EP0920357A1 - Dekorationsverfahren - Google Patents
DekorationsverfahrenInfo
- Publication number
- EP0920357A1 EP0920357A1 EP98930881A EP98930881A EP0920357A1 EP 0920357 A1 EP0920357 A1 EP 0920357A1 EP 98930881 A EP98930881 A EP 98930881A EP 98930881 A EP98930881 A EP 98930881A EP 0920357 A1 EP0920357 A1 EP 0920357A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mixture
- coating material
- article
- period
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 37
- 238000005034 decoration Methods 0.000 title claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 27
- 239000004922 lacquer Substances 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims description 31
- 239000011248 coating agent Substances 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 26
- 239000000976 ink Substances 0.000 claims description 15
- 230000002045 lasting effect Effects 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 4
- 238000001723 curing Methods 0.000 claims description 4
- 238000007590 electrostatic spraying Methods 0.000 claims description 4
- 238000013007 heat curing Methods 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- 239000004924 water-based lacquer Substances 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 239000012190 activator Substances 0.000 claims description 2
- 235000013399 edible fruits Nutrition 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
- B05D5/061—Special surface effect
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F1/00—Designs or pictures characterised by special or unusual light effects
- B44F1/08—Designs or pictures characterised by special or unusual light effects characterised by colour effects
- B44F1/10—Changing, amusing, or secret pictures
Definitions
- This invention concerns a decoration method and particularly but not exclusively a decoration method usable on products such as items of tableware.
- Thermochromic inks are materials which at a specified temperature change colour, or become transparent or at least translucent.
- thermochromic ink with a first coating material
- applying the mixture onto part or all of a surface of the article once the mixture is set applying a second coating material onto said surface of the article.
- the second coating material is preferably transparent.
- the second coating material is desirably substantially dishwasher proof.
- the first coating material is preferably transparent.
- the first and/or second coating materials preferably comprise lacquers.
- the first coating material preferably comprises an organic water based lacquer, though the lacquer could be acrylic based.
- the second coating material preferably comprises a two-part epoxy fortified acrylic resin, including an activator and a thinner.
- the proportion of ink in the mixture is preferably within the range 5-
- the mixture and/or second coating material are preferably cured following application onto the article.
- the curing preferably commences with a period in an infra red shortwave drier followed by a heat cure.
- the heat cure preferably comprises a lower temperature first period, followed by a higher temperature second period.
- the first period preferably lasts between one and two minutes at 35°C to 65°C, with the second period lasting eight to twelve minutes at 140 to 220°C.
- the first period preferably lasts between eight and twelve minutes at 35 to 65°C, with the second period lasting twenty five to thirty minutes at 110 to 165°C.
- a decoration may be provided on the article beneath the mixture such that when the thermochromic ink is at least translucent, said decoration is visible.
- the mixture may comprise a plurality of thermochromic inks with different colour change temperatures, and the inks may be of different colours.
- the mixture and/or second coating material may be applied to the article by spraying, and desirable electrostatic spraying.
- an electrostatic thinner may be added to the mixture and/or second coating prior to spraying.
- the mixture and/or the second coating material are preferably sprayed to a thickness of between 12 and 24 microns.
- thermochromic outer layer is then applied as follows.
- a dark blue thermochromic ink is mixed with an organic water-based lacquer with 5 to 25% of the ink, dependent on the strength of colour required.
- An electrostatic thinner is added to the mixture which is then applied by electrostatic spraying using an RD-3000 Turbodisc system. The mixture is sprayed to provide a 20 micron layer.
- This layer is then cured by an initial pass through an infra red shortwave drier and then a subsequent pass through a gas convection drier or driers with an initial first stage of one to two minutes at 35 to 65°C, and a second stage lasting eight to twelve minutes at 140 to 220°C.
- a transparent outer coating is then applied to the teapot as follows.
- a two-part epoxy fortified acrylic resin is mixed together and applied by electrostatic spraying in a similar manner to the first layer outlined above.
- This second layer is then cured again with a first pass through a shortwave infra red drier and then subsequent passes through a gas convection drier initially for eight to twelve minutes at 35 to 65°C, and then twenty five to thirty minutes at 110 to 165°C.
- the finished product has a durable glossy finish which is substantially dishwasher proof.
- the teapot is dark blue.
- the thermochromic ink changes to a substantially transparent state such that the fruit pattern beneath the thermochromic coating can be clearly seen.
- the dark blue colouring will return to again obscure the fruit pattern.
- decorations can be provided using a method according to the present invention, to provide for example decorations which appear or disappear at below or above room temperature. These decorations can selectively obscure decorations, messages etc. therebeneath. It is possible for a plurality of different inks with different colour change temperatures and perhaps also different colours to be mixed, such that a decoration can pass from one colour perhaps to reveal a pattern or decoration therebeneath, and subsequently to move to a further colour as the temperature rises or falls. A wide range of colours can be used as is available.
- the coatings could be applied by different techniques and perhaps only to cover part of the surface of an article to provide particular effects. Different spraying and/or curing conditions can be used etc., as are appropriate to particular materials used.
- the technique whilst ideally suited to decorating tableware, can be used on a wide range of articles.
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
- Electromechanical Clocks (AREA)
- Toys (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Steering Controls (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9712825 | 1997-06-19 | ||
| GB9712825A GB2325182B (en) | 1997-06-19 | 1997-06-19 | Decoration method |
| PCT/GB1998/001778 WO1998057760A1 (en) | 1997-06-19 | 1998-06-17 | Decoration method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0920357A1 true EP0920357A1 (de) | 1999-06-09 |
| EP0920357B1 EP0920357B1 (de) | 2003-01-02 |
Family
ID=10814494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP98930881A Expired - Lifetime EP0920357B1 (de) | 1997-06-19 | 1998-06-17 | Dekorationsverfahren |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0920357B1 (de) |
| AT (1) | ATE230309T1 (de) |
| DE (1) | DE69810430T2 (de) |
| ES (1) | ES2189192T3 (de) |
| GB (1) | GB2325182B (de) |
| PT (1) | PT920357E (de) |
| WO (1) | WO1998057760A1 (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2325182B (en) | 1997-06-19 | 1999-03-31 | Promotion Consultancy Limited | Decoration method |
| US6281165B1 (en) | 1999-01-29 | 2001-08-28 | World Wide Art Studios | Therochromatic ink covered article having image disposed thereon and method of making the same |
| GB0226916D0 (en) * | 2002-11-19 | 2002-12-24 | Walker Timothy | Improved coating process |
| GB2419306B (en) * | 2004-10-22 | 2006-12-13 | Ram Sharma | Decorating ceramic articles |
| GB0425068D0 (en) * | 2004-11-12 | 2004-12-15 | Listawood Holdings Ltd | A method of decorating a substrate |
| US8092866B2 (en) | 2005-03-22 | 2012-01-10 | World Wide Lines, Inc. | Thermochromatic pigment covered article and method of making the same |
| GB0601779D0 (en) * | 2006-01-28 | 2006-03-08 | Wilkinson Alan R | Thermochromic Indicator |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4425161A (en) | 1980-11-27 | 1984-01-10 | Yutaka Shibahashi | Thermochromic materials |
| US4917643A (en) | 1987-06-26 | 1990-04-17 | Mattel, Inc. | Toy vehicle with thermochromic material |
| US5219625A (en) | 1991-07-09 | 1993-06-15 | The Pilot Ink Co., Ltd. | Thermochromic laminate member and toy utilizing the same |
| US5588747A (en) | 1994-06-01 | 1996-12-31 | Blevins; Terry D. | Measuring cup with externally-mounted liquid crystal thermometer |
| GB2325182B (en) | 1997-06-19 | 1999-03-31 | Promotion Consultancy Limited | Decoration method |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1217233A (en) * | 1967-01-12 | 1970-12-31 | Arne Bybjerg Pedersen | Heatable hair rollers |
| US4156365A (en) * | 1976-08-02 | 1979-05-29 | Ferdinand Heinmets | Temperature indicator |
| JPH072398B2 (ja) * | 1988-05-07 | 1995-01-18 | 川崎製鉄株式会社 | 熱変色ステンレス鋼板 |
| JPH0376783A (ja) * | 1989-08-21 | 1991-04-02 | Matsui Shikiso Kagaku Kogyosho:Kk | 多色顕現感温変色性組成物 |
| DE3927753A1 (de) * | 1989-08-23 | 1991-02-28 | Ralf Jeising | Warneinrichtungen vor glatteisgefahr oder vor verbruehungsgefahr |
| US5352649A (en) * | 1991-07-04 | 1994-10-04 | The Pilot Ink Co., Ltd. | Thermochromic laminate member, and composition and sheet for producing the same |
| US5215491A (en) * | 1992-02-07 | 1993-06-01 | Mattel, Inc. | Water actuated toy kitchen set |
| JP2957042B2 (ja) * | 1992-02-29 | 1999-10-04 | 鐘紡株式会社 | 装飾石鹸およびその製法 |
| JPH0680912A (ja) * | 1992-09-04 | 1994-03-22 | Nissan Motor Co Ltd | 自動車用塗料組成物およびそれを塗布してなる塗装物 |
| JP3134108B2 (ja) * | 1992-10-26 | 2001-02-13 | パイロットインキ株式会社 | 熱変色性遮光性組成物及びこれを用いた積層体及び前記積層体を用いた内部隠顕立体物 |
| FR2698321B1 (fr) * | 1992-11-25 | 1995-01-13 | Ebauchesfabrik Eta Ag | Objet en matière plastique dont au moins une partie de la surface extérieure est décorée. |
| GB2274428B (en) * | 1993-01-20 | 1996-08-21 | Portals | Security threads |
| JP3306607B2 (ja) * | 1994-03-25 | 2002-07-24 | パイロットインキ株式会社 | 熱変色性遮光−透光性組成物及びこれを用いた積層体及び前記積層体を用いた内部隠顕立体物 |
| GB2312955A (en) * | 1996-05-08 | 1997-11-12 | Willett Int Ltd | Monitoring temperatures of surfaces of heat exchangers |
| US5618581A (en) * | 1996-07-01 | 1997-04-08 | Calladium Corporation | Method for making thermochromic writing instruments having a reptilian texture |
| WO1998007345A1 (en) * | 1996-08-16 | 1998-02-26 | Monty Lawrence P | Thermochromic handheld hair curling iron |
-
1997
- 1997-06-19 GB GB9712825A patent/GB2325182B/en not_active Expired - Lifetime
-
1998
- 1998-06-17 WO PCT/GB1998/001778 patent/WO1998057760A1/en not_active Ceased
- 1998-06-17 AT AT98930881T patent/ATE230309T1/de not_active IP Right Cessation
- 1998-06-17 EP EP98930881A patent/EP0920357B1/de not_active Expired - Lifetime
- 1998-06-17 ES ES98930881T patent/ES2189192T3/es not_active Expired - Lifetime
- 1998-06-17 DE DE69810430T patent/DE69810430T2/de not_active Expired - Lifetime
- 1998-06-17 PT PT98930881T patent/PT920357E/pt unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4425161A (en) | 1980-11-27 | 1984-01-10 | Yutaka Shibahashi | Thermochromic materials |
| US4917643A (en) | 1987-06-26 | 1990-04-17 | Mattel, Inc. | Toy vehicle with thermochromic material |
| US5219625A (en) | 1991-07-09 | 1993-06-15 | The Pilot Ink Co., Ltd. | Thermochromic laminate member and toy utilizing the same |
| US5588747A (en) | 1994-06-01 | 1996-12-31 | Blevins; Terry D. | Measuring cup with externally-mounted liquid crystal thermometer |
| GB2325182B (en) | 1997-06-19 | 1999-03-31 | Promotion Consultancy Limited | Decoration method |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE230309T1 (de) | 2003-01-15 |
| WO1998057760A1 (en) | 1998-12-23 |
| GB2325182A (en) | 1998-11-18 |
| ES2189192T3 (es) | 2003-07-01 |
| GB9712825D0 (en) | 1997-08-20 |
| GB2325182B (en) | 1999-03-31 |
| DE69810430T2 (de) | 2003-09-25 |
| EP0920357B1 (de) | 2003-01-02 |
| PT920357E (pt) | 2003-03-31 |
| DE69810430D1 (de) | 2003-02-06 |
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