EP1009052A4 - Polymer-elektrolyt-brennstoffzelle und verfahren zu dessen herstellung - Google Patents
Polymer-elektrolyt-brennstoffzelle und verfahren zu dessen herstellungInfo
- Publication number
- EP1009052A4 EP1009052A4 EP99922549A EP99922549A EP1009052A4 EP 1009052 A4 EP1009052 A4 EP 1009052A4 EP 99922549 A EP99922549 A EP 99922549A EP 99922549 A EP99922549 A EP 99922549A EP 1009052 A4 EP1009052 A4 EP 1009052A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- electrodes
- polymer electrolyte
- fuel cell
- sealant
- electrolyte fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0213—Gas-impermeable carbon-containing materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0221—Organic resins; Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0223—Composites
- H01M8/0228—Composites in the form of layered or coated products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0258—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
- H01M8/0263—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant having meandering or serpentine paths
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0267—Collectors; Separators, e.g. bipolar separators; Interconnectors having heating or cooling means, e.g. heaters or coolant flow channels
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0223—Composites
- H01M8/0226—Composites in the form of mixtures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04029—Heat exchange using liquids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04067—Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
- H01M8/04074—Heat exchange unit structures specially adapted for fuel cell
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
- H01M8/04119—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15247098A JP3640333B2 (ja) | 1998-06-02 | 1998-06-02 | 高分子電解質型燃料電池 |
| JP15247098 | 1998-06-02 | ||
| JP23474898 | 1998-08-20 | ||
| JP23474898A JP4321887B2 (ja) | 1998-08-20 | 1998-08-20 | 固体高分子型燃料電池およびその製造法 |
| PCT/JP1999/002832 WO1999063610A1 (en) | 1998-06-02 | 1999-05-27 | Polymer electrolyte fuel cell and method of manufacture thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP1009052A1 EP1009052A1 (de) | 2000-06-14 |
| EP1009052A4 true EP1009052A4 (de) | 2005-05-11 |
| EP1009052B1 EP1009052B1 (de) | 2012-02-15 |
Family
ID=26481381
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP99922549A Expired - Lifetime EP1009052B1 (de) | 1998-06-02 | 1999-05-27 | Polymer-elektrolyt-brennstoffzelle und verfahren zu dessen herstellung |
Country Status (4)
| Country | Link |
|---|---|
| US (3) | US6531236B1 (de) |
| EP (1) | EP1009052B1 (de) |
| KR (1) | KR100372926B1 (de) |
| WO (1) | WO1999063610A1 (de) |
Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU5247100A (en) * | 1999-07-13 | 2001-01-30 | Nok Corporation | Gasket for fuel cell and method of forming it |
| CN1183619C (zh) * | 1999-10-21 | 2005-01-05 | 松下电器产业株式会社 | 高分子电解质型燃料电池 |
| US20040072055A1 (en) * | 2000-04-14 | 2004-04-15 | Getz Matthew George | Graphite article useful as a fuel cell component substrate |
| JP3542550B2 (ja) * | 2000-07-19 | 2004-07-14 | 本田技研工業株式会社 | 燃料電池用シールの成形方法 |
| EP1312126A2 (de) * | 2000-08-23 | 2003-05-21 | Dana Corporation | Isolierungs- und abdichtungszusammensetzung geeignet für brennstoffzellenanordnung |
| US6824874B1 (en) | 2000-08-23 | 2004-11-30 | Dana Corporation | Insulator and seal for fuel cell assemblies |
| WO2002017422A2 (en) * | 2000-08-23 | 2002-02-28 | Dana Corporation | Epoxy nitrile insulator and seal for fuel cell assemblies |
| US7220786B1 (en) | 2000-08-23 | 2007-05-22 | Dana Corporation | Ultraviolet radiation curable coating for MLS head gasket applications |
| JP3683799B2 (ja) * | 2000-10-24 | 2005-08-17 | 本田技研工業株式会社 | 固体高分子電解質膜 |
| JP2002164062A (ja) * | 2000-11-28 | 2002-06-07 | Araco Corp | 燃料電池用セパレータおよびその製造方法 |
| EP1349224A4 (de) * | 2000-12-05 | 2007-05-16 | Matsushita Electric Industrial Co Ltd | Brennstoffzelle des polyelektrolyttyps und betriebsverfahren dafür |
| DE10060839A1 (de) * | 2000-12-07 | 2002-06-13 | Sgl Carbon Ag | Imprägnierter Körper aus expandiertem Graphit |
| CN1288782C (zh) * | 2001-02-15 | 2006-12-06 | 松下电器产业株式会社 | 高分子电解质型燃料电池 |
| US6605380B2 (en) * | 2001-02-27 | 2003-08-12 | Dana Corporation | Fuel cell plate with variable thickness sealing beads |
| US6599653B1 (en) | 2001-05-15 | 2003-07-29 | Dana Corporation | Molded fuel cell plates with seals |
| US20040258977A1 (en) * | 2003-01-24 | 2004-12-23 | Hydrogenics Corporation | Apparatus for and method of forming seals in fuel cells and fuel cell stacks |
| US6852439B2 (en) | 2001-05-15 | 2005-02-08 | Hydrogenics Corporation | Apparatus for and method of forming seals in fuel cells and fuel cell stacks |
| US6803142B2 (en) * | 2001-06-06 | 2004-10-12 | Toyota Jidosha Kabushiki Kaisha | Fuel cell |
| JP4259041B2 (ja) * | 2001-06-14 | 2009-04-30 | トヨタ自動車株式会社 | 燃料電池 |
| JP4383008B2 (ja) * | 2001-07-06 | 2009-12-16 | 本田技研工業株式会社 | 燃料電池用セパレータ及び膜・電極接合体の積層方法及び同積層装置 |
| US6869717B2 (en) * | 2001-07-09 | 2005-03-22 | Hydrogenics Corporation | Manifold for a fuel cell system |
| US7306864B2 (en) * | 2001-10-22 | 2007-12-11 | Protonex Technology Corporation | One-shot fabrication of membrane-based electrochemical cell stacks |
| DE10203612C1 (de) * | 2002-01-23 | 2003-06-26 | Reinz Dichtungs Gmbh & Co Kg | Brennstoffzellenpaket sowie dafür geeignete bipolare Platte |
| EP1335441A3 (de) * | 2002-02-08 | 2007-08-08 | Behr GmbH & Co. KG | Brennstoffzelle |
| US7196120B2 (en) | 2002-08-29 | 2007-03-27 | Dana Corporation | Ultraviolet radiation curable coating for MLS head gasket applications |
| KR20040098530A (ko) * | 2003-05-13 | 2004-11-20 | 마쯔시다덴기산교 가부시키가이샤 | 연료전지 및 그 분해방법 |
| US7655339B1 (en) | 2003-06-06 | 2010-02-02 | Dana Automotive Systems Group, Llc | Molded fuel cell plates with seals |
| JP2005044688A (ja) * | 2003-07-24 | 2005-02-17 | Honda Motor Co Ltd | 燃料電池スタック |
| CA2477358C (en) * | 2003-08-22 | 2012-03-27 | Matsushita Electric Industrial Co., Ltd. | Polymer electrolyte fuel cell |
| WO2005028712A1 (en) | 2003-09-22 | 2005-03-31 | Hydrogenics Corporation | Electrolyzer cell stack system |
| US20050183948A1 (en) | 2003-09-22 | 2005-08-25 | Ali Rusta-Sallehy | Apparatus and method for reducing instances of pump de-priming |
| JP2005223122A (ja) * | 2004-02-05 | 2005-08-18 | Matsushita Electric Ind Co Ltd | チップ型アルミ電解コンデンサ及びその製造方法 |
| US7727658B2 (en) * | 2004-03-17 | 2010-06-01 | Honda Motor Co., Ltd. | Method for joining laser transmitting resin member and porous member, method for joining thermoplastic resin, and fuel cell |
| KR100599715B1 (ko) * | 2004-06-23 | 2006-07-12 | 삼성에스디아이 주식회사 | 연료전지 시스템, 스택, 및 세퍼레이터 |
| US7318973B2 (en) | 2004-08-12 | 2008-01-15 | General Motors Corporation | Stamped bridges and plates for reactant delivery for a fuel cell |
| JP2006085926A (ja) * | 2004-09-14 | 2006-03-30 | Nissan Motor Co Ltd | 燃料電池 |
| JP4771271B2 (ja) * | 2004-09-24 | 2011-09-14 | トヨタ自動車株式会社 | 単電池、単電池の製造方法、燃料電池、燃料電池の製造方法 |
| JP2006156099A (ja) * | 2004-11-29 | 2006-06-15 | Mitsubishi Electric Corp | 加湿器およびその製造方法 |
| HUP0500170A3 (en) * | 2005-02-03 | 2007-11-28 | Richter Gedeon Nyrt | Piperazine derivatives, process for producing them and pharmaceutical compositions containing them |
| US20070212587A1 (en) * | 2005-04-01 | 2007-09-13 | Nick Fragiadakis | Apparatus for and method of forming seals in an electrochemical cell assembly |
| FR2887688B1 (fr) * | 2005-06-28 | 2007-09-14 | Peugeot Citroen Automobiles Sa | Plaque bipolaire pour pile a combustible comprenant des nervures d'etancheite |
| FR2887692A1 (fr) * | 2005-07-11 | 2006-12-29 | Peugeot Citroen Automobiles Sa | Cellule elementaire de pile a combustible a canaux reactionnels juxtaposes |
| US7807312B2 (en) * | 2006-01-12 | 2010-10-05 | Ultracell Corporation | Portable electrical energy generation equipment |
| BRPI0706615A2 (pt) * | 2006-01-17 | 2011-04-05 | Henkel Corp | célula de combustìvel, e, método para formar a mesma |
| KR101482799B1 (ko) * | 2006-01-17 | 2015-01-14 | 헨켈 유에스 아이피 엘엘씨 | 실란트 통합 연료 전지 성분 및 이를 제조하기 위한 방법 및 시스템 |
| US20070207364A1 (en) * | 2006-03-03 | 2007-09-06 | Abd Elhamid Mahmoud H | Fuel cells comprising moldable gaskets, and methods of making |
| JP2008066087A (ja) * | 2006-09-06 | 2008-03-21 | Toyota Motor Corp | 燃料電池システム |
| JP2008159447A (ja) * | 2006-12-25 | 2008-07-10 | Shinko Electric Ind Co Ltd | 固体酸化物型燃料電池発電装置 |
| WO2008129779A1 (ja) * | 2007-04-13 | 2008-10-30 | Panasonic Corporation | 燃料電池セルと燃料電池および燃料電池セルの製造方法 |
| KR100830980B1 (ko) * | 2007-05-28 | 2008-05-20 | 삼성에스디아이 주식회사 | 연료 전지용 스택 |
| JP5133616B2 (ja) * | 2007-06-28 | 2013-01-30 | 本田技研工業株式会社 | 燃料電池 |
| RU2387053C1 (ru) * | 2008-12-23 | 2010-04-20 | Яков Аронович Гофман | Способ изготовления батареи топливных элементов с твердым полимерным электролитом |
| JP2011076721A (ja) * | 2009-09-29 | 2011-04-14 | Toyota Motor Corp | 燃料電池 |
| US9735438B2 (en) | 2011-01-13 | 2017-08-15 | Dana Canada Corporation | Humidifier for fuel cell systems |
| FR3031788B1 (fr) * | 2015-01-16 | 2017-12-01 | Areva Stockage D'energie | Procede de fabrication de joints sur des composants de reacteur electrochimique et plaque de moulage correspondante |
| US20180108902A1 (en) * | 2016-10-17 | 2018-04-19 | The Paper Battery Company, Inc. | Filling and sealing energy storage structures, and fabrication tools therefor |
| JP6608798B2 (ja) * | 2016-10-27 | 2019-11-20 | トヨタ自動車株式会社 | 燃料電池スタック |
| JP6790968B2 (ja) * | 2017-03-31 | 2020-11-25 | トヨタ紡織株式会社 | 燃料電池スタックのエンドプレート及び燃料電池スタックのシール構造 |
| JP6763337B2 (ja) * | 2017-04-24 | 2020-09-30 | トヨタ紡織株式会社 | 燃料電池スタックのエンドプレート |
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|---|---|---|---|---|
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| JP3682786B2 (ja) | 1995-07-17 | 2005-08-10 | 株式会社カネカ | 電解コンデンサ封口体 |
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- 1999-05-27 KR KR10-2000-7000934A patent/KR100372926B1/ko not_active Expired - Fee Related
- 1999-05-27 EP EP99922549A patent/EP1009052B1/de not_active Expired - Lifetime
- 1999-05-27 WO PCT/JP1999/002832 patent/WO1999063610A1/ja not_active Ceased
-
2000
- 2000-02-02 US US09/497,058 patent/US6531236B1/en not_active Expired - Lifetime
-
2002
- 2002-12-27 US US10/330,886 patent/US6869719B2/en not_active Expired - Lifetime
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2004
- 2004-08-03 US US10/910,044 patent/US20050003260A1/en not_active Abandoned
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| JPS60257069A (ja) * | 1984-06-01 | 1985-12-18 | Fuji Elelctrochem Co Ltd | 薄形電池 |
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Also Published As
| Publication number | Publication date |
|---|---|
| US6531236B1 (en) | 2003-03-11 |
| KR100372926B1 (ko) | 2003-02-25 |
| KR20010022355A (ko) | 2001-03-15 |
| EP1009052B1 (de) | 2012-02-15 |
| US6869719B2 (en) | 2005-03-22 |
| WO1999063610A1 (en) | 1999-12-09 |
| EP1009052A1 (de) | 2000-06-14 |
| US20030134173A1 (en) | 2003-07-17 |
| US20050003260A1 (en) | 2005-01-06 |
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