EP0897973A1 - Agents de lavage et de nettoyage - Google Patents

Agents de lavage et de nettoyage Download PDF

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Publication number
EP0897973A1
EP0897973A1 EP98114591A EP98114591A EP0897973A1 EP 0897973 A1 EP0897973 A1 EP 0897973A1 EP 98114591 A EP98114591 A EP 98114591A EP 98114591 A EP98114591 A EP 98114591A EP 0897973 A1 EP0897973 A1 EP 0897973A1
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weight
alkyl
detergent
surfactants
contain
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EP98114591A
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German (de)
English (en)
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Werner Dr. Antwerpen
Ulrike Reploeg
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Clariant Produkte Deutschland GmbH
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Clariant GmbH
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/384—Animal products

Definitions

  • WO 94/09100 from Procter and Gamble describes the use of polyhydroxy fatty acid amides as a readily biodegradable nonionic surfactant with very good fat dispersibility and based on renewable raw materials in dishwashing detergents.
  • DE 44 30 085 from Henkel describes the use of fatty acid N-alkylpolyhydroxyalkylamides and alkyl and / or alkenyl (ether) phosphates in surface-active cleaning agents.
  • EP 0 569 376 describes a liquid detergent which contains alkyl polyglycoside and fatty alcohol sulfate.
  • sweet whey powder the main constituent of which is lactose monohydrate and the minor constituents of which are essentially minerals and proteins, in combination with all the usual surfactants and surfactant mixtures has excellent skin compatibility and very good emulsifying effects, which prevent deposits of oils and fats .
  • An improvement in the solubilizing capacity can also be achieved by adding sweet whey. Foaming is not impaired by the addition of whey, even when exposed to fat. A good drainage effect is significant, especially for glass and porcelain.
  • sweet whey powder into liquid all-purpose cleaners, an improvement of the whole, in particular of plastic surfaces and in mild detergents, a caring and softening effect, in particular for wool, was achieved.
  • the invention thus relates to detergents and cleaning agents with a Sweet whey content.
  • a sweet whey in powder form is used as sweet whey spray-dried ultrafiltration permeate powder.
  • Such a product contains 50 to 100, preferably 70 to 95, in particular 83 to 90% by weight of lactose monohydrate. Minor components are minerals (approx. 6 to 10% by weight), proteins (approx. 3 to 5 % By weight) and water (up to 3% by weight).
  • This sweet whey can be used in all common solid and liquid washing and Detergents can be incorporated by methods known per se.
  • the sweet whey is preferably used for the production of Hand dishwashing liquid, liquid all-purpose cleaner or liquid Delicates, as these formulations are excellent Skin compatibility of sweet whey is particularly important.
  • the detergents and cleaning agents according to the invention can contain the sweet whey in Amounts from 0.1 to 15, preferably from 2 to 7, in particular from 4 to 6% by weight contain.
  • these detergents and cleaning agents also contain those for these products common and typical ingredients such as surfactants and auxiliary and Additives.
  • the surfactants contained in the washing and cleaning agents according to the invention can be anionic, cationic, zwitterionic (amphoteric) or non-ionic Be nature.
  • Suitable anionic surfactants are alkyl sulfates, sulfonates, carboxylates, -phosphates and mixtures of the compounds mentioned. In the following should some of the types of anionic surfactants in question to be discribed.
  • Alkyl ester sulfonates are linear esters of C 8 -C 20 carboxylic acids (ie fatty acids) which are sulfonated by SO 3 , as described in "The Journal of the American Oil Chemists Society", 52 (1975), pp. 323-329. Suitable starting materials are natural fat derivatives, such as tallow or palm oil fatty acid.
  • Preferred alkyl ester sulfonates, especially for detergent applications are compounds of the formula wherein R 3 is a C 8 -C 20 hydrocarbon radical, preferably alkyl or a mixture of alkyl radicals, R 4 is a C 1 -C 6 hydrocarbon radical, preferably alkyl or a mixture of alkyl radicals.
  • M stands for a cation that forms a water-soluble salt with the alkyl ester sulfonate.
  • Suitable cations are metals such as sodium, hardly any, lithium or substituted or unsubstituted ammonium cations such as monoethanolamine, diethanolamine and triethanolamine.
  • R 3 is C 10 -C 16 alkyl and R 4 is methyl, ethyl or isopropyl.
  • Methyl ester sulfonates in which R 3 is C 10 -C 16 alkyl are particularly preferred.
  • Alkyl sulfates are water-soluble salts or acids of the formula ROSO 3 M, in which R is preferably a C 10 -C 24 hydrocarbon radical, preferably an alkyl or hydroxyalkyl radical having 10 to 20 C atoms, particularly preferably a C 12 -C 18 alkyl or Represents hydroxyalkyl.
  • R is preferably a C 10 -C 24 hydrocarbon radical, preferably an alkyl or hydroxyalkyl radical having 10 to 20 C atoms, particularly preferably a C 12 -C 18 alkyl or Represents hydroxyalkyl.
  • M is hydrogen or a cation, for example an alkali metal cation (for example sodium, potassium, lithium) or ammonium or substituted ammonium, for example a methyl, dimethyl and trimethylammonium cation or a quaternary ammonium cation such as tetramethylammonium and dimethylpiperidinium cation and quaternary ammonium cations derived from alkylamines such as ethylamine, diethylamine, triethylamine and mixtures thereof.
  • Alkyl chains with C 12 -C 16 are preferred for low washing temperatures (eg below approx. 50 ° C) and alkyl chains with C 16 -C 18 are preferred for higher washing temperatures (eg above approx. 50 ° C).
  • the alkyl ether sulfates are water-soluble salts or acids of the formula RO (A) SO 3 M, in which R is an unsubstituted C 10 -C 24 alkyl or hydroxyalkyl radical having 10 to 24 C atoms, preferably a C 12 -C 20 alkyl or Hydroxyalkyl radical, particularly preferably a C 12 -C 18 alkyl or hydroxyalkyl radical.
  • A is an ethoxy or propoxy unit
  • m is a number greater than 0, typically between approximately 0.5 and approximately 6, particularly preferably between approximately 0.5 and approximately 3
  • M is a hydrogen atom or a cation such as e.g. a metal cation (e.g.
  • substituted ammonium cations are methyl, dimethyl, trimethylammonium and quaternary ammonium cations such as tetramethylammonium and dimethylpiperidinium cations, as well as those derived from alkylamines such as ethylamine, diethylamine, triethylamine, mixtures thereof and the like.
  • Examples include C 12 -C 18 alkyl polyethoxylate (1.0) sulfate, (C 12 -C 18 E (1.0) M), C 12 -C 18 alkyl polyethoxylate (2.25 ) sulfate (C 12 -C 18 E (2.25) M), C 12 -C 18 alkyl polyethoxylate (3.0) sulfate, (C 12 -C 18 E (3.0) M), C 12 -C 18 alkyl polyethoxylate (4.0) sulfate, (C 12 -C 18 E (4.0) M), where M is sodium or potassium.
  • alkylbenzenesulfonate Another suitable anionic surfactant that can be used according to the invention is alkylbenzenesulfonate.
  • the alkyl group can be either saturated or unsaturated, branched or linear and optionally substituted with a hydroxyl group.
  • the preferred alkylbenzenesulfonates contain linear alkyl chains with 9 to 25 carbon atoms, preferably 10 to 13 carbon atoms, the cation is sodium, potassium, ammonium, mono-, di- or triethanolammonium, calcium or magnesium and mixtures thereof. Magnesium is preferred as the cation for mild surfactant systems, while sodium is preferred for standard washing applications.
  • the alkyl group can either be saturated or unsaturated, branched or linear and optionally with a hydroxyl group be substituted.
  • the sulfo group is statistically distributed over the entire C chain, with the primary methyl groups at the beginning and end of the chain none Wear sulfonate groups.
  • the preferred secondary alkanesulfonates contain linear alkyl chains with 9 to 25 carbon atoms, preferably from 10 to 20 Carbon atoms and particularly preferably 13 to 17 carbon atoms.
  • the Cation is sodium, hardly, ammonium, mono-, di- or triethanolammonium, Calcium or magnesium and mixtures thereof. Sodium as the cation is preferred.
  • carboxylates e.g. Fatty acid soaps and comparable surfactants.
  • the soaps can be saturated or unsaturated and can have various substituents, such as hydroxyl groups or alpha sulfonate groups contain.
  • Linear saturated or unsaturated are preferred Hydrocarbon residues as a hydrophobic component in the soaps.
  • contain the hydrophobic components 6 to 30 carbon atoms, preferably 10 up to 18 carbon atoms.
  • the cation (M) of the carboxylate surfactants can be a Alkali metal, e.g. Sodium or potassium, an alkaline earth metal, e.g. Calcium or Magnesium, ammonium or substituted ammonium including mono-, di- and Be triethanolammonium. Mixtures of the cations can be advantageous be.
  • anionic surfactants are the salts of acylaminocarboxylic acids, by the reaction of fatty acid chlorides with sodium sarcosinate in alkaline Medium arise (acyl sarcosinate) or fatty acid-protein condensation products which are obtained by reacting fatty acid chlorides with oligopeptides, as well as the salts of alkylsulfamidocarboxylic acids and the salts of alkyl and Alkylaryl ether carboxylic acids.
  • anionic surfactants for use in detergents and cleaning agents are C 8 -C 24 -olefin sulfonates, sulfonated polycarboxylic acids, prepared by sulfonating the pyrolysis products of alkaline earth metal citrates, as described, for example, in GB 1,082,179, alkyl glycerol sulfates, fatty acyl glycerol sulfates, oleyl glycerol sulfate sulfates, alkylphenol parolate, primary phenolate sulfates Alkyl ether phosphates, isethionates, such as acyl isethionates, N-acyl taurides, alkyl succinamates, sulfosuccinates, monoesters of sulfosuccinates (especially saturated and unsaturated C 12 -C 18 monoesters) and diesters of sulfosuccinates (especially saturated and uns
  • Resin acids or hydrogenated resin acids such as rosin or hydrogenated rosin or tall oil resins and tall oil resin acids can also be used. Further examples are described in "Surface Active Agents and Detergents” (Vol. I and II, Schwartz, Perry and Berch).
  • anionic surfactants are alkylbenzenesulfonates, Alkane sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, ⁇ -methyl ester sulfonates, Sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, Hydroxy mixed ether sulfates, fatty acid amide (ether) sulfates, mono- and Dialkyl sulfosuccinates, mono- and dialkyl sulfosuccinates, sulfotriglycerides, Amide soaps, alkyl oligoglucoside sulfates, alkyl amino sugar sulfates and alkyl (ether) phosphates. If the anionic surfactants contain polyglycol ether chains, they have a conventional or narrow homolog distribution.
  • the ratio of anionic surfactants to sweet whey powder can be between 99: 1 and 1:99 vary.
  • Typical examples of cationic surfactants in the context of the present invention are quaternary ammonium salts and ester quats, especially quaternized ones Fatty acid alkanolamine ester salts and trialkylaminopropylamine ester salts.
  • the quaternary ammonium salts are preferably those of the type RN (CH 3 ) 3 Cl and R 2 N (CH 3 ) 2 Cl with an alkyl radical R whose chain length is between 8 and 24 C atoms, preferably between 10 and 18 C. -Atoms lies.
  • amphoteric surfactants which are suitable for the formulations of the present invention are, above all, those which can be described very generally as derivatives of aliphatic secondary and tertiary amines in which the aliphatic radical can be linear or branched and one of the aliphatic substituents contains between 8 and 18 carbon atoms and which contain an anionic, water-soluble group such as carboxy, sulfonate, sulfate, phosphate or phosphonate.
  • Amphoteric surfactants are, for example, imidazolium surfactants of the following formula: wherein R 1 is a C 8 -C 22 alkyl or alkenyl radical, preferably C 12 -C 16 , R 2 is hydrogen or CH 2 CO 2 M, R 3 is CH 2 CH 2 OH or CH 2 CH 2 OCH 2 CHCOOM, R 4 is hydrogen, CH 2 CH 2 OH or CH 2 CH 2 OCH 2 CHCOOM, Z is CO 2 M or CH 2 CO 2 M, n is 2 or 3, preferably 2, M is hydrogen or a cation such as alkali metal , Alkaline earth metal, ammonia or alkanolammonium.
  • R 1 is a C 8 -C 22 alkyl or alkenyl radical, preferably C 12 -C 16
  • R 2 is hydrogen or CH 2 CO 2 M
  • R 3 is CH 2 CH 2 OH or CH 2 CH 2 OCH 2 CHCOOM
  • R 4 is hydrogen, CH 2 CH 2 OH or CH 2 CH 2 OCH
  • Preferred amphoteric surfactants of the above formula are monocarboxylates and Dicarboxylates. Examples of these compounds are cocoamphocarboxypropionate, Cocoamidocarboxypropionic acid, Cocoamphocarboxyglycinat (or also as Cocoamphodiacetate) and Cocoamphoacetat.
  • amphoteric surfactants are alkyldimethylbetaines, Alkyl amido betaines and alkyl dipolyethoxy betaines with an alkyl radical having 8 to 22, preferably with 8 to 18 carbon atoms. These connections are e.g. of the Hoechst AG is marketed under the trade name ®Genagen CAB.
  • Suitable nonionic surfactants are described in US 3,929,678. A Selection is given below.
  • Polyethylene, polypropylene and polybutylene oxide adducts of alkylphenols are preferred here.
  • This Compounds include the condensation products of alkylphenols with one Alkyl group of 6 to 12 carbon atoms, which are either linear or branched can, with alkene oxides. These compounds preferably contain ethylene oxide in a ratio of about 5 to about 25 moles per mole of alkylphenol.
  • Commercially Available surfactants of this type are e.g. Igepal TM CO-630 (GAF Corporation), Triton TM X-45, X-114, X-100 and X102 (Rohm and Haas) and the Arkopal TM N brands (Clariant GmbH). These surfactants are called alkylphenol alkoxylates, e.g. Alkylphenol ethoxylates.
  • the alkyl chain of the aliphatic alcohols can be linear or branched, primary or be secondary, and generally contains from 8 to 22 carbon atoms.
  • the condensation products of alcohols are particularly preferred Contain alkyl chain of 10 to 20 carbons, with 2 to 18 mol ethylene oxide per moles of alcohol.
  • the alkyl chain can be saturated or unsaturated.
  • the alcohol ethoxylates can have a narrow homolog distribution of the ethylene oxide ("Narrow Range Ethoxilates") or a broad homolog distribution of the Have ethylene oxides ("Broad Range Ethoxylates").
  • nonionic surfactants of this type are Teritol TM 15-S-9 (Condensation product of a C11-C15 linear secondary alcohol with 9 mol Ethylene oxide), Tergitol TM 24-L-NMW (condensation product of a C12-C14 linear primary alcohol with 6 mol ethylene oxide with a narrow molecular weight distribution).
  • Teritol TM 15-S-9 Condensation product of a C11-C15 linear secondary alcohol with 9 mol Ethylene oxide
  • Tergitol TM 24-L-NMW condensation product of a C12-C14 linear primary alcohol with 6 mol ethylene oxide with a narrow molecular weight distribution.
  • Genapol TM brands from Clariant GmbH fall under this product class.
  • the hydrophobic part of these compounds preferably has a molecular weight between about 1500 and 1800 and is water-insoluble.
  • the attachment of Polyoxyethylene units on this hydrophobic part leads to an improvement the water solubility of the entire molecule.
  • the product is liquid up to one Polyoxyethylene content of approx. 50% of the total weight of the Condensation product, which is a condensation with up to about 40 mol of ethylene oxide corresponds.
  • Commercially available examples of this product class are the Pluronic TM brands from BASF and Genapol TM PF brands from Clariant GmbH.
  • the hydrophobic unit of these compounds consists of the reaction product of ethylenediamine and excess propylene oxide and generally has Molecular weight from about 2500 to 3000. This hydrophobic unit is ready condensed with ethylene oxide until the condensation product is approximately 40% by weight to approximately Contains 80 wt .-% polyoxyethylene and a molecular weight of about 5000 to 11000 having.
  • Commercially available examples of this class of compounds are Tetronic TM brands from BASF and the Genapol TM PN brands from Clariant GmbH.
  • This special category of nonionic compounds includes water-soluble amine oxides, phosphine oxides and sulfoxides which contain an alkyl radical with 10 to 18 carbon atoms and one or two alkyl groups or hydroxyalkyl groups with 1 to 3 carbon atoms.
  • This type of surfactant also includes amine oxides of the formula one in which R 3 represents an alkyl, hydroxyalkyl or alkylphenol group or mixtures thereof with a chain length of 8 to 22 carbon atoms, R is an alkylene or hydroxyalkylene group with 2 to 3 carbon atoms or mixtures thereof, each radical R 5 is an alkyl or hydroxyalkyl group having 1 to 3 carbon atoms or a polyethylene oxide group having 1 to 3 ethylene oxide units.
  • the R 5 groups can be connected to one another via an oxygen or nitrogen atom and thus form a ring.
  • Amine oxides of this type are especially C 10 -C 18 alkyl dimethyl amine oxides and C 8 -C 12 alkoxyethyl dihydroxyethyl amine oxides.
  • Fatty acid amides have the formula R 6 -CON (R 7 ) 2 wherein R 6 is an alkyl group with 7 to 21, preferably with 9 to 17 carbon atoms and each radical R is hydrogen, C 1 -C 4 alkyl, C 1 -C 4 hydroxyalkyl and (C 2 H 4 O) x H, where x varies from 1 to 3.
  • R 6 is an alkyl group with 7 to 21, preferably with 9 to 17 carbon atoms and each radical R is hydrogen, C 1 -C 4 alkyl, C 1 -C 4 hydroxyalkyl and (C 2 H 4 O) x H, where x varies from 1 to 3.
  • C 8 -C 20 amides, monoethanolamides, diethanolamides and isopropanolamides are preferred.
  • nonionic surfactants are Fatty acid polyglycol ester, fatty acid amide polyglycol ether, fatty amine polyglycol ether, alkoxylated triglycerides, mixed ethers or mixed formals, alk (en) yl oligoglycosides, Fatty acid N-alkylglucamides and protein hydrolyzates (especially vegetable Soy-based products).
  • the weight ratio between non-ionic surfactants and sweet whey can fluctuate within very wide limits.
  • Suitable nonionic surfactants are very generally described in US 3,929,678 described. A selection is given below.
  • polyethylene oxide condensates are preferred here.
  • This Compounds include the condensation products of alkylphenols with one Alkyl group of 6 to 12 carbon atoms, which are either linear or branched can, with alkene oxides. These compounds preferably contain ethylene oxide in a ratio of about 5 to about 25 moles per mole of alkylphenol.
  • Commercially Available surfactants of this type are e.g. Igepal TM CO-630, Triton TM X-45, X-114, X-100 and X-102.
  • the formulations according to the invention contain in addition to the surfactants mentioned, the specific auxiliaries and Additives, for example builders, foam inhibitors, salts, bleaches, Bleach activators, optical brighteners, graying inhibitors, solubilizers, Enzymes, thickeners, preservatives, fragrances and dyes, Pearlescent agents, emulsifiers, superfatting agents, biogenic agents (Plant extracts and vitamin complexes), sequestering agents.
  • the specific auxiliaries and Additives for example builders, foam inhibitors, salts, bleaches, Bleach activators, optical brighteners, graying inhibitors, solubilizers, Enzymes, thickeners, preservatives, fragrances and dyes, Pearlescent agents, emulsifiers, superfatting agents, biogenic agents (Plant extracts and vitamin complexes), sequestering agents.
  • Suitable organic and inorganic builders are neutral or, in particular, alkaline salts which can precipitate or bind calcium ions in a complex manner.
  • Suitable and in particular ecologically harmless builder substances are finely crystalline, synthetic water-containing zeolites of the NaA type, which have a calcium binding capacity in the range from 100 to 200 mg CaO / g.
  • Layered silicates are preferably used in non-aqueous systems. Zeolites and layered silicates can be contained in an amount of up to 20% by weight.
  • Usable organic builders are, for example, the percarboxylic acids preferably used in the form of their sodium salts, such as citric acid, nitriloacetate (NTA), ethylenediaminetetraacetic acid.
  • polymeric carboxylates and their salts can also be used. These include, for example, the salts of homopolymeric or copolymeric polyacrylates, polymethacrylates and in particular copolymers of acrylic acid with maleic acid, preferably those made from 50% to 10% maleic acid and also polyvinylpyrrolidone and urethanes.
  • the relative molecular weight of the homopolymers is generally between 1000 and 100,000, that of the copolymers between 2000 and 200,000, preferably 50,000 to 120,000, based on the free acid.
  • Water-soluble polyacrylates which are crosslinked, for example, with about 1% of a sugar polyallyl ether and which have a relative molecular weight above one million are also particularly suitable.
  • the crosslinked polyacrylates are used in amounts of not more than 1% by weight, preferably in amounts of 0.2 to 0.7% by weight.
  • These framework substances can be used in amounts of up to 5% by weight.
  • the agents according to the invention can be used as foam inhibitors Fatty acid alkyl ester alkoxylates, organopolysiloxanes and their mixtures with microfine, optionally silanized silica as well as paraffins, waxes, Microcrystalline waxes and their mixtures with silanated silica.
  • foam inhibitors Fatty acid alkyl ester alkoxylates, organopolysiloxanes and their mixtures with microfine, optionally silanized silica as well as paraffins, waxes, Microcrystalline waxes and their mixtures with silanated silica.
  • foam inhibitors can also be used advantageously, e.g. those made of silicone oil, paraffin oil or waxes.
  • Liquid detergents can be optical brighteners, for example derivatives of Contain diaminostilbenedisulfonic acid or its alkali metal salts, which are good in let the dispersion work in.
  • the maximum amount of brighteners in the Agents according to the invention is 0.5 wt .-%, preferably amounts of 0.02 to 0.25 wt .-% used.
  • the desired viscosity of the agents can be adjusted by adding water and / or organic solvents or by adding a combination of organic solvents and thickeners.
  • organic solvents all monohydric or polyhydric alcohols are suitable as organic solvents.
  • Alcohols with 1 to 4 carbon atoms such as methanol, ethanol, propanol, isopropanol, straight-chain and branched butanol, glycerol and mixtures of the alcohols mentioned are preferably used.
  • Further preferred alcohols are polyethylene glycols with a relative molecular weight below 2000.
  • polyethylene glycol with a relative molecular weight between 200 and 600 and in amounts up to 45% by weight and of polyethylene glycol with a relative molecular weight between 400 and 600 in amounts of 5 to 25% by weight is preferred.
  • An advantageous mixture of solvents consists of monomeric alcohol, for example ethanol and polyethylene glycol in a ratio of 0.5: 1 to 1.2: 1, it being possible for liquid detergents according to the invention to contain 8 to 12% by weight of such a mixture.
  • suitable solvents are, for example, triacetin (glycerol triacetate) and 1-methoxy-2-propanol.
  • Preferred thickeners are hardened castor oil, salts of long-chain fatty acids, preferably in amounts of 0 to 5% by weight and in particular in amounts of 0.5 to 2% by weight, for example sodium, potassium, aluminum, magnesium - And titanium stearates or the sodium and / or potassium salts of behenic acid, and polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, as well as higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates , Polyvinyl alcohol and polyvinyl pyrrolidone and electrolytes such as table salt and ammonium chloride are used.
  • Proteases, lipases, amylases or mixtures thereof come in as enzymes Question. Their proportion can be 0.2 to 1% by weight.
  • the enzymes can Carrier substances are adsorbed and / or embedded in coating substances.
  • HEDP 1-hydroxyethane-1,1-diphosphonic acid
  • DTPMP Diethylenetriaminepentamethylenephosphonic acid
  • Suitable preservatives are, for example, phenoxyethanol, Formaldehyde solution, parabens, pentadiol or sorbic acid.
  • pearlescent agents examples include glycol distearic acid esters such as Ethylene glycol distearate, but also fatty acid monoglycol esters into consideration.
  • Suitable salts or adjusting agents are, for example, sodium sulfate, sodium carbonate or sodium silicate (water glass).
  • Typical individual examples for further additives are sodium borate, starch, sucrose, polydextrose, TAED, stilbene compounds, methyl cellulose, toluenesulfonate, cumene sulfonate, soaps and silicones.
  • sweet whey powder according to the invention in detergents and cleaning agents, in particular in household cleaning agents, such as hand dishwashing detergents, liquid all-purpose cleaners and mild detergents, particularly skin-friendly, environmentally friendly and powerful cleaning agents can be produced on the basis of a natural product.
  • household cleaning agents such as hand dishwashing detergents, liquid all-purpose cleaners and mild detergents, particularly skin-friendly, environmentally friendly and powerful cleaning agents can be produced on the basis of a natural product.
  • a Genapol DU 80 6.00% by weight Fatty acid mixture (Prifac 7949: palm kernel oil / oleic acid) 5.00% by weight Potassium hydroxide (w 85%) 0.80% by weight Triethanolamine 0.69% by weight B E-water (approx. 50 ° C) C. Hostapur SAS 60 5.10% by weight tri sodium citrate 2 hydrate 5.00% by weight D Ethanol 2.00% by weight Citric acid 1 hydrate 0.20% by weight Serusweet 83 6.00% by weight E Acticide SPX- (L) 0.20% by weight

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
EP98114591A 1997-08-18 1998-08-04 Agents de lavage et de nettoyage Withdrawn EP0897973A1 (fr)

Applications Claiming Priority (2)

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DE19735763 1997-08-18
DE1997135763 DE19735763A1 (de) 1997-08-18 1997-08-18 Wasch- und Reinigungsmittel

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Cited By (6)

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RU2158290C1 (ru) * 1999-05-25 2000-10-27 Кравцов Евгений Евгеньевич Моющий ингибированный раствор для очистки металлических поверхностей
WO2001055290A1 (fr) * 2000-01-27 2001-08-02 Henkel Kommanditgesellschaft Auf Aktien Combinaison d'agents tensioactifs
DE102005042603A1 (de) * 2005-09-07 2007-03-08 Henkel Kgaa Hautpflegendes Handgeschirrspülmittel
WO2007057080A1 (fr) * 2005-11-18 2007-05-24 Henkel Ag & Co. Kgaa Agent de traitement pour textile contenant un produit laitier
RU2308480C1 (ru) * 2006-05-23 2007-10-20 Татьяна Николаевна Крутикова Моющее средство
EP2770043A1 (fr) * 2013-02-21 2014-08-27 Lina Line ® E.U. Détergent

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Publication number Priority date Publication date Assignee Title
WO2016097178A1 (fr) 2014-12-19 2016-06-23 Clariant International Ltd Compositions adjuvantes aqueuses contenant un électrolyte, compositions contenant une substance active et utilisation desdites compositions

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2158290C1 (ru) * 1999-05-25 2000-10-27 Кравцов Евгений Евгеньевич Моющий ингибированный раствор для очистки металлических поверхностей
WO2001055290A1 (fr) * 2000-01-27 2001-08-02 Henkel Kommanditgesellschaft Auf Aktien Combinaison d'agents tensioactifs
EP1564283A3 (fr) * 2000-01-27 2006-06-07 Henkel Kommanditgesellschaft auf Aktien combinaison de tensio-actifs
DE102005042603A1 (de) * 2005-09-07 2007-03-08 Henkel Kgaa Hautpflegendes Handgeschirrspülmittel
WO2007057080A1 (fr) * 2005-11-18 2007-05-24 Henkel Ag & Co. Kgaa Agent de traitement pour textile contenant un produit laitier
RU2308480C1 (ru) * 2006-05-23 2007-10-20 Татьяна Николаевна Крутикова Моющее средство
EP2770043A1 (fr) * 2013-02-21 2014-08-27 Lina Line ® E.U. Détergent

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