EP0894873A1 - Acier pour paliers allié au vanadium - Google Patents
Acier pour paliers allié au vanadium Download PDFInfo
- Publication number
- EP0894873A1 EP0894873A1 EP98850125A EP98850125A EP0894873A1 EP 0894873 A1 EP0894873 A1 EP 0894873A1 EP 98850125 A EP98850125 A EP 98850125A EP 98850125 A EP98850125 A EP 98850125A EP 0894873 A1 EP0894873 A1 EP 0894873A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steel
- vanadium
- bearing steel
- weight
- carbon content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 30
- 239000010959 steel Substances 0.000 title claims abstract description 30
- 229910052720 vanadium Inorganic materials 0.000 title claims abstract description 11
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title claims abstract description 10
- 239000012535 impurity Substances 0.000 claims abstract description 7
- 238000005275 alloying Methods 0.000 claims abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 16
- 229910052799 carbon Inorganic materials 0.000 description 16
- 150000001247 metal acetylides Chemical class 0.000 description 7
- 238000007792 addition Methods 0.000 description 6
- 229910001566 austenite Inorganic materials 0.000 description 5
- 229910000734 martensite Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- ZLANVVMKMCTKMT-UHFFFAOYSA-N methanidylidynevanadium(1+) Chemical class [V+]#[C-] ZLANVVMKMCTKMT-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003681 vanadium Chemical class 0.000 description 1
- -1 vanadium forms carbides Chemical class 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
Definitions
- the present invention relates to an improved vanadium alloyed bearing steel.
- the hardness after martensitic hardening of a soft annealed bearing steel e.g. AISE 52100 is highly dependent on the carbon content in solid solution and thus the austenitisation conditions for a given quench.
- a higher austenitisation temperature or longer time leads to more dissolution of carbides.
- the optimum carbon content in solid solution to give the highest hardness is considered to be somewhere between 0.6 to 0.8 weight% for an oil quenched component.
- a lower carbon content will give a softer martensite.
- a higher carbon content will lead to an increased retained austenite content which would decrease the hardness and give a disadvantageous martensite morphology. Furthermore, a too large amount of retained austenite will give poor structural stability.
- Hardened bearing steels are often subjected to wear. To improve wear properties it is necessary to maximize the hardness. However, this could also be further improved by introducing a fraction of hard carbides such as VC.
- the toughness of a component made from a bearing steel is relatively low. This could result in catastrophically failure and it would therefore be appreciated to increase the toughness. This could be achieved by alloying with Ni which is an element that improves the toughness.
- Structural stability is important for critical applications and could be improved by Si alloying. Si retards the precipitation of carbide during tempering and thus improves the stability. This could also be beneficial for reducing tempering embrittlement since the precipitation of grain boundary carbides could be reduced.
- the object of the invention is to provide a steel designed to exhibit greater tolerances in austenitising temperature and time to give optimum carbon content.
- carbide formers preferably V and also Cr
- carbide formers preferably V and also Cr
- an optimal carbon content is obtained.
- a higher wear resistance is obtained because of the presence hard VC carbides.
- Improved toughness can be obtained by Ni addition and a high structural stability can be obtained with Si additions.
- the required hardenability is balanced by adding Cr, Mo and Mn.
- the steel has the following analysis, in weight-%: C 0.60 - 1.00 Si 0.40 - 2.10 Mn 0.10 - 1.00 Ni 0.50 - 2.00 Cr 0 - 2.00 Mo 0 - 0.50 V 0.25 - 1.00 Fe incl. possible impurities - ad. 100%.
- the steel has the following analysis, in weight-%: C 0.75 - 0.95 Si 0.80 - 1.80 Mn 0.10 - 1.00 Ni 0.50 - 1.50 Cr 0 - 2.00 Mo 0 - 0.50 V 0.40 - 0.80 Fe incl. possible impurities - ad. 100%.
- the steel should have sufficient vanadium content to form vanadium carbides which stops excessive carbon from going into solid solution at the austenitisation temperature range.
- the carbon content and vanadium content should be balanced so that the equilibrium carbon content is optimal at the chosen austenitisation temperature.
- Such a composition is shown in Table 1.
- Vanadium alloyed bearing steel according to the invention C Si Mn Cr Ni Mo V min 0.60 0 0 0 0 0.25 max 1.10 2.10 2.00 2.00 2.00 0.75 1.00
- a graph illustrating the mole percentage of phases in equilibrium versus temperature is shown for a steel according to Table 2.
- a carbide VC
- Fig. 2 the corresponding graph illustrates that steel B does not have this fraction of carbides.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Sliding-Contact Bearings (AREA)
- Rolling Contact Bearings (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9702851A SE9702851D0 (sv) | 1997-08-01 | 1997-08-01 | Vanadium alloyed bearing steel |
| SE9702851 | 1997-08-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0894873A1 true EP0894873A1 (fr) | 1999-02-03 |
Family
ID=20407866
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP98850125A Withdrawn EP0894873A1 (fr) | 1997-08-01 | 1998-07-30 | Acier pour paliers allié au vanadium |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0894873A1 (fr) |
| JP (1) | JPH11117040A (fr) |
| CN (1) | CN1211634A (fr) |
| SE (1) | SE9702851D0 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1035226A1 (fr) * | 1999-03-10 | 2000-09-13 | Ovako Steel AB | Acier pour paliers |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2647733B1 (fr) | 2010-11-29 | 2015-09-23 | JFE Steel Corporation | Acier à roulement présentant une excellente aptitude à l'usinage après un recuit de sphéroïdisation et une excellente résistance à la fatigue due à l'hydrogène après une trempe/un revenu |
| CN103189535B (zh) * | 2010-11-29 | 2016-07-06 | 杰富意钢铁株式会社 | 球化退火后的加工性优异且淬火回火后的耐氢疲劳特性优异的轴承钢 |
| CN102399533A (zh) * | 2011-09-26 | 2012-04-04 | 宁国市东方碾磨材料有限责任公司 | 耐磨耐腐蚀纳米研磨材料及其制备方法 |
| CN111926255A (zh) * | 2020-08-11 | 2020-11-13 | 江苏联峰实业有限公司 | 一种高碳铬轴承钢及其生产方法 |
| CN112011739B (zh) * | 2020-08-27 | 2021-08-06 | 江苏大学 | 一种高韧性铁合金及其制备方法和应用 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0458646A1 (fr) * | 1990-05-23 | 1991-11-27 | Aichi Steel Works, Ltd. | Acier pour paliers |
| JPH06287708A (ja) * | 1993-03-30 | 1994-10-11 | Kawasaki Steel Corp | 繰り返し応力負荷によるミクロ組織変化の遅延特性に優れた軸受鋼 |
| JPH07216508A (ja) * | 1994-02-04 | 1995-08-15 | Daido Steel Co Ltd | 軸受鋼 |
| JPH07238341A (ja) * | 1994-02-24 | 1995-09-12 | Daido Steel Co Ltd | 高面圧疲労強度に優れた高周波焼入用鋼 |
-
1997
- 1997-08-01 SE SE9702851A patent/SE9702851D0/xx unknown
-
1998
- 1998-07-24 JP JP22373398A patent/JPH11117040A/ja active Pending
- 1998-07-30 EP EP98850125A patent/EP0894873A1/fr not_active Withdrawn
- 1998-07-31 CN CN 98116776 patent/CN1211634A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0458646A1 (fr) * | 1990-05-23 | 1991-11-27 | Aichi Steel Works, Ltd. | Acier pour paliers |
| JPH06287708A (ja) * | 1993-03-30 | 1994-10-11 | Kawasaki Steel Corp | 繰り返し応力負荷によるミクロ組織変化の遅延特性に優れた軸受鋼 |
| JPH07216508A (ja) * | 1994-02-04 | 1995-08-15 | Daido Steel Co Ltd | 軸受鋼 |
| JPH07238341A (ja) * | 1994-02-24 | 1995-09-12 | Daido Steel Co Ltd | 高面圧疲労強度に優れた高周波焼入用鋼 |
Non-Patent Citations (4)
| Title |
|---|
| PATENT ABSTRACTS OF JAPAN vol. 095, no. 001 28 February 1995 (1995-02-28) * |
| PATENT ABSTRACTS OF JAPAN vol. 095, no. 011 26 December 1995 (1995-12-26) * |
| PATENT ABSTRACTS OF JAPAN vol. 096, no. 001 31 January 1996 (1996-01-31) * |
| WEGST C.W.: "Stahlschlüssel", 1986, VERLAG STAHLSCHLÜSSEL WEGST, MARBACH, GERMANY, XP002083413 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1035226A1 (fr) * | 1999-03-10 | 2000-09-13 | Ovako Steel AB | Acier pour paliers |
Also Published As
| Publication number | Publication date |
|---|---|
| SE9702851D0 (sv) | 1997-08-01 |
| JPH11117040A (ja) | 1999-04-27 |
| CN1211634A (zh) | 1999-03-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): DE ES FR GB IT |
|
| AX | Request for extension of the european patent |
Free format text: AL;LT;LV;MK;RO;SI |
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| 17P | Request for examination filed |
Effective date: 19990803 |
|
| AKX | Designation fees paid |
Free format text: DE ES FR GB IT |
|
| 17Q | First examination report despatched |
Effective date: 20011105 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
| 18W | Application withdrawn |
Withdrawal date: 20020304 |