EP0888224A1 - Feuille decorative pour decorer des surfaces de substrat tridimensionnelles - Google Patents

Feuille decorative pour decorer des surfaces de substrat tridimensionnelles

Info

Publication number
EP0888224A1
EP0888224A1 EP96907272A EP96907272A EP0888224A1 EP 0888224 A1 EP0888224 A1 EP 0888224A1 EP 96907272 A EP96907272 A EP 96907272A EP 96907272 A EP96907272 A EP 96907272A EP 0888224 A1 EP0888224 A1 EP 0888224A1
Authority
EP
European Patent Office
Prior art keywords
decorative
layer
film
carrier film
film according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP96907272A
Other languages
German (de)
English (en)
Other versions
EP0888224B1 (fr
Inventor
Robert Reck
Joachim Süss
Heinrich Wild
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Leonhard Kurz Stiftung and Co KG
Original Assignee
Leonhard Kurz GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Leonhard Kurz GmbH and Co KG filed Critical Leonhard Kurz GmbH and Co KG
Publication of EP0888224A1 publication Critical patent/EP0888224A1/fr
Application granted granted Critical
Publication of EP0888224B1 publication Critical patent/EP0888224B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • B44C1/1729—Hot stamping techniques
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/10—Applying flat materials, e.g. leaflets, pieces of fabrics
    • B44C1/105—Applying flat materials, e.g. leaflets, pieces of fabrics comprising an adhesive layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]

Definitions

  • the invention relates to decorative foils for decorating three-dimensional substrate surfaces with heating, which consist of a carrier film and a decorative layer arranged thereon, which is formed by at least one lacquer layer printed to form a precisely fitting decor.
  • Such decorative films can be constructed both as transfer films in the manner of a hot stamping film and as a laminating film, the decorative layer being detached from the carrier film during the transfer process when used as a transfer film
  • Total laminating films i.e. Both the carrier film and the decorative layer are transferred to the substrate to be decorated.
  • Decorative films made from a carrier film and a decorative layer forming the actual decoration are used in a wide variety of fields, one of the fields of application being the decoration of three-dimensional surfaces. If you have one If the surface is to be provided with a decorative film, the decorative film used to apply the decorative film must be able to adapt as precisely as possible to the surface irregularities, for which purpose it is also necessary that the decorative film can be stretched sufficiently under certain circumstances. This property plays a role above all in the decoration of three-dimensional molded parts in presses, in which the decorative film is applied against the surface of the molded part, be it with the aid of a membrane or only with the formation of corresponding pressure differences. Another area of application is the so-called "insert molding", in which the film is placed in an injection mold and then back-injected with plastic to form the molded part.
  • the invention is based on the object of creating a decorative film which is particularly suitable for the decoration of finely structured, three-dimensional substrate surfaces, wherein, moreover, a precisely fitting decor present in the layer when the decorative film is applied to the three-dimensional substrate is not or only in a predetermined manner Modified so that it becomes possible when using a decorative film according to the invention, finely structured, three-dimensional Decorate substrate surfaces flawlessly and with a precisely predictable pattern.
  • this object can be achieved in an extremely simple manner in that an essentially amorphous, unstretched polyester, polyamide or polyamide copolymer film is used as the carrier film, the carrier film preferably being a polyethylene terephthalate film.
  • Decorative films according to the invention with an amorphous, unstretched polyamide or polyester film as a carrier have the advantage, in particular, for the specially provided fields of application that they can be deformed to a great extent, even at relatively low temperatures.
  • polyester films, which is known per se are very resistant to the usual solvents.
  • Another advantage of the carrier film proposed according to the invention is its comparatively low price.
  • the inventor's merit in the present case is to have recognized that these problems can be prevented if the carrier film is skilfully guided during the printing process and the decor is appropriately designed, and can also be made using the amorphous, unstretched film, which per se appears to be unsuitable Have polyester or polyamide produce suitable decorative foils for the intended purposes.
  • the already mentioned resistance of the carrier film to the solvents and aqueous systems commonly used in paints or surface coatings offers the advantage that a wide range of paints can be used, e.g. it is also possible to design the gloss level of the carrier film (which is generally slightly matt and semi-transparent) by means of an appropriate lacquer intermediate layer to meet the respective needs.
  • the decorative layer comprises at least one decorative lacquer layer forming the precisely fitting decor and a protective lacquer layer covering it in use after application to the substrate surface, the protective lacquer layer for example having a correspondingly high mechanical strength or UV light resistance.
  • the decorative layer forms at least one that forms the precisely fitting decor
  • Decorative lacquer layer and in use after application to the substrate surface under the decorative lacquer layer, applied over the entire surface color lacquer layer, which opens up further design options.
  • an adhesive layer is provided for attachment to the substrate surface.
  • consideration can be given to the type and surface of the substrate to be decorated.
  • it would also be conceivable to dispense with the adhesive layer be it that the decorative layer itself has sufficient adhesive properties or be that the adhesive layer is applied to the substrate before the decorative film is applied.
  • the decorative layer is arranged between the carrier film and the adhesive layer in order to use the decorative film as a heat transfer film, expedient in such a case a release layer is provided between the decorative layer and the carrier film, which facilitates the removal of the carrier film after the application of the decorative layer on the substrate.
  • a heat transfer film according to the invention is expediently constructed such that the release layer, the protective lacquer layer, the decorative lacquer layer, the colored lacquer layer and the adhesive layer are arranged in succession on the carrier film, if present.
  • the decorative film according to the invention can be designed not only as a heat transfer film but also as a laminating film, the carrier film according to the invention between the decorative layer and the
  • Adhesive layer is arranged.
  • the carrier film carries the color lacquer layer, the decorative lacquer layer and the protective lacquer layer in succession on its side facing away from the adhesive layer.
  • Fig. 1 is a heat transfer film
  • Fig. 2 is a laminating film. 97/34774 PO7DE96 / 00516
  • the heat transfer film shown in Fig. 1 comprises a carrier film 1, on which a release layer 2, e.g. a wax layer, a total of 3 decorative layer is defined.
  • a release layer 2 e.g. a wax layer
  • the carrier film 1 is an essentially amorphous, unstretched polyester film which can have a thickness of 20 to 100 ⁇ m, depending on the area of use.
  • Amorphous, unstretched polyethylene terephthalate films have been found to be particularly suitable, their softening range being between 70 ° C. and 80 ° C.
  • the elasticity is greater than 300% when the softening temperature is exceeded.
  • polyester in particular polyethylene terephthalate films, amorphous, unstretched polyamide films and films made from copolymers based on polyamide with softening temperatures of less than 120 ° C. and an extensibility of over 300% when this temperature is exceeded have also proven to be suitable.
  • the decorative layer 3 of the exemplary embodiment in FIG. 1 then includes a transparent protective lacquer layer 4 after the release layer 2.
  • a continuous colored lacquer layer 6 is provided after the decorative lacquer layer 5.
  • the last layer of the decorative layer 3 forms an adhesive layer 7, for example from a heat-activatable adhesive.
  • the layer thicknesses in the heat transfer film of Fig.l are as follows:
  • Removal layer 0.01 to 0.50 ⁇ m protective lacquer layer 1 to 5 ⁇ m decorative lacquer layer 0.1 to 2 ⁇ m colored lacquer layer 3 to 25 ⁇ m adhesive layer 5 to 20 ⁇ m
  • the heat transfer film according to FIG. 1 is pressed against the correspondingly structured surface of a substrate either by means of a membrane or else only by means of a corresponding pressure difference - using the heat transfer film itself as a membrane, the decorative layer 3 pointing towards the substrate and is fixed to the substrate surface by means of the adhesive layer 7. After complete application of the heat transfer film to the substrate surface and, if necessary, some cooling, the carrier film 1 is then removed from the
  • the release layer 2 can be dispensed with if the protective lacquer layer 4 is composed in such a way that it can be easily removed from the surface of the carrier film 1 accordingly.
  • the structure of the decorative layer 3 can differ from the exemplary embodiment in FIG. 1.
  • the colored lacquer layer 6 or the protective lacquer layer 4 can be dispensed with under certain circumstances. It is essential, however, that a correspondingly precisely printed decorative lacquer layer 5 is present.
  • the adhesive layer 7 can also under certain circumstances 10
  • the layers forming the decorative layer 3 can e.g. be composed as follows:
  • Methyl methacrylate copolymer (Tg 86 ° C) 60
  • Ketone-formaldehyde resin (Ext. Point: 85 ° C) 60
  • a laminating film is shown: i.e. a film which is transferred as a whole to the surface of a substrate and remains there as such without the carrier film being removed.
  • the carrier film 11 is applied with an adhesive layer 17 on its one side which, in use, touches the substrate surface on the other side of the carrier film 11 is the decorative layer 13, which - similar to the embodiment of FIG. 1 - also a transparent protective lacquer layer 14, a pattern, for example has a grain-forming decorative lacquer layer 15 and a continuous colored lacquer layer 16.
  • the layer thicknesses in the laminating film of FIG. 2 are as follows:
  • Decorative lacquer layer 15 0.1 to 2 ⁇ m
  • the carrier film 11 of the exemplary embodiment in FIG. 2 corresponds in terms of its composition to the carrier film 1 in FIG. 1.
  • lacquer or adhesive layers can expediently be composed as follows:
  • Polyethylene wax (FP 140 ° C, 20% in toluene) 100
  • Aromatic polyisocyanate (50% in ethyl acetate, NCO content 8%) 180 Decorative lacquer layer fMaserunql 15
  • Ketone-formaldehyde resin (Ext.: 115 ° C) 60
  • Ketone-formaldehyde resin (advanced point: 85 ° C) 80
  • Ethyl methacrylate copolymer (Tg 50 ° C) 80 highly disperse silica (particle size 10 ⁇ m) 5 high molecular weight dispersing additive
  • compositions of the different lacquer layers can be varied depending on the specific areas of use, it being possible in particular to dispense with individual layers.
  • the thickness of the layers depends on the respective field of application and must above all take into account the extent to which stretching of the film and thus parallel thinning of the layers upon penetration onto the three-dimensional surface of the substrate can be expected.

Landscapes

  • Laminated Bodies (AREA)
  • Decoration By Transfer Pictures (AREA)

Abstract

Il est proposé une feuille décorative permettant de décorer des surfaces de substrat tridimensionnelles, cette opération impliquant un chauffage. Cette feuille consiste en un support pelliculaire (film polyester ou polyamide sensiblement amorphe, non-étiré) sur lequel se trouve une couche décorative constituée au minimum par une couche de vernis surimprimée formant une décoration adaptée avec précision.
EP19960907272 1994-12-23 1996-03-18 Feuille decorative pour decorer des surfaces de substrat tridimensionnelles Expired - Lifetime EP0888224B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4446255A DE4446255C2 (de) 1994-12-23 1994-12-23 Dekorationsfolie zum Dekorieren von dreidimensionalen Substratoberflächen
PCT/DE1996/000516 WO1997034774A1 (fr) 1994-12-23 1996-03-18 Feuille decorative pour decorer des surfaces de substrat tridimensionnelles

Publications (2)

Publication Number Publication Date
EP0888224A1 true EP0888224A1 (fr) 1999-01-07
EP0888224B1 EP0888224B1 (fr) 2000-06-07

Family

ID=25943240

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19960907272 Expired - Lifetime EP0888224B1 (fr) 1994-12-23 1996-03-18 Feuille decorative pour decorer des surfaces de substrat tridimensionnelles

Country Status (8)

Country Link
US (1) US6387472B1 (fr)
EP (1) EP0888224B1 (fr)
JP (1) JPH08183143A (fr)
AU (1) AU713604B2 (fr)
BR (1) BR9612563A (fr)
DE (1) DE4446255C2 (fr)
ES (1) ES2148738T3 (fr)
WO (1) WO1997034774A1 (fr)

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FR2873622B1 (fr) * 2004-07-30 2007-02-16 Cera Procede de decoration d'une piece au moyen d'un transfert a chaud d'un motif a base d'encre
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EP1785268A1 (fr) * 2005-11-12 2007-05-16 Hueck Folien Ges.m.b.H Feuille décorative
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Also Published As

Publication number Publication date
DE4446255C2 (de) 1997-05-28
US6387472B1 (en) 2002-05-14
HK1016133A1 (en) 1999-10-29
AU5099296A (en) 1997-10-10
JPH08183143A (ja) 1996-07-16
ES2148738T3 (es) 2000-10-16
EP0888224B1 (fr) 2000-06-07
WO1997034774A1 (fr) 1997-09-25
BR9612563A (pt) 1999-07-20
DE4446255A1 (de) 1996-06-27
AU713604B2 (en) 1999-12-09

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Legal Events

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