
| AT (1) | ATE227598T1 (de) |
| AU (1) | AU714634B2 (de) |
| DE (1) | DE69809310T2 (de) |
| DK (1) | DK0860183T3 (de) |
| ES (1) | ES2186931T3 (de) |
| MY (1) | MY121329A (de) |
| NO (1) | NO316905B1 (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597387B (zh) * | 2009-05-22 | 2011-12-07 | 上海岚淼水处理科技有限公司 | 用于工业水处理的多糖纳米除氯剂的制备方法 |
| US9440218B2 (en) * | 2013-06-13 | 2016-09-13 | Clariant Corporation | Methods and active materials for reducing halide concentration in gas streams |
| CN104971609B (zh) * | 2015-07-22 | 2017-04-05 | 南京格洛特环境工程股份有限公司 | 一种氟化氢废气治理及资源化利用的方法及设备 |
| CN108339365B (zh) * | 2017-01-24 | 2020-09-25 | 内蒙古大学 | 一种用于控制化工工业废气排放的装置及方法 |
| CN109001007A (zh) * | 2018-08-22 | 2018-12-14 | 汉能新材料科技有限公司 | 一种物料的处理方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4938936A (en) * | 1988-09-01 | 1990-07-03 | Mobil Oil Corporation | Hydrogen fluoride vapor containment and neutralization |
| DE3839799A1 (de) * | 1988-11-25 | 1990-07-05 | Rwe Entsorgung Ag | Verfahren zur aufarbeitung kontaminierter oele |
| US5064526A (en) * | 1990-04-27 | 1991-11-12 | The United States Of America As Represented By The Administrator Of The Environmental Protection Agency | Method for the base-catalyzed decomposition of halogenated and non-halogenated organic compounds in a contaminated medium |
| US5039350A (en) * | 1990-04-27 | 1991-08-13 | The United States Of America As Represented By The Administrator Of The Environmental Protection Agency | Method for the decomposition of halogenated organic compounds in a contaminated medium |
| JP3213134B2 (ja) * | 1993-09-13 | 2001-10-02 | 株式会社東芝 | 加熱油化方法及びその装置 |
| JP3288164B2 (ja) * | 1993-12-28 | 2002-06-04 | 株式会社東芝 | 廃プラスチックの熱分解装置 |
| JPH06179877A (ja) * | 1991-12-20 | 1994-06-28 | Toshiba Corp | 廃プラスチックの熱分解方法及び装置 |
| CA2159521C (en) * | 1994-10-07 | 1999-11-09 | Shigeo Iiyama | Method for desulfurizing exhaust gas |
| NO308831B1 (no) * | 1995-03-22 | 2000-11-06 | Nkt Res Ct As | FremgangsmÕte for behandling av halogenholdig avfallsmateriale |
-
1998
- 1998-02-18 DK DK98102829T patent/DK0860183T3/da active
- 1998-02-18 DE DE69809310T patent/DE69809310T2/de not_active Expired - Fee Related
- 1998-02-18 AT AT98102829T patent/ATE227598T1/de not_active IP Right Cessation
- 1998-02-18 ES ES98102829T patent/ES2186931T3/es not_active Expired - Lifetime
- 1998-02-18 EP EP98102829A patent/EP0860183B1/de not_active Expired - Lifetime
- 1998-02-23 CN CN98107704A patent/CN1095687C/zh not_active Expired - Fee Related
- 1998-02-23 KR KR1019980005575A patent/KR100341551B1/ko not_active Expired - Fee Related
- 1998-02-23 MY MYPI98000755A patent/MY121329A/en unknown
- 1998-02-23 NO NO19980758A patent/NO316905B1/no unknown
- 1998-02-24 AU AU56329/98A patent/AU714634B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| AU5632998A (en) | 1998-08-27 |
| NO316905B1 (no) | 2004-06-21 |
| DE69809310D1 (de) | 2002-12-19 |
| KR19980071609A (ko) | 1998-10-26 |
| AU714634B2 (en) | 2000-01-06 |
| DE69809310T2 (de) | 2003-03-20 |
| EP0860183A3 (de) | 1999-01-20 |
| CN1095687C (zh) | 2002-12-11 |
| ES2186931T3 (es) | 2003-05-16 |
| ATE227598T1 (de) | 2002-11-15 |
| EP0860183A2 (de) | 1998-08-26 |
| MY121329A (en) | 2006-01-28 |
| CN1197685A (zh) | 1998-11-04 |
| KR100341551B1 (ko) | 2002-08-22 |
| NO980758L (no) | 1998-08-25 |
| DK0860183T3 (da) | 2003-03-10 |
| NO980758D0 (no) | 1998-02-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0937766B1 (de) | Verfahren und System zur Behandlung schadstoffhaltiger Materialien | |
| EP0860183A2 (de) | Verfahren und Mittel zur Entfernung von Schadstoffen | |
| JP3785789B2 (ja) | 有害成分含有物の処理方法と処理装置 | |
| JPH1121573A (ja) | Rdfの脱塩素処理方法 | |
| JPH10235308A (ja) | 水分含有被処理物の脱塩素処理方法 | |
| JP2000044299A (ja) | セメントクリンカーの製造方法 | |
| JP3852204B2 (ja) | 有害成分含有物の処理方法と処理装置 | |
| JPH1119617A (ja) | 固形化処理済み物の脱塩素処理方法 | |
| JPH11333438A (ja) | 有害成分含有物の処理装置 | |
| JP2000044962A (ja) | 排ガス燃焼装置を備えた廃棄物等の処理施設 | |
| JPH11244814A (ja) | 有害成分含有物の処理方法と処理装置 | |
| JPH10235147A (ja) | 脱塩素処理方法 | |
| JP2000015214A (ja) | 廃棄物等の処理方法 | |
| JPH10132233A (ja) | 廃棄物の燃焼処理装置及び廃棄物の燃焼処理方法 | |
| JPH10249308A (ja) | 塩素を含むプラスチック材の乾留処理方法 | |
| JPH11333404A (ja) | 有害成分含有物の処理装置 | |
| JP2000005725A (ja) | 有害成分含有物の処理方法と処理装置 | |
| JP2000008045A (ja) | 有害成分含有物の処理方法と処理装置 | |
| JP2000015213A (ja) | 廃棄物等の加熱処理炉の運転方法 | |
| JPH115867A (ja) | 塩素を含むプラスチック材の乾留処理方法 | |
| JPH11333417A (ja) | 有害成分含有物の処理装置 | |
| JPH11244813A (ja) | 有害成分含有物の処理装置 | |
| JPH11104454A (ja) | 排ガス中の有害成分除去方法 | |
| JPH1110112A (ja) | プラスチック材の脱塩素処理方法 | |
| JPH10235150A (ja) | 排ガス処理方法と排ガス処理反応塔 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 19980218 |
|
| AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE CH DE DK ES FI FR GB IT LI NL SE |
|
| AX | Request for extension of the european patent |
Free format text: AL;LT;LV;MK;RO;SI |
|
| PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
| AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
|
| AX | Request for extension of the european patent |
Free format text: AL;LT;LV;MK;RO;SI |
|
| AKX | Designation fees paid |
Free format text: AT BE CH DE DK ES FI FR GB IT LI NL SE |
|
| 17Q | First examination report despatched |
Effective date: 20000320 |
|
| GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
| RTI1 | Title (correction) |
Free format text: NOXIOUS COMPONENT REMOVAL PROCESS AND SYSTEM |
|
| GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
| GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
| GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH DE DK ES FI FR GB IT LI NL SE |
|
| REF | Corresponds to: |
Ref document number: 227598 Country of ref document: AT Date of ref document: 20021115 Kind code of ref document: T |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
| REF | Corresponds to: |
Ref document number: 69809310 Country of ref document: DE Date of ref document: 20021219 |
|
| REG | Reference to a national code |
Ref country code: DK Ref legal event code: T3 |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2186931 Country of ref document: ES Kind code of ref document: T3 |
|
| ET | Fr: translation filed | ||
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| 26N | No opposition filed |
Effective date: 20030814 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20050210 Year of fee payment: 8 Ref country code: FI Payment date: 20050210 Year of fee payment: 8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: AT Payment date: 20050211 Year of fee payment: 8 Ref country code: DK Payment date: 20050211 Year of fee payment: 8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20050216 Year of fee payment: 8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20050217 Year of fee payment: 8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20050309 Year of fee payment: 8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20060216 Year of fee payment: 9 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20060218 Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20060218 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20060219 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20060220 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20060228 Ref country code: DK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20060228 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20060228 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20060228 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20060228 Year of fee payment: 9 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20060428 Year of fee payment: 9 |
|
| REG | Reference to a national code |
Ref country code: DK Ref legal event code: EBP |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| EUG | Se: european patent has lapsed | ||
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20070213 Year of fee payment: 10 |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20060220 |
|
| GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20070218 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20071030 |
|
| BERE | Be: lapsed |
Owner name: *MEIDENSHA K.K. Effective date: 20060228 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070901 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070218 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070228 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20060221 Year of fee payment: 9 |
|
| NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee |
Effective date: 20080901 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080901 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070218 |